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Goethite ore are the third most abundant source of iron. The overwhelming part of these ore is represented by low-grade varieties which cannot be used in iron and steel industry without preliminary beneficiation. Biomass is a renewable solid fuel, which is feasible for the substitution of coke and coal in the manufacturing due to its lower contents of harmful elements and abundant raw material sources. Utilization of biomass in iron ore sintering process as heating agent and reducing agent contributes to energy conservation and emission reduction. The biomass was mixed together with goethite ore for roasting process to investigate the effects of reduction roasting. The results show that the goethite ore is dramatically reduced and magnetized into maghemite by biomass with the biomass dosage less than 20% and the roasting temperature below 650 oC. When the goethite ore roasted with biomass, the magnetization values could be enhanced more than two orders of magnitude, meets the standard of magnetic separation, which could significantly reduce the iron beneficiation cost. Keywords: biomass, goethite, reduction, magnetization, roasting

Sep 1, 2012

By L. Weitkämper

The big challenge at present and in the future is the economization of resources. This is applied for the whole industry but particularly in fields of mineral processing. The most important resources are energy and water. The shortage and price advance of energy is worldwide noticeable whereas the shortage of water is regionally limited at present. However due to the increasing world population, associated with a rising standard of living, water will become more and more important. Studies of the Unesco from 2001 indicate that the total water consumption raised seven times since the last 100 years at a growth of population of just three times. (UNESCO-Currier, 10/2001). This trend is going to be increased. While today more than 90 % of the humanity has access to clean water, in 2050 just about 50 % will be in the same situation. These figures indicate the importance of a gentle handling with the resource water. Further more the disposal of fine products, containing most of the water, is an environmental concern and in the future the mining and processing of raw materials will become important and necessary in desert, arid or permafrost areas. In these areas just efficient dry cleaning technologies will allow an economical beneficiation or better enable the processing at all. Most of the separation technologies with high throughput rates in mineral processing are based on wet processes. This applies especially for the separation of fines. Though there are some dry technologies available for the separation of coarse materials, like pneumatic gravity separation [air jigs and air tables], magnetic separation and not least sensor based sorters. Dry separation of fines is bounded mostly on cost intensive and low throughput technologies. The pneumatic separation undergoes at present a renaissance, mainly due to the development of the all air jig by the German supplier Allmineral. This newly developed sorting device yields good results in the separation of coarse to medium size material. All these facts and figures show the potential and motivation for developing an efficient dry separation device for fines. The following article delineates the development, performance and chance of a new dry separation technology for fines.

Jan 1, 2014

By R. C. Miranda

Artificial vision systems are increasingly used to assist humans to perform different tasks in different areas. These systems are able to recognize patterns in complex images, which can provide multiple data. Currently, vision systems are used in both; monitoring traffic - which uses radars for vehicular plate recognition- as in metallurgical and food industries for strict quality inspections. Their use in mining occurs in measuring the speed of froth over the lip of a cell, in determining the shape and size of pellets, in obtaining from the tendency of mineral content and as a replacement for laboratory analysis of particle size. With this advanced tool, it is possible to achieve significant improvements in quality, productivity, and especially in reducing costs in pelletizing plant of iron ore. The objective of this paper is to contemplate the current situation of image analysis in the pelleting plants and glimpse at the potential applications that are being developed. This paper also presents the conception and implementation of an automatic control system of the pellets size distribution applied on a pelletizing plant of iron ore. The article demonstrates the strategy used for measuring the size distribution of the iron ore pellets, based on image analysis and the strategy implemented on advanced process control, which shows substantial gain on plant performance.

Sep 1, 2012

By Junji Shibata

In a present process to treat the tungsten carbide tool waste, the wastes are roasted in air and then an alkali leaching is carried out in an autoclave. An environmentally friendly process is required to recover rare metals (Co and W) from the wastes. The effect of mechano-chemical (MC) treatment on leaching of rare metals was investigated in this study. The solvent extraction and crystallization-stripping methods were applied to separate and recover tungsten and cobalt in the leached solutions. The MC treatment for the rare metal leaching is effective to dissolve rare metals from the wastes due to the change in crystalline structure of WC and oxidation of WC with KMnO4. Cobalt ions are extracted with D2EHPA by a cation exchange reaction. Tungsten in the leachate can be extracted by TOA (tri-octyl amine) as an extractant, because tungsten species exist as a form of anionic species in acidic solution. The rare metals in organic phase are recovered as insoluble salts such as oxalates and ammonium salts in the crystallization-stripping process. Keywords:unheated oxidation, solvent extraction, crystallization-stripping, recycling

Sep 1, 2012

By I. Gombköto

In the EU-region, the automatically operated approximately 200 (rotating hammer) shredder plants processing large technical equipment (end-of-life vehicles, large household appliances) annually produces 8-9 million tons of non-metallic grinded by-product, which ends in landfills, without recovery. Although this by-product is organic material, still contains large amount of metal components worth recycling. These operations, such as shredding and processing end of life vehicles or mixed metal components are a growing market and it is become more potential if EU directive 2002/96/EC will become obligatory for new member and candidate countries and they have to apply EU regulations. Eddy current separators (ECS) are one of the most important units of separation of non-ferrous metals from insulators in waste recycling. The product of ECS processing of shredded ELV?s is usually a mixture of Al, Cu, Brass and stainless steel. This mixture has relatively low price on the market, while purified metal products are required by smelters for which shredder operators are able to get even higher price. Our aim at University of Miskolc was to find solution producing pure metal products using dry separation processes. Authors are presenting a possible solution, using ECS. Institute of Raw Material Preparation and Environmental Processing possesses an ECS, equipped with 305 mm wide belt, and a concentric magnetic rotor. The subject of our work was to investigate the behaviour of model particles with different shape, conductivity (aluminium and brass), orientation and size in order to separate Al and Brass. We used model particles with similar shapes of shredder plant originated ones. The magnetic flux and magnetic frequency was constant and derived by the design of the rotor. During our research work, belt speed and rotor speed of ECS were varied. The particle distance and trajectory caused by throwing was determined and the results are reported in this paper.

Sep 1, 2012

By B. Das

The separation of iron values from a typical Indian iron ore slimes containing 57.2% Fe, 5.81% SiO2 and 7.05% Al2O3 by wet magnetic separation and selective magnetic coating is investigated. The iron phases, which are mostly paramagnetic in nature, have been coated with magnetite or colloidal magnetite in presence of surfactant by manipulating the surface properties of the minerals. The studies have indicated that an iron concentrate containing 62.32% Fe with 66.5% iron recovery can be obtained at medium magnetic intensity of 7.8 kG which is much less compared to normal magnetic intensity of 13 kG to14 kG required for hematite-goethite separation. The performance of this technique with respect to both grade and recovery is superior to conventional magnetic separation or flotation of iron ore slimes.

Jan 1, 2014

By Zoran S. Markovic

The extensive laboratory investigations were carried out in order to determinate behavior of sulphide and nonsulphide copper bearing particles during the flotation. The present ore sample were contained 0.55% Cu with 20.1% of nonsulphide copper in it and gangue material with higher contents of alumina about 19.07%. In this paper will be presented some results such as: effect of particle size, pH and applied collectors. The main goal was in application of collectors S-7518, as well as mixture of KEX and Z-96. Z-96 is a product from Chemical Industry Zupa Krusevac which was used as auxiliary collector in mixture with xanthates. The best results were done with this mixture in ratio KEX / Z-96 as 77/23 % in area of oxidized minerals flotation, but the collector S-7518 was achieved better results in sulphide mineral flotation. The S-7518 has better selectivity between copper minerals and pyrite comparing to mixture of KEX/Z-96 in mentioned optimal ratio. Flotation recovery and copper grade in concentrate were studied by flotation kinetics tests.

Sep 1, 2012

By Ashish Kumar

High grade ore deposits in the world are fast depleting and the valuables in the low-grade ores are finely disseminated. The feed grade to flotation circuit is also declining. Attainment of suitable grind is preferred, which inevitably creates more fines of the gangue minerals to interfere with the flotation process because of the undue competition between the fines and the valuables for the collector ion adsorption. Besides the use of polymeric or long chain hydrocarbon depressants for the gangue mineral, microbial induced flotation also has potential to float minerals selectively. Thiobacillus ferroxidans and Thiobacillus thiooxidans adhere on the minerals to modify its surface properties and affect the minerals flotation acting as depressants. Hindustan Zinc has conducted laboratory studies to understand the adhesion of microorganism on the mineral surfaces and its impact on the selective flotation. The experiments were further designed to reduce consumption of depressing reagents for graphitic carbon, pyrite, and galena. Preliminary studies reveal that desired quality of concentrate can be achieved with reasonable recovery. Keywords: thiobacillus thioxidans, thiobacillus ferroxidans, bioflotation, microbial induced flotation

Sep 1, 2012

By S. A. Vorobyev, Yu. L. Mikhlin, Ye. V. Tomashevich, A. A. Karacharov, M. N. Likhatski1, A. S. Romanchenko, S. V. Saikova

"A set of state-of-the-art methods have been applied to study ultrafine particles and nanoscale species arising on mineral surfaces upon milling, interaction with flotation reagents, and leaching of base metal sulfide ores in order to gain insights into interfacial mechanisms. The fine fractions produced by ball milling of a Pb-Zn Gorevsky ore and four Cu-Ni sulfide ores studied with laser diffraction, dynamic light scattering, zeta-potential measurement, Xray photoelectron spectroscopy (XPS), SEM, TEM and other techniques. The particle size distributions had, aside from the peaks at 20-60 ?m, maxima near 1-2 ?m; the flotation was considerably suppressed when the yield of positively charged ultrafine particles approached tenths % (several kg per ton). High-energy XPS and X-ray absorption spectra revealed that sulfide minerals depleted in metal in air and aqueous solutions were composed of outer “polysulfide” layers, strata with disulfide species, and heavily defective underlayers, and “passivation” was explained by stability of the metal-deficit structures. Dixanthogen at pyrite and copper-activated sphalerite, dixanthogen and then cuprous xanthate on chalcopyrite, and chemisorbed xanthate at galena were specified as the main interfacial products using cryo-XPS of fast-frozen flotation slurries. The particle size, zeta-potential and behavior of colloids of Cu and Pb xanthates and dixanthogens were largely determined by the initial ratio of a cation and collector; the properties of copper xanthate nanoparticles were also affected by incorporated dixanthogen (about 15 wt.%). Submicrometer gas domains of 3-8 nm in height and “hydrophobic” forces upon the probe retraction were found on xanthate-treated minerals using atomic force microscopy and spectroscopy; their impact on flotation is briefly discussed.INTRODUCTIONInterfacial phenomena play a key role in flotation, leaching, water purification and related environmental processes. The mineral processing and extraction of metal from sulfide ores commonly involves milling the ore, which produces, along with the particles of 20 µm to 100 µm, mineral entities ranging from micrometer to submicrometer and nanometer scale. Furthermore, ultrafine particles of flotation reagents, products of metal sulfide oxidation, and so on may form spontaneously and accumulate in production water, flotation froth, deposit on mineral surfaces, affecting the flotation performance, and then enter waste waters, mine and natural drainage, polluting soils, surface- and ground waters (Miettinen et al., 2010; Wang et al., 2014). The efficiency of flotation and hydrometallurgical recovery of values, environmental issues are crucially dependent on the state of mineral surfaces. Particularly, it is generally accepted that the surface non-stoichiometry of sulfide minerals induced by oxidation and leaching should affect their hydrophobicity and reactivity, including so-called “passivation”, but the nature of such surface layers are still a matter of controversy (see, for example, Holmes and Crundwell, 2013). Another phenomenon attracting rapidly growing interest in several areas is low-dimensional gas species (“nanobubbles”) at hydrophobic surfaces that may play a decisive role in particle-bubble attachment in flotation but remains scarcely investigated up to now (Xing et al., 2017). Here, we survey our recent results on the abovementioned problems applying a series of rather new methods and approaches; more details can be found in refs. Karacharov et al., 2016; Mikhlin et al., 2015; 2016; 2016a; 2016b; 2016c; 2016d; 2017; 2017a; Vorobyev et al., 2017."

Jan 1, 2018

By F. Karakas

Water based paint formulations consist of some industrial minerals with quantities varying from 20 to 50 %. Quality of paint is directly related to these minerals used as pigment or filler in the production. Titanium dioxide is the most important and expensive pigment in paint formulations. Other minerals such as calcite and calcined kaolin are used as filler and mainly as a substitute for TiO2. Consequently, particle-particle interactions including adsorption, coating and size distribution of pigment mixture directly affects the paint quality. In the present paper, a new type of pigment mixture for possible use in architectural water based paints was developed through grinding. The effect of different types of grinding methods on physical properties of TiO2 and calcite mixture and the quality of paint produced by these mixtures have been revealed. Three different types of mills; conventional ball mill, vibratory ball mill and high-speed attritor were used for grinding of TiO2 and calcite. Viscosity, zeta potential and particle size distributions were used to characterize the pigment mixtures obtained upon grinding. The quality of paint was evaluated by standards based on both wet and dry paints such as viscosity, density, opacity and gloss. The paint produced with the pigment mixtures prepared in vibratory ball mill and high speed attritor showed improvement in physical properties particularly in the distribution and dispersion of mineral particles. Keywords: grinding, pigment, paint, TiO2, calcite

Sep 1, 2012

By József Faitli, Barnabás Csoke, Károly Solymár, Zoltán Hatvani, Dimitri Papanastassiou

"Grinding has a significant economic impact on ore dressing/processing, therefore the sizing of mills has an outstanding role.In most cases, the sizing of dry or wet mills for ore processing is primarily based on the determination of the Bond grindability index, using the Bond-Kjos-Rowland relations. In several cases, grinding takes place under conditions different from these and the grinding conditions have a great influence on the post-grinding process. This is particularly true for the grinding of bauxites where grinding takes place in alkali, often in higher temperature (up to 100 ºC) in alkali Liquor. So it is necessary to develop a testing method providing a reliable grindability index even under these special circumstances (grinding in alkalis medium at different temperatures) and allowing a more precise mill sizing. The new heated mill is suitable to determine the grindability index under temperature-controlled circumstances, in liquids with different temperatures (water, alkali). This paper presents in detail the equipment, the conditions (parameters) of the testing process for wet and alkaline grinding, the measuring results and the conclusions."

Jan 1, 2003

By Morin D. H., Battaglia-Brunet F., D'Hugues P.

"In the mineral-processing field, bioleaching of metal sulphide concentrates is currently operated in very large mechanically agitated tanks. Such bioreactors have considerable requirements in terms of power consumption for mixing, aeration and heat transfer. The use of slurry bubble column, where the particles are suspended by gas motion as well as by liquid upward flow, could be an alternative to achieve bioleaching in more economical conditions. In order to compare these two techniques, a unit of stirred reactors in cascade and a bubble column were comparatively operated at laboratory scale in the bioleaching of a pyrite concentrate. For both pieces of equipment, experiments were performed not only in batch mode but also in continuous conditions.Bubble column performances were significantly affected by unpredictable technical difficulties met to maintain continuous feeding in the bubble column and by a significant settling of the heavy solid particles. Nonetheless, theoretical kinetic data, extrapolated from results in batch conditions, could be compared to those obtained in continuous tests, in bubble column and in mechanically agitated reactors. These kinetic data were used to evaluate the influence of reactor design and configuration choice on bioleaching performances."

Jan 1, 2003

By M. Mirnezami

Pentlandite samples were obtained as Ni concentrate from three Canadian plants and one specimen sample from Ward?s Scientific Establishment. The samples were upgraded using gravity and magnetic separation techniques. Nickel concentration was determined by atomic absorption spectroscopy. Microprobe analysis identified a range in Co and Cu lattice substitutions. All samples exhibited similar zeta potential-pH trend with isoelectric points from 2 to 3, and similar responses to copper activation and addition of xanthate. The similar trends indicate that the variations in lattice substitution identified have no significant effect on electrokinetic properties; that is, samples from any source likely yield results that can be generalized.

Sep 1, 2012

By Jochen Petersen, Steven Bradshaw, Guven Akdogan, Ngoie Mpinga, James Mwase, Jacques Eksteen, Cornelius Snyders

"The platinum group metals (PGMs) and associated minerals are particularly refractory to most traditional direct leach processes. However, the remoteness of many new ore deposits, socio-political risks, the scarcity of skilled labor and constraints on the availability of water and electrical power makes it increasingly more difficult to implement the conventional mill-float-smelt-refine process routes to extract and refine PGMs in remote areas. This paper discusses a process to extract PGM’s from low grade ore and concentrate using a sequential stage heap leach process entailing heap bioleaching and high temperature cyanide leaching, and evaluates the feasibility of implementing a carbon-in-pulp process to recover the PGMs from the pregnant leach solution. The heap bioleaching extracts the base metals in an acidic sulfate medium using a mixed culture of thermophiles. After heap bioleaching the heap is reclaimed, rinsed, agglomerated and restacked for high temperature cyanide leaching where the cyanide liquor is directly heated via solar energy in panels. Palladium, gold and platinum are recovered during the cyanide leaching stage. The pregnant leach solution was evaluated for potential carbon-in-pulp adsorption and subsequent elution similar to gold processing. The kinetics of adsorption and elution compared well with gold adsorption and elution."

Jan 1, 2014

By S. Serranti

The recycling of end-of-life concrete into new concrete is one of the most interesting options for reducing worldwide natural resources use and emissions associated with the building materials sector. The possibility to realize a larger re-use of silica aggregates from old concrete, strongly contributes to reduce environmental impact (reduced exploitation of natural resources, reduction of CO2 emissions, airborne dust production, etc.).To reach this goal, innovative processing techniques, as well as innovative sensing units and architectures have to be developed. In this perspective an analytical approach, based on hyperspectral sensing techniques, is proposed, discussed and critically evaluated in order to perform an automatic quality control assessment, finalized to maintain a high standard of concrete demolition waste, from the earliest stage of recycling to the further processing stages, according to the detected in-situ demolition waste characteristics. The paper deals with the analysis and the evaluation of the problems related to the integration of this approach with state-of-the-art demolition and building processes and procedures. Keywords: end-of-life concrete, recycling, hyperspectral imaging, NIR spectroscopy, quality control

Sep 1, 2012

By J. S. S. Allwin Ebinesar

The bioremediation of zinc was carried out using Pseudomonas alcaligenes, a Gram negative heterotroph. The parameters such as pH, bacterial cell number, initial metal concentration, and interaction time on the biosorption of zinc were studied. The maximum zinc uptake was found to be about 95% at pH 5 and biomass loading of 2.7x1010cells/mL. The biosorption isotherm for zinc exhibited Langmuirian behavior and the Gibbs free energy of biosorption was determined to be -31.2 kJ/mol, indicative of coordination of zinc with the functional groups on the bacterial surface. The adsorption kinetics followed a pseudo-second order equation. FTIR and EDAX studies confirmed the interaction of zinc with the biomass. The mechanisms of metal-microbe interactions are discussed.

Sep 1, 2012

By Rakesh Kumar, S. Mehrotra, T. Alex

"This paper, an overview of our recent findings on mechanical activation (MA) of minerals/materials, emphasizes the importance of sample genesis, mechanically induced/altered porosity and surface area, mineral interactions, glassy inorganic materials, surface alteration and zeta potential changes and, mechanically induced reactivity of solids. Materials investigated include Al-oxyhydroxides (gibbsite and boehmite), fly ash and granulated blast furnace slag. Planetary, attrition, vibratory and conventional ball mills are used for MA. Genesis of boehmite has been found to have a bearing on its behavior during MA. For example, BET specific surface area (SSA) of boehmite prepared by thermal dehydroxylation of gibbsite has decreased from 265 to 65 m2/g during 240 min of MA; in contrast, the SSA of hydrothermal boehmite has increased from ~2 to 36 m2/g. Mechanisms of surface area changes in the two boehmite samples differing in their genesis is explored. MA of gibbsite and its mixture with hematite/quartz using attrition milling has indicated that the presence of the second phase promotes amorphisation. Amorphous materials show signs of change in nature of bonding during milling as illustrated by MA of fly ash. Physicochemical changes during MA are not restricted to the bulk phase. The genesis of zeta potential changes in MA solids can be many; for example texture induced zeta potential changes as observed for gibbsite, while zeta potential changes during the milling of granulated blast furnace slag occur due to enhanced (possibly non-congruent) dissolution. Interesting manifestations of mechanically induced reactivity and its correlation with physicochemical changes are illustrated in terms of alkali leaching of boehmite and, hydration of MA slag. New findings reported here are associated with several open questions and are highlighted in the paper."

Jan 1, 2014

By G. I. Voiloshnikov, V. E. Dementyev

"One of the most important advances in the world gold metallurgy is the introduction of adsorption technologies for processing of ores and concentrates. «Adsorbent-In-Pulp» process allows to eliminate pulp filtration that is especially important during processing of clay and slime bearing ores. “Adsorbent-In-Leach” process is one of the ways for processing of preg-robbing (carbonaceous) products. High efficiency, increased metals recovery, decrease in capital and operational costs, possibility of easy control and adjustment are the advantages of adsorption processes. Anion-exchange resins and activated carbons are used as adsorbents. This paper presents Irgiredmet experience on gold adsorption technology using both adsorbents (RIP, RIL, CIP, CIL processes). It includes results of long-term studies of different theoretical and practical issues of adsorption processes. Irgiredmet started development of ion exchange technology (RIP, RIL) in 1964. Laboratory and pilot plant tests were conducted to develop process design criteria for 15 RIP plants of the former USSR. During this test work a great number of newly synthesized resins including strong- and medium-base resins was studied, different types of adsorption feed (ores and concentrates) were tested; some theoretical regularities of adsorption process were investigated; the technology of two stage adsorption for silver gold ore, improved flowsheet for gold elution and resin regeneration, designs of technological equipment for adsorption, elution, electrowinning processes including pulsation columns, electrowinning cells etc. were developed. Irgiredmet took part in commissioning of practically all RIP plants in the former USSR. Due to its efforts RIP process became to be the standard technology. Last Irgiredmet RIP projects include the development of adsorption technology using medium-base resin for the three mines owned by GC Petropavlovsk (Amur region, Russia). The complex of the testworks on activated carbon gold adsorption technology including the search of prospective activated carbons; study on gold adsorption mechanism; development, testing and introduction of process flowsheets and the equipment for their realization was conducted. The original gold elution process was developed. The developed CIP technology was firstly introduced at Lebedinsky gold plant (Yakutia). Now carbon adsorption technology is widely used at Russian gold mines as CIP, CIL, CIC processes. The most relevant example of CIP introduction is Svetlinsky gold plant (Ural, Russia) with capacity 8 Mt of ore/ year."

Jan 1, 2018

By Fuqiang Zheng, Shuai Wang, Feng Chen, Yufeng Guo, Guanzhou Qiu, Tao Jiang

"The direct reduced iron powder and Ti-V-rich material was prepared from vanadium titanomagnetite concentrate by solid-state reduction-magnetic separation. The result indicated that under the studied conditions, adding KS can effectively improve the metallization rate of pellets. 2% KS was well mixed with vanadium titanomagnetite concentrate to make the pellets. The green pellet was preheated at 900 ? for 6 min. The preheated pellet was reduced at 1050 ? for 100 min, then crushed and ground to more than 80% was below 0.045 mm. The direct reduced iron powder and Ti-V-rich material were separated from the slurry by wet magnetic separation at 800Gs. The TFe content of magnetic material was 90.63%, and the Fe recovery rate reached 96.53%. The TiO2 and V2O5 contents of Ti-V-rich material were 28.40 % and 1.64 %, respectively. The TiO2 and V2O5 recovery rates were 69.05% and 96.82%, respectively. 1. Introduction The ilmenite and rutile are the main titanium resources which can be used in the present technical level and economic conditions[1,2]. However, with the rapid development of China’s economy, the market demand of titanium products is increasing sharply. The current supply of ilmenite and rutile cannot meet the needs of chemical industry[3]. China is rich in vanadium titanomagnetite concentrate which contains abundant titanium and vanadium resources. The TiO2 and V2O5 content of vanadium titanomagnetite concentrate are usually about 7% and 0.3%, respectively[4]. Because the TiO2 and V2O5 grades are low, it generally requires pre-concentrated to Ti-V-rich material before extracting the titanium and vanadium. Therefore, it is vital to find effective processes for pre-concentrating the titanium and vanadium in vanadium titanomagnetite concentrate. There are many methods[5-13] developed or under development to pre-concentrate Ti-V-rich material from vanadium titanomagnetite concentrate, including the blast furnace process, pre-reduction electric furnace process, to utilized vanadium titanomagnetite concentrate are direct reduction-electric furnace smelting, sodium salt roasting-direct reduction-electric furnace smelting and direct reduction-magnetic separation and so on. The blast furnace process and other methods cannot effectively utilize the titanium and vanadium resource due to the technical or environmental problems[9]. In this study, the vanadium titanomagnetite concentrate was obtained from Panxi region of China, the reserves of which account for 11.6% of vanadium and 35.17% of titanium all over the world[3]. The preparation of direct reduced iron powder and Ti-V-rich material based on reduction-magnetic separation is proposed. The process utilizes a new catalyst for titanium ore reduction in rotary kiln followed by magnetic separation. Using this novel technology, the titanium-vanadium and iron are successfully separated. Compared to the traditional reduction of Ti-bearing ore, the reduction temperature reduced to 1050 ?, leading to higher efficiency, lower energy consumption and investment, and broader applications."

Jan 1, 2018

By D. Pienaar, B. McFadzean, T. Jordaan

"Dithiophosphate (DTP) collectors have the lowest affinity for sulfide mineral surfaces compared to other common sulfide mineral collectors, such as xanthates and dithiocarbamates. In some cases it has been found that DTP does not adsorb onto the mineral surface at all and yet increases in recoveries and grades are noticed with the addition of DTP. Many studies have investigated the interactive effects of collector mixtures. However, there have been relatively few studies on the interactive effects between frother molecules and collectors. This study investigates the interactions between different types of frothers and sodium diethyl dithiophosphate.The study found that there were large increases in pyrite and galena microflotation recoveries at both pH4 and pH9 when DTP was mixed with small amounts of frother at a constant bubble size, showing that these increases were neither mineral-specific nor pH-specific. The same effect was not present when xanthate was used as a collector. The increases in recovery when using the DTP-frother mixture were similar irrespective of the type of alcohol or polypropylene glycol frother that was used. In an attempt to distinguish the mechanism of enhanced flotation recovery, various supplementary experiments were performed. It was found through adsorption experiments that no DTP was adsorbing on to the mineral surface. Therefore, interactions at the air-water interface were performed. Surface tension and critical coalescence concentration tests showed that, while DTP is a weak surfactant at the air-water interface, it does not have a synergistic effect in the presence of frother. DTP-frother mixtures do, however, show interactions in the froth phase, indicating an interaction in the thin films. It is proposed that there is a DTP-frother interaction on the bubble surface that enhances the rate of film thinning at the 3-phase bubble-particle contact."

Jan 1, 2018