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By W. E. Wallace, V. Castranova, P. Hathaway, F. H. Y. Green, E. D. Recad, V. Vallyathan, M. J. Keane

Inhaled particle contact with pulmonary surfactant in the hypophase lining pulmonary alveoli was modeled in vitro by exposing two respirable sized dusts, kaolin and silica quartz, to lecithin, a major component of pulmonary surfactant, emulsified in physiologic saline. Lecithin adsorbs to the dusts upon incubation at 37º C and suppresses their cytotoxicity as measured by pulmonary macrophage and erythrocyte assays, suggesting that pulmonary surfactant provides a defense system against prompt cell membrane lysis by inhaled dusts. Subsequent pulmonary macrophage phagocytosis and lysosomal enzyme digestion of the coated dusts was modeled in vitro by incubation with phospholipase A2 for one hour. With increasing lipase activity, silica hemolytic potential was restored to native silica levels. Kaolin was retoxified to levels far in excess of native kaolin hemolytic potential. Elution, thin layer chromatography and phosphate assay of treated dusts indicate most lecithin on silica is digested to lysolecithin and desorbed, silica retoxification being due to surface and adherent lysolecithin effects. Most lecithin on kaolin is not digested in this same time; that which is results in adherent lysolecithin which is responsible for the kaolin retoxification. Digestion with phospholipases A2 and C together produces only weakly retoxified kaolin. Results suggest that surface adsorption properties which control the adherence of prophylactic surfactant distinguish the pathogenic potentials of quartz, kaolin and mixed dust.

Jun 1, 1988

By LB. Berger

"INTRODUCTION The use of gasoline engines as the motive power for lift trucks, tractors, and other types of mobile equipment operated in enclosed spaces, such as industrial plants and warehouses, may create a hazard because of the carbon monoxide present in the exhaust gases of the engines; gasoline-powered equipment should not be used in mines or tunnels. Because the equipment is mobile, local ventilation usually is impracticable, and general ventilation of the spaces is nec-essary to dilute and remove the carbon monoxide. To estimate the rate of ventilation required in such situations, information is necessary on the concentration of carbon monoxide in the exhaust gas and the rate at which exhaust gas is produced under given operating conditions. The purpose of this paper is to present data that may be used in making estimates of ventilation requirements.COMPOSITION OF GASOLINE-ENGINE EXHAUST GASThe exhaust gas of a gasoline engine consists mainly of carbon dioxide, carbon monoxide, hydrogen, oxygen, and unburned hydrocarbons (usually reported as methane), together with the nitrogen present as a residue from the air sup-plied for combustion. 3/ The exhaust also contains water vapor resulting from combustion of the hydrogen of the fuel. The water-vapor content is not included in exhaust-gas analyses calculated on a ""dry"" basis and is not involved in the estimation of ventilation requirements."

Jun 1, 1947

By Chas F. Jackson

 The annual reports of the supervising engineers of the several sections of the Mining Division are assembled herein and comprise the annual report of the division. During the year under review the work was oriented entirely to the war program by applying apparatus and technique previously developed in research directly to war problems, as well as by intensified search for and exploration of deposits of minerals necessary in the war.

Oct 1, 1942

By Pablo Velasco

The Ecuadorean mineral sector and overall economy have retained their traditional dependence upon the production and export of hydrocarbon products. Exports of crude oil and its products accounted for 62% of the country's export earnings in 1985. Ecuador's major mineral commodities produced and exported were cement, gold, limestone, liquefied natural gas, liquefied petroleum gas, natural gas, natural gasoline, crude petroleum and condensate, raw steel, semimanufactured steel products, and sulfur.

Jan 1, 1987

By Fred N. Kissell

Methane-flow and pressure data taken from a mine in the Pocahontas No. 3 coalbed are compared with flow rates from lump coal obtained in laboratory experiments. From this, it is concluded that the main source of gas is the intact coalbed rather than a "crushed zone" near the working face. The permeability and sorption capacity of the intact coalbed are calculated and gas emission rates are theoretically accounted for.

Jan 1, 1972

By Fred N. Kissell

Methane-flow and pressure data taken from a mine in the Pocahontas No. 3 coalbed are compared with flow rates from lump coal obtained in laboratory experiments. From this, it is concluded that the main source of gas is the intact coalbed rather than a "crushed zone" near the working face. The permeability and sorption capacity of the intact coalbed are calculated and gas emission rates are theoretically accounted for.

Jan 1, 1972

By Kenneth C. Stewart

Eight brands (three samples of each kind) of commercially available audio-dosimeters were performance-tested. Each unit was placed in an anechoic chamber and subjected to various acoustic signals to measure its A-weighting response and overall integration accuracy. All units met the A-weighting tolerance for type II sould level meters, and six brands were within the Bureau I s overall accuracy requirements of ±2 dbA referred to input.

Jan 1, 1974

By W. W. Weller

Low-temperature heat capacity measurements were conducted, and entropies at 298.15° K were evaluated for sodium monomolybdate (Na2Mo04), magnesium monomolybdate (MgMo04), and calcium monomolybdate (CaMo04). The 298.15° K entropy values were sodium monomolybdate, 38.1±0.3 cal/deg mole, magnesium monomolybdate, 28.4±0.2 cal/deg mole, and calcium monomolybdate, 29.3±0.2 cal/deg mole.

Jan 1, 1963

By E. V. Cilento, K. A. DiGregorlo, R. C. Lantz

A kinetic model was developed to describe the production of superoxide (02) by single pulmonary alveolar macrophages (PAM). Model predictions were compared to experimental results obtained from single rat PAM. The O2 - was quantified by measuring the reduction of nitroblue tetrazolium (NBT) to a diformazan precipitate (NBTH2) from video-recorded images of individual cells. The kinetic model considered three reactions: (1) the production of extracellular 0 - from the reduction of oxygen by NADPH oxidase using intracellular NADPH as the substrate, (2) the subsequent dismutation of o2- to from O2 , and (3) the reaction of o2- and NBT. NBT specificity for o2- was analyzed by comparing results in the presence and absence of superoxide dismutase (SOD) which catalyzes the dismutation of o2- to H2o2. Measured PAM heterogeneity was accounted for by varying the concentration of intracellular NADPH, its rate of depletion, and the concentration of intracellular NADPH oxidase in the kinetic model. Model predictions compared favorably with experimental results except when SOD was present. This discrepancy may be due to diffusional limitations since NBT is a relatively small molecule (818 MW) compared to SOD (34000 MW). In addition, the cell surface is both ruffled and negatively charged, which may introduce steric hindrances and/or electrostatic effects since SOD is also negatively charged.

Jan 1, 1988

By T. E. Marshall, D. R. Dolinar, C. S. Cornpton, L. J. Prosser, A. T. Iannacchione, D. C. Oyler

The U.S., Australian, and United Kingdom coal and the Canadian hard rock mining industries have long recognized the significance of high horizontal stresses as a factor affecting the stability of roof and rib conditions in underground mines. Recently, a growing segment of the U.S. underground stone mining industry has also begun to recognize that horizontal stresses occur in some of its more than 90 mines. Considering the typically high strength and massive nature of limestone, this fact is a revelation in itself. High horizontal stresses produce extensive and sudden rock failures and, in some cases, resulted in injuries to mine workers. Through the years diverse control strategies have been proposed and experimented with. Reorientation of mine entries to reduce stress concentrations have proven successful and are widely accepted in practice. Other solutions, like rock reinforcement, are poorly understood and less accepted in practice. It is the purpose of this National Institute for Occupational Safety and Health (NIOSH) study to develop a better fundamental understanding of these ground control strategies under high horizontal stress conditions through a series of field and laboratory studies. To this end a design technique is presented which provides stone miners with a method for making stability assessments. The consequences of widening rooms, changing geology and horizontal stresses, and different rock bolts on roof beam failures are discussed.

By Brian White, Hamid Maleki

Sudden, violent failures of rock around mine openings influence access, ventilation, and safety in both hard-rock and coal mines. To develop predictive tools for assessing the potential for violent failure, the authors initiated a comprehensive study using (1) multiple linear regression and numerical modeling analyses of geological and mining conditions at 25 sites to identify the most significant factors contributing to stress bumps in coal mines and (2) investigations of the geological and mining factors contributing to rock bursts in the Coeur d'Alene Mining District of northern Idaho, particularly the influence of preexisting structures on rock bursts. Twenty-five factors were initially considered in the study of coal bumps. The most important variables were identified as (1) mechanical properties of strata, (2) gate road geometry and/or gate pillar factors of safety, (3) roof beam thickness, joint spacing, and stiffness characteristics, and (4) stress gradients associated with previous mining and anomalous geologic conditions. In the Coeur d'Alene district, burst damage related to preexisting structures results primarily from (1) sudden buckling and crushing of rock layers where surfaces of development and production openings lie at low angles to bedding, faults, or other planar structures and (2) disturbance of loose ground caused by seismic fault-slip on preexisting faults or previously sheared bedding planes that intersect veins near pillar-stope margins.

By Arno C. Fieldner

In connection with investigations relating to fuels belonging to or for the use of the United States Government, the causes of accidents in coal mines, the geologic relations of coal beds, and the character of the coal and the value of the fuel in the public lands, many mine samples of coal are analyzed each year in the laboratories of the Bureau of Mines. The systematic collection and analysis of coal samples in connection with investigations of fuels was begun in 1904 at the Government fuel-testing plant at the Louisiana Purchase Exposition, and was under the direction of the United States Geo- logical Survey for six years. Descriptions of the coal samples col- lected in connection with these investigations between the beginning of this work, July 1, 1904, and the transfer of the fuel-testing and mine-accident investigations to the Bureau of Mines, July 1, 1910, were compiled and published in Bureau of Mines Bulletin 22. The present bulletin presents analyses and descriptions of samples collected during the fiscal years 1911 to 1913. In order that the material in this bulletin may be used to supplement that presented in Bulletin 22, the same plan of geographical classification has been fol- lowed, the analyses and descriptions of the samples being grouped in alphabetical order according to the State, county, and town near which the mines or prospects sampled are situated.

Jan 1, 1914

By Liming Yuan, Charles D. Litton

This paper presents experimental results for conveyor belt flame spread from tests conducted in a small-scale tunnel. The purpose of this study is to investigate the effects of belt type, ventilation velocity, belt surface-to-roof distance and ignition source power on the flame spread properties. The tunnel used was 4.9 m long by 0.46 m square with the ventilation velocity ranging from 0.7 to 3.2 m/s. The ignition source was an impinged methane jet burner with heat output ranging from 7 to 21 kW. The belts tested included non-fire resistant rubber belts, fire-resistant rubber belts, fire-resistant neoprene belt and fire-resistant PVC belt with belt samples measuring 0.23 m wide by 2.5 m long. Experimental results show that with a ventilation velocity of 1.02 m/s all conveyor belts could be ignited, and that with sufficient ignition source power, flames spread the full length of the belt sample. The data showed a coupling effect of the ventilation air velocity and the belt surface-to-roof distance on the flame spread rate. For instance, flames could not spread with a ventilation velocity higher than 1.52 m/s and a surface-to-roof distance of 0.22 m. The use of the measured CO/CO2 ratio as an indicator of combustion stoichiometry is also discussed.

Provide the U.S. mining industry with the means to measure and control exhaust emissions of diesel engines used in underground mines. Approach Diesel research is divided into four primary areas: exhaust aerosol measurement, particulate control, gaseous emission control, and chemical and biological characterizition of particulate matter. Diesel research is frequently cosponsored by industry; collaborative research ventures between industry, academia, other government agencies, and the Bureau arc common. Diesel research at the Bureau is conducted in the diesel engine research facility at the Bureau?s Twin Cities Research Center (TCRC). This facility is a state-of-the-art laboratory capable of performing emissions testing, exhaust control evaluations, and safety tests. Background Exposure of mine workers to airborne contaminants from diesel engine exhaust is potentially harmful. The National Institute for Occupational Safety and Health has recommended that whole diesel exhaust be regarded as "a potential occupational carcinogen" and that ?reductions in exposure to diesel exhaust in the workplace would reduce the risk." The U.S. Mine Safely and Health Administration (MSHA) convened an Advisory Committee on Standards and Regulations for Diesel-Powered Equipment and is beginning to implement its recommendations, which cover health, safety, and certification and approval issues surrounding the use of diesels underground. In January 1992, MSHA published an advance notice of proposed rulemaking to regulate diesel particulate matter in underground mines.

Jan 1, 1992

By R. V. Ramani, C. B. Manula, A. Owili-Eger

• MINE VENTILATION NETWORK PROBLEM (NATURAL SPLITTING; FIXED • QUANTITY BRANCHES; METHANE SIMULATION; NETWORK TOPOLOGY REVISION; • ABSOLUTE PRESSURE) • NFIXB = NO. OF FIXED QUANTITY BRANCHES • DD(I) = AIR QUANTITY ASSIGNED TO FIXED QUANTITY BRANCH I, IN KCFP • NFBPF = NO. OF FIXED QUANTITY BRANCHES PLUS FAN • NFBPFG = NO. OF FIXED QUANTITY BRANCHES PLUS FAN PLUS METHANE • EMISSION BRANCHES • NBWNVP = NO. OF BRANCHES WITH NATURAL.VENTILATION PRESSURE • NVP(I) = NATURAL VENTILATION PRESSURE ASSOCIATED WITH • THE I-TH BRANCH • NF = NUMBER OF FANS • NB = NUMBER OF BRANCHES • MAXIT = MAXIMUM NUMBER OF ITERATIONS • MAXJ = MAXIMUM NUMBER OF JUNCTIONS • NJ = NUMBER OF JUNCTIONS INVOLVED IN THE SOLUTION * NM = NUMBER OF MESHES • NP = NO. OF POINTS TO DESIGNATE FAN CHARACTERISTIC * Q = QUANTITY OF AIR FLOW IN KCFM • R = RESISTANCE OF AN AIRWAY • WIDTH = AIRWAY DIMENSION • LENGTH = AIRWAY DIMENSION • HEIGHT = AIRWAY DIMENSION • SUMNVP = SUMMATION OF NATURAL VENTILATION PRESSURE FOR ANY MESH • X (I) = QUANTITY OF AIR, IN KCFM, ASSOCIATED WITH THE I-TB POINT • ON A FAN CHARACTERISTIC • E = ERROR FOR CONVERGENCE • FF = FRICTION FACTOR • FX(I) = FAN PRESSURE, INS INCHES OF WATER GAGE, CORRESPONDING • • TO A QUANTITY X(I) • H = HEAD LOSS IN INCHES OF WATER GAGE • I = BRANCH NUMBER • J, J1, J2 = JUNCTION, J1 AND J2 ARE TWO NODES WHICH DEFINE A • BRANCH • KEY = NO. WHICH SIGNALS THE TYPE OF FAN CHARACTERISTIC TO BE • EXPECTED

Jan 1, 1975

By Ruth A. Holmes

A Bureau of Mines method for recovering nickel, cobalt, and copper from low-grade domestic laterites is described, which includes the unit operations of solvent extraction and electrowinning. Previous Bureau work indicated that addition of Na2S04 (sodium sulfate) to the nickel electrolyte improved current efficiency in nickel electrowinning. The present study determines the compatibility of Na2S04 with nickel strip-ping in the solvent extraction operation of the Bureau method. The effect of adding 100 g/l Na2S04 on nickel stripping, phase disengagement, and pH was determined in comparative laboratory-scale tests. In continuous-circuit testing, Na2S04 reduced stripping efficiency to the extent that five, instead of four, strip stages were required for complete stripping of nickel from the loaded solvent. In tests made in a phase-disengagement cell that had a variable settler area, the addition of Na2S04 did not significantly affect phase separation characteristics. The pH of the nickel electrolyte in the temperature range of 20° to 65° C was also unaffected by the addition of Na2S04. An economic evaluation showed that the energy saved by adding Na2S04 to the electrolyte would more than offset the cost of adding another stripping stage.

Jan 1, 1983

By T. M. Klemetti, G. M. Molinda, D. M. Pappas

Some of the most difficult coal mine roof in the U.S. can be found in the Illinois Basin. Factors contributing to the high roof fall rate include: weak moisture-sensitive roof rock, high horizontal stress, and limited longwall mining. The depth of cover ranges from 90-1,000 ft and roof damage from horizontal stress can be severe. Moisture sensitive-roof rock is common above the Springfield-Harrisburg Herrin #5 and #6 seams in the Illinois Basin, and contributes to roof skin deterioration. The roof fall rate increases significantly in the humid summer months. The National Institute for Occupational Safety and Health (NIOSH) has shown, using lab and field studies, that highly moisture-sensitive roof rock can be directly correlated to poor roof conditions. Controlling the skin is the key to reducing rock fall injuries, and roof screening is, by far, the best remedy. Illinois Basin coal operators have been successful in reducing the number of rock fall injuries in recent years. NIOSH has documented best practices for screen installation which has resulted in safe, efficient operations. Other solutions to skin failure include: the use of denser five bolts per row patterns to reduce spans between bolts, systematic supplemental support in intersections, straps and large pans protecting operators, and air conditioning to remove moisture from the intake air.

By Earl C. Lane

This is the second of a series of reports on a survey of petroleum products manufactured on the Pacific Coast from California crude oils. California crudes differ in many characteristics from the petroleum produced in other parts of the United States, and the claim has been made that some of the present federal Specifications for petroleum products tend to discriminate against California products. The purposes of the present survey are to determine what particular specification requirements California petroleum products characteristically fail to meet, how widely the products deviate from these requirements, and if possible to show whether the fault lies with the specifications or the products, or along what 'lines investigation to determine the question should proceed. The first report* of the series gave the physical and chemical properties of gasoline and mineral spirits made from California crudes. The present report deals with lubricating oils. Sixty-one samples of lubricating stocks and finished commercial products were generously donated by four of the large refining companies of California. Fifteen samples of automobile lubricating oils, made in California from California crudes, were purchased in the open market. Nine samples of lubricating oils mode from Gulf Coast crude were contributed for comparison by a company in Texas. The refining companies have continued the helpful and cordial cooperation shown by them in connection with the earlier work of the survey.

Jan 1, 1923

By Joseph C. Zelanko, Anthony T. Iannacchione

One of the most difficult and longstanding engineering problems associated with coal mining is the catastrophic failure phenomenon known as coal mine bursts (known in the United States as bumps). For more than 70 years, researchers and practitioners have attempted to determine whether this destruction observed underground is caused by stress conditions within the coal pillar or from distant seismic sources in the mine roof and floor strata. The role of confinement and the extent of failure in solid pillars and panels have also proven difficult to define. These are important issues, since control solutions need to be based on a fundamental understanding of the problem. Obsenations by U.S. Bureau of Mines researchers over the last decade have helped to clarify certain aspects of these issues. Microseismic sensors and geomechanic field measurements have located areas of excess energy release, identified stress conditions in coalbeds close to failure, and recorded the response of mine structures prone to bursts. In the present study, data available for a range of U.S. bursts were considered in an effort to evaluate both common and distinctive features. Although the attempt revealed little commonality, encouraging results were produced by categorizing coal bursts by source mechanisms. When a coal burst is thus categorized, differences in environmental factors-such as geology, stress fields, and mining methods-are highlighted, and viable control strategies are readily recognized.

By Karl R. Becker

Detonators representing a sampling of various domestic commercial delay detonators were fired at various direct-current (dc) firing levels. Results of firings using well-below-recommended firing levels showed marked increases in delay times above the nominal values. There was also a marked increase in variation, to the extent that out-of-sequence firings would be essentially assured in any typical blasting round at these low firing levels. Within the range of recommended levels the effects of current increases were not considered to be of great importance relative to other overriding effects, such as the significant difference noted in average values of detonators from different lots having the same nominal delay. This effect, when combined with the normal variation noted among members from the same lot, would cause out-of-sequence firings with detonators from a neighboring delay period. Where comparisons with results from another study were possible, it was found that both studies observed quite similar variations in delay times about the average values, and a lower probability of out-of-sequence firings for the shorter delay period groups. The criterion of the previous study for assessing the likelihood of observing out-of-sequence firings, when applied to the Bureau of Mines data, properly identified two neighboring delay period groups where out-of-sequence firings would occur.

Jan 1, 1981