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By H. W. J. P. Neomagus, J. R. Bunt, T. S. Mthombo, C. A. Strydom

"Low-cost calcium lignosulphonate (CL), which is a byproduct of the wood pulping industry, was investigated as a potential binder during laboratoryscale pelletization of inertinite-rich high-ash coal fines from the Highveld Coalfield of South Africa. Coal-binder mixtures containing between 1 and 15% calcium lignosulphonate were prepared, pressed, and ultimate, proximate, porosity, XRD, and XRF analyses obtained. It was found that increased pressure during pelletization results in increased attractive forces, due to increased interparticle contact areas. FTIR analysis showed that chemical interactions occur between coal fines and the binder, as evidenced by the formation of new C-O ether-type bonds. The presence of moisture during pelletization enhanced surfactant activity of the binder. Chemical interactions between the coal and the binder seem to be mainly electrostatic, driven by Ca2+ from the calcium lignosulphonate, which may act as a bridge between the anionic parts of the binder and the surface of the coal. IntroductionCoal has over the years remained South Africa’s major energy source, with over 90% of the country’s electricity being produced via coal-fired processes (Arndt et al., 2016). Sasol’s coal conversion technology alone provides more than 40% of South Africa’s liquid fuel requirements (van Dyk, Keyser, and Coertzen, 2006). The production of high-grade coal requires the processing of run-of-mine (ROM) resources by a combination of processes which include crushing, screening, and washing (Radloff, Kirsten, and Anderson, 2003). These processes result in the generation of coal fines (< 0.5 mm) which, until recently, have been discarded into slimes dams (le Roux, Campbell, and Smit, 2012). Several issues are associated with slimes dams, among which are the costs of transportation of these fines from the place of origin to the discard point (often a considerable distance), and the potential environmental effects due to seepage of toxic materials into surrounding ecosystems (Clausen, 1973).Consequently, utilization of these coal fines is an area of great interest. Mechanical densification of fine coal by means of pelletization and/or briquetting to larger sizes for use in technologies that require lump coal, such as chain-grate stokers and fixed-bed gasifiers, has been shown not only to reduce environmental risks (Mangena et al., 2004), but also to significantly reduce storage and transportation costs (Mani et al., 2001). Pelletization is the process by which solid particles are consolidated into uniform, usually hard, impact-resistant agglomerates, rendering them useful as a fuel with sufficient calorific value for domestic and industrial utilization (Finney, Sharifi, and Swithenbank, 2009)."

Dec 1, 2018

By G. R. Drennan, N. J. Wagner, M. J. T. Sebola

The Soutpansberg Coalfield hosts South Africa's hard coking coal reserves. However, coals in this region are understudied compared to other coalfields in the country. This study characterizes the properties of fine-float fraction samples extracted from a wide diameter borehole core in the Makhado Project, Tshipise sub-basin, Soutpansberg coalfield. Conventional analyses were used to determine the coal quality, petrographic composition, mineralogy, geochemistry (including trace element and rare earth element composition), and free swelling index of samples from six coal horizons and three partings from the economic No.6 Seam. The coal samples are classified as medium rank bituminous C coals (0.88 %RoVmr, 0.92 %Rmax) and are highly vitrinitic in composition (97 vol% mineral matter free (mmf)). The samples show strong caking potential (FSI of 9). The total rare earth concentrations range between 570 and 3193 ppm in the ash samples. Preliminary analysis show all but two samples are promising sources of rare earth elements as the total concentrations exceeded the 1000 ppm cut-off grade. Further research is required to confirm these preliminary findings.

Aug 2, 2022

By S. A. Lorentz, Y. Xu, C. Theron

The failure of tailings storage facilities (TSFs) results in the discharge of significant quantities of hazardous waste material into the natural environment. Research studies relating to slope instability have identified physical mechanisms such as rainfall-induced erosion, liquefaction, and shear failure as the main triggers. The generation of transient pressure waves and the mobilization of pre-event water in the unsaturated zone have been found to trigger shallow landslides in natural hillslopes. In this paper we review these physical mechanisms, known as groundwater ridging (GWR) and the Lisse effect (LE), from other studies. Previous researchers have explained both these phenomena through field and laboratory observations, numerical modelling, as well as conceptual discussions. These case studies demonstrate the impact of rainfall characteristics on the generation of transient pressure waves that rapidly increase the phreatic surface and change pore water suction. Reference is also made to the influence and behaviour of physical porous medium characteristics on the establishment of a continuous water phase that facilitates the transmission of an induced pressure head. However, previous studies fail to recognize the possibility that the pressure increase in pre-event water through pore air propagation could cause slope instability in tailings dams. The authors suggest that the physical properties and hydraulic behaviour of unsaturated porous tailings media make it susceptible to GWR and the LE, resulting in the creation of a potential failure plane.

Feb 2, 2022

The most important event in the Institute&apos;s recent history is the strategic plan, which was drawn up in 1986 during Henry James&apos;s term of office. This plan was formulated at a workshop attended by most of the senior members of Council, and from it has flowed a number of changes that have been introduced over the past four years.

Jan 1, 1990

By Karl-H. Daum

Over many decades, numerous feasibility studies have demonstrated, that the production of sulphuric acid remains the most viable option of sulphur recovery from smelter off gas and abatement of SO2 emissions to the atmosphere. This is particularly more pronounced as smaller but more concentrated off-gas flows are to be treated from smelters, and enhanced sulphuric acid processes be-come available. Off-gas handling systems represent a significant capital and operating cost burden to the metallurgical operation. Modern pyrometallurgical smelter processes for sulphide ores based on the use of oxygen-enriched air, produce relatively small off-gas flows with high SO2 concentrations in the smelter gas of 30?60 %-vol. of SO2. This is a prerequisite for substantial cost reductions in the smelter off-gas handling and treatment system. As an alternative to sulphuric acid production, numerous scrubbing concepts with alkali or dual-alkali combinations as well as organic absorbents have been proposed. Also the reduction of the SO2 to elemental sulphur has frequently been studied. Very few of those alternative processes have been built in industrial scale, but all were generally characterized by none sustainable operation due to cost reasons, problems with issues related to chemicals used and by-products or poor availability. Thus the traditional concept of converting the SO2 to sulphuric acid is most common, although regarded as un-economic, but is at least a proven, environmentally sustainable and reliable way of sulphur gas processing. With the high acid price levels these days, operating companies are even able to generate significant revenue with their otherwise ?fatal? acid. Even though smelter gas is available at high SO2 concentrations, in a conventional acid plant one would add large amounts of air to dilute the gas down to a suitable concentration of 12?13 (14) %-vol. SO2. Dealing with higher SO2 concentrations in smelter acid plants is not feasible, as the gas exit temperature of the catalytic oxidation step would exceed the allowable limit for the catalyst. Hence those conventional acid plants are characterised by the use of large equipment, i.e. high capital cost, high energy consumption and limited flexibility. The newly developed LUREC® process can handle off-gas with significantly higher gas concentrations, even in excess of 25 %-vol. SO2. It is entirely based on well-proven equipment and unit operations. The first industrial application, operating with 16?18 %-vol. SO2 will be presented in this paper, along with the fundamentals of the process. It will be demonstrated that the process requires inherently lower capital cost, fewer operating cost, offers better energy recovery and lower emissions as compared to conventional design. While most existing smelter acid plants would have some built-in spare capacity, any significant increase of smelter capacity, say of 30%, can basically not be accommodated without installing an additional parallel new acid plant unit. An add-on LUREC® module can remove any such restriction, while simultaneously de-bottlenecking the existing acid plant. The paper also discusses the present status of the add-on technology for smelter acid plant expansions with respect to technical boundary conditions of different process alternatives as well as economic and environmental aspects. Application of the LUREC® process to modern smelter acid plants operating with high SO2 gas concentration, will lead to a substantial reduction of the specific size of the gas processing equipment and equivalent savings in capital and operating cost. The LUREC® process is patented worldwide by OUTOTEC.

Jan 1, 2009

The Annual General Meeting of the Institute was held in Kelvin House, Johannesburg, on Wednesday, 27th August, 1969, at 4.15 p.m. Mr. R. C. J. Goode (President) was in the Chair. There were also present seventy Members, ten As¬sociate Members, two Affiliates, one Student and twelve Visitors making a total of ninety-five. The President declared the meeting open at 4.20 p.m. OBITUARIES The President: "It is my very sad duty to announce the deaths of the following members of the Institute: Mr James Charles Napoleon Humphreys, a Life Member who joined the Institute on 1st April, 1935, and passed away on 6th February, 1969. Mr Michael John Worrall, Graduate Member, who joined the Institute in 1960 and passed away on 2nd June, 1969. Mr Eric Adam Conrad Dickson, Associate Member, who joined the Institute on 13th June, 1952 and who passed away on 8th June, 1969. Mr Robert Jack, Associate Member, who joined the Institute on 2nd August, 1956, and passed away on 14th June, 1969. Mr R. A. H. Flugge-de-Smidt, Honorary Life Member and Gold Medallist, who joined the Institute in 1922 and passed away on 17th June, 1969. Mr John Gordon Craig, a Member who joined the Institute on 23rd August, 1960, and passed away on 6th August, 1969. As a mark of respect to the memory of the deceased, and in sympathy with the bereaved, I would ask you to rise and observe a few moments silence." MINUTES The President: "May we confirm the Minutes of the General Meeting held on 18th June, 1969, as published in the July, 1969, issue of the Journal?"-Agreed. WELCOME TO VISITORS The President: "We are honoured this afternoon by the presence of the Institute&apos;s Honorary President, Mr R. S. Cooke, President of the Chamber of Mines of South Africa, and by one of our Honorary Vice-Presidents, Mr T. L. Gibbs, the Government Mining Engineer, as well as by the presence of many distinguished guests, to all of whom I extend a most cordial welcome. We are happy to have present, Mr S. C. M. Naude, Director of the Witwatersrand Technical College, Mr G. A. P. Louw, Vice-President of the Associated Scientific and Technical Societies, Mr R. P. Randall, Senior Vice-President of the South African Institute of Electrical Engineers, Mr W. T. L. Wayman, President of the South African Institution of Mechanical Engineers, Mr D. F. Odendaal, President of the Institution of Certificated Mechanical and Electrical Engineers of South Africa, Mr E. Haacke, President of the Institute of Land Surveyors of the Transvaal, Mr B. L. Loffell, Vice-President of the South African Institution of Civil Engineers, Mr J. F. Leatherbarrow, President of the South African Institute of Assayers and Analysts, Dr W. S. Rapson, President of the Joint Council of the South African Scientific Societies, Dr P. L. Carman, President of the South African Chemical Institute, Mr F. Jackson, President of the Federation of Societies of Professional Engineers, Mr W. E. Kirkwood, President, S.E.I.F.S.A., Mr J. Steele, President of the South African Institute of Foundrymen, Mr M. Waite, President of the South African Institution of Welding, Mr M. R. Gericke, President of the South African Council of Professional Engineers, Mr G. C. Sowry, Chairman, Witbank-Middelburg Branch, Mr T. Groenewald, Chairman of the South African Chemical Institute (Southern Transvaal Section), Professor O. B. Volckman, Chairman of the South African Institution of Chemical Engineers, Mr H. W. Le Roux, Chairman of the South African Federation of University Engineer¬ing Students, Dr R. E. Robinson, Director of the National Institute for Metallurgy, Mr P. H. Anderson, Deputy-Chairman of Rand Mines Limited, Mr E. Boden, Manager of the A.S. and T.S. and Count Folchi-Vici, from Italy, who has lime interests in this country. I also extend a very special welcome to the lady guests here this afternoon, and to all the visitors." MEMBERSHIP The President: "I have pleasure in announcing that the names of the following candidates, having been published in accordance with By-Law 5.2.2, Council has elected them to membership in the following grades: NEW APPLICATIONS Members: Stuart Denston Hill, Robert Roy Richardson, Gert Paulus van der Vyver. Affiliates: Henry Clifford Read, Allen Edward Hooper, Alan Edwin Edkins. Graduates: Lester Winston Sturgess, Erroll Vincent Bosman. Students: Terence Vernon van Heerden, David Curtis Lindley. MEMBERS TRANSFERRED TO A HIGHER GRADE From Associate Member to Member: Andries Willem van Zyl, Roy Lardner, Nugent Gerald Ward Comyn. From Student to Graduate: Michael John Worrell (now passed away), Peter John Hamilton Short. I wish to welcome the new members to the Institute, and to congratulate those members who have been transferred to a higher grade." ANNUAL REPORT OF THE COUNCIL AND ACCOUNTS FOR THE YEAR ENDED 30th JUNE, 1969 The President: "Ladies and gentlemen, It is with much pleasure that I present to you the Annual Report and Accounts for the year ended 30th June, 1969. These have been laid on the chairs and before calling for their adoption I would like to make a few comments. The Accounts show an excess of expenditure over income of R2,124 and our Honorary Treasurer, Mr D. G. Maxwell, will in due course comment on this. The main difficulty has again been the cost of the Journal and I think most of you are aware of the changes that we propose to make. I shall be sorry to see the last of our old format but then I have always had rather a con¬servative outlook.

"Chairman: Professor H. S. SICHEL Rapporteur: Miss M. I. WATSONPapers:Unrolling of Copperbelt orebodies by J. H. E. Perry and V. H. WiikAn exploration model for tabular orebodies by G. S. Koch and R. F. LinkHarmonic analysis of copper and gold occurrences in the Arbitibi area of the Canadian Shield by F. P. Agterberg and A. G. FabbriMathematical models of orebodies by M. J. Newton and A. G. Royle Estimation of lateritic-type orebodies by A. JournelIn his presentation Mr Wiik said that unrolling could be regarded as a reversal of the natural process of folding, so that the aim of an unrolling procedure would be the reconstruction of original pre-tectonic conditions. While simply formulated, this aim might not always be achieved. The geometrical relationship between points on the deformed surface and corresponding points on the original surface is process-dependent, and a true reconstruction could be achieved only if the deformation history were known in detail.In this computer unrolling procedure all these complexities were ignored. Referring to one particular marker horizon, Mr Wiik said that it was assumed in the procedure that this marker was deposited as a horizontal stratum and that it had subsequently been deformed by simple flexure-type folding.The procedure allowed the geologist to incorporate his knowledge and conception of the deposit through repeated re-contouring with dummy points. This &apos;manumatic&apos; aspect of the procedure had proved invaluable, not only in resolving specific unrolling problems but also in making the system more acceptable to the geologists in general.Unrolling served towards removing what might be termed `tectonic noise&apos; superimposed on the primary distribution patterns for regionalized variables such as metal content and orebody thickness. From this point of view, variograms derived on the basis of unrolled-plan co-ordinates should be more meaningful in terms of depositional environment than are variograms calculated from a normal map projection.Mr M. M. Oosterveld remarked that it appeared from the paper that there were problems in applying the unrolling technique to ore reserve calculation, and asked whether there were not other methods that might be used for that purpose.Mr Wiik replied that at present unrolling played only a minor role in practical ore reserve estimation within Roan Consolidated Mines, Limited. The techniques currently in use differed from one orebody to another, but in general they involved projection onto a vertical longitudinal section or a horizontal plan, with subsequent grid interpolation by means of a standard computer contouring package."

Jan 1, 2014

By A. D. Pienaar

The aqueous chemistry of niobium and tantalum compounds with hydrofluoric acid is a mature field of investigation. In contrast, very little attention has been paid to reactions of these compounds in non-aqueous environments. Similarly, reactions of elemental fluorine with niobium and tantalum compounds have received little more than cursory attention in literature. This work discusses the isothermal reaction kinetics derived from thermogravimetry, using a less redundant approach than is currently the standard. We also discuss the most likely kinetic models for this reaction.

Jan 1, 2012

By G. Dellas, R. Mangera, A. Voigt

"X-ray transmission (XRT) sorting has become the preferred recovery technology option in several parts of the diamond-winning flow sheet. In the De Beers Group, applications of XRT are found across kimberlite, alluvial, and marine operations. This is the result of intensive R&D conducted over the years to arrive at a suite of machine embodiments capable of sorting and auditing diamonds across all size ranges.The first applications in the marine environment used the technology in an auditing mode, and served as a useful early predictor of diamond content weeks ahead of sorthouse returns. The same machines are now available with ejection capability to produce high final product grades. The next application was tests on coarse alluvial gravels as an alternative to dense medium separation. The results were very encouraging, and tests are planned for both green- and brownfield kimberlite environments, as well as to explore an alternative to conventional techniques in final diamond recovery. At the Jwaneng mine Large Diamond Pilot Plant (LDPP), the objective is to recover diamonds in the size fraction –45 +25 mm.The technical challenge remains in the finer sizes, for high-capacitymachines as direct alternatives to conventional diamond recovery technologies. This is an area of ongoing R&D and it is only a matter of time before the breakthrough emerges. X-ray transmission fundementalsXRT makes use of X-ray imaging techniques to analyse objects and materials, and has a wide range of applications from baggage scanning for security purposes (Martz et al., 2016), to recycling of waste material (Owada, 2014). During the last decade XRT has been applied to an increasing extent in the minerals processing industry (von Ketelhodt and Bergmann, 2010; Sasman, Deetlefs, and van der Westhuyzen, 2018). Dual-energy XRT (DE-XRT), in which images of the target material are obtained at both high and low Xray energies, allows for elemental analysis and therefore can be used to discriminate between various minerals.A DE-XRT system makes use of a dualenergy X-ray line scan sensor to generate images of transmitted X-rays (Figure 1). Dualenergy refers to the camera, which contains two sensors, one responding to low-energy Xrays and one to high-energy X-rays. Feed material can be imaged either while on the belt, or while in flight."

Feb 1, 2019

By T. P. Letsebe, L. Magwaza, T. A. Sethu, S. M. Rupprecht

"The authors were tasked with introducing safe and efficient drilling and blasting practices to a small artisanal mine located in the Eastern Province of Rwanda. The current mining methods employed at the mine are inefficient as rockbreaking is conducted utilizing hammer and chisel, or by drilling and blasting with no understanding of the rockbreaking process. The paper discusses the drill and blast cycle, as well as the associated activities necessary to support the mining cycle. The challenges and critical aspects in implementing drill and blast activities are discussed, as well as some of the technical aspects, i.e.drilling pattern, initiation and timing of the blast, and handling of misfires. Ancillary issues such as ventilation, training, communication, effective planning, logistics, and human relations are also examined. IntroductionRockbreaking accounts for 60% of the direct mining costs in small-scale mining. When drilling and blasting practices are poorly implemented the process becomes inefficient and dangerous. The introduction of a proven drill and blast system to artisanal mining offers a number of challenges, with safety being considered the backbone of any sustainable operation and a standard that cannot be compromised.The paper is based on a project at an artisanal cassiterite (tin) mining operation in a small village in the Kayonza District in the Eastern Province of Rwanda. A drill and blast programme utilizing industry best practice was introduced at an underground development end; a raise developed at an inclination of 23 degrees. The underground working is accessed via a 17 degree incline shaft with an operating length of 105 m and serviced by a single drum winder. The winder operates at a speed of about 3.5 m/min hoisting two 1 t wagons from the bottom of the incline to surface for tipping (Figure 1)."

Jan 1, 2017

By M. Rudolph, R. Tolosana-Delgado, G. van den Boogaart, M. Reuter, U. Peuker

This paper addresses the challenge to define a concept of entropy (state of order) for a textured particle system. Both the particle texture, the intergrowth respectively, and the particle size influence the order of a particle system. The smaller the particles become, the more particles form the solid system and the more permutations of the structure of the particle bed are possible. The texture within a particle is fixed, as long as it is not subjected to changes due to comminution, flocculation or agglomeration. The paper will present a definition of entropy, which is able to reflect qualitatively and quantitatively the intergrowth and the size (distribution) of the particles. Theoretical examples will show how different breakage mechanisms can be identified using the entropy definition. Furthermore, we will define the specifications for data sets to calculate the entropy of a particle system. Keywords: Milling, mineral liberation, intergrowth, statistical entropy, modelling

Jan 1, 2020

For the past 12 years, the Universities of Stellenbosch and Cape Town have hosted an annual symposium to discuss research topics in Minerals Processing. Since 1987, this meeting has been held under the auspices of the Western Cape Branch of the South African Institute of Mining and Metallurgy, and has enjoyed much national and international support. In 1993, in place of the usual Symposium, the Branch and Universities collaborated with CSM Associates Ltd and Minerals Engineering Journal is organizing the international Minerals Engineering &apos;93 Conference in Cape Town.

Jan 1, 1993

By G. R. Marchant, B. K. Loveday

"A mathematical model has been developed for flotation circuit simulation. This model was designed to investigate the effect of varying the circulating loads and to determine whether an improvement in overall efficiency could be gained by a size separation prior to flotation.Model parameters were obtained by regression to plant data. Highly correlated parameters in the model were combined to reduce the number of parameters so that the need for excessive data gathering was eliminated. Mass balance smoothing was used to obtain a consistent data set for regression.The results of the simulation indicate that for the same grade of concentrate, an increase in copper recovery of 0.6 per cent may be Possible by increasing the circulating loads. The results of the simulation also indicated that recleaning of the plus 200-mesh material may be beneficiaL."

Jan 1, 2014

By F. M. Ramadhan, M. R. Pratama

Monitoring open-pit mine road conditions has become very critical nowadays. There are several benefits to in conducting research on this field such as opportunity to improve truck’s speed which directly influences truck’s productivity. This research aims to provide a semi real-time, and sensors-based automatic road damage detector that predicts the road quality through road damage exact location tracing, road damages auto-classification, and real-time instruction in the form of work order format to mining road maintenance, and repair authorities through mobile apps and maintenance unit’s in-cabin display. It will also provide the maintenance/repair activity performance evaluation via integrated dashboards. The artificial neural network algorithm is applied during the process of data training regarding classifying road damages and severities which resulted in a valid model. The road damage classification model has a precision level of 80.5% in predicting whether the road is damaged or not. Using this approach, we are expecting to visualise a road quality map of all active roads on mine site.

Sep 1, 2021

By R. Koen, H. Visser, A. Roodt

"SynopsisThe tetraethylammonium salt of the mono-anionic coordination compound mer-oxidotrichlorido(thenoyltrifluoroacetylacetonato- K2O,O’)niobate(V) (NEt4)[NbOCl3](ttfa)], has been prepared under aerobic conditions and characterized by single-crystal X-ray diffraction. (NEt4)[NbOCl3](ttfa)] crystallized in the monoclinic P21/c space group, with a = 11.483 (5), b = 12.563 (5), c = 17.110(5) Å, and ß = 100.838 (5)o. The complex structure exists in a 50.0% (NbA) : 50.0% (NbB) positional disorder ratio.IntroductionComplexes containing organometallic type ß- diketone ligands with O,O and O,N donor atoms are used widely in coordination chemistry and have applications in catalysis, radiopharmaceuticals, etc. (Schutte et al., 2011; Roodt, Visser and Brink, 2011; Brink et al., 2010; Otto et al., 1998). These ligand systems are very useful because of their highly coordinative nature, high solubility, and also due to their ability to be functionalized with various substituents on the carbonyl carbon atoms (Schutte et al., 2011).Only a small number of ß-diketonate ligands have successfully been coordinated to a Nb(V) metal centre, with only a select few being characterized by X-ray crystallography (Viljoen, 2009; Bullen, Mason and Pauling, 1965; Preuss, Lamding and Mueller-Becker, 1994; Funk, 1934; Davies, Leedlam and Jones, 1999; Allen, 2002. The synthesis and crystal structure determination at room temperature of mer-oxidotrichlorido (thenoyltrifluoroacetylacetonato- k2O,O’)niobate(V) {(NEt4)[NbOCl3(ttfa)]} was first reported by Daran et al. in 1979. Accordingly, for this current investigation, (NEt4)[NbOCl3(ttfa)] was re-evaluated at 100 K to determine if the structural features might change with temperature."

Jan 1, 2015

By G. Peinaar

Superhardening is a new development by which a substantial increase in hardenability above the normal can be achieved in Iow-alloy steels. This paper concerns the reversible temper-embrittlement behaviour of steels with a superhardenability characteristic. Steels of type BS 530A40 with manganese modifications varying from 0,72 to 1,27 per cent in the superhardenable and conventional condition were compared. It was concluded that superhardenability in itself does not affect the susceptibility of a particular steel to temper embrittlement. However, an increase in manganese content, which was intended to increase the base hardenability of the steel, caused serious deterioration of the temper-embrittlement properties. As the use of manganese, chromium, and nickel to increase base hardenability results in an increase in susceptibility to temper embrittlement, it is suggested that this effect should be countered by the addition of 0,2 to 0,3 per cent molybdenum.

Jan 1, 1984

By P. Kitobo, T. Nduba, D. Mbay, J. B. Vangu, R. Ciband

The flotation plant tailings at Kamoa Copper Mine concentrator were found to contain a high proportion of extremely fine particles. The potential issues with settling these fine solids were resolved by the use of a poly-di-allyl-di-methyl ammonium chloride (DADMAC) coagulant, Flobead DB 45 VHM, in conjunction with a standard anionic polyacrylamide flocculant. This paper outlines some of the issues encountered and how they were resolved at the Kamoa concentrator. The potential to use this process and technology at other sites is also considered

Jan 1, 2023

By C. C. E. Pretorius, V. M. Mathoho, A. van Zyl, R. J. Mostert

The in-service degradation of the mechanical properties of steel components through the damage mechanism of high temperature hydrogen attack (HTHA), is a topic of concern in the refining and green hydrogen industry. This damage mechanism occurs in susceptible steels operating in environments at high temperatures and hydrogen pressures. The current investigation deals with the indirect monitoring of mechanical degradation via tracking of the swelling strain in affected structures. An autoclave with an AISI 316 shell was utilized to simulate accelerated HTHA damage at 550 °C and 46 bar for exposure times ranging from zero to 700 hours. The progress of the HTHA damage was tracked using encapsulated high-temperature strain gauges. The correlation between the swelling strain and mechanical property degradation was studied to develop a methodology for the continuous monitoring of embrittlement. The tensile sample orientation of the carbon steel plate was included as a variable, i.e., samples parallel, transverse, or perpendicular to the plate rolling direction were included, since it has been shown that the sample orientation influences the HTHA damage features. For the through-thickness orientation, and upon exceeding a threshold value of exposure time, all tensile properties were severely degraded, with values in the order of a 90 per cent reduction being observed. It was found that the degradation of carbon steel mechanical properties can be correlated to the swelling strain measured during exposure. The critical point for mechanical property degradation in the plate through-thickness orientation, whereafter a severe decrease in the ductility of the material occurs, was found to be in the order of 1% of the total swelling strain measured during exposure, equivalent to 65 microstrain. This threshold was found to be significantly lower than that expected from the literature, where limits of 400 to 1000 microstrain were postulated.

Nov 27, 2024

By H. Möller, M. Tshibalanganda, C. Taute, A. du Plessis, M. Leary

Additive manufacturing can be used to produce complex and custom geometries, consolidating different parts into one, which in turn reduces the required number of assemblies and allows distributed manufacturing with short lead times. Defects, such as porosity and surface roughness, associated with parts manufactured by laser powder bed fusion, can severely limit industrial application. The effect these defects have on corrosion and hence long-term structural integrity must also be taken into consideration. The aim of this paper is to report on the characterization of porosity in samples produced by laser powder bed fusion, with the differences in porosity induced by changes in the process parameters. The alloy used in this investigation is AlSi10Mg, which is widely used in the aerospace and automotive industries. The sample characteristics, obtained by X-ray tomography, are reported. The design and production of additively manufactured parts can be improved when these defects are better understood.

Apr 1, 2021

By Q. G. Reynolds

The presence of dust and fume suspended in the freeboard region is a common feature of the operation of direct current (DC) plasma smelting furnaces. This occurs primarily as a result of the use of fine feed materials together with the open-arc, open-bath operation of such smelters, and is exacerbated by the high velocities and turbulent mixing of the gas in the vicinity of the arc jet. Dust and fume losses into the furnace off-gas system can be significant in some cases and may have economic, operational, and environmental impacts on the process. A computational modelling study is presented in which the concentration of dust material was considered as a continuous field subject to a governing partial differential equation. Settling behaviour was calculated as a function of particle size, local gas/plasma temperature, and other physical properties. Development of the coupling between the concentration field and a magneto-hydrodynamic description of the arc is shown, and the resulting models were used to compute various aspects of the behaviour of the concentration field in the arc region for a variety of furnace conditions. Time-averaged as well as transient models of the arc were used to generate the results presented. Qualitative case studies produced several practical suggestions for furnace operation, including increased dust capture by the bath when feed ports are located closer to the electrode, and the possible effects of feed segregation in the furnace freeboard based on dust particle size and density.

Jan 1, 2014