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By Jack C. White

The purpose of this Bureau of Mines work was to develop information useful in improving copper recovery during copper milling operations. Eleven copper mill tailings from the Western United States were subjected to froth flotation and cyanide leaching to provide an experimental basis for comparing their beneficiation response. Recoveries in flotation concentrates made from mill tailings ranged from 65 to 15 percent, at copper grades of 13 and 2.2 percent, respectively. Liberated copper sulfide minerals present in two samples were readily recovered by laboratory froth flotation. Nine of the samples were less amenable to froth flotation because of physical locking between copper sulfide minerals and gangue. Correlations among tailings indicated that recovery of sulfide copper by flotation was directly related to the sulfide copper content. Empirical equations derived from flotation data provided average values for unrecoverable copper and for recovery efficiency. Flotation response of copper mill tailings may be predicted from the equations. Data from cyanide leaching provides an equation describing the limiting high values for removal of copper by this method.

Jan 1, 1974

By T. J. Driscoll

In this Bureau of Mines investigation, the electrochemical polarization behavior of Fe and Fe-1BCr has been characterized in rigorously controlled 1[N] H2S04 solutions stirred with oxygen or an inert gas. Samples that under-went various levels of corrosion or passivation were examined using Auger electron spectroscopy (AES) and ion sputtering. Passivation of iron occurred at a potential of approximately 0.6 volt (1) in poorly stirred, oxygen-saturated solutions for forward polarization (scanning from cathodic to anodic potentials); (2) in pH-adjusted (increased), well-stirred, oxygen-saturated solutions for forward polarization; and (3) in well~ and poorly stirred, oxygen-and helium-saturated solutions for reverse polarization. Passivation of Fe-18Cr occurred at a potential of approximately -0.1 volt in helium-, nitrogen-, and oxygen-saturated solutions for all cases of forward polarization and most cases of reverse polarization. Elemental depth profiles obtained from AES sputtering measurements indicated that films or adsorbed species were present on iron samples in solution subjected to open-circuit, active, and transpassive corrosion, cathodic reduction, and passivation. This conclusion was reached by considering the distribution of the solution species, primarily sulfur, in the films, which were composed primarily of iron and oxygen. Sulfur was present throughout the films on actively corroding samples, in the outer regions of films of passive and transpassive samples, and on the film surfaces of open-circuit and cathodically reduced samples. For Fe-18Cr, sulfur was found on the surfaces of films on passive samples only, indicating that only the passive samples had films on their surfaces in solution. The films on electropolished and passive Fe-1BCr samples had the largest chromium concentrations, estimated to be approximately 45 at. pct, with less chromium in films of cathodically reduced, active, and open-circuit samples, in that order.

Jan 1, 1979

By Joan C. Biordi

In this research by the Bureau of Mines, slightly lean CH4-O2-Ar flames at 0.042 atm with and without small amounts of the inhibitor CF3Br were probed using molecular beam and mass spectrometric techniques. Ratios of product concentrations to reactant concentrations were formed and compared with the equilibrium constant for seven reactions--(l) H+O2 = OH+O, (2) O+H2 = OH+H, (3) OH+H2 = H2O+H, (4) OH+OH = H2O+O, (5) CO+OH = CO2+H, (6) Br+HBr = Br2+H, and (7) H+HBr =H2+Br--to determine to what extent they may be considered balanced in various regions of the flame. With the possible exception of reaction 4, none of the reactions are completely balanced until maximum flame temperature is reached. Once the reactions become equilibrated, their balance is maintained as the temperature and radical concentrations falloff in the secondary reaction zone. Reaction 7, in inhibited flames, is balanced at relatively low temperatures, comparable to reaction 4. Reaction 6 was found not to balance in either the secondary or primary reaction zones. Radical decay in the secondary reaction zone was analyzed using the pool-decay concept. The important recombination reactions were judged to be H+OH+M~H2O+M, and H+O2+M?HO2+M. A rate coefficient of 2x1016 cm6 mole-2 sec-1 is calculated for M = the burnt gas mixture of Ar, HaO, CO2, and 5x1015 cm6 mole-a sec-1 is calculated for M = Ar (both for T = 1,750±150 K).

Jan 1, 1977

By F. E. Brantley

Optimum autoclaving conditions were determined for separation of iron and manganese values from pregnant leach liquor produced in extracting manganese from low-grade umber are. The umber was leached with a synthetic anolyte similar to a recycle solution, used in manganese electrolysis cell operations, that had been renewed with ferrous sulfate and sulfuric acid. The equipment used and results obtained are presented for the several conditions employed. The kinetics of the separation were studied. Rate equations were derived for the formation of solid ammonium-manganese sulfate, (NH4)2 Mn2 (S04)3.

Jan 1, 1968

By C. Sunderman, J. Johnson, S. Signer

Researchers at the National Institute for Occupational Safety and Health have developed a miniature data acquisition system (MIDAS) that can measure resistance changes and temperature, store data for later retrieval, and illuminate LED lights. This instrument can be used with strain-gaged bolts, cable bolts, CSIRO stress-measuring gages, string pots, and any other instrument that uses single-ended, resistance-type gages. MIDAS has the capability to measure up to 16 gages at preset time intervals and store more than 2000 scans, yet is small enough to fit in a 35-mm hole. Because the MIDAS consumes little power, a 9-V alkaline battery will operate the system for 6 months. Data from the MIDAS can be sent to a PC via an RS232/RS485/IRdA port. A software program was written to set operation parameters, graph data, and store all information directly to a spreadsheet. Three LED lights change from green to yellow then red based on reading levels and/or rates of change. This feature can be used with different types of gages to warn miners of possible rock instabilities. The MIDAS has received MSHA experimental permissibility approval and is currently being tested at several mines.

By C. M. McKinney

Sulfur content data from Bureau of Mines routine analyses of 1,060 United States crude oils were used with crude oil production data for the years 1956-66 to prepare tables and charts that illustrate the volume and percentage distribution according to sulfur content of crude oil produced in 10 geographical areas of the United States. Similar relationships for foreign crude oils based on analyses of 201 crude oils and production during 1966 are illustrated for Africa, Canada, Middle East, and South America. Tables are included giving field name, sulfur content, geologic name and age of producing formation, depth of producing formation, and production during 1966 for 882 United States crude oils and 201 .foreign crude oils. Between 1955 and 1966 the average sulfur content of crude oils produced in the United States decreased from 0.73 to 0.67 percent.

Jan 1, 1967

By R. J. Hundhausen

The continued worldwide shortage and strategic value of nickel place great importance upon the continued development and exploitation of new sources of nickel in the United States, The deposits of nickel-bearing minerals in Oregon and Washington have attracted considerable attention, particularly since the Hanna Development Co. has engaged in development work aimed at producing ferronickel from the Nickel Mountain deposit, near Riddle, Douglas County, Greg. The Red Flats nickel deposit in Curry County, Oreg., was first examined by the Bureau of Mines in dune 1945, but it was not until 1952 that the deposit was drilled and sampled. In 1953, a 15-ton sample of Red Flats material was procured and subjected to continuous smelting tests in the Bureau's Northwest Electrodevelopment Laboratory, Albany, Greg.

Jan 1, 1954

By J. Douglas Causey

In 1985, at the request of the Bureau of Land Management, the U.S. Bureau of Mines studied a portion of the 110,000 acre Massacre Rim Wilderness Study Area (CA-020-1013). The area studied, containing 23,260 acres, is located in northwest Washoe County, Nevada, about 25 miles west of Vya adjoining the Charles Sheldon National Wildlife Refuge. Basalt caps older tuffaceous sedimentary rocks in an area that contains no claims or prospects. No mineral resources were identified during this investigation.

Jan 1, 1987

By Robert M. Becker

A multistage probability model for assessing the reliability of mineral samples following any number of stages of sample reduction is presented. Sample reduction is the process of alternately crushing or grinding and sampling mineral particles prior to assaying. The final multistage model developed accurately describes the ideal sample reduction practice. This model is based on previously developed and experimentally tested models for a single stage of sampling. The problem is approached through the probability distributions for the various stages of sampling. The probability distribution, moments, and moment relationships for a single stage of sampling are first reviewed, and the useful concept of unit moments is defined. In presenting the models for two stages of sampling, emphasis is placed on the physical description of the sample reduction process which leads quite naturally to its mathematical representation. In this representation, crushing or particle-size reduction between the stages of sampling is viewed as a random process with respect to the number and proportion of particles of the various kinds produced. The physical and mathematical description is extended to more than two stages of sample reduction, and the first three moments for any number of stages are developed. In common sample reduction practice the effects of a finite population (finite amount of material) at each stage of sampling appear to be important in describing the variance contribution of each stage. This is also true for the third moment about the mean. An example is cited in which the skewness increases by more than an order of magnitude when several stages of sampling are considered. This is largely due to the dependence of the multistage third moment about the mean on the variance. In general the model and results should be useful in helping to understand, control, and reduce the random errors that arise in the sample reduction process.

Jan 1, 1968

By W. E. Miller, Kennedy. R. E., G. W. Jones

"INTRODUCTION Ethyl mercaptan (CH3,CH2SH), a combustible organic liquid of the thioalcohol type, is employed at an odorant in many types of fuel gases and dangerous atmospheres, which in themselves are devoid of characteristic odors, to give warring against leakage of such gases or atmospheres into places where they might constitute health or explosion hazards.Ethyl mercaptan has a penetrating disagreeable odor resembling that of onions, garlic, hydrogen sulfide, or rotting cabbage, that exceedingly low concentrations of it can be detected. The of odorants as a beans of detecting leakage of gases and atmospheres has been investigated extensively by chemists and engineers of the Bureau of Mines, and numerous reports as to its value have been published."

Jun 1, 1942

By D. W. Frommer

Processing of nonmagnetic taconites by selective flocculation-des liming and anionic flotation of calcium-activated silica has been investigated using innovative procedures as a means of improving operating costs. Areas chosen for cost-cutting evaluation were grinding, fine screening, and water conservation and reclamation. The investigation was performed on Marquette range nonmagnetic taconites in the Bureau of Mines Twin Cities Metallurgy Research Center flotation pilot plant, at feed rates ranging between 900 and 1,100 lb/hr. With fully integrated water reclamation, flotation concentrates containing 65.8 percent Fe and 3.4 percent Si02 were made in the best operating period, with accompanying weight and iron recoveries of 40 and 74 percent, respectively. During this same period, the estimated cost of both flotation and water reclamation reagents was only $0.80 per ton of concentrate (1968 pricing basis). This cost is about 15 percent lower than obtained previously at this Center for flotation reagents only. The investigation demonstrated additional potential savings in operating costs of approximately $0.96 per ton of concentrate through autogenous grinding as a substitute for ballmilling. Fine screening of intermediate concentrates was employed advantageously, but the frequency of blinding may be a factor militating against use of the screen in this flotation system.

Jan 1, 1973

By C. W. JEFFERS

During the past few years the use of mechanical equipment for the loading and transportation of coal at the working face has rapidly increased . Many mining officials are of the opinion that mechanical methods have tended to reduce the hazards of mining, and a number of statements have been made to this effect . Little actual data upon which to base conclusions in regard to the relative safety of various methods of mining have been made available . While it may be possible that these systems of mechanical mining are inherently less hazardous , obvious dangers should not be disregarded in the belief that the mere act of installing mechanical loading equipment automatically brings about better accident records . The same rules and regulations , modified to meet the new regime must be applied with the same discipline as heretofore . By diligent study and application there is reason to believe that new methods of concentrated mining can be utilized with at least a possibility of increased accident performance . With the idea of preventing accidents by taking available precautions against their occurrence , attention should be directed to the dangers that exist where room and face conveyors are in operation . Due to the cost pressure prevalent in the mining industry at the present time mechanical means are often used in an attempt to decrease cost of production. The management , after having spent considerable sums of money for new equipment , is expected by stockholders and investors to show results by increasing tonnage and reducing operating costs . Consequently the operating officials apply the same pressure to local mine officials to obtain results . The natural reaction of the superintendent and mine foreman is to secure the maximum production from the new method , and unfortunately safety is frequently , if not generally , sacrificed to this end . In many instances , operators of new types of mechanical loaders are difficult to secure and after being obtained are difficult to hold , especially if the new equipment is more or less in the experimental stage . The tendency is to handle the machine operators with " gloved hands " and to permit many unsafe practices which ordinarily would not be allowed, in order to keep from antagonizing them and losing their services . Although these unsafe practices become habitual and even uneconomical , conditions thus established are difficult , sometimes impossible , to change .

Jul 1, 1930

By Richard H. Oitto

The Bureau of Mines and Kaiser Steel Corp. are cooperatively demonstrating the shield-type roof support in the longwall mining of a 10-1/2-foot-thick coalbed at the York Canyon mine near Raton, N. Mex. As part of the demonstration, the shield supports have been successfully and safely moved from a completed longwall face to a new longwall face. When these shield supports were moved in 1976 they were the largest and heaviest longwall support system in use in U.S. coal mines. The shield supports, preparations for moving them, the actual move, and installation at the new face are discussed.

Jan 1, 1977

By Joan C. Biordi

The Bureau of Mines used molecular beam-mass spectrometry to determine the microstructure of a 10.1% CH4-2l.2% 02-67.6% Ar-1.1% CF3Br inhibited flame and its uninhibited analog, both stabilized at 32 torr on a cooled flat-flame burner. Composition profiles of atomic, radical, and stable species and temperature profiles for both flames were obtained and compared. Kinetic analyses of the profiles yielded values for the rate coefficients of several elementary methane flame reactions and information on the reactions of formation and decay of the observed halocarbon species. CF3Br is judged to decay by thermal decomposition as well as by abstraction reactions, and the fluorocarbon chemistry occurring in the inhibited flame is due primarily to CF2 radical reactions. Rate coefficients and mechanisms for reactions of the inhibitor-related species are given.

Jan 1, 1978

This chapter analyses the parameters influencing initial design of communication systems, for new mines and upgrading existing systems. Paragraph 5.2 outlines those variables that must be taken into account during the design stages of a new wired phone system. Recommended features, general requirements, and how they can be implemented are treated in this section. Paragraph 5.3 describes ways of improving or extending the range of trolley carrier phone systems and pager phone systems already installed in the mine. 5.2 New Phone System Design The task of designing an adequate communication, control, and monitoring system for an underground mine must be addressed on a system basis. In addition to insuring that effective voice communication is established, any new system should take into account present and future requirements of remote control and monitoring functions. Chapter 4 illustrated the drastic savings in response time that can be realized when remote control and monitoring are integrated into the overall communication system. The importance of including control and monitoring in the overall design plan for any system cannot be overemphasized. Because each mine is unique, and thus usually has its own special operating characteristics and communication requirements, there is no such thing as "the one best system" to meet the requirements of all mines. The optimum communication, control, and monitoring system for a mine must be one that has been tailored to meet the special requirements of that particular mine. Factors that must be considered during system design include- a. Type of mine and mining methods (low- or high-seam coal, deep hardrock mine, stope caving, longwall, room and pillar, etc.). b. Maximum number of working sections. c. Expected mine growth rate and eventual maximum size. d. Haulage methods (tracked trolley, diesel, belt, etc.). e. Underground power distribution system (dc, ac, or both). f. Features desired (two-way radio paging, private line capability for emergency use, etc.). g. Redundant or backup systems for use during outages of the normal system. Although no two mines are alike, the following items have been established as the main characteristics desired for any underground communication system: 1. Multiple Communication Paths to Outside--the objective here is to give all telephones a second method of communicating with the surface. 2. Audible Emergency Signaling--the communication system provides the main means of alerting miners during emergencies. The system should include means to broadcast distinct audible signals for emergency signaling. Initiation of these signals should probably be controlled from. a central outside point, such as a surface control room. 3. Emergency Override--provisions should be included to permit any conversation to be overridden with emergency communication. 4. Selective Area Page--as mines grow larger it is apparent that the entire telephone system paging mode need not be activated each time a call is initiated. When the general area of a

Jan 1, 1984

By Russell. Paul L.

"INTRODUCTION Preliminary reports by Bureau of Mines engineers 3/ and by the Federal Geological Survey 4/ suggested that exploration would discover substantial reserves of minable ore in the Contact mine, Grant County, New Mexico. During February and March 1943, a sampling program was conducted on this property under the direction of the author. This was art of a general survey of the manganese districts of southwestern New Mexico.In its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources, to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as practicable soon as after its conclusion. The Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocer, chief, analyzes samples and performs beneficiation tests. Both these branches are under the supervision of Dr. S. Dean, assistant director. With respect to this report, special acknowledgment is due to C. H. Johnson, district engineer for New Mexico, and E. D. Gardner, regional engineer, and his staff, of the Central Region of the Bureau of Mines at the time of this work in 1943; also to Kenworthy, metallurgist at the Rolla. Mo., Laboratory of the Bureau of Mines, for work on beneficietion of the ore, and Sherman K. Neuschel, geologist of the Federal Geological Survey, for assistance in interpreting geological data at the project."

Oct 1, 1946

By J. H. Perry, D. W. Houseknecth, C. A. Kertis, A. T. Iannacchione

Major problems facing the development of coal and gas resources of the Hartshorne Coalbeds include the complex distribution of minable and unminable coal, high methane content and bed pressure, faulting, variations in degree of dip, presence of natural gas fields in associated sandstones, and legal problems, caused by local geologic characteris- tics, in identifying gas origin. This Bureau of Mines study provides pertinent geologic information for long-range planning of subsurface coal and gas production from the Hartshorne Coalbeds. Pittsburg, Coal, Hughes, and Atoka Counties, OK, have approximately 1 billion metric tons (1.1 billion short tons) of Hartshorne coal in place. The methane resource of Hartshorne Coalbeds is estimated at 9.2 billion m3 (325 billion ft3) and varies with overburden and rank, These estimates were compiled from gas well density logs, coal-core data, out- crop measurements, abandoned mine maps, and the literature. The Hartshorne Coalbeds represent a valuable coal and gas resource which at present is contributing nothing to coal and gas production. This report discusses potential problems and serves as a reference for future exploration and development work. Recognition of these potential geologically related problems prior to development of this basin will reduce hazards and allow for an economic recovery of these resources.

Jan 1, 1983

By By Staff

"This publication summarizes, for potential contractors and all other interested parties, the research, development, and demonstration of in-house and contract projects programmed by the Bureau of Mines for fiscal year 1982(October 1, 1981-September 30, 1982) under its Minerals Health and Safety Technology program. The objective of these projects is to provide an ordered and sequenced series of advance toward the Bureau's overall goal of providing the systems technology required to create a more healthful and safer working environment for the Nation's mining and minerals processing workersINTRODUCTION The Bureau of Mines conducts a balanced, continuing in-house research and development program to accelerate systematic improvements in health and safety conditions in U.S. mines. Part I of this report outlines the Bureau's present in-house effort to all interested parties; in particular, potential contractors can refer to it when submitting USP's (unsolicited proposals), thus avoiding proposing research that duplicates work being performed by the Bureau.It is the policy of the Bureau of Mines to utilize as fully as possible the capabilities of the private sector in minerals research, and to that endPart II of this report outlines the Bureau's current projected contract research needs.The projects presented were planned at the beginning of the fiscal year and are subject to change based on emerging priorities and availability of funds. Contingencies may require that a significant portion of the program be deferred into fiscal year 1983 (FY 83) or beyond. It is important to realize that since this is a summary document, the project descriptions related to a design, fabrications, and demonstration effort do not necessarily imply total package procurement."

Jan 1, 1982

By A. G. Starliper

Research was conducted by the Bureau of Mines to determine feasible roasting methods for the removal and the recovery of germanium, cadmium, and lead as enriched fractions from sphalerite concentrates. The two types of roasting processes studied were: (1) Batch, with a stationary bed, and (2) continuous, with a suspended bed, Results indicated that either method gave satisfactory metallurgical recoveries} but the continuous process is recommended because of inherent advantages. Final products were enriched fractions that could be treated by conventional methods for production of metallic germanium, cadmium, and lead. In the batch process, the concentrates were placed in a large tube furnace and heated at 1,080° C, an average of 3 hours. During the heating period, inert, reducing} or sulfur-laden gases were passed over the stationary charge to convey the sublimed metal sulfides from the hot portion of the tube to a lower temperature condensing zone at the end of the tube, where the metal sulfides were collected on baffles and recovered. In the batch and fluidizing roasting processes alike, the gases passed over or through the charge and served only as carriers for the sublimates and as suspension media in fluidization roasting. Since both processes depended on the volatilization, at relatively high vapor pressures, of the sulfides of germanium, cadmium, and lead, it was imperative that very little oxygen come in contact with the charge to alter the sulfide minerals. Germanium has a high affinity for oxygen, but in this instance it was buffered by being in solid solution in zinc sulfide.

Jan 1, 1961

By H. C. Ko

As part of the Bureau of Mines effort to provide thermodynamic data for the advancement of mineral technology, the standard enthalpies of formation for ZnO?2ZnSO4 and COS04-6H20 were determined by HC1 acid solution calorimetry. The values are -550.31 ±0.28 and -641.33 ±0.15 kcal/mot, respectively.

Jan 1, 1982