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By Wilbert T. Malenka

In its search for a highly productive mining system for anthracite beds pitching from 100 to 200, where conventional mobile equipment cannot be used) the Bureau initiated a longwall project by introducing a shearer drum cutter loader of European origin. Because of the undulating nature of the roof and floor and changing bed thicknesses, the machine proved inflexible and extra work was required in lifting bottom coal and blasting top coal.

Jan 1, 1966

By W. F. Hughes

The thermodynamics of an electromagnetic field-fluid interaction system is discussed. A review of the thermodynamics of linear media (the permittivity and permeability taken as functions of density and temperature) is presented; then an extension is made to nonlinear media (the permittivity and permeability taken as functions of the fields). Expressions for thermodynamic properties and reversible work are derived and the first law of thermodynamics for magnetohydrodynamic flow is discussed.

Jan 1, 1968

By D. Cummins

This Information Circular presents a brief history of the lead-acid battery and describes ways to prevent serious injury from battery explosions when servicing and charging lead-acid batteries, particularly in the surface mining industry. The Mining Safety and Health Administration (MSHA), U.S. Consumer Product Safety Commission, battery manufacturers, and the mining industry have all contributed information as well as recommendations for injury-free handling for this report.

Jan 1, 1980

By Dennis Dolinar, Christopher Mark, Gregory M. Molinda

In 1999, 2,087 unplanned roof falls were reported from 841 mines. Nearly 55% of all mines reported at least one roof fall, and nearly 17% of the mines reported five or more falls. In order to investigate the variables that contribute to roof falls, the National Institute for Occupational Safety and Health (NIOSH) compiled a national database of roof performance from 37 coal mines. Geotechnical factors and their effect on roof fall rates were compiled from over 1,500 miles of drivage. The factor that is the best predictor of roof fall rate is the Coal Mine Roof Rating (CMRR). For a low CMRR (#30), almost all cases have high roof fall rates. Conversely, high roof fall rates are rare for strong roof rocks (CMRR $ 60). Roof fall rates were also higher in deeper mines, probably because of greater stresses. Intersections were much more likely to fall than roadways, and four-way intersections were more prone to fall than three-way intersections. In a controlled comparison of the effect of increasing bolt length on roof fall rates, it was found that longer bolts reduced the roof fall rates in 11 of 13 cases. A relationship between the roof fall rate, the intersection span, and the CMRR was also found. Finally, a systematic method for tracking roof performance and geotechnical variables was demonstrated.

Jan 10, 2000

Reduce longwall equipment transfer time between panels by utilizing a predriven recovery room, and thus eliminate the premove preparation associated with most equipment recovery methods. Background and Approach The recovery point for a retreating longwall is a predetermined position near the end of the panel where mining is terminated and equipment is disassembled and removed. However, to prepare for equipment removal at the recovery point, bolting and wire meshing arc required before the recovery point is reached. Usually, preparations for equipment recovery begin about 35 ft from the recovery point, significantly impeding the normal rate of advance of the longwall and, consequently, production. Recently, BethEnergy Mines, Inc., and the Bureau of Mines cooperated to evaluate the applicability of utilizing predriven recovery rooms to improve longwall equipment recovery. A predriven recovery room is an entry driven parallel to the longwall face at the end of the panel, having standard dimensions (for that particular mine) and supported with bolts, wire mesh, and supplemental support. The preparation of this entry is completed before it experiences mining-induced effects from the approaching longwall face. This enables the face to continue to mine at its normal rate of advance until the panel is completed. The supplemental support is required to control the loads imposed by the front abutment and is the most vital component of the recovery room.

Jan 1, 1989

A construction material based on plasticized sulfur and mineral aggregate, that is superior in corrosion resistance and strength to portland cement concrete. The material can be used in the chemical, metallurgical, and fertilizer industries, and will also provide an attractive market for by-product sulfur resulting from compliance with pollution regulations. How It Is Made Sulfur concrete is thermoplastic material. Plasticized sulfur is mixed with sand and gravel aggregate heated to 375-400° F. The sulfur melts and acts as the binder or cement. The sulfur concrete is poured hot and sets at a temperature of 200° F. Full strength is attained in a few hours, compared to several days for portland cement concretes. Sulfur concrete even pours and sets in freezing weather. Although unmodified sulfur with aggregate will produce a sulfur concrete with good initial properties, it undergoes crystallographic modifications, and deteriorates with time, particularly when exposed to moisture or freeze-thaw conditions. The Bureau of Mines has developed plasticizers which, when reacted with the sulfur, give sulfur concretes with excellent moisture and freeze-thaw resistance. The plasticizers are based on mixtures of dicyclopentadlene (DCPD) and ollgomers of cyclopentadiene. About 5 percent by weight of the plasticizers is reacted with molten sui fur for several hours. The sulfur cement can be used directly or allowed to solidify for easier handling and storage.

Jan 1, 1981

By Seth C. Schaefer

The Bureau of Mines investigated thermodynamic properties of Mn304 (manganomanganic oxide) and Mn203 (manganese sesquioxide). The standard Gibbs energies of formation (?Gf°) of Mn304 and Mn203 from their lower oxides were determined with high-temperature galvanic cells using stabilized Zr02 (zirconia) as the electrolyte. Potential measurements were obtained for the cell Pt, MnO, Mn304//Zr0 2//02(g, 0.0112 atm), Pt, with the overall cell reaction 6Mn0(c) + 02(g, 0.0112 atm) = 2Mn304(c), where- 02 refers to indicated partial pressure of oxygen at the reference electrode. Similar measurements were obtained for the cell Pt, Mn304, Mn203//ZrO2//02(g, 0.0115 atm), Pt, with the overall cell reaction 4Mn304(c) + 02(g, 0.0115 atm) = 6Mn203(c). Equilibrium oxygen pressures for the Mn0-Mn304-02 and Mn304-Mn203-02 systems were measured and may be expressed for the respective systems as [23,400 109 P02 T + 11.91 (764.9 - 1,208.6 K) and log p02 = - 11,957 + 9.66 T (968.6 - 1,208.2 K),] where pressure (p02) is in atmospheres and temperature (T) is in kelvins. Standard thermodynamic properties of Mn304 and Mn203 were derived from these measurements and auxiliary thermodynamic data from the literature.

Jan 1, 1982

By Bruce D. Sartwell

The Bureau of Mines is using characteristic X-rays produced by proton bombardment of a solid surface to provide quantitative compositional analyses of surface layers of metals. An integral X-ray yield equation has been developed that quantitatively relates the measured X-ray yield to the thickness of thin films ranging from less than a monolayer to several thousand angstroms. The use of the integral yield equation is demonstrated for the growth of a thin film by vacuum evaporation. Results are presented that show haw proton-induced X-ray emission (PIXE) has been used to determine the oxidation kinetics of iron that had been implanted with several different species of heavy ions. The sensitivity of PIXE for the measurement of very-thin-film growth kinetics is demonstrated from studies of the effect of fractional mono-layer coverages of sulfur on the initial oxidation kinetics of iron. Results are also presented in which PIXE has been used to study the redistribution of alloying elements in components of a gas turbine that had fractured due to corrosion fatigue. By combining PIXE with low-energy ion sputtering, quantitative composition depth profiles of surface layers are obtained. Examples are presented for the profiling of iron samples implanted with 25-kev nickel ions and for a platinum coating on an Fe-5Cr substrate.

Jan 1, 1980

By Peter J. Clarke

Afghanistan's mineral industry continued to be dominated by the production and export of natural gas, although several mining and related industrial projects, all under the supervision of Soviet technicians, were in the planning stage in 1982. Afghanistan produced minor quantities of barite, cement, coal, fertilizer materials, iron, and lapis lazuli, all for domestic consumption.2 Large-scale projects being investigated were a copper mine and concentrating plant at Ainak, extensive mining of the Hajigak iron ore deposit near Kabul, construction of an oil refinery at Angot, increasing production and processing of natural gas, and implementing an intensive geologic prospecting and exploration program for areas of mineral potential. Afghanistan's gross domestic product (GDP) was estimated at $2.76 billion3 and has remained stagnant for the past several years. Total exports in 1982 were estimated at $700 million, only a marginal increase from the 1981 figure of $694 million. Exports of natural gas to the U.S.S.R. earned $385 million in 1982, representing just over one-half of Afghanistan's total exports. Natural gas revenues were down approximately 11% from the 1981 level, owing primarily to increased antigovernment activity in the northern part of the country.4 About 90% of the country's natural gas production was exported to the U.S.S.R.5 About 38% of Afghanistan's development budget had been earmarked for mining and industrial projects in 1982.6

Jan 1, 1984

By William P. Diamonds, David C. Oyler

Stimulated vertical boreholes are an effective means of removing gas from coalbeds in advance of mining. This Bureau of Mines report examines the coal mine roof damage potential of stimulation treatments. Twenty-two Government-sponsored stimulation treatments have been mined through to determine the effects on the coalbed and roof strata. Vertical fractures in the coalbed were discernible for most treatments and horizontal fractures were present for about half of the stimulations. Sand-propped vertical fractures were usually short in lateral extent. Evidence of stimulation fluid movement could generally be traced beyond the maximum extent of sand-filled fractures when fluorescent paint was added to the treatment fluids. The maximum lateral extent for a sand-filled vertical fracture was 416 ft and a paint-coated vertical fracture extended 630 ft. Horizontal fractures were generally found within bedding planes, most commonly on top of the coalbed. The maximum lateral extent for a horizontal fracture was 265 ft at a coalbed depth of 630 ft. Horizontal fractures have been found to occur as deep as 1,145 ft. Penetration of strata overlying coalbeds was observed in nearly half of the treatments intercepted. Most of these occurrences have been interpreted to be penetrations into preexisting joints. No roof falls or adverse mining conditions were encountered that could be attributed to the stimulations.

Jan 1, 1987

By L. C. IlsLey

The Burrell methane indicator developed by Col. G. A. Burrell in 1915 was modified during 1918 to the " insulated type " Burrell indicator . Though this instrument has been used in mines since its first introduction , it was not formally approved as safe and efficient for use in gaseous mines until March , 1922. The indicator is built by the Mine Safety Appliances Co. , Pittsburgh , Pa . Approval No. 800 has been assigned to this company covering the device in the form approved . The principle of the Burrell indicator is fairly well known . It works on the same principle as the Haldane apparatus - measuring by means of a graduated scale , the contraction resulting from burning the methane content of an air and gas sample . A given aniount of the mine atmosphere to be tested for methane is taken into the indicator . This sample is then thoroughly shaken with the water in the indicator for one minute . The methane in the sample is now burned for two minutes by a heated platinum coil , which is energized by a small storage battery containing two Edison cells connected in series . After the glower or coil has burned for two minutes , it is disconnected from the battery , and the indicator is again shaken for The amount of contraction observed by reading the height the water rises in the U- tube of the indicator , which is calibrated to register the percentage of gas in the sample . The indicator as approved by the Bureau of Mines is equipped with an Edison M- 8 mine- lamp battery , and with a glass and scale graduated from zerɔ tɔ four per cent methane . The approval of a corbination service that is , an attachment for giving illumination from the same battery from which the platinum glower is operated has been withheld pending the development of a battery with larger capacity . - Under laboratory operating conditions , a single glower was capable of making at least 20 determinations if proper precautions were observed with respect to the use of freshly charged batteries . A battery should be allowed to stand off charge several hours before using in an indicator , as the peak voltage of a freshly charged Edison cell is abnormally high and is likely to send enough current through the glower to melt the platinum wire . Fifty-seven satisfactory operations were obtained from a completely charged battery . The point where the voltage of the cell fell below 2.3 volts with the glower attached was taken as the lower limit of successful operation . A voltage less than 2.3 does not permit the lower to burn at a temperature that will completely burn the gas in the air , thus giving a false indication .

Jun 1, 1922

By Peter. PH. D. Cain

Smoky River Coal Ltd. mines low-volatile metallurgical coal by surface and underground methods in the foothills of the Rocky Mountains of Alberta, Canada. Current underground operations are confined to the 5B-4 Mine. Development of 5B-4 began in January 1998; production from depillaring sections commenced in July 1998. This paper describes the history of underground mining on the Smoky River property in terms of extraction methods and pillar design. The development of the present pillar design guidelines is discussed in this context. Recent work to prepare a number of case histories for back-analysis using the Analysis of Retreat Mining Pillar Stability (ARMPS) method is described, along with the modifications developed for calculating the ARMPS stability factor for retreat extraction of thick seams. The design criteria are described, as well as the geotechnical program implemented in order to verify its applicability.

Jan 5, 1999

By G. B. Atkinson

Properties of catalysts prepared from intermetallic compound precursors were investigated by the Bureau of Mines as part of its mission to decrease U.S. dependence on foreign sources for scarce catalytic materials, such as nickel, cobalt, and chromium. Methods were developed whereby catalysts with surface areas of 30 to 40 m2/g were prepared from intermetallic compounds. Activity of these catalysts for the methanation reaction and methanol synthesis was deter-mined using a fixed-bed, single-pass, flow-through reactor. Catalysts prepared from rare-earth-nickel intermetallics had specific activity for methanation that was five times greater than that of commercial catalysts and were equal to or better than commercial catalysts with regard to sulfur tolerance. Under identical reaction conditions, catalysts prepared from thorium-copper intermetallics produced more than 10 times as much methanol as a commercial low-pressure catalyst and exhibited a high degree of catalytic stability.

Jan 1, 1982

By Wilton Johnson

Native asphalt was produced by four companies in two States, Texas and Utah. Bituminous limestone, used primarily as a paving material for street and road repair, was produced by one firm. R. L. White Co., Dabney Quarry, Uvalde County, TX. Gilsonite, a solidified hydrocarbon found only in Utah and Colorado, was mined by three firms: American Gilsonite Co., a division of Chevron Resources Co. (a subsidiary of Standard Oil Co. of California); Ziegler Chemical and Mineral Corp.; and Hydrocarbon Mining Co. (a subsidiary of Oberon Oil Inc., a Utah corporation), from properties in Uintah County, UT. Gilsonite is used for a variety of purposes including automobile bodysealer, light-weight aggregate for cement used in oil well drilling, asphaltic building board, protective coverings, anticorrosive paints, and roofing compounds. Gilsonite production in 1985 declined 57% owing primarily to reduced oil well drilling activity. The value per ton was essentially unchanged.

Jan 1, 1987

By Willard L. Hunter

The separation of tantalum and columbium by solvent extraction was under-taken as part of the Bureau of Mines research program to improve methods for extracting, separating, and reducing these elements to metal. The diethyl ketone aqueous HCl-HF system was one of several systems studied to determine the effect of metal and acid concentrations in aqueous solutions upon the transfer of tantalum and columbium into selected ketones. The tantalum-columbium oxide mixture used in this investigation was obtained by chemical extraction from Geomines slag. The investigation showed that tantalum 99.4 percent pure and columbium 97.2 percent pure can be produced by the selective transfer of tantalum into diethyl ketone from a solution of 2-N HF and 1-N HC1. The relatively low acid concentration necessary for tantalum transfer and the excellent selectivity of the system recommend its use for the separation of tantalum and columbium.

Jan 1, 1961

Provide mine personnel with a convenient means of determining the optimum installation geometry of roof trusses in bedded roof. Background Mine operators frequently ask the following questions concerning roof truss installations: 1. Where should the bearing plates or brackets be placed or where should the inclined holes be started? 2. At what angle should the holes for the inclined chords or angle holts be drilled? 3. What tension should be put into the inclined chords so as to achieve the most effective results for the effort and expense? Truss hardware manufacturers have responded to these questions with answers based on what seems to work best. While designs based on past experience are frequently reliable, there was a need for a rational approach that could accommodate a variety of conditions. The Bureau has developed a procedure that enables mine operators to optimize roof truss installations in bedded roof.

Jan 1, 1989

By James W. Vogh

The report covers initial findings in an experimental program to identify diesel exhaust odorants and determine their contributions to diesel odor. The approach was to isolate selected component groups from exhaust and to evaluate the contribution of each group to exhaust odor. Results were obtained for those carbonyls and phenols that could be isolated from exhaust through inter-mediate conversion to oxime derivatives. Unsaturated aliphatic aldehydes and sterically hindered carbonyls were not included. Hydrocarbons intermediate in the diesel range were "also evaluated and an odor contribution was found from those of the aromatic group. The evaluated carbonyls, phenols, and hydrocarbons were found to account for about 20 pct of the total odor in exhaust from an indirect-injection engine during idle. For exhaust from the indirect-injection engine operating under load and from a direct-injection engine at no load, these compounds were found to have no significant levels of odor.

Jan 1, 1972

By Robert L. Lagace, Alfred G. Emslie

This report presents a mathematical model for the propagation of UHF radio waves in the large cross-section tunnels of a room and pillar limestone mine, and describes the analysis of a small amount of propagation data obtained in a limestone mine. The model and analysis is based on the waveguide mode theory developed earlier for the transmission of UHF waves in coal mine tunnels, with allowance for propagation losses due to refraction into the tunnel walls, to scattering by wall roughness, and to long range random tilt of the walls. Propagation around corners and through pillars is also examined based on a ray theory approach, together with the beneficial effects of placing reflectors at intersections to significantly reduce corner losses. The theory is found to be in fair agreement with the data; however, additional in-mine measurements are needed to provide a more conclusive test of the model.

Jan 1, 1979

By W. A. Cole

This report covers the preliminary phase of an investigation of clays, shales, and certain rocks in Wisconsin to determine the feasibility of processing lightweight aggregate in the State. The study was extended to include rotary-kiln testing of a limited number of shale samples, and to an appraisal of the Maquoketa shale resources in eastern Wisconsin. A total of 45 samples of clays, shales, and other argillaceous rocks of Wisconsin were tested. The lower Maquoketa shale is the only material found to date that offers possibilities as a source of material that can be processed in a rotary kiln for lightweight aggregate. Bedrock occurrences of the Maquoketa shale are found in the eastern and southwestern parts of the State. The populous southeastern region of Wisconsin presents a large potential marketing area for lightweight aggregate. For this reason special study was directed to the Maquoketa shale in the eastern district.

Jan 1, 1961

By H. K. Kutter

The pressure pulse generated by an underwater spark \vas investigated in relation to its potential use for rock fragmentation. The study established (1) the relation between the peak discharge current and the peak wave pressure; (2) the relationships among the peak wave pressure, the discharge voltage, and the spark gap width; (3) the type and pulse duration of the generated wave; (4) the percentage of energy transmitted in the spark as a function of spark gap width and discharge voltage; and (5) the percentage of energy converted into the pressure wave as a function of gap width and discharge voltage. Spark-generated fractures were studied in two-and three-dimensional rock and plastic specimens. The laboratory results indicated that the pressure pulse generated by an underwater spark is a potential practical tool for rock fragmentation. The paper contains an appendix describing the capacitive pressure gage specially developed for the laboratory tests.

Jan 1, 1969