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By Aarne Visnapuu

Dissociation and vaporization of gold chlorides and bromides were investigated by a static pressure method and by Knudsen cell mass spectrometer. Two distinct chlorine and three distinct bromine pressure-temperature relation-ships were observed for the respective salts. The chlorine pressures are attributed to the dissociation of Au2Cl6 and Au2C12, and the bromine pressures to the dissociation of Au2Br6, Au2Br4, and AU2Br2, These pressure-temperature relationships were used to calculate dissociation pressure equations, enthalpies, and entropies of dissociation for each salt. Mass analysis of the vapors over AU2Cls between 83° and 152° C confirmed the existence of gaseous AU2C16. Ionization potential of this molecule is 11.0±0.1 ev and enthalpy of vaporization is 28.l±2.0 kcal/mole. Mass analysis of the vapors over the gold bromides detected only Bra in the temperature range 15°-150° C.

Jan 1, 1971

By Jack G. Croeni

A study was made by the Bureau of Mines to determine the influence of high energy-rate deformation on the structures and properties of low-carbon steel, stainless steel, titanium, titanium-6 percent aluminum-4 percent vanadium, beryllium, molybdenum, and tungsten. The purpose of this study was to determine relative formability, the effect of energy and temperature on metalworking parameters and resulting structures, and the properties of materials formed by this technique. Forming techniques were limited to upset forging and direct extrusion on pneumatic-mechanical forming machines. Results show that considerable grain refinement can be achieved by careful control of deformation and forming temperature by high energy-rate techniques. Significant improvements in strength were observed as a result of this refined structure. Approximate deformation resistance as a function of temperature was determined for a variety of materials.

Jan 1, 1966

By Clarence O. Babcock

In this report, the Bureau of Mines presents a method for reducing the complexity of designing room-and-pillar mining systems by treating them as anisotropic soft inclusions in the surrounding ore or host rock. Theoretical models were derived for the calculation of the effective Young's moduli for these systems. The predicted behavior of the plate-type elements used in these models agreed well with test results from 21 plates each with 49 holes spaced on a 7 X 7 Cartesian grid. The plates behaved as anisotropic solids, the effective Young's moduli of which could be predicted from the scaled hole size and spacing. Actual hole shape was insignificant. The effective Young's moduli for simple mining systems are calculated in sample problems. This approach should provide information about field stress in the mining region and the stress distribution in the surrounding ore or host rock when the actual mining configuration is replaced by an anisotropic inclusion in a finite element analysis. The field stress within the inclusion can then be applied to the actual opening shape to determine the stress distribution within the mining region.

Jan 1, 1970

By Albert L. Brautigam, Michael C. Leigh, August J. Kwitowski

The U.S. Bureau of Mines developed and tested a teleoperating system to control a new highwall mining system. A remote operator was provided out-of-sight sensory information and control of coal extraction and haulage equipment. Surface and production testing proved that the teleoperating system supplied the operator with sufficient sensory information to operate the mining system. Details on the teleoperating system provided in this report include (1) sensor selection, (2) a description of the electronic control system, (3) equipment selection and modifications, (4) the positive test results, and (5) recommendations for system improvements.

Jan 1, 1992

By R. J. Heemstra

A continuous flowing paper electrophoresis cell was used to separate petroleum and petroleum extracts into characteristic patterns. The electrophoresis of Bachaquero, Lagunillas, Boscan, and Gibson petroleums in nitro-benzene and acetic acid-based electrolytes was investigated. The extent of separation in the patterns was studied by measuring the metal and porphyrin contents of the effluents. Qualitative separations were achieved in some systems, whereas either system demonstrated only a high degree of electrophoretic migration.

Jan 1, 1967

By H. E. Powell

A solvent extraction procedure was developed on a laboratory scale for recovering trisodium phosphate, zinc, and iron from waste phosphate sludge as separate products. The sludge was dissolved in hydrochloric acid, and iron was extracted as ferric chloride by isopropyl ether. Zinc was extracted by di-2-ethylhexyl phosphoric acid in kerosine. The efficiencies of the one-and two-stage extractions ranged from 98 to nearly 100 percent. Trisodium phosphate was recovered by crystallization from the raffinate. The value of two marketable products is considerably more than than the costs of the major reagent. The process was developed to permit recycling of values in this waste and to consequently reduce stream pollution from this source.

Jan 1, 1972

By John Nagy

The effect of low percentages of methane (0 to 5 pet.) in an air atmosphere on spark initiated explosions of coal dust was investigated. With low dust concentrations (0.1 to 0.4 oz./cu, ft.), small amounts of methane increase the explosion pressure; with larger dust concentrations (0.5 to 2.0 oz./cu. ft.), small amounts of methane decrease the explosion pressure. The rate of pressure rise of a coal dust explosion increases with increase in methane concentration; about 3 to 4 pct. further addition of methane yields a decrease in the rate of pressure rise. Convection currents created by the air or gas blast used to disperse dust produce an increase in explosion pressure and rate of pressure rise. The minimum explosive concentration of the coal dust decreases about linearly as the concentration of methane increases from 0 to 5 pct. The explosion pressure increases linearly as the initial pressure within the chamber increases. Similarities between coal dust and methane explosions are indicated, INTRODUCTION During coal mining, methane occluded in coal or adjoining strata is liberated into the mine atmosphere,4 Normally, the methane is diluted and swept away by the ventilating air. Under some conditions, through accidental disruption of the ventilation system, sudden outburst, or because insufficient fresh air is supplied to a working place, low percentages of methane may be present during mining operations. If it is permitted to accumulate, methane itself presents an explosion hazard; its limits of explosibility arc approximately 5 and 15 pct. The effect of low percentages of methane on the explosibility of coal dust was studied to provide a broader understanding of the hazards of ignition and explosion and thus to facilitate development of control

Jan 1, 1961

By R. Van A. Mills

Crude oils are capable of dissolving quantities of gas under pressure. This fact has been known for some time, but questions have arisen as to the effects of gas in solution upon the characteristics of the oil. Previous investigations4 show that gas in solution in an oil affects the viscosity and surface tension of the oil, but the effect's on the volume and A. P. I. gravity of the oil have not been known. The results given in this report show that there is a decided change both in volume and in the A. P. I. gravity of the oil due to the solution of the gas in the oil under pressure. As gas is dissolved, the volume of the oil and the A. P. I. gravity increase. The converse of this phenomenon is also true: if the gas is released from a saturated oil, there is a shrinkage in volume and a decrease in A.P.I. gravity due to the release of gas from solution. However, various oils show marked tendencies to retain a portion of the dissolved gas upon releasing the pressure to that of the atmosphere. This retained gas has an appreciable effect on the volume and A. P. I. gravity of the oil because the oil does not resume its initial volume or gravity while it retains dissolved gas. In a sense the oil has been "Freshened" and will not return to its original or weathered volume until it loses some of the lighter fractions. Wiggins5 has shown that a fresh oil decreases both in volume and in gravity because of the weathering of the lighter fractions while the oil is standing in storage tanks.

Jan 1, 1928

By Allen D. Look, Norman King

For many years, much thought and effort have been devoted to the achievement of safety in the use of explosives by those interested in the preservation of human life and the protection of property. As a result, we now have adequate rules pertaining to the safe use of explosives , which, if observed, would prevent many, perhaps ail , of the explosives accidents that yet occur . Although the rules respecting the use of explosives are believed to be well - known, many accidents occur because they are disregarded . The mental awareness aroused by a tragic accident usually will cause safety precautions to be taken for a while ; however , this awareness gradually disappears unless a sincere effort is made permanently to prevent similar accidents . Frequently, because safe methods are more irksome than unsafe methods , the lessons taught by accident experience are forgotten in a short time , vigilance is relaxed , and there is a gradual return to unsafe , easy methods of performing work. If the preservation of human life is important , the unfortunate experiences of others and the lessons taught by them should be applied to reduce unnecessary loss of life . The value of a life lost as the resuit of accident should be calculated not only from the monetary and humanitarian standpoint but also according to what the accident could contribute in the way of saving other lives and suffering . This saving of other lives can and will , if the lessons from unfortunate accidents are applied , convert a loss to a gain a gain of such magnitude that the accident victim could be considered

May 1, 1944

By J. B. Gayle

Both immediate and long-range economic factors are associated with blending anthrafines to produce metallurgical cokes, and they warrant careful consideration of the technology of carbonization of blends containing significant proportions of inert substances in general and anthrafines in particular. This situation has resulted in numerous publications dealing with various phases of the overall problem, particular emphasis being placed on the effects of inert substances on the yields and quality of cokes produced. Because relatively little attention has been given to the expansion behavior of coal blends containing inert substances, an investigation of this problem was undertaken using the Bureau of Mines sole-heated oven. Since experiments in the sole-heated oven do not measure wall pressures directly, a new method of interpretation of sole-heated oven data, which permits estimates of wall pressures, has been proposed.

Jan 1, 1955

Exposure to airborne respirable crystalline silica dust can lead to silicosis, a debilitating lung disease. On surface coal mining and construction sites, blast hole drills are notorious sources of airborne respirable dust that may contain significant amounts of silica. The drill operator and drill helper usually receive the greatest silica exposure compared with other occupations. As a result, many drilling operations have been, and still are, on more stringent dust standards. Drilling through various rock formations naturally presents a strong potential for silica dust generation for several reasons. First, drilling is a pulverizing process that generates large amounts of very small dust particles. Second, the bailing air used to flush cuttings from the hole leaves the hole at a very high velocity and can be difficult to contain. Third, many fixed shrouds used to enclose the area beneath the drill deck have a significant amount of leakage due to 1) gaps between the shroud and ground created by raising/leveling the drill, 2) gaps in the corner seams, and 3) tom deck shrouds. CONTROLS A dry dust collection system is typically connected to the drill deck to collect dust as the bailing airflow transports the cuttings (and significant amounts of airborne respirable dust) out of the drill hole. Deck shrouds are installed in an attempt to enclose the volume around the drill steel and prevent dust escaping. However, most deck shrouds are rectangular and constructed of four separate pieces of rubber belting attached to the deck. Because of this design, there is usually a significant amount of dust escaping from the open seams as well as the open area between the shroud and the ground. This dust can be a significant source of silica exposure to drill operators as well as other personnel downwind of the drill.

By Albert E. Long

Since December 10, 1945, the Mount Weather Branch, Mining Division, Bureau of Mines, has been maintaining detailed performance and cost records on the diamond coring bits used throughout the United States by the Bureau of Mince. Figure 1 is a copy of a typical master record sheet showing the scope and type of information recorded for each bit. It is the intention of the Bureau of Mines to issue analytical reports covering the effects of diamond size and quality on the cost of core drilling in different rocks as the information on a significant number of bits used in any one type of rock is accumulated. This report is the first of such a proposed series and is based on the diamond loss and bit costs incurred in the use of 539 AX bits in coring operations on 10 different projects involving 6,097 feet of drilling in gneiss. The 10 projects were located in New York, Pennsylvania, and New Jersey (fig. 2). As a result of the information accumulated on the use of diamond-coring bits in drilling in gneiss, it has been found that the type of bit, the matrix, the percent of core recovered, and the size and quality of diamonds used have a definite effect on the cost of bits per foot drilled.

Jan 1, 1950

By W. R. Crane

Recent papers on support of roof and top rock in mines representing present practice in so far as it hits been described by engineers in all of the principal mining countries, cover a relatively aide range of topics. The papers abstracted herein include such subjects as the testing of materials of support, failure and movement of rock above workings, effect of excessive pressures on rock masses, axed the application in mines of timber, metal, concrete, packing, and filling support. It is not within the scope of this paper to present a logical and orderly discussion of the elements of support and their application to conditions influenced by the material worked or the method of mining. Only the essential facts of a paper appear in the abstracts, the idea being to give a fairly clear picture of the behavior of various types of support under brows conditions and to put into concise form important information concerning present practice, modifications of practice, and the trend toward new practice. With such valuable facts from others experience made readily available, it Is hoped that the engineer with particular and often trying problems may obtain suggestions that will be immediately helpful.

Jan 1, 1932

By D. J. Bauer

A solvent-extraction system employing selective stripping of a pre loaded organic phase was investigated for recovering Sm203 from a light-group rare-earth mixture. The samarium concentrated in the organic phase, and a >99-pct-pure samarium oxide product was obtained at 76-pct recovery in a 20-stage operation using di(2-ethylhexyl) phosphoric acid (EHPA) as the organic phase. The stripping agent was a 1.5-pct hydrochloric acid solution containing 200 g NH4C1/1.

Jan 1, 1972

By W. L. O'Brien, E. A. Rowe

Electrorefined vanadium with additions of up to 5 percent by weight of yttrium, cerium , lanthanum , praseodymium, neodymium, and samarium was melted to ingots in a nonconsumable electrode arc in a helium atmosphere . The ingots were rolled into strips and evaluated for the effect of the alloying elements on hardness , tensile strength , ductility , recrystallization temperature , and microstructure . Except for samarium , average additions of alloying elements of 1 to 2 weight - percent resulted in the retention of 0.12 to 1.05 weight - percent in the alloys and reduced the ultimate tensile strength from about 48,000 to approximately 30,600 psi . The corresponding yield stress (0.2 percent offset ) was reduced from about 40,700 to approximately 20 , 200 psi . Diamond pyramid hardness (DPH) was reduced from 117 to an average of 62 kg /mm² . Increased malleability at room temperature resulted with yttrium and all rare - earth- metal additions , except samarium , particularly with more than 0.25 weight - percent additions . Decreasing oxygen contents corresponded with the changes noted in the mechanical properties of the alloys . The recrystallization temperature of electrorefined vanadium was reduced from approximately 950 ° to 800 ° C. Yttrium or a rare- earth metal content , except samarium , in excess of 0.1 weight - percent in vanadium produced a second phase suggestive of an eutectic which indicated a possible maximum solubility of less than 0.1 weight - percent for both room and elevated temperatures .

Jan 1, 1964

By X. C. Shi

Bacterial mutagenicity and mammalian cell chromosomal and DNA damage in vitro assays were performed on a diesel exhaust particulate material (DPM) standard in two preparations: as an organic solvent extract, and as an aqueous dispersion in a simulated pulmonary surfactant. U.S. National Institute for Standards and Technology DPM SRM 2975 expressed mutagenic activity in the Salmonella reversion assay, and for in vitro genotoxicity to mammalian cells as micronucleus induction and as DNA damage in both preparations: as an acetone extract of the DPM mixed into dimethylsulfoxide, and as a mixture of whole DPM in a dispersion of dipalmitoyl phosphatidyl choline. Dispersion in surfactant was used to model the conditioning of DPM depositing on the deep respiratory airways of the lung. DPM solid residue after acetone extraction was inactive when assayed as a surfactant dispersion in the micronucleus induction assay, as was surfactant dispersion of a respirable particulate carbon black. In general, a given mass of the DPM in surfactant dispersion expressed greater activity than the solvent extract of an equal mass of DPM.

Jan 1, 2009

By John Durkin

The Bureau of Mines has conducted field studies in coal mines through- out the United States to determine the effectiveness of electromagnetic techniques in locating miners trapped underground following a mine accident. Data from these tests have been used to generate models of expected signal and noise distributions as found above mines throughout the coalfields. These distributions have aided in placing the expected performance of a through-the-earth electromagnetic communications technique into a probabilistic framework. Results show that at a 10-pct false alarm rate, the expected probability of detecting a miner's signal from a depth of 1,000 ft is 54 pct; at 500 ft it is 95 pct. These depths exceed the actual depths of 90 pct and 50 pct, respectively, of U.S. coal mines. Sensitivity studies have shown that at a depth of 1,000 ft, for every 3 db of improvement in signal-to-noise ratio, the probability of detection increases 6 to 8 pct.

Jan 1, 1982

By John E. Pahlman

The Bureau of Mines conducted column-leaching tests on 25 domestic Mn ores to determine the feasibility of extracting Mn by in situ or heap leaching with dissolved sulfur dioxide (S02) solutions. The ores tested were obtained from deposits in Arizona, Arkansas, California, Colorado. Maine, Minnesota, Nevada, and South Dakota. Dissolved S02 was found to be effective for leaching Mn; extractions greater than 90 pct were obtained with solution application rates of 1 mL/min from uncalcined, minus 2.5-plus 1.3-cm ore pieces. Leaching these ores with solutions containing only 5-wt-pct S02 and no added H2S04 resulted in Mn being selectively extracted over Fe except when Fe was present as goethite or siderite. Ca solubilization was inhibited by controlling the solution application rate (1 mL/min). The rate of leaching was found to be principally dependent upon the rate at which the leaching solution can penetrate the ore, since the solubilization of Mn upon contact with S02 was observed to be rapid. Despite low water permeabilities of the ores (as low as 10-2 to 10-4 darcy). greater than 90 pct of the Mn was extracted from even the largest ore pieces tested (approximately 10 cm in diameter). It appears, therefore. that leaching Mn opens up the pores, allowing penetration of the leach solution into the ore pieces.

Jan 1, 1988

By J. M. Mutmansky, L. Xu

"IntroductionSince the establishment of the star,just concentration of 2 mg/m3, a strong effort has made by mining engineers and researchers to provide better dust control equipment and procedures for underground coal mines.Particular areas of success have been implementation of better coal-cutting strategy to control dust generation, better design of water sprays for dust suppression and air movement, use of scrubbers, and improved design of face ventilation systems. A drastic improvement occurred over time such that the average dust concentrations for continuous miner operators dropped from 6.5 mg/m3 in 1968 to 1.3 mg/m3 in 1980 and for auger, cutter, longwall, and roof bolter occupations from 2.7 mg/m3 in 1973 to 1.6 mg/m3 in 1980 (Niewiadomski, 1983).While dust concentrations in mining sections have been dropping considerably, one problem area has been mining sections where quartz is a considerable portion of the airborne dust. The federal regulations require that quartz content must be held below 0.1 mg/m3 in the air regardless of the concentration of the total dust. This legislation limits the allowable dust concentration to a ""reduced standard"" of 10/ (% quartz) when the quartz content of respirable dust in the mine atmosphere is more than 5%. Today, approximately one-third of underground coal mining operations have designated areas with more stringent dust standards in place, and many mines experience considerable difficulty in meeting these standards (Jankowski, and Babbitt, 1989).It is well known that metal miners subjected to respirable dusts high in quartz have a higher incidence of silicosis than those exposed to dust low in quartz. However, the role of quartz in the development of coal workers' pneumoconiosis is still a highly controversial question, in spite of the large number of research projects devoted to this subject over the last 20 years. Because coal seams contain less quartz than metal ores and quartz often comes from sources outside the coal seam (e.g., roof and floor), it is difficult to relate studies that deal with the quartz content in coal seams and the incidence of coal workers' pneumoconiosis. Hamilton, Ogden, and Vincent (1983) have provided a plausible explanation for the incidence of the disease by hypothesizing that the quartz content does not affect the probability of developing pneumoconiosis until some threshold value (generally thought to be about 10%) is exceeded.The objective of the research studies summarized here was to obtain a better understanding of quartz occurrences in airborne coal mine dust by studying the variations of the quartz levels in different dust sizes and the relationship between the quartz content in airborne coal mine dust and the quartz content in the mined material. The implications of the results to control of dust in high-quartz sections will also be discussed."

Mar 1, 1992

By R. P. Maloney

The economic viability of four depleted mines near Kennicott, Alaska, was determined by the Bureau of Mines to assess their profitability if they were developed today and thus estimate cost data for a medium-sized mine, mill, and town complex. This information should help the State and Federal Governments appraise the potential development of similar-sized mining operations in Alaska. Modern conventional mining and milling techniques were assumed, and I capital and operating costs were derived using flowsheets and standard costing methods. A total capital investment of $37.6 million was necessary to install a 1,000-ton-per-day shrinkage stope mine, flotation-type mill, and support facilities; capital requirements were divided about evenly among the three components. Operating costs, including labor, supplies, power, water, and ' indirect and fixed costs, totaled $42.79 per ton of ore; the mining accounted for nearly one-half the cost. To obtain a 12-percent discounted cash flow rate of return on investment, the analysis showed that the ore could be mined and milled, and the concentrate could be trucked via public roads to a dock facility in Valdez, Alaska, barged to Tacoma, Wash., and smelted and refined for 34.7 cents per pound for copper and 104.0 cents per ounce for silver. The average May 1972 price was 52.6 cents for copper and 158.3 cents for silver. The same set of data was used to examine the economic viability of the mine with the cost of constructing a private road from McCarthy, Alaska, To Valdez, Alaska. The 148-mile road added $53.3 million to the original capital costs and raised the required price of copper to 57.4 cents per pound and the required price of silver to 172.0 cents per ounce. The additional coat of building, maintaining, and paying taxes on a private road from McCarthy, Alaska, to Valdez, Alaska, would make this venture uneconomical.

Jan 1, 1973