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By B. C. Cornilsen, X. Shan, D. H. Carlson, J. H. Johnson

Airborne respirable Diesel Particulate (DP) presents an additional health hazard in that it has been shown to be mutagenic. This problem is of increasing concern as more coal mines introduce diesel vehicles. If the DP present in coal mine air is to be controlled it must first be measured. This paper describes development of the laser Raman spectroscopic measurement of the amount of DP in DP/coal mixtures collected on filters in the laboratory and in coal mines. The Raman technique provides a chemical measure of the carbonaceous material in each component, and is not dependent upon particle size. When this work was begun there were no known analytical methods for this measurement. Side-by-side in-mine comparisons of the results obtained from Raman, neutron activation analysis, and size selective analyses (MOUDI and personal samplers) are presented. The neutron activation and size selective analyses were obtained by the USBM Twin Cities Research Center and University of Minnesota. Good agreement has been found among these three methods.

Jan 1, 1991

By Gemei Yang, Yihui Zhao

In caved goaf, the friction loss of fluid head is: [h = (R'+ R/Q/ )] Q (for one-dimensional transition flow). The R' and R, which are the functions of two dimensional spaces, are calculated through an empirical formula. Then, the bulking factor and permeability are determined. It is supposed that the airflow in porous media are similar to those in tiny tubes crossing each other. Therefore, the network calculation technique can be used to tackle the field transition flow problem. A lot of case studies showed that the emission of methane in mines mainly depends on the air velocity and has little relation to air pressure. Summing up our experience and experiments, we provide an empirical formula to calculate the gas emission rate per unit area. By means of mass conservation and network calculation, the methane content distribution in steady-state is worked out. Then the dynamic change in airflows and gas content can be analyzed by the characteristic-difference method.

Jan 1, 1987

By Michael P. Foose

In 1994, more than 41 of the approximately 160 coal-fired, electrical- power plants within the six-state Ohio River Valley region used flue-gas desulfurization (FGD) units to desulfurize their emissions, an approximately 100% increase over the number of plants using FGD units in 1989. This increase represents a trend that may continue with greater efforts to meet Federal Clean Air Act standards. Abundant limestone resources exist in the Ohio River Valley and are accessed by approximately 975 quarries. However, only 35 of these are believed to have supplied limestone for FGD electrical generating facilities. The locations of these limestone suppliers do not show a simple spatial correlation with FGD facilities, and the closest quarries are not being used in most cases. Thus, reduction in transportation costs may be possible in some cases. Most waste generated by FGD electrical-generating plants is not recycled. However, many FGD sites are relatively close to gypsum wallboard producers that may be able to process some of their waste.

Jan 1, 1999

By Gary A. Almeraris, Thomas F. Peyton

This paper chronicles the mining of a main interceptor sewer through a residential neighborhood for the MWRA's Boston Harbor clean-up. The Wellesley Extension Sewer Tunnel consisted of 490 m (1600 ft) of rock tunnel, 107 m (35V ft) of mixed face and 336 m (1100 ft) of softground. The tunnel was located 4.6 m (15 ft) below water table and passed directly beneath six buildings with as little as 7 m (23 ft) of cover. In addition, the tunnel ran parallel to and within 4.6 m (15 ft) of an existing sewer tunnel with flows up to 187,5 million liters (50 million gal.) per day. The rock encountered by the tunnel was comprised of gramodiorite, amphibilite and diabase. The soils which passed through the tunnel face consisted of tills, sands and non-cohesive plastic silts. The techniques developed and the equipment utilized to successfully mine this complicated ground are described.

Jan 1, 1991

By Fathi Habashi

SELENIUM AND tellurium are by-products of electrolytic copper refining. Copper anodes contain 0.01-0.2 % Se and up to 0.04 % Te; during electrolysis these deposit as a slime at the bottom of the cell. Such slimes contain 2-15% Se and 0.5-8 % Te, as selenides and tellurides of gold, silver, and copper. The following compounds have been identified in the slimes: (Ag, Au)Te2, Ag2Se, Ag2Te, CuAgSe, Cu2Se, Cu2Te. Anodic slimes from copper electro¬lytic refining are a grayish black powder, minus 200 mesh. When this complex mixture is decomposed in an acid medium, elemental selenium and tellurium can be obtained, while in an alkaline medium, both metals go into solution. Acid leaching The slime is charged in acid digesters of 800-900 lb capacity, heated to 260°C with 78 % H2SO4, for 8-12 hr. During digestion the following reactions take place:

Jan 1, 1970

By Bruce T. Stanley

Though most porphyry-molybdenum deposits lend themselves to various reserve estimating techniques, still there must exist the constant effort to not merely obtain an estimate but rather to obtain the best estimate. To answer the challenge of a complete ore reserve estimation, one must attack the problem with the purpose of obtaining the results closest to reality. What we wish to determine is simple: metric tons (short tons), grade, and kilograms (pounds) of molybdenum contained. In order to effectively accomplish this task, further consideration must be given to the ease of using the information obtained and its inherent reliability. The only known method for ore reserve estimation that supplies the needed results along with its distribution and a measure of confidence provided by sound mathematical backup is geostatistics. The following review is an example of geostatistical application of an ore reserve estimate at the AMAX Henderson mine demonstrating technique, viability, and usefulness of results.

Jan 1, 1979

By P. R. Khangaonkar, G. Bhaskar Raju

Three types of flotation columns were developed with a column dia of 8.0 cm and a length of 160 cm. The first type consists of an ordinary column fitted with a porous plate at the bottom. The second type consists of two electrodes at the bottom to obtain very fine and uniform bubbles generated electrolytically and the third is a combination of first and second types, i.e. to get both electrolytic bubbles and air from the compressor through porous plate. Three different ores were tested-gold tailings for recovery of scheelite, copper tailings (chalcopyrite) and oxide copper ore. In the case of scheelite and copper oxides, good results were obtained with the first type of column itself, whereas the third type column was found fairly effective in the recovery of chalcopyrite. The variables like the effect of reagent concentration, column height above the feed point, feed flow rate, current density, air flow rate, particle size etc. were examined.

Jan 1, 1988

By W. Petruk

Mineral liberations that would be obtained by grinding an ore to a specific size can be predicted by analyzing unbroken ore pieces, and mineral liberations in ground ores and mill products can be determined directly by image analysis. Predictions of mineral liberations are made by measuring size distributions and textures of mineral grains by image analysis and using liberation models. Ground ores and mill products are analyzed to determine the proportion of mineral that is liberated, and the data are used to evaluate mineral behavior during mineral beneficiation. The liberation data for minerals in a suite of mill products from a circuit are processed by a materials balancing technique to calculate recoveries of minerals in different types of particles throughout the circuit. The liberation-materials balance data define mineral recoveries; define the behavior of an ore in a concentrator, pilot plant or bench test: and indicate whether recovery improvements are possible and/or feasible.

Jan 1, 1992

By S. Ersayin, I. Iwasaki

Laboratory- and pilot-scale tests were carried out to study the effects of a magnetically enhanced hydroseparator on a magnetic taconite sample. The test parameters included feed flow rate, percent solids and magnetic field strength. Laboratory tests showed that magnetic iron losses could be effectively prevented by applying a magnetic field strength of 0.003 T (30 gauss) to a hydroseparator. A relatively uniform magnetic field within a pilot-scale hydroseparator was obtained by installing a magnetic grid within the device. The test parameters for the pilot-scale study also included the effects of magnetizing/demagnetizing the feed and magnetizing current. Magnetic iron losses were substantially reduced, even when the hydroseparator was operated at very high upward velocities. Results also show that increasing the field strength decreased the losses, but magnetic enhancement was successful even at the lowest field strengths, and the results show that magnetic iron losses were lower when the feed was magnetized. Key words: Hydroseparator, Magnetic field, Magnetic grid, Taconite processing, Magnetizing, Demagnetizing.

Jan 1, 2003

By M. Rossi

The use of service variables in geostatistics (grade-thickness) is common in industry when developing block grade models and geologic resource estimates. This is particularly true in the case of sedimentary and stratabound-type deposits. The approach has proven merits when assessing ore reserves. However, there are cases where its application for preliminary data analysis produces biased estimates. One such case is encountered in uranium disequilibrium studies. This paper demonstrates the inadequacy of service variables when performing uranium disequilibrium studies. Disequilibrium analysis is a necessary preprocessing step when radiation counts are used as raw data to calculate uranium reserves. Typically, a probe is used to obtain the gamma counts from open drill holes. These counts are then regressed (and corrected) against chemical assays obtained from core samples. During this process the grade-thickness variable produces an optimistic image of the relationship between probe grades and chemical (true) grades, causing overestimation of the final geologic resource. The problem is analyzed through a case study.

Jan 1, 1993

By L. Piga, P. Cipriani, F. Pochetti

High-temperature roasting of alunite in the presence of K2CO3 gives rise to a reaction that results in up to an 80% recovery of its potassium content as K2SO4 by leaching of the roasted mixture. K2SO4 is also generated from the reaction between the added K2CO3 and the SO3 driven off during roasting of the alunite. This limits the environmental and corrosive problems involved in the thermal treatment of this mineral. A solid residue containing mainly aluminum oxide is also obtained. This could be used as raw material for the production of aluminum, as the use of K2CO3 does not introduce different cations than are in the ore. A statistical study was performed on the factors assumed to affect the recovery of potassium, namely, roasting temperature, K2CO3- alunite stoichiometric ratio and leaching temperature.

Jan 1, 2000

By James M. Prudden, E. P. Jucevic

The Divide mining district occupies the center of a Tertiary caldera hosting the famous Divide silver lode and the crosscutting Gold Mountain mines. The northwest-southeast trending silver lode hosted ore with typically a 100:1 silver:gold ratio, high molybdenum content and argillic alteration dated at 16.5 m.y. within the Fraction Tuff. The east-west trending Oddie Rhyolite flow dome at Gold Mountain experienced possibly several periods of resurgence with repetitive silicification, brecciation and attendant precious metal deposition forming stockwork type mineralization. Silver-gold ratios average 10:1 for the mineralization phase of this 16.4 m.y. intrusive event. Similar chalcedonic mineralization registering a 3:1 silver:gold ratio cements conformable breccias within the Oddie Rhyolite basal flows unconformably overlying the Siebert Tuff on the northern flanks of Gold Mountain. Gray and red chalcedonic breccia matrix in the King Tonopah member of the Fraction Tuff contains a 50:1 silver :gold ratio.

Jan 1, 1990

By Donald E. Hulse

Selection of a block size for a computerized 3 dimensional ore body model is an exercise in compromises. Larger blocks decrease the use of computer resources and decrease the variance of the block estimates. Smaller blocks increase the resolution of the model and the selectivity which can be used in the planning, but increase the variance of estimates in the individual blocks. A common rule is that blocks can be as small as one fourth the average sample spacing, however this ignores the interrelationship between the block size, the sample spacing, and the variogram model. This paper will explore this relationship Kriging estimation variance will be used as a comparative measure of estimate quality. Graphical techniques will be used to show that there is a point where smaller block sizes cease to contribute to the resolution of the model. A method of evaluating the consequences of block size decisions will be examined.

Jan 1, 1992

By Charles Dr. Li, John Dr. Box

Selective flotation and adsorption behavior of zircon and rutile under hot soap conditions have been examined. Conditioning temperature, pH and washing steps were shown to control the flotation selectivity. The adsorption of the sodium soap of oleic acid at zircon- water and rutile-water interfaces was investigated through micro- electrophoresis and adsorption density measurements. The soap adsorption on the zircon surface increased markedly with increasing temperature due to a strong chemisorption/surface reaction, and was almost independent of pH. In contrast, the soap adsorption on rutile decreased at high pH values. A simple physisorption plus hydrophobic interaction appeared to be the principal mechanism for the soap adsorption on rutile at moderate temperatures (below ~70(C), beyond which it may change to chemisorption through an activation process. Water wash, particularly under acidic conditions (pH 2-3), of the rutile particles treated with soap, will lead to a desorption of the soap from the rutile surface by forming an acid salt precipitate.

Jan 1, 1995

By Eleanora I. Robbins, Motoaki Sato

Many problems associated with acid mine drainage (AMD) are caused by the complex way molecular oxygen (O2) oxidizes reduced matter at surface temperatures. In aqueous solution, O2 kinetically "prefers" to go through the formation of hydrogen peroxide (H2O2) as an intermediate. Being innately unstable, H2O2 is quickly decomposed back to water and oxygen in the presence of dissolved Fe and Mn, both catalysts for the decomposition. Direct addition of H2O2 to AMD produced similar results. Ozone (O3) is a much faster and stronger oxidizer than either O2 or H2O2. In the laboratory, O3 rapidly precipitated Mn, Fe, Ni, Co, Pb, and Ag even in acidic solutions. The experiments indicate that AMD can probably be processed with ozone and metal oxides/hydroxide recovered in flow systems using only septic-tank-size reactors and small sedimentation ponds.

Jan 1, 2000

By Sushil Bhandari

A computer model is developed for the problem of dispersal of dust (suspended particulate matter) resulting from blasting operations in surface mines. Undulated surface (lower boundary) simulation was carried through sixth order polynomial by least square approximation. Segmentwise terrain simulation was linearly added to build ground feature extending either side of the blast location. Assuming the initial dust concentration in the vertical column to. be uniform and treating the finite vertical line sources as a series of point sources to height, H varying from zero to top of the dust mushroom, integration was done of the concentration effects from H = 0 toL tan[0] (L = horizontal distance of the blast location and [0] is the angle of the top of dust cloud from the point of observation). Using frame of reference moving with the mean wind, the ground level 'concentration (GLC) has been computed over the undulated terrain. Standard deviation (s) of concentration has been parameterized based on mixed layer similarity theory in convective boundary layer.

Jan 1, 2002

By S. Saklar, i. Bayraktar

The effect of the feed size distribution on the kinetic parameters in pyrite flotation was studied. The kinetic parameters of the particular sizes were determined as a function of whether other particle sizes were present. From the data, a relation between the pyrite flotation rate and the particle size distributions was obtained. It was shown that the flotation rate constant (k) is a function of the size modulus (dt) of the Gates-Gaudin-Schuhmann distribution, and its variation may be expressed as k = a • exp(b . d,) for either individual size fractions or composite feed. Parameters a and b are dependent on the particle size distribution of the feed. Specifically, parameter a increases linearly as the distribution becomes coarser. The above relationship was also tested under conditions in which the collector (KAX) dosage was varied from 130 to 278 g/t. It was shown that the established relation was not dependent on the collector dosage.

Jan 1, 2002

By Robert Underwood, Boleslaw Tolwinski

In 1965 Helmut Lerchs and lngo Grossmann presented to the mining community an algorithm to find the optimum design for an open pit mine. In their words, "the objective is to design the contour of a pit so as to maximize the difference between total mine value of the ore extracted and the total extraction cost of of ore and waste." They modeled the problem in graph theoretic terms and showed that an optimal solution of the ultimate pit problem is equivalent to finding the maximum closure of their graph based model. In this paper. we explain how a dual simplex algorithm can be used to solve the same problem. We show how this algorithm is closely related to Lerchs and Grossmann's and how the steps in their algorithm can be viewed in mathematical programming terms. This analysis adds insight to the algorithm of Lerchs and Grossmann and shows how it can be simplified.

Jan 1, 1996

By R. L. Bleifuss, S. Zhong, H. E. Geotzman

Microwave heating of iron ore was investigated as an alternative to conventional reduction processes to solve the problem of slow heat transfer. Microwave heating and reduction tests were run on composite green balls made from coal and magnetite concentrate. Benchscale tests were run on both powdered and pelletized feeds using a 15 kW microwave generator. A significant increase in the reduction rate was obtained. With 20% excess stoichiometric carbon in the mix, more than 90% reduction of the iron ore can be achieved in about 10 min at temperatures of around 1,000°C. The reduction of iron ore with coal by microwave heating produces a pure, dust free, high-Btu flue gas that can be used in related thermal operations. Depending on the purity, the reduced iron product could be fed directly to an electric arc furnace for melting. In some cases, the removal of a slag phase may be required to eliminate excess silica and alumina.

Jan 1, 1997

By K. N. Han, M. C. Fuerstenau, T. B. Onlin

A mathematical model describing the concentration profile of fine particles in the axial direction in liquid fluidized beds has been developed for the removal of fine particles. A forward finite differentiation technique has been used to solve a continuity equation with a source term to predict the concentration profile and, hence the recovery as a function of time. With the aid of experimental results obtained using a fluidized bed of 3-cm diam, dimensionless parameters were identified. These parameters were used to predict the concentration profile of fine particles in fluidized beds of larger sizes. Four different sizes of fluidized beds, namely, 1.3, 3.0, 4.0, and 7.5 cm in diam, were used in this investigation. The amounts of bed particles used included 4, 8, 16, 24, 59, and 120 g, and the size of bed particles were 48x100, 100x150 and 150x200 mesh.

Jan 1, 1987