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By A. S. Malicsi, M. D. Baker, I. Iwasaki

Fine grinding may he required for- some coals to remove sulfur and ash or to prepare coal-water slurry. Fine grinding leads to increased hall wear and its effect on the surface properties of the ground coal becomes of concern. Marked hall wear - tests were performed to study the effects of oxygen, pH, the soluble species of coal, and the addition of pyrrhotite on hall wear. The synergistic action of coal and oxygen greatly enhanced the corrosion of mild steel halls during grinding. Elec.trochemica1 measurements on a mild steel electrode in coal slurries and SEM observations of grinding hall surfaces were carried out to explore the corrosive wear mechanism.

Jan 1, 1991

By K. A. Natarajan

This paper deals with the various electro- and biochemical mechanisms involved in the bioleaching of multisulfide minerals such as those containing copper-lead-zinc and copper-nickel-iron. Galvanic series for sulfide minerals consisting of pyrite, chalcopyrite, galena, sphalerite, pentlundite, and pyrrhotite in an acid bacterial leaching system is illustrated, and the role of relative electrochemical activity on selective dissolution is discussed. Typical leaching results are shown to illustrate the practical applicability of galvanic effects in bioleaching of multisulfides. Attachment of Thiobacillus fewooxidans onto chalcopyrite and sphalerite mineral substrates is illustrated through scanning electron micrographs. The role of high-metal-tolerant, specially adapted strains in the leaching of multimetal concentrates is also outlined.

Jan 1, 1987

By L. G. Austin, R. C. Klimpel

Batch breakage kinetic tests were performed in a mill of 0.3 m diameter for a range of mill conditions. Accurate simulation required the measurement and use of factors which accelerated the specific rates of breakage of the top sizes as finer material accumulated in the slurry. These factors depended on the size distribution expressed relative to the top size, not the absolute size, suggesting that they are due to a packing effect not a rheological effect. The data simulated correctly a series of steady-state continuous tests in a mill of the same diameter providing values were corrected to the hold-up, ball load, slurry density, and size distribution measured in the continuous mill tests.

Jan 1, 1990

By Hassan El-Shall, M. N. Ahmad, Ponisseril Somasundaran, C. R. Holland, G. M. Walker, N. Iles, R. D. Chandler, Regis Stana, B. Duddy, Patrick Zhang

Phosphoric acid is a major raw material for the production of ammonium phosphate (AP) that is used as an intermediate in fertilizer production. Impurities within commercial grade wet process phosphoric acid are important in producing a fertilizer granule with good handling properties. The impurities identified as being important are; iron (III), aluminium and fluorine-containing compounds. Results show that the viscosity of the AP slurry produced increases by increasing the amount of impurity in the acid. Bench scale tests have been successfully replicated on a plant scale leading to a better understanding of the composition of impurity levels within phosphoric acid required to produce a high quality, free flowing, hard, spherical and non-caking granular fertilizer.

Jan 1, 2002

By G. A. Munoz, J. D. Miller

Gold leaching of an auriferous pyrite ore from the Portovelo deposit in Ecuador indicates that noncyanide leaching systems, such as thiocyanate and thiourea, are not as effective as the traditional cyanide system. For example, whereas approximately 95% of the gold can be leached from the ore with cyanide, only about 50% gold dissolution can be achieved with a thiocyanate leaching system. Electrochemical measurements indicate that gold is not cathodically protected by pyrite in these systems. Based on the results of preliminary diagnostic experiments, it appears that gold dissolution in thiocyanate and thiourea systems is limited by passivation due to the formation of either elemental sulfur or sulfur compounds on the gold surface.

Jan 1, 2000

By M. K. Larson, R. G. Wade

Researchers at the National Institute for Occupational Safety and Health (NIOSH) are studying the time- dependent response of rock stressed along weakness planes. The objective is to improve mine safety by reducing the number of roof falls that cause injuries and fatalities to miners. Researchers conducted direct- shear tests on mudstone overcored from a coal mine roof. Results showed frictional strength weakens with displacement along the shearing planes. Results of direct-shear creep tests also showed time-dependent deformation. Test measurements were compared to classical analytical models. Results suggest that the risk of roof collapse may be decreased through layout and support design to reduce creep rates and thus slow progression toward failure.

Jan 1, 2002

By C. N. Bensley, S. K. Nicol

The major developments in fine coal processing in Australia are reviewed. Emphasis is placed on the approaches taken by various Australian coal producers to improve the recovery of the coarse size fractions (minus 0.5 plus 0.25mm) and upgrade the selectivity of flotation at ultrafine sizes (minus 0.075mm). The effects on fine coal preparation of flotation circuit changes, the influence of physical and chemical variables on coarse coal flotation and the impact of spiral concentrators and column flotation, are discussed. Reference is also made to the development of oil agglomeration technology for the treatment of fine coal refuse and some of the factors which have led to its current demise.

Jan 1, 1988

By Chun K. Ip, Simon T. Johnson, Robert J. Fowell

Laboratory conducted cutting tests at traverse speeds up to 1 m/s have been undertaken with high pressure water jets assisting the cutting action of drag tools. Four sandstones and one limestone have been investigated, which represents a wide range of compressive strength. Variables investigated include water jet pressure, nozzle diameter, depth of cut, traverse speed, jet position, and tool bluntness. The test programme has allowed a model to be developed which describes the action of water jet assistance for three conditions dependent on the ability of the jet to penetrate the rock: where no significant penetration occurs, where penetration is greater than 50% of the tool depth, and an optimum condition around 30% of tool depth.

Jan 1, 1986

By J. P. Golightly

The nickeliferous laterites of Soroako are described in their setting in the huge Cretaceous ultramafic complexes of central Sulawesi, Indonesia. The ore bodies occur on spurs, ridges and hill flanks beneath remnants of extensive erosional surfaces. Weathering pro- files that have developed on unserpentinized harzburgite and on strongly serpentinized lherzolites show distinctive laterite structures, mineralogy and chemistry. The former are unique to the Soroako area and permit an unusual degree of upgrading by rejection of unserpentinized peridotite boulders. A mass balance calculated for a selection of profiles indicates that in situ leaching of a column of peridotite 20-50 meters thick has taken place with only minor lateral migration of nickel in solution.

Jan 1, 1979

By J. M. Kruger

High-resolution ground-penetrating radar (GPR) was used to image the near-surface extent of two exposed Late Cretaceous kimberlites intruded into lower Permian limestone and dolomite host rocks in northeast Kansas. Six parallel GPR profiles identify the margin of the Randolph 1 kimberlite by the up-bending and termination of limestone reflectors. Five radially-intersecting GPR profiles identify the elliptical margin of the Randolph 2 kimberlite by the termination of dolomite reflectors near or below the kimberlite's mushroom-shaped cap. These results suggest GPR may augment magnetic methods for the delineation of kimberlites or other forceful intrusions in a layered host rock where thick, conductive soil or shale is not present at the surface.

Jan 1, 1997

By Eric Forssberg, Ming-wei Gao

Four parameters of the Drais stirred ball mitt, i.e., bead load, bead size, flow rate and top feed size have been studied regarding their influence on the specific surface area. A factorially designed scheme was employed for conducting 27 mitting tests. The results show that the bead toad is the most important parameter in terms of increasing the specific surface area with less energy consumption. The bead size is also important. The optimum ratio of bead size to top feed size is found to be 14 to 80, which is much wider than in bat2 milling. The variations in flow rate and top feed size appear to influence the process insignificantly.

Jan 1, 1992

By R. Q. Honaker, D. P. Patil, A. Sirkeci

Because of increasing production of fine coal during mining over the past century and because of inefficient fine-coal recovery technologies, a vast reserve of high-quality coal now exists in refuse ponds. A novel finecoal circuit, consisting of a hindered-bed classifier, an enhanced gravity concentrator and a flotation column, was evaluated for the recovery of fine coal from refuse ponds. The treatment of a pond derived from Pittsburgh No. 8 seam coal resulted in the production of a premium fuel containing less than 5% ash and a calorific value of about 30,170 kJ/kg with 60% mass yield. Results from the treatment of two refuse pond materials are presented in this paper.

Jan 1, 2002

By F. M. Doyle, K. Osseo-Asare, E. Peters

With the aid of molecular orbital theory, a discussion is presented of the relationship between the electronic structures of ions and molecules, and the elementary steps involved in homogeneous electron transfer reactions. An electronic theory of the reactivity of oxidants and the mechanism of action of oxidation catalysts is then presented, with emphasis on the oxidative decomposition of metal sulfides. For model oxidants, two molecular reagents: O2 and Cl2, and two ionic reagents: Fe3+ and CU2+ were selected; silver (1) was chosen as the model catalyst. The reactivities of these reagents are rationalized in terms of constraints on orbital overlap, the availability of unoccupied d orbitals, and the rearrangement of electronic configurations.

Jan 1, 1993

By C. D. Harrison, G. S. Stallard

The 199O Clean Air Act Amendments specify national objectives for reducing sulfur dioxide emissions from coal fired power plants. System-wide reductions can be achieved by combining various emissions control technologies and allowances, or compliance credits, that can be purchased, sold or traded. As part of the Coal Quality Expert development project funded by the US Department of Energy and the Electric Power Research Institute (EPRI), Black & Veatch has developed an interactive computer tool, the Acid Rain Advisor (ARA). Through this program, integrated, system-wide compliance plans are generated by comparing the costs and emissions reduction benefits of emissions allowances and various SO2-control technologies (coal cleaning, fuel switching, scrubber retrofits, etc.)

Jan 1, 1993

By M. Abdel-latif, R. W. Bartlett, P. R. Taylor

A cyclone reactor system for the partial reduction and melting of taconite concentrate fines was designed and operated. A nontransferred arc plasma torch was employed as a heat source. Taconite fines, carbon monoxide and carbon dioxide were fed axially into the reactor, while the plasma gas was introduced tangentially into the cyclone. The average reactor temperature was maintained above 1673 OK (1400°C), and reduction experiments were performed under various conditions. The influence of the following parameters on the reduction of taconite was investigated: carbonmonoxide to carbon dioxide inlet feed ratio, carbon monoxide inlet partial pres- sure and average reactor temperature. The interaction of the graphite lining with carbon dioxide and taconite were also studied.

Jan 1, 1995

By John Waggoner, Steve Klein, John Townsend, Jay Arabshahi

The Riverside Badlands Tunnel is a 13 km (8 mile) long segment of the Inland Feeder Project. This 3.65 m (12 ft) finished diameter water tunnel presented many challenges that had to be overcome to take the project from concept to reality, not the least of which were the diverse ground conditions. Construction of the tunnel was carried out by a single tunnel boring machine (TBM) in one tunnel drive. The project is considered a success due to the accurate baseline established for the ground conditions; the approaches used to mitigate adverse conditions; and the appropriate use of TBM excavation methods, which achieved rapid advance rates despite the challenging ground conditions.

Jan 1, 2003

By L. E. Krys, K. D. Harrison, C. G. Anderson

Since 1984, nitrogen-species catalyzed pressure leaching has been utilized at Sunshine Mining and Refining Company for the recovery of precious metals from a refractory sulfide concentrate. The process operates without the use of cyanide. The plant is now the only industrial-scale commercial application of this technology. Since the inception of the process, changes have been implemented to improve efficiencies and throughputs. Two of these changes, the replacement of nitric acid by sodium nitrite and a concentrate regrind, have recently been implemented. This paper discusses the development and potential mechanisms involved in these recently patented plant-process changes. A companion publication (Anderson et al., 1996) covers the plant integration and potential applicability of the technology.

Jan 1, 1997

By W. Petruk

Imaging is a fundamental requirement when characterizing minerals, ores and related products. Images are used for presentation, texture analysis, characterization, image analysis, identification, etc. The image mode that is utilized is dependent on the application, mineral properties and available instruments. Different instruments produce images that display different features. In order of increasing complexity they are: hand specimens, a non-polarizing microscope, polarizing optical microscope, scanning electron microscope (SEM), low vacuum SEM, microprobe, secondary ion mass spectrometer, staining, cathodoluminescence, tomography and others. Image analysis uses images produced with either an optical microscope or a SEM, but the SEM images are superior in this application. Key words: Mineralogy, Imaging, Mineral characteristics, Scanning electron microscopy, Optical microscopy, Cathodoluminescence

Jan 1, 2003

By M. M. Hajdasinski

For decades, the internal rate of return (IRR) project-evaluation criterion has been under increasing criticism. Torries (1998a) defends the beleaguered criterion. He claims that, as a project-evaluation and ranking instrument, the IRR is as suitable as the net present value (NPV). Torries also maintains that using the IRR to rank projects does not require the incremental approach and introduces his own alternative ranking approach. This paper disputes Torries' pro-IRR arguments and demonstrates that the IRR is a theoretically flawed and operationally dysfunctional criterion whose true meaning has persistently been misinterpreted. In a forthcoming paper by the author it will be shown that Torries' IRR-based project-ranking approach is flawed as well.

Jan 1, 2000

By D. W. Fuerstenau

In mineral processing, the last century of the current millenium has been the century of froth flotation. The process did not result from fundamental research, but was developed over the years by empirical methods. In more recent years, our understanding of the fundamental principles of the flotation process have made significant strides. This paper reviews some of the historical perspectives of developments in flotation reagents, the development and application of experimental tools for delineating flotability and interfactial phenomena, advances in flotation fundamentals, and the development of flotation kinetics, both macroscopic and microscopic subprocesses. Through the application of surface chemistry, the flotation process has permitted economic utilization of a vast array of complex ores.

Jan 1, 1999