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By Robert L. Cheek, Sid McIlveen

Sodium sulfate is an important industrial chemical. As recently as ten years ago it was produced and consumed in the United States in quantities exceeding 1 Mtpy. Since then, both its production and use have declined; however, approximately half the production still comes from natural sources. [Fig. 1] illustrates the history of production of natural sodium sulfate in the United States. Production of natural sodium sulfate from various types of deposits is the main source of this chemical in Canada and Mexico, and probably in Argentina, Chile, Iran, Spain, and the Russian Republics. MINERALOGY AND PHYSICAL PROPERTIES Sodium sulfate is widespread in occurrence and is a common constituent of many mineral waters, as well as seawater. Atmospheric precipitation contains sulfate; it is one of the major dissolved constituents of rain and snow (Davis and Dewiest, 1966). Many of the saline lakes throughout the world contain varying amounts of sodium sulfate. Because sodium is usually the dominant cation, some workers make an anionic distinction, referring to lakes containing predominantly sulfate as bitter lakes and those containing predominantly carbonate as alkali or soda lakes (Bateman, 1950). Sodium sulfate in its natural form is found in two principal minerals, mirabilite and thenardite. Mirabilite, the hydrous form, is commonly called Glauber's salt. It was discovered by the German chemist, J.R. Glauber (1603-1668), who derived its name from the Latin, sal mirabile, meaning wonderful salt. Thenardite, the anhydrous variety, was named for the French chemist, Louis Jacques Thenard (1777-1857) of the University of Paris (Mitchell, 1979). The largest quantities occur in the form of mirabilite. Sodium sulfate is found in varying degrees of purity, from theoretically pure efflorescent crystals of mirabilite to combinations and admixtures of other salts and impurities. It is a common constituent of some brines; from this source much is extracted commercially. Sodium sulfate also is found in compounds, such as the minerals glauberite, the double salt of anhydrous sodium and calcium sulfate, bloedite, the hydrous double-salt of sodium sulfate and magnesium sulfate, and burkeite, the anhydrous double-salt of sodium carbonate and sodium sulfate. Over 40 minerals contain sodium sulfate in varying proportions; many are of special interest because of their frequent occurrence. Table 1 lists some sodium-sulfate bearing minerals. The reader is referred to other publications (Cole, 1926, Dana, 1932, Grabau, 1920, and Dietrich, 1969) for descriptions of these minerals. Only mirabilite and thenardite will be described herein. Mirabilite Na$04.10H20, contains 55.9% water of crystallization. It is noted for its efflorescence or spontaneous loss of water. On dehydration it changes to the anhydrous form, Na2S0,. Mirabilite is an opaque to colorless, water-soluble mineral that tastes first cool, then slightly bitter. It has a specific gravity of 1.48. It frequently forms as efflorescent, needlelike monoclinic crystals, but generally is found in the massive form. Thenardite, the anhydrous mineral, Na2S04, contains 43.68% Na20 and 56.32% SO3. It ranges from colorless to white and may be tinted shades of gray or brown. It is a water soluble mineral with a slightly salty taste. Its specific gravity (2.67) and hardness (2.5 to 3) exceed those of mirabilite. It commonly occurs in the massive form without visible crystals. Its crystals are frequently tabular pyramids of the orthorhombic system. Sodium sulfate also occurs as a heptahydrate, containing seven molecules of water, but this is unstable and has not been found in the natural environment. The solubility of sodium sulfate has an important effect on the crystallization of the salt in nature, as well as in its production. Its solubility in water generally increases as a nonlinear function of temperature. Below 1.2°C, ice and mirabilite form. As the temperature is increased above O°C, increasing amounts of sodium sulfate become soluble. At 32.4°C, a transition point on the solubility curve is reached, as the decahydrate melts in its own water of crystallization and the anhydrous form crystallizes. With in- creasing temperatures, solubility decreases somewhat. The presence of other dissolved salts changes the transition temperature and solubility characteristics of sodium sulfate.

Jan 1, 1994

By L. C. E. FEIO, R. RAMSDEN

In many parts of the world deep level mining relies heavily on the use of refrigeration for providing safe thermal underground conditions. The trend in South Africa in recent years has been to locate the refrigeration plants on surface and to use these plants to chill water that is then distributed throughout the mine. The surface cooling installation normally consists of a pre-cooling tower in which water is first chilled before it is sent to one or more refrigeration plants for further cooling. Presently, the majority of these refrigeration plants use CFC refrigerants; however, to conform with the Montreal Protocol, these plants will have to be replaced or converted for use with alternative refrigerants. The optimum design criteria for installations using the new generation of refrigerants will be affected by their characteristics and are likely to be different from those currently in use. In light of these developments the industry is examining a number of alternative systems for future installations including water vapour refrigeration. Factors that affect the decision on the type of refrigeration system to be used in mine installations are reviewed. INTRODUCTION Gold mining has been carried out in South Africa for over 100 years and most of the reserves close to surface have been mined out; this has led to mining taking place at greater depths, approaching 4000 m below surface. One of the consequences of operating at these greater depths is that it is necessary to install refrigeration plants to cool the ventilation air so as to provide safe and healthy working conditions. With the current low precious metal prices there is pressure on mines to cut costs and in recent years there has been considerable effort devoted to the design of more cost effective and efficient refrigeration plants and cooling systems. In the last 10 years there have been many studies into the use of ice for specific applications (Eschenburg et al., 1986; Hemp, 1988 and Ramsden and Lloyd, 1992) and at present there are three ice making plants in operation on South African mines, each of which produces ice in different processes. In addition, detailed design studies have been carried out on the "split ammonia system" (Napier and Patterson, 1992). In this refrigeration system the evaporator is located underground close to where the cooling is needed, whilst the condenser and heat rejection system is on surface. As far as refrigeration plants are concerned the trend has been to move away from standard package units to custom built refrigeration installations. This has given the design engineer greater flexibility in the choice of key components for refrigeration installations. For example both screw and centrifugal compressors are used, the heat exchangers for the evaporators and condensers may be either plate or shell and tube, and in a number of installations evaporative condensers are used. In addition, the following refrigerants are in use, R12, R22 and ammonia. The acceptance of the Montreal Protocol and its amendments by the South African government will restrict the use of CFC refrigerants and it will be necessary to re-evaluate various refrigeration systems, including those that do not use conventional refrigerants, such as air cycle and water vapour systems, for new surface installations. Although new systems and refrigerants are being developed, only the following refrigeration installations will be compared in this paper: - a refrigeration system using R134a which has properties similar to R12 - refrigeration system using R22 or a new alternative refrigerant with very similar properties - an ammonia refrigeration system - a water vapour refrigeration system The benefits of new cooling systems are not discussed in detail, since they are largely mine specific and outside the scope of the present paper. Since the optimum design for an air cycle system (del Castillo, 1988) is dependent on the mine layout, this system is also not included.

Jan 1, 1993

By Thomas W. Healy, David V. Boger, Yee-Kwong Leong, Lee R. White, Peter J. Scales

The concentration of mineral slurries by conventional thickening devices is discussed. The role of additives on the compression of mineral slurries is also examined. Results for a range of flocculation conditions are presented. The compression of flocculated mineral slurries is found to be highly dependent on the fundamental particle-particle interaction forces and hence, the rheology of the particulate fluid. It is demonstrated that a detailed knowledge of the properties of both the mode of operation of the thickening device and of the solid/liquid interface is required for improvement in the rate and in particular, the extent of dewatering.

Jan 1, 1995

By Robert L. Bonomi

One of the major operating costs for any labor-intensive operation is that of its employees' wage and benefits package. Today's packages are extremely complex, with multiple pay rates for different grades and shifts, intricate bonus criteria, and expansive benefit packages that include all sorts of medical, dental, pension and other costs that can be "hidden" from direct examination and consideration. The problems of estimating the total cost of such a package to a company becomes even more acute at negotiation time, when pressure from both sides to settle intensify and changes to package offers come rapidly. A comprehensive system is needed that can evaluate these costs and perform sensitivity analyses, on the various components of an agreement so as to aid in the solving of major labor deadlocks, productivity problems, and cost impacts created by those agreements.

Jan 1, 1982

By Jeffrey C. Reid

Computer processing and high resolution graphics display of geochemical data were used to quickly, accurately, and efficiently obtain impor¬tant decision-making information for tin (cassiterite) exploration, Seward Peninsula, Alaska (USA). Primary geochemical dispersion patterns were determined for tin-bearing intrusive granite phases of Late Cretaceous age with exploration bedrock lithogeochemistry at the Kougarok tin prospect. Expensive diamond drilling footage was required to reach exploration objectives. Recogni¬tion of element distribution and dispersion patterns was useful in subsurface interpretation and correla¬tion, and to aid location of other holes. Tin was its own best pathfinder. Arsenic, also a useful pathfinder element, forms a discrete halo peripheral to tin mineralization. The arsenic halo is expressed in hand specimens by asenopyrite and/or scorodite staining.

Jan 1, 1989

By S. D. Thompson

Several discrete-event simulation models have been developed for designing the conveying system capacities of underground coal mines. Most of these models require the use of a step function approach to mimic the loading process at each conveyor loading point. Over the years, practitioners have generally employed one of three versions of the step function approach. An important issue is how these three versions compare to each other in terms of simulated capacity requirements for belt conveyors. Another issue is how they compare to the peak capacity design. This paper addresses these issues by statistically and quantitatively comparing their simulation results. The consequences and problems associated with using each version are also discussed and summarized.

Jan 1, 1998

By V. Ciribeni, R. J. Ferretti, C. de Arrieta, E. E. Rossi

The relationship between collector concentration and the solution pH at which flotation occurs is discussed for different minerals. When flotation results are plotted as log of the concentration against pH, the values define areas of total, partial or no flotation. The experiments were performed in three different conditions: a) floating with the same solution used for conditioning; b) floating with water at the same pH as the conditioning solution; and c) floating with water at pH = 7. In each case, the results obtained are quite different. It is suggested that the presence of a second layer of collector reduces flotation over some domains in the graphs. These domains are called depression areas.

Jan 1, 1992

By Robert C. Dunne, Maurice E. Freeman, Denis S. Yan

A laboratory tower mill was used to investigate the effect of some variables on the power requirements of a plant mill. The grinding laws were tested for fine grinding and Charles' law and Rittinger's law found to be most closely satisfy the experimental data. The effects of ball size, ball charge mass and media type were investigated. The screw speed was altered to control the power input as required. The results indicate that changes in these variables will change the grinding kinetics but in terms of the grinding efficiency they have no effect on the size-energy relationship. The main factor in the specific energy efficiency is the transfer of the input energy to the charge by variation of the agitation mechanism. The efficiency of a tumbling ball mill and a pin stirred mill were tested for comparison.

Jan 1, 1995

By S. D. Thompson

Several discrete-event simulation models have been developed for designing the conveying system capacities of underground coal mines. Most of these models require the use of a step function approach to mimic the loading process at each conveyor loading point. Over the years, practitioners have generally employed one of three versions of the step function approach. An important issue is how these three versions compare to each; other in terms of simulated capacity requirements for belt conveyors. Another issue is how they compare to the peak capacity design. This paper addresses these issues by statistically and quantitatively comparing their simulation results. The consequences and problems associated with using each version are also discussed and summarized.

Jan 1, 1997

By D. Bahrami, G. Danko

Spatial and temporal temperature and humidity variations for 5000 years are simulated in an emplacement airway within the conceptual, high-level nuclear waste repository proposed to be built at Yucca Mountain, Nevada. A multi-scale model is configured using MULTIFLUX, a thermohydrologic-ventilation code. The predicted surface temperature of most waste packages during post-closure exceed 140oC, the threshold limit known for likely localized corrosion for Alloy 22 waste package material. Small amounts of infiltration airflow through the mountain in Panel 5 are found to transport liquid water condensate to some of the waste packages emplaced along the peripheral section of the drift due to edge cooling.

Jan 1, 2004

By M. Niinae, Y. Nakahiro, T. Wakamatsu

In some cases, the extraction and separation efficiency of metals with a combined extractant are better than those with either extractant alone. However, the extraction and separation efficiency of metals with a combined extractant are not always better than those with either extractant alone. As part of the fundamental studies on the extraction and separation of metals with combined extractants, the extraction and separation efficiency of Au and Fe(III) added as an oxidizer in the leaching of Au from a sulphuric acid solution containing thiourea, and the extraction and separation efficiency of Nd and Sm from hydrochloric acid and sulphuric acid solutions were examined. The combined extractants for Au and Fe(III) were di(2-ethylhexyl) phosphosphoric acid (D2EHPA)/tri-n-butyl phosphate (TBP), D2EHPA/trioctyl phosphine oxide (TOPO). tri-n-octylamine (TOA)/TBP and TOA/TOPO, and those for Nd and Sm were D2EHPA/TOA. D2EHPA/TOPO. 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (EHPNA)/TOA and EHPNA/TOPO

Jan 1, 1994

By Y. M. Jiang, D. W. Park, S. M. Lee

A vast majority of longwall operations in the US use shield-type hydraulic supports to provide ground control along the longwall face. The three-dimensional, finite-element technique combined with a progressive failure approach was utilized to simulate interaction between shields and surrounding strata and determine various loading conditions. In addition, a separate finite-element model of the shield structure was made to study responses of each longwall shield to the different loading conditions. Shield responses under various loading conditions and the shield characteristics, such as shield stiffness, the ability of resisting horizontal forces, and the effect of shield height, were studied based on the results from finite-element analyses. The results can provide the basis of effective shield design and be used for evaluation of the shield performance. It is suggested that a technique incorporating the finite-element method be developed to evaluate real-time shield performance for the purpose of effective ground control.

Jan 1, 1993

By J. Y. Hwang, M. L. Jeong, R. C. Greenlund

Various aluminum-smelting by-products from three production sources were received and characterized. The waste materials were tested for compound identification and environmental acceptance. A coarse metallic aluminum recovery test using an Eddy Current separator (ECS) was performed using two different Circuit configurations. White dross performed equally well with either Circuit, while black dross processing shows significant difference on the separation results. It was found that ECS technology was effective for particle sizes down to 6-10 mesh.

Jan 1, 2001

By A. D. Davis, C. J. Webb

Brohm Mining Co.'s Gilt Edge Mine in the northern Black Hills was a surface heap-leach operation that was active from the 1980s until 1999. Financing problems and acid drainage concerns at the mine were reported in the late 1990s. In February 1999 the Governor of South Dakota announced plans to request the US Environmental Protection Agency to help clean up acidic water at the mine and reclaim the site. In July 1999 the parent company of Brohm, Dakota Mining, filed for bankruptcy in Canada. Because of the bankruptcy and environmental problems, the State of South Dakota intervened and began water treatment. The mine was declared a Superfund site in 2000. Hydrologic issues include the potential for acidic drainage from the site. The mine is at the headwaters of Strawberry Creek, which drains into Bear Butte Creek. About four miles downstream, Bear Butte Creek loses its discharge to swallow holes in the karstic Madison Limestone aquifer, a regionally extensive and valuable groundwater reservoir. Other concerns at the site include treatment of acidic water in mine pits and a waste rock dump.

Jan 1, 2003

By Simona Markic

With the aim of environment protection the program package HOMOGEN is used for realizing the planning and noxious components control in the coal produced. Using the program package PRIPREMA the division in levels and transformation (Hermite polynoms) in the N (0,1) distribution are made. By separated kriging 50 m x 50 m blocks are estimated on the levels and detailed distributions of the estimated component content are obtained. The face - longwall face is built in the blocks estimated in this way, and the direction of mining is determined. Using the stochastic simulation the distribution of the estimated production component (e.g. sulfur) on the face is obtained. Simulating the production of all faces in operation the distribution of the estimated daily mine production component is obtained. The estimated depot component is obtained in the same way. This procedure is used in the short-term planning of the estimated component movement for a given period in advance, and also in the daily production control in the case of changing conditions, e.g. the increased atmospheric pressure. The technology is successfully applied to the Velenje Lignite Mine Slovenia.

Jan 1, 1992

By Estban M. Domic

The modem copper industry presents an excellent opportunity for the application of clean, environmentally friendly techniques using currently available hydrometallurgical technologies. This paper briefly reviews key events in the development of modern hydrometallurgy in Chile. Discussion is given to those prominent events whose impact continues to be felt on most projects currently underway. Mention is also made of the foundations of heap leaching technologies, preceded by agglomeration and acid curing, known as the T.L. Leaching Process, the cornerstone of more recent developments. A review is also presented of the leading copper hydrometallurgy projects of the 1990s. A list of those projects, their tonnages and the estimated date of implementation is provided. The conclusion provides an overview of developments in research and the trends in the implementation of copper hydrometallurgy projects in Chile for the coming years.

Jan 1, 1998

By K. A. Natarajan, J. M. Modak, P. Anand

A microbial survey of Jamnagar bauxite mines in Gujarat, India, revealed the indigenous presence of a variety of autotrophic and heterotrophic bacteria and fungi associated with the ore body and water ponds in the vicinity. Among these, bacteria belonging to the genera Thiobacillus, Bacillus and Pseudomonas are implicated in the weathering of aluminosilicates; the precipitation of iron oxyhydroxides; the dissolution and conversion of alkaline metal species; and the formation of alumina, silica and calcite minerals. Fungi belonging to the genus Cladosporium can reduce ferric iron and dissolve alumina silicates. Biogenesis thus plays a significant role in bauxite mineralization. Various types of bacteria and fungi, such as Bacillus polymyxa, Bacillus coagulans and Aspergillus niger, were found to be efficient in significant calcium solubilization and partial iron removal from bauxite ore. Probable mechanisms in the biobeneficiation process are analyzed. Biobeneficiation is shown to be an effective technique for the removal of iron and calcium from bauxite ores for use in refractories and ceramics.

Jan 1, 1998

By Richard Jr. Ray, Richard Druesedow

The Virginia Operations of Consolidation Coal Co. include a diversity of mine fan configurations which have been tested to quantify pressure losses through the inlet ductwork. Airflow and pressure measurements were taken at four shaft sites to calculate losses for the 90-degree bend at the top of the shaft and the self-closing dampers or closing doors located between the shaft and fan. Velocity contours were then developed from the test data to determine flow patterns in each fan system component. In addition, yaw and pitch angles of airflow through the fan annulus were measured to evaluate turbulence levels created by various inlet ductwork designs. The test results indicate that proper design of the shaft collar and ductwork arrangement for main mine fans can substantially reduce system pressure losses and air turbulence. BY minimizing the pressure drop experienced on the surface, these design improvements enable the bulk of the total pressure developed by the fan(s) to be utilized in the mine.

Jan 1, 1995

One of the major objectives of cost analysis is to enable the manager to predict the financial outcomes of decisions. To accomplish this, the future costs and benefits of alternative courses of action must be determined. If care- fully used, information about past financial performance can be helpful in this analysis despite the fact that, by definition, financial reporting information is historical. In many cases, both revenues and costs need to be estimated for decision- making. For the production manager, additional revenue is a result of increased throughput or recovery of valuable material from the stream of mined material. A reduction in operating cost, although similar to a revenue increase in its financial impact, is estimated using slightly different techniques. Generally, the estimation of cost is more difficult than the estimation of revenue. Most cost estimates have two components: an estimate of fixed costs and an estimate of variable costs. As discussed in chapter 5, the total cost of an activity during a specified period can be expressed as: Total cost = (Variable cost per unit of activity) x (Units of activity) + Fixed cost or TC = VX+F

Jan 1, 1999

By T. T. Chen, J. L. Jambor, J. E. Dutrizac

A reconnaissance study of the neutralization potential of 30 diverse minerals, 28 of which are silicates and aluminosilicates, has shown that most of these minerals contribute minimally to the neutralization potential (NP) in standard static tests. Feldspars in particular give low NP values and would not be expected to attenuate the acidity to any significant extent in acid rock drainage settings. The BET-determined surface areas of the minerals vary considerably, and the large surface areas of some of the pulverized samples have clearly affected the NP values even though the standard static-test protocol was used for the preparation of the samples. The low NP values of most silicates and aluminosilicates are in general agreement with the laboratory-determined slow dissolution rates for these minerals. The results suggest that, in the prediction of whether rocks will be acid-producing, the most realistic measure is that of the carbonate content. In mine wastes from metalliferous ore deposits, the contribution to the NP by the non-carbonate gangue assemblage is unlikely to be more than a token amount until well after the establishment of an acid rock drainage situation.

Jan 1, 2000