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By U. Dmitrakova, G. Sedelnikova, D. Kim, E. Savari

"The paper presents the results of research on the development of gold and silver extraction technology from refractory gold sulphide flotation concentrate of one deposits of Nord-East of Russia. The concentrate is due to the complex mineral composition. Gold and silver are finely disseminated in sulphide minerals (arsenopyrite and pyrite partially oxidized by 7-11%). These are characterized by high content of silver 219 g/t and sulphide sulfur 32%, the presence of poorly soluble silver minerals (silver sulfosalts, fahlore, finely dispersed hypergenic acanthite in iron hydroxides and jarosite, etc.), and impurity minerals capable of interacting with cyanide (pyrrhotite, marcasite, nonferrous sulphides) and causing higher than normal cyanide consumption. Pretreatment of refractory sulphide concentrate by biooxidation using a mixed association of mesophilic and moderately thermophilic bacteria at a temperature of 36-40 °C for 120 hours oxidized arsenopyrite by 97.5%, pyrite by 93.5%, unlocked refractory gold, and generally oxidized the minerals absorbing cyanide and oxygen before cyanidation. Further oxidation of these minerals-absorbents was facilitated by the aeration in calcareous medium of the solid biooxidation residues of the concentrate. Sorption cyanidation of the solid biooxidation residues with addition of lead (II) of recovered 91.2% of gold and 82.9% silver from biooxidation residue, compared with 80.1% and 46.6%, respectively, for sorption cyanidation without the preceding biooxidation step. Biooxidation of the concentrate prior to cyanidation improves the recovery of precious metals, especially silver, and significantly reduces cyanide consumption from 18.7 kg/t to 3-5 kg/t of concentrate. INTRODUCTION Biooxidation of gold sulphide concentrates using acidophilic microorganisms has been successfully applied worldwide (van Aswegen et al., 2007; Gericke et al., 2009; Sovmen et al., 2007; Sovmen et al., 2009). At least 15 full-scale plants for tank biooxidation of sulphide concentrates are presently in operation, and the construction of new ones is planned (Bulaev et al, 2015)."

Jan 1, 2018

By Hong Zhong, Shuai Wang, Xin Ma

"In this paper, we report a simple and effective process for producing a surfactant mixture of O-isopropyl-N-ethyl thionocarbamate (IPETC) and 4-(tert-butyl)benzyl mercaptan (BBSH). The composite collector was synthesized via one-pot reaction of sodium isopropyl xanthate, 4-tert-butylbenzylchloride and ethylamine using tert-butyl alcohol as solvent. The whole process for the synthesis of composite collector involves neither foul smelling reagents or intermediates, nor any by-products requires special treatment for disposal, and thus can be scaled up to an industrial level. The flotation response of chalcopyrite and pyrite independently with IPETC and BBSH collectors and with their mixture (the mole ratio of IPETC and BBSH is 1:1) was assessed. The microflotation results showed that the collecting ability of BBSH was slightly stronger than that of IPETC and that IPETC was more selective collector than BBSH against pyrite, and that the composite collector displayed a stronger collecting ability toward chalcopyrite than IPETC, and superior selectivity for chalcopyrite against pyrite than BBSH. The batch flotation results showed that composite collector exhibited better performance than IPETC and BBSH. It was demonstrated that the mixing of IPETC and BBSH would give rise to a synergistic effect significantly enhancing overall flotation performance. In addition, the adsorption mechanism of BBSH on the surface of chalcopyrite was conducted by adsorption test and infrared spectrum measurement, and the results showed that the interaction of BBSH on the chalcopyrite surface was dominated by the chemical adsorption, and the formation of a strong S-M bond plays a key role in the adsorption of mercaptans on minerals surfaces. The developed flotation reagents with special preparation method is the author’s original design, patented (patent of the People’s Republic of China) and have no analogues in the world of mineral processing. (Application number 201810100107.1, ""Alkyl thioether alcohol compounds, methods for their preparation and applications thereof "", China).1. INTRODUCTION Froth flotation is an essential method widely used in the mineral processing industry to selectively separate valuable minerals from gangues[1]. Worldwide, more than 109 tons of materials are treated annually by this method with the majority being metal sulfides and oxides[2]. Nowadays, the judicious utilization of complex sulfides to meet the ever-growing demand of mineral resources gains more attention, due to the gradual depletion of deposits with high grade, making imperative the development of new high-efficiency collectors and mixtures of collectors to process complex minerals. In comparison to individual collectors, the use of mixtures has several notable benefits including lower dosage requirements, improved selectivity, rates and recovery and an increase in the recovery of coarse particles[3-9]. Moreover, in terms of cost and environmental issues, using collector mixtures can reduce the total amount of agents used, thus reducing the overall effect on the environment and economic costs without affecting the flotation performance. Therefore, the search for high-efficiency mixtures of collectors is still interesting and relevant."

Jan 1, 2018

By Qidong Zhang, Yongsheng Song, Wenjuan Li, Guiying Zhou, Kun Song

"Molybdenum is a very important rare mineral resources, which exists largely in oxidized ores and sulphide ores in nature. About 99% of metallic molybdenum comes from molybdenite. The talcose molybdenum resources are abundant but the resources utilization is low, because the talc is naturally hydrophobic and the floatability of talc is similar with molybdenite, which lead to difficult separation by flotation. Talc is easy entry into concentrate in flotation which can cause the content of MgO overhigh, therefore the molybdenum concentrate grade can not meet the industrial requirements. Thus the utilization level of talcose molybdenum resources has been restricted greatly.The adsorption of water on talc and molybdenite surfaces and natural floatability of minerals were studied by density functional theory method. The results showed that molybdenite and talc were layered minerals which exhibited similar surface wettability and H2O molecule prefers to stay with water rather than the minerals surfaces. N2 is adsorbed on talc and molybdenite surfaces more easily than H2O. The interaction and flotation behavior were studied by SEM and flotation experiments. The reason why talc interferes with the flotation molybdenite has been revealed. The agglomeration between molybenite and talc was caused easily in neutral or acidity solution, and it was dispersing between molybenite and talc particles in alkaline solution. The flotation results showed that good floatability of talc was the key factor causing a low grade of concentrate in alkaline solution. Thus, it is the key factor to enlarge floatability difference between molybdenite and talc.INTRODUCTIONMolybdenum is a kind of important rare metal and strategic reserve resources (Zhitao Y et al, 2016a). Due to excellent characteristic, such as high melting point, good thermal property and et al, it’s widely used in metallurgy, machinery, chemical, aerospace, and many other areas. It has become an indispensable metal in modern industry. Molybdenum generally exist in the form of molybdenite which is a kind of mineral with excellent natural floatability. Talc is a kind of typical hydrous and layered magnesium silicate minerals (Beattie D et al,2006a), which is one of the most common gangue mineral of the platinum group metal ores and metal sulfide ores (Tao L et al,2011). Due to its good native floatability, talc is easy entry into the concentrate product with foam in the process of sulfide ore flotation (Kelebek S and Smith S, 2006b), which resulted in decreasing concentrate indexes. Not on that, the high-content MgO of concentrate will also produce a series of adverse impact to the subsequent smelting (Lotter N O et al, 2008). Therefore, it is difficult to separate talc from sulfide ore concentrate effectively."

Jan 1, 2018

By S. Castro, L. Uribe

Seawater can be considered as a particular process water with a high concentration of NaCl (about 0.5- 0.6 mole/L) and high concentration of hydrolyzing metal cations (mainly, Mg2+ and Ca2+ ions). Micro-flotation tests, induction time measurements, and zeta potential measurements have been used to investigate the effect of these ions on the natural floatability of molybdenite. The results demonstrate that molybdenite is strongly depressed in the alkaline pH range over which hydrolysis products of Mg2+ and Ca2+ ions are formed. At pH 10, colloidal magnesium hydroxide seems to be responsible for molybdenite depression in seawater and in Mg2+ solutions. This is also supported by the measurements of the effect of Mg2+ ions on the zeta potential of molybdenite. The mechanism of depression of molybdenite with Ca2+ ions is different, and depression takes place in the pH range were Ca(OH)+ complexes are formed, below the pH of precipitation of calcium hydroxide. Adsorption of the cationic hydroxy species and/or hetero-coagulation of the positive charged colloidal hydroxide on the negative charged molybdenite particles seem to be the main mechanisms involved.

Jan 1, 2014

By Lina Chica, Arturo Barrientos, O. Bustamante

Hydrocyclone is a device commonly used in mineral processing industry. Underflow control plays a fundamental role in hydrocyclone operation. This affirmation supports the fact that hydrocyclone underflow has effect in some aspects of separation performance like capacity, split ratio, cut size and bypass. Hydrocyclone operation state is associated to underflow characteristics: air core formation and discharge shape. Many studies attempt to understand size separation phenomenon and the discharge influence but none of them has taken an energy point of view. This work presents the results of a mechanical energy dissipation for hydrocyclone operation from a mechanical energy balance. The experimental results related to Newtonian suspensions show that underflow energy dissipation does not control the operation because this magnitude is small compared to interior energy dissipation. However, discharge energy dissipation provides enough information to describe underflow conditions and its influence in separation conditions. In the modelling non dimensional parameters have been considered for hydrodynamic description and for geometrical and operation hydrocyclone characteristics. Energy dissipation from the continua media approximation results into a relevant concept to understand the hydrocyclone performance and improve industrial installations.

Jan 1, 2014

By Kumar Ranjan, Kumari A. V. Asha, G. E. Sreedhar, Banerjee R. Raja, M. Narasimha, R. Shivakumar

In this paper, numerical simulation of magnetite, medium segregation and coal partitioning have been made in a 350 mm diameter cyclone. An attempt is made to assess the nature of impairment in efficiency in relation to the increasing amount of near gravity materials in coal. The CFD model approaches the Algebraic Mixture (ASM) model with the granular option and Reynolds stress model (RSM) to resolve the air core and turbulent mixing of the medium and coal particles. The partition characteristics of the DMC were modelled using both Lagrangian & Eulerian particle tracking for particles ranging in size from 0.5 to 8 mm and in density from 1200 to 2000 kg.m-3. Lagrangian frame work based Discrete Phase model used to simulate the coal particle trajectories inside the DMC and attempted to understand the residence time of different size and density coal particles. It was observed that coal particles having density near to separation-density (having fifty percent of probability to under flow and overflow) are exhibiting increased residence time than any density particles. As expected the smaller size coal particles shows higher residence time than the coarse coal particles. CFD simulations on effect of NGM mass fraction are simulated and analyzed using ASM model including for coal and magnetite. Coal particles with high NGM content show significant effect in misplacement of coal particles towards wrong products at all relative densities. The residence time of the particles increases because of its increased interaction with near dense particles. The effect of NGM fraction on overall cyclone performance as well as detailed flow assessment in terms of residence time distribution, NGM particle concentration profiles with respect to LZVV is presented.

Jan 1, 2018

In looking to the future of mineral processing the focus is typically on improved processing units. Basically it is a search for an elusive wonder machine that could revolutionise the economy of mining: the sorter that strips 50% of the ore with only a few % loss of value; the comminution device that uses 5% of the energy while producing fully liberated particles; or the recovery device capable of producing a 99% recovery at 99% grade. These aspirations are propounded against a reality backdrop of sorters rusting in back yards, mill throughputs below design and varying by 30%, cyclones flaring and cut-sizes fluctuating, mediocre recoveries and soaring processing costs. This disconnect between aspiration and reality appears, to these authors at least, to be a mighty chasm. Moreover, it remains one over which we are expected to magically leap rather than methodically bridge. Indeed one may be forgiven for thinking that should such a wonder machine come along, taking advantage of it would be highly improbable. Questions would inevitably emerge on how to feed the correct material, how to cope with the wide variability of feeds, how to control such advanced equipment and how to handle the new product from such a machine. It is likely these questions might lie unanswered, or more regrettably, unasked. It is generally accepted that as an industry we are exceedingly unlikely to teleport from the current status quo to an entirely new reality in a single flash. It is our thesis that the probability of these magical machines materialising is remote, and even if they miraculously appeared, we simply wouldn?t know what to do with them. Rather, it is our contention, that a step change will only arise through a staircase rather than from a single giant leap. We should focus on building those steps and linking them together into a firm structure ? a workable mineral processing circuit. This paper addresses the alternative of a coherent set of modest but significant improvements, integrated to produce the step change we desire: essentially, a reduction of processing energy to below 40%, which we believe is achievable without recourse to any mystical machines. A key underlying capability to designing these dramatically improved processes, is the weaving of independent process models into a coherent circuit simulation, in order to design the new generation of mineral processing circuits. Keywords: step change, circuit design, circuit simulation, energy reduction

Sep 1, 2012

By V. Panayotov, M. Panayotova

"Wastewater from ores processing is often polluted by molybdate and sulfate (SO42-) ions. Sorption is one of suitable methods for removing those pollutants when presenting in low concentrations. This work reports results on adsorption of sulfate and molybdate ions on metal modified (with barium - Ba and lead - Pb) and organic reagent modified (with Hexadecyl-trimethyl-ammonium bromide - HDTMA) clinoptilolite. Zeolite’s modification with Pb, Ba and HDTMA increases its uptake capacity with respect to Mo(VI) at pH 3, with the uptake capacity decreasing in the order CL-Pb > CL-HDTMA > CL-Ba. Lead-modified clinoptilolite shows high uptake with respect to Mo(VI) in acidic, neutral and slightly alkaline conditions. The presence of SO42- in concentrations twice higher than the amount of Mo(VI) do not interfere with the Mo(VI) removal by CL-Pb. Zeolite’s modification with Ba and Pb renders it able to immobilize SO42- from water in the pH range 3-9. Kinetics of the uptake process is best described by the pseudo-first order kinetic equation. Increasing the initial concentrations of Mo(VI) and SO42- increases the removed amount of pollutants. INTRODUCTION Wastewater from copper-molybdenum ores processing is often polluted by molybdate and sulfate ions. Molybdenum (Mo) migrates easily in water and consequently the Mo polluted areas could extend for hundreds and thousands of meters (Ryzhenko, 2010). Molybdate anion is the only Mo(VI) species in natural water, i.e. at pH > 6.0. Its median freshwater hazardous concentration affecting 5% of the species (HC 5.50%) is 38.2 mg Mo/L (De-Schamphelaere et al., 2010). The marine water chronic toxicity (HC 5.50%) is assessed at 5.74 mg Mo/L (Heijerick et al., 2012). The predicted no-effect concentrations (PNEC) are 12.7 mg Mo/L and 1.92 mg Mo/L correspondingly for freshwater and marine water (Heijerick et al., 2012a). When sulfates present in drinking water in excess of 250 mg/L they cause a cathartic action (especially in children) in the presence of sodium and magnesium, and when the concentration exceeds 600 mg/L, diarrhea. When sulfate-rich effluents are discharged into the environment, they may increase the acidity of water bodies and soils (Guimarães and Leão, 2014). Because of the adverse effects to human health and the environment, limits are set for SO42- concentrations in waters and wastewaters in the range of 250 / 500 mg/L."

Jan 1, 2018

By Francisco Cubillos, Jorge Menacho, Cesar Gomez, Juan Rodríguez

Mineral flotation is the most used process to selectively separate particles of one or more minerals of interest. The process uses natural or induced hydrophobicity to collect particles on the surface of rising bubbles through collisions and formation of bubble-particle aggregates. Flotation machines must keep particles in suspension and well distributed, while at the same time, disperse a mass of air into a population of small bubbles. The efficiency of the separation depends primarily on the characteristics of the bubble population generated in the machine and its distribution and flow throughout its volume. The formation and separation of bubble-particle aggregates create two zones, with strong interactions between them, and with markedly different hydrodynamics conditions. A model describing two-phase hydrodynamics of the continuous and dispersed phases (frother solutions and bubbles, respectively), moving along the whole unit, is proposed. Bubble populations are characterized at the formation stage including the effect of the presence of frothers. Flow through the aggregates formation zone, where bubbles move freely and are closely spherical, is modeled using drift-flux analysis. In the aggregates separation zone, bubbles initially pack maintaining a water layer thick enough to prevent capillary forces to affect their shape. As water drainage proceeds, bubbles deform, capillary channels form, and a network of channels with a diameter size distribution develops; channels become narrower (permeability is reduced) as the distance from the interface increases. Froth hydrodynamics is characterized using models originally developed to describe unsaturated flow through porous solid particle beds. Effects of hydrostatic pressure are considered.

Jan 1, 2014

By Chiharu Tokoro

Acid Mine Drainage (AMD), high acid water containing heavy metals discharged from mines, has been recognized as major cause of mine pollution. In Japan, the government spends billions of yen every year to prevent pollution caused by AMD in about 80 abandoned mines. It is widely recognized that the treatment could continue for long decades or an even century. However, costs and environmental loads are uncertain during the treatment because a predictive model for the quality of AMD, the dosage of neutralizer, and the amount of sludge that is applicable for abandoned mines with limited data has not yet been established. In this study, a two-steps predictive model for solution composition and neutralization chemical requirements of AMD in future was constructed based on the geochemical modeling. Requisite input data of the model was the past historical water quality data from AMD monitoring, such as metal concentration and pH in the solution, instead of the sample rocks as other conventional prediction methods. In the first step, solution composition of AMD in the future was extrapolated from the available historical data using geochemical simulation considering the first order kinetics for the mineral dissolution. In the second step, neutralizer dosage and sludge generation in the future was predicted based on the geochemical simulation supposing the chemical equilibrium and oxidation state for all of elements in the solution. Based on case studies of two abandoned mines in Japan, solution composition, neutralizer dosage and sludge generation were estimated. The results of this study demonstrate the effectiveness of our model for the prediction of AMD quality and chemical requirements of neutralization treatment after mine closing. The model is useful for the estimation of the neutralizer dosage and the sludge volume in abandoned mines with limited data. Keywords: acid mine drainage, predictive model, geochemical modeling, first order kinetics, water monitoring

Sep 1, 2012

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisingerm

"As deposits of high-grade base metal sulphides become depleted, attention must be focused on the treatment of complex sulphides, which contain significant fractions of precious metals such as gold and silver. Acid pressure oxidation is a promising process for these materials and the recovery of silver and gold will improve the economy of the process. Gold can be recovered from the oxidised residues, however, silver is incorporated into the jarosite specie and the cyanidation of the resulting residue yields very low recovery.Pressure oxidation of various complex sulphides was carried out at 110-150°C in sulphate media with additions of potassium iodide under conditions similar to industrial autoclaving. The resulting residues were subjected to cyanidation. High recovery of silver, up to 98%, was achieved because its incorporation into lead-hydronium jarosite during the pressure oxidation was minimised, while its deportment into the cyanide-soluble silver iodide was favoured. Silver recovery decreased slightly at high temperatures (140° and 150°C) because of the enhanced stability and kinetics of lead-hydronium jarosite, but this could be overcome by increasing acidity and iodide concentration of the autoclave slurry."

Jan 1, 2003

In this paper, the recovery of copper minerals and molybdenite in the rougher/scavenger banks of two separate mineral processing plants is compared with recovery in laboratory (batch) cells. A number of metallurgical surveys were conducted in two plants treating porphyry copper and molyb-denum ore. Batch flotation tests were performed on plant conditioned flotation feed slurry, in parallel with the plant metallurgical surveys. The effect of flotation feed density on recovery of copper minerals and molybdenite in the plant and batch laboratory cells was investigated. Changes in flotation pulp density had little effect on copper mineral recovery, in both plant and laboratory cells. The ultimate recovery for molybdenite, on the contrary, increased considerably when the pulp density was reduced, both at plant and laboratory scale. Recovery of copper minerals in the plant and laboratory cells was comparable, while molybdenite recovery in laboratory flotation cells was 3%~13% higher than in plant. It is hypothesised that the flotation rate of molybdenite is sensitive to cell hydrodynamic conditions (i.e. local turbulent energy dissipation) more than the flotation rate of copper. The flotation behaviour of molybdenite particles is likely to be predominantly controlled by bubble-particle collision frequency, which is enhanced in high local turbulent energy dissipation environment. For chalcopyrite, the flotation recovery is mostly determined by attachment and stability efficiencies. An increase in local turbulent energy dissipation, while increasing collision efficiency, may negatively impact on attachment and stability efficiencies. The outcomes may have a considerable impact on increasing molybdenite recovery from porphyry ores.

Jan 1, 2014

By Kal Sastry, Anshuman Prasad

This paper presents a population balance model (PBM) for describing the agglomeration process and select a suitable coalescence kernel that can simultaneously describe nucleation, layering and coalescence mechanisms. The PBM is solved numerically by making use of a size discretization procedure in order to simulate iron ore agglomeration in rotating drums where moist feed is added to preformed seeds. Subsequently, a comparison of computer simulation results with the previously published experimental data is provided. Finally, the paper discusses how the current approach can be further extended to the simulation of industrial iron ore agglomeration circuits operated in closed circuit.

Jan 1, 2003

By Urs Peuker, Thomas Mütze, Thomas Leißner, Inga Osbahr

"Mining in the Ore Mountains (Germany) has taken place for hundreds of years and in several stages. Each stage produced its typical tailing. According to the former state of the art of the processing much valuables could not be extracted. This was caused by complex interlocking of the minerals, low grades, or by upgrading processes not sensitive enough for small particle sizes. Thus the processing of these fractions was uneconomically. Modern technical possibilities and rising metal prices bring these tailings disposals into focus for the processing of strategic metals. Mining disposals can be classified in heaps with coarse, low grade rock, which did not undergo a processing, slags and fly ash from smelting, and tailing disposals from mineral processing. The latter is under investigation to integrate them into a geographic information system. The mineral processing of the material will be part of the database besides information about geographic location, structure, amount of valuables, and details of ownership of the heap. The tailings disposals are composed of coarse, low grade, interlocked particles from density separation processes, medium size particles, which are tailings from flotation, and fines with liberated valuables, which did not undergo flotation. Therefore mineral processing of these disposals comprises the separation of liberated gangue by classification, beneficiation of locked valuables with density separation, liberation of valuables by grinding, and beneficiation of liberated valuables with flotation. The presented work shows the results concerning the composition of one exemplary heap and results of the classification as well as of the preconcentration tests achieved with material from this heap."

Jan 1, 2014

By l. Bokányi, T. Varga

"The recycling of waste car tyres is a very important environmental task. The waste tyres usually are re-used or recycled by thermal processes like pyrolysis, gasification or incineration. The main problem associated with these processes is the sulphur content of waste tyres originated from the vulcanisation process, which pollutes the environment and the valuable products (i.e. pyrolysis oil) as well. In our research the desulphurisation of waste, mechanically prepared tyre sample was systematically investigated by the biosolubilisation with Acidithiobacillus thiooxidans, strain Karitas. Parallel, the experiments with sterile 9K nutrient medium were also carried out. It was found that the vulcanisation sulphur can be solubilised due to both the bio- and the chemical leaching, although the bioleaching is more effective. The solubilised vulcanisation sulphur then forms precipitates. The precipitates are forming in the bulk solution, as well as on the surface of rubber particles. The origin of the precipitates was investigated using XRD and scanning microscopy with micro probe. The origin of the precipitates is different: while in the process of the vulcanisation sulphur solubilisation with 9K medium the jarosite (KFe3+3(SO4)2(OH)6) forms, the course of the biosolubilisation with Acidithiobacillus ferrooxidans Karitas is accompanied by the formation of the jarosite and the halotrichite (FeAl2(SO4)4 · 22H2O) as well. The formation of the latter is the biomineralisation. The mechanisms of the bio- and chemical solubilisations are rather different as it was found and experimentally proved by several tests, and depends on the retention time of the solubilisation. Special efforts were done to elaborate the proper separation of the precipitates from rubber particles. Combination of intense dynamic stirring and recycling flotation process to remove the precipitates was applied for this purpose. The surface properties of synthetic jarosite were revealed using zeta-potential measurements at different pH and in presence of collectors. The parameters of the flotation were chosen based on the revealed surface properties of the precipitates. Finally, the sulphur recovery of the recycled rubber was achieved as low as <0.5%, sulphur content of it 0.17%, 12-times lower than that of the waste tyre sample after mechanical preparation."

Jan 1, 2018

By Z. F. Hu

Tourmaline has the characteristics of piezoelectricity, thermoelectricity, spontaneous polarization and far-off infrared radiations. Ultra-fine powders of tourmaline have extensive applications in the fields of electron, chemical and environment protection, as well as health protection. The preparation technology of ultra-fine tourmaline powder is discussed. The key equipment of a pilot plant for producing ultra-fine tourmaline powder with jet mill and stirred ball mill is described. Using this pilot plant facility it is possible to produce tourmaline powder with particle size smaller than 100 nm, and a continuous production process can be realized. The final powder product has many superior performance such as high whiteness and large specific surface area, and it?s a negative ions emission can reach the value of 7190 ions per cubic centimeter.

Jan 1, 2014

By Neill Bartie, Jacques Eksteen, Sharif Jahanshahi, Shouyi Sun

The gradual increase in Cr2O3 levels of UG-2 ores has become a matter of concern for platinum producers in South Africa due to the formation of chromite spinels in melters. The effect of bulk FeOx/MgO ratio, Cr2O3, temperature and oxygen partial pressure on phase stability and composition in the system FeOx-MgOSiO2- Cr2O3-Al2O3-CaO has been studied between 1400°C and 1600°C using the drop-quench technique. An increase in temperature was found to result in a decrease in [Fe/Cr]spinel. An increase in bulk FeOx/MgO caused Mg, Al and Cr in spinel to decrease, forming more magnetite relative to other spinels. [Fe]spinel decreased and [Cr]glass increased with a decrease in oxygen partial pressure.

Jan 1, 2003

By Yuki Tsunazawa, Shuji Owada, Kazuki Tahara, Shinobu Ogino, Chiharu Tokoro

"Printed circuit boards (PCBs) are an important constituent of waste electric and electronic equipment (WEEE), and contain many electronic components with valuable, hazardous or both materials. Recycling of PCBs is an important subject not only from the treatment of waste but also from the recovery of valuable materials. Demand for rare earth metals is expected to accelerate because of their growing use in next generation high technologies. Since some of these metals are concentrated in a specific electronic component, for example, Ta in capacitors, a special and selective grinding such as parts detachment from the board is effective for the recycling of a part of rare metals. However, direct computer simulation method to investigate a comminution/detachment process of PCBs has not yet been established. In this study, our objective was revealing the mechanism of breakage phenomena in comminution / detachment process of PCBs using computer simulation. A special and selective grinding using an agitation mill promoted the removal of components from a PCB by detachment and was an effective method for the recovery of rare metals. Simulant PCBs on which some capacitors were solder-mounted were used for the comminution test using drum type mill with agitator. To describe this mechanism of the parts detachment process, a computer simulation using discrete element method (DEM) was conducted. Although only an indirect simulation using the spherical particle model was possible for part detachment and board breakage, the particle-based rigid body model could directly represent the behaviour of PCBs. Simulation results successfully corresponded to comminution experimental results."

Jan 1, 2014

By Richter, E. Charikinya

"Mineral processing unit models require information on particulate properties such as particle size, solids flowrate and mineralogical composition to model their operations. Process models that describe the separation process can be classified based on the level of information required from the ore, i.e. the feed stream to the separating unit. The most comprehensive level of mineral processing models is the particle-based modelling approach. Particle based modelling describes a modelling approach where mineral composition, mineral liberation and textural information of particles making up the process streams is used in modelling. The advantage of this approach is that all model streams carry particle level information (size, liberation, shape). This information is obtained by applying automated mineralogy techniques such as Quantitative Evaluation of Minerals by Scanning Electron Microscopy (QEMSCAN) analysis which provide accurate and detailed information on process stream particle properties. Currently the use of liberation information in modelling and simulation is rare, due to the limited number of separation models that liberation data as input. The objective of this study is to develop a particle based model for a dry magnetic separator, where mineralogical information is used directly to simulate a dry magnetic separator operation. Magnetic separation tests were carried out on high, medium and low grade magnetite ores using a laboratory magnetic separator. Streams from the separator were sampled and sized for chemical and liberation analyses. A sized mass and elemental balance around the magnetic separator was carried out. The elemental assays of each stream were converted to mineral quantities and a sized mineral balance was done. QEMSCAN measured liberation data was reconciled to the mineral balance based on mineral quantities obtained from chemical assays. This was followed by the development of a particle based model that calculates the trajectory of a single particle based on its mineral composition and textural properties. The model was tested on experimental data and was able to predict the effect of variation in process feed stream mineralogical attributes (liberation, grade, particle size) on magnetic separation performance. Results of this study highlight the benefits of the particle based modelling approach. INTRODUCTION The extraction of mineral values from ore requires liberation of the value minerals from the gangue followed by their separation. Liberation is achieved by size reduction operations (Desmond, 2008; Fuerstenau and Abouzeid, 2002). Separation of gangue material from value mineral takes place in various mineral upgrading stages such as classification, magnetic separation and flotation. In these concentration stages value minerals are separated from gangue minerals based on the physical properties of the ore particles making up the feed such as size, liberation, volume of magnetic material and density. The success of separation is related to the liberation of the feed particles, the performance of the separation technology applied, as well as the inherent characteristics of the feed material (Leißner et al., 2013)."

Jan 1, 2018

By Sudarshan Martins, Peter Radziszewski

"Tumbling mills are machine, operating in non-equilibrium, capable of applying forces on the ore contained within, causing the ore to break down. The action of the mill on the ore is very inefficient, producing a large quantity of heat. The inefficiencies of the mill drive the desire for improvement, spawning research and development activities. Given the non-equilibrium nature of the mill, the theory of Large Deviations is proposed as the framework that captures the state of the mill. The theory of Large Deviations allows for the determination of the rate function and the scaled cumulant generating function (SCGF), for systems in either equilibrium or non-equilibrium. Powerful connections can been made between familiar concepts of statistical physics and the concepts introduced by the theory of Large Deviations: entropy can be associated with the rate function; the scaled cumulant generating function with the free energy. It is shown that observables, compatible with Large Deviation theory, can be identified for the tumbling mill. Here, the time series of the energy associated with an element of the charge is such an observable. Furthermore, using some experimental data, it is shown that the time series of the energy can define a rate function, thereby describing the system within the Large Deviation framework. Finally, a discussion of the results is given, particularly how this theory can be further developed for tumbling mills."

Jan 1, 2014