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By Rob Morrison, Andrew Scott

"Long before a modern mine commences operations it has already become a wealth of information. After start up, it can generate enormous quantities of data – especially with semi-automated data acquisition by instrumented mine equipment. Much of this data is of limited use for evaluation of (potential) performance unless it links in some way to the site business model.An underlying reason for this waste of data is that the different cultures, financial, technical, community, environmental, etc, not only have many areas of interest but also have very different conceptual models by which they evaluate performance.It is too ambitious to attempt to bring all of these cultures together – in a single step. However, the success of the Mine to Mill ™ project has demonstrated that substantial operational value can be added by using a more integrated approach to comminution. The next logical step is to integrate measured data and then to track performance from ore body model to saleable product and waste disposal.The path from resource to product also represents a path from very sparse, highly variable data to much more detailed measurement and more representative sampling. However, in both cases the data collected is usually strongly focused on the technical requirements – not on the business model.This paper emphasises the difference between data and information. There is considerable potential for confusion between the two as both data and information are often expressed as numbers. For the purpose of this paper, data and information are distinguished by their uses.A data point (or datum) is a measurement. By way of contrast, information provides a basis for decision making."

Jan 1, 2003

By Mary Stewart, Jim G. Petrie, Geoff Brent

"Life Cycle Assessment (LCA) is gaining increasing acceptance as a decision-support tool by which to evaluate the environmental performance of a product, process or service. This is evidenced by its inclusion in international policy documents (for example in the European Union’s Integrated Product Policy) and in environmental management standards (the ISO 14 040 series of environmental management codes relate to LCA). In response to this, the minerals industry has conducted a number of commodity-specific LCAs. These include studies for global production of a number of commodities including copper, nickel, aluminium and steel. In addition, a number of minerals companies profess to use LCA as part of their suite of project and technology assessment tools. Often, this collected use represents more a situation of “we do this because we’re told it’s good for business” rather than from any demonstrable evidence of this fact. This has led to a situation of much confusion and disillusionment within the industry, exacerbated by the obvious current limitations of LCA to accurately reflect the environmental performance of minerals and metals.Our point of departure here is that LCA, conforming as it does to the tenets of environmental systems analysis, is a valuable starting point, and that there is merit in exploring to what extent the methodology can be enhanced to better reflect the environmental performance of minerals and metals. Specifically, we explore here the further development of LCA to address the following:• Land Use issues• Consumption of Abiotic Resources including metallic and non-metallic minerals, water and soil)• Human and Eco-toxicity issues relating to mobility and bio-availability of metals• Salinityand address these through selected experimental and simulation case studies relating to energy- and base minerals production. Advances resulting from the United Nations Environment Programme/Society for Environmental Toxicology and Chemistry Life Cycle Initiative are presented in that they directly affect the application of LCA to mining, minerals and metals. Comments are offered on how best the mining and minerals industry might interface with future developments resulting from this Initiative in order that the Initiative can deliver outcomes which render LCA a useful tool for decision making in mining and minerals processing."

Jan 1, 2003

By L. A. Vaisberg

"Crushing and grinding are the two most common industrial processes. These processes consume nearly 20 per cent of the entire electric power produced worldwide. This enormous amount of electric power consumed results from the fact that modern crushing and grinding machines employ the processes first introduced by the prehistoric man, namely those of compression, impact, attrition, and cutting. The material thus handled decomposes indiscriminately, and almost completely ignoring the microscopic cracks and other defects of its structure. Apart from the irrational use of the power, the crushing and grinding processes currently in use result in irretrievable loss of useful components or else in a substantial deterioration of the final products obtained, all as a result of incomplete grinding or, reversely, of overgrinding, palletizing, or fracture of particles.The principal type of equipment that has almost universally been used all over the world for more than 150 years for crushing both natural and synthetic minerals comprises unbalanced jaw and cone crushers. The driving element of crushing bodies in these machines is an unbalanced weight, which transfers the crushing body, allowing it to squeeze the material within the eccentricity value only. The maximum reduction ratio achieved by such a drive is 5, which is due to the rigid kinematic arrangement of the crusher, its dynamic unbalance, and the impossibility of increasing the number of impacts on the material being crushed. Moreover, conventional machines cannot cope with super hard materials, and their mechanism is vulnerable to damage by uncrushable objects.On the basis of fundamental research into the theories of solid body and vibration, OAO Mekhanobr- Tekhnika have developed a range of vibrating jaw and cone inertia crushers that make a reduction ratio of 30 feasible in an open-circuit operation with the reduction ratio monitored within a wide range. In these crushers, the eccentric drive is replaced with a vibrating one. In this way the rigid kinematic drive became dynamic, thus allowing pieces of material to be crushed in a thick layer due to the effect of their bumping into each other, and with the amplitude changing automatically. This results in a number of advantages as compared with conventional crushers:"

Jan 1, 2003

By E. Barsky

"The aim of separation is to obtain two products that are as distinct as possible from each other. It is currently believed that the most objective criteria for the quality of a separation are the Hancock criterion and the entropy criterion.1. Hancock criterion:- for yield of fine product"

Jan 1, 2003

By M. Salas, L. Rolf, H. Z. Kuyumcu

"Industrial use of abrasive stress takes place in the area of fine grinding and in order to clean surface contaminated soil particles. Also, at many mechanical operations abrasion emerge as an unintended side effect. At the Institute for Raw and Waste Material Processing at the Technical University of Berlin systematic investigations are carried out, to further the knowledge regarding the dependence of abrasion process on material properties and stress mechanisms as a basis for design and optimisation of the process or for its avoidance. Aim was the mathematical description of the abrasion process running with a single particle stress. For the purpose of investigations an agitation cell was used. Limestone served as material.In the presented work the influence of particle diameter, particle shape and collision energy on the mass and particle size distribution of abrasion debris was studied. The surface geometry of the particle was characterised by the particle shape factor ?x and the particle diameter dp. The particle shape factor ?x stays in direct relation with the abrasion degree x, and can be substituted by a mathematical function of x.Physically the particle shape factor ?x can be interpreted as a proportion of abrasive stresses splitting up complete crystals and crystal fragments. These two different mechanisms depend on different ratios of curvature of the surface of the stressed particle. The abrasive stress of strongly curved surface areas leads to separation of complete crystals. The abrasive stress of weakly curved surface areas leads to separation of crystals fragments. Accordingly the mass of wear mAb and median diameter of the abrasion debris d50 are different. The derived mathematical relations consider this behaviour by the particle shape factor ?x , which represents the ratio of the mixture of both stress mechanisms. The dependence of the particle shape factor ?x on the abrasion degree x with an exponent approximately to 2/3 points out that the particle shape factor ?x represents a surface area relation."

Jan 1, 2003

By Jochen Petersen, David G. Dixon

"Although heap leaching may be perceived as a somewhat low-tech route for the extraction of low-grade minerals, the underlying physical, chemical and biological processes are in fact extremely complex. There has been increased interest in heap leaching of sulphide minerals in recent years with the advent of controlled bio-heap leaching, and the need to mine more marginal ore deposits.A detailed investigation into the dynamics of heap leach processes has provided much insight into the underlying complexities, and has led to the development of a sophisticated modelling tool, HeapSim. Some of the sub-processes that are modelled include mineral kinetics, particle size effects, bacterial growth, oxidation and adsorption, gas adsorption, pore diffusion, bulk advection, gas balance and heat conservation. The interplay of these various sub-processes is illustrated in the paper.Two case studies are presented which illustrate specific features of the model for different applications and how these have helped to identify key areas of concern. The first is focussed on chalcocite heap bioleaching, which shows that by nature of the reaction the process is strongly dependent on the initial supply of acid to the mineral site. In heaps this acid supply can be severely limited by the rate of diffusion from channels of flowing solution into stagnant zones of the heap, whereas in narrow-bore laboratory columns this effect is not observed."

Jan 1, 2003

By Kari Moen, John Rasmus Leinum, Jarle Hjelen, Terje Malvik

"Industrial minerals may contain the same elements in approximately the same amount. In these cases backscatter electron imaging or chemical analysis are not sufficient to identify the minerals. Another problem arises when micro textures are not detectable in traditional imaging or the grain size is smaller than the X-ray spatial resolution.As a supplementary technique in these cases, application of crystallographic information by electron backscatter diffraction (EBSD) in the scanning electron microscope (SEM) may be a suitable method. The technique has been demonstrated on three Norwegian mineral raw materials and one Italian marble and shows that it has some advantages compared to traditional techniques.• quantitative measurements by ebsdCommon automatic techniques describing the mineral contents and the occurrence of minerals in free and locked particles, are based on optical-, backscattered electron (BSE)- or X-ray-signals. There are various commercial software systems on feature analysis by backscattered and X-ray signals in combination with image analysis (e.g. Oxford Inca Feature, CSIRO QemScan).Especially in silicates, the occurrence of similar elements in the different minerals is common. Sometimes the various minerals not only contain the same elements, but also approximately the same amount of each element. In these cases BSE imaging and chemical analysis are not always sufficient for identification."

Jan 1, 2003

By Máximo Pérez, Julio C. Videla, Rosa Dzioba

"This paper reports the hydrometallurgical treatment of gravity concentrates of gold samples and outcrops associated with graphite ores obtained from:• flotation tailings of crystalline graphite minerals• outcrop samples of graphitic rock associated with auriferous minerals and free gold located in the Villa Union district and surrounding areas - La Rioja Province - Argentina.Previous studies of the flotation potential of crystalline graphite minerals failed to consider the presence of noble metals.The samples represent a mineralized zone of crystalline graphite which is distributed in different formations with a NE - SW trend in Maz, Punta Colorada and Las Ramaditas hills, covering an area of about 300 square kilometers."

Jan 1, 2003

By Malcolm Mudge

"One of the oldest mining areas in the World exist in Africa and the Middle East. This area is being exploited by foreign and local mining entities. Several large plants, both foreign and local as well as small operators, conduct their mining business on a scale which would be could be prohibited in any other part of the world. Relatively recent European disaster with tailing disposal and breakout has highlighted the problem.More important to the author is that the presence of foreign entities in zones which have not remedied the situation but has heightened the concern due to those entities using similar outrageous methods in treatment of waste. The abject misuse of technology cannot be permitted to continue and the lack of any metallurgical knowledge in the treatment of gold ores is considered deplorable for the majority of third world countries.The destruction of cyanide is simple and straightforward and requires no special skills. In South America, we developed a system that is modular, compact and can be operated in batch mode to cater for several clients, as required. Larger installations would require a separate module, as treatmentwould be on a continuous basis."

Jan 1, 2003

By N. Raeis Hosseiny, S. H. Bassir

"Chador-Malu iron ore is one of the most important iron mines of Iran.About 98 percent of Fe in the ore is in shape of Magnetite, Hematite, Martite, aqua oxide of Iron and the other irons are with ferrous silicates, actinolite, cholorite and ferrous dolomites. 1% of Fe has replaced in pyrite. The phosphor distribution in the ore is non-hemogenous and its average in the whole of the deposit is 94%. It is in shape of Apatite.This mine contains considerable phosphor, which makes it useless for metallurgical uses. At this mine the phosphor is reduced in the iron ore at two steps. At the first step, magnetic part of the ore is separated from the gangues and phosphors by magnetic separator. At the second step, the ore is enriched by the flotation methods. Experimental flotation methods to obtain the optimum conditions are as follows:• Effect of Starch as Hematite depressant with ATRAC as Apatite collector• Effect of Sodium silicate as Hematite depressant with ATRAC as Apatite collector• Effect of ASAM as Apatite collector with Sodium silicate as Hematite depressant• Effect of ATRAC (BEROL) as Apatite collector with Sodium silicate as Hematite depressant• Effect of ASAM & ATRAC mixture as Apatite collector with Sodium silicate as Hematite depressant• Effect of Kcarbonate as pH-modifier• Final test to Optimize pH, Collector, DepressantAt this research we have found the optimum circumstance of the flotation of Chador-Malu iron ore in order to decreasing phosphors of iron oxide and floating of Apatite to make pure Hematite.To reach the optimum conditions, some tests were done with different amounts of pH, collector and depressant. The results are as follows:"

Jan 1, 2003

By Elena L. Chanturiya, Vladimir A. Bocharov, Roman A. Amosov

"In many volcanogenic base metal deposits of Russia the gold is closely associated with copper sulphides and pyrite. The recovery of gold associated with pyrite is especially difficult problem.Investigations of gold chemical state and mineral forms in copper-zinc sulphide ores of Gay and Barsuchiy Log deposits in the Urals have been made using EPMA, optic image-analysis, XRA, SEM, thermo-electrical force measurements and selective gold leaching experiments.Two gold varieties are determined: 1) free native gold particles (from 5 µm up to 0,25-1,0 mm), which can be liberated after grinding of ore up to 0,074 µm and named “free gold”; 2)”invisible” gold, including finely disseminated native gold and chemically bound gold. The second variety can’t be disclosed during grinding. Free gold can be recovered by gravitation and flotation while the processing behaviour of “invisible” gold is determined by properties of gold-bearing sulphides: pyrite and chalcopyrite. According to results of diagnostic leaching experiments in ores of deposits mentioned above the part by weight of free gold reaches 70%, the part by weight of the ”invisible” gold is up to 20%. About 10% of gold is enclosed in quartz and acid-soluble minerals.Theoretically (taking into account gold distribution data) it’s may anticipate gold recovery by gravitation up to 60%. However after grinding up to 50-60% of class –0,074 mm only about 40% of gold passes into oversize product including 30% of free gold and 8% of ”invisible” one. It can be recovered by gravitation. Remaining free gold and ”invisible” gold can be extracted by flotation – 25% in total. Inevitable gold losses in tailings may reach 8-10%."

Jan 1, 2003

By Osvaldo A. Bascur, J. Pat Kennedy

"The profitability of mining and metallurgical operations continues to lag behind that of other industries despite the technical advances that have occurred in recent years. A primary reason for poor performing in this economic sector is the lack of integration of mining and metallurgical information. The mine cut-off grade can be optimized if mining and metallurgical engineers have the data to optimize milling for the type of ore in hand.Integration of mine transactions, stockpile inventories, process flows and assays is the key to determining the economics for each blast strategy in a mining site. Real-time information from manufacturing assets greatly affects the profitability and flexibility of a company, but gross errors from faulty sensors, inaccurate instrument calibration, or incorrect process models may corrupt actionable information. New software tools can model the process, sift through available data to identify and eliminate gross errors, and use statistical data reconciliation to create materially balanced and consistent readings. The reconciled data is unified for use by both monitoring and decision making processes.Creating a real-time information environment where upgrade and change are allowed is becoming an accepted methodology to accelerate and simplify the integration of applications such as production monitoring, equipment performance management and yield and inventory management."

Jan 1, 2003

By Leon Lorenzen, Charlene Gokhale

"In excess of 24 x 106 tons (Eskom, 1997) of coal-derived fly ash is produced annually in South Africa for the production of electric power. A large quantity of this ash is disposed of as a solid waste in landfills, thus posing a serious environmental problem. Due to the shortage of landfill sites, new ways of utilising fly ash are needed. Recently several authors have shown that various combustion fly ashes can be converted into zeolites to obtain industrial products with applicability in environmental management. Geopolymerisation has emerged during the last few years as a possible solution to some waste stabilisation and solidification problems. henolic compounds have been shown to be toxic to soil microorganisms at the parts-per-million level. Indeed several of the organic compounds classified by the U.S. Environmental Protection Agency as priority pollutants, are phenols. Immobilisation of phenols by adsorption on zeolites and encapsulation in a geopolymer appears to be a promising solution to this problem.This paper reports a technique for the production of a low-silica sodium zeolitic material from fly ash (zeolite NaP1), and its application for the stabilisation of phenols by adsorption and subsequent encapsulation in a geopolymer matrix. A commercial zeolite, clinoptilolite was also utilised as an adsorbent. Due to their uniform pore sizes and large surface areas, zeolitic materials are suitable for ion exchange and adsorption of certain organic substances. Adsorption data show that the commercial zeolite, clinoptilolite was an effective adsorbent for organics. Adsorption data showed that between 51.2 ppm and 74.3 ppm of chlorophenol or between 15.4 ppm and 32.5 ppm of phenol could be adsorbed. Physical encapsulation of the coated zeolite loaded with organic within a geopolymeric matrix increased the compressive strength of the matrix from 28.80 kN to 40.79 kN. Leaching data for the various geopolymer matrices with encapsulated and loaded zeolites show no organics being leached from the system at a detection level of 2ppm. According to the SABS these would have been acceptable organic concentrations within a waste water stream."

Jan 1, 2003

By Susanna G. de Jager, Francis W. Petersen

"To enable the prediction of reagents suitable for fine coal flotation, it is necessary to develop a methodology applicable to different South African coal types. Statistical confirmation of the applicability of this methodology is important to avoid recommendation of reagents on a trial and error basis.The study included 5 coal samples from different collieries and included Highveld seam 3 and 4 coal (as one sample), Waterberg coal (zone 10 -11), Highveld seam 5 upper coal and Witbank seam 2 and seam 4 coal. Seam 3 and 4 (mixture) coal, Waterberg and the seam 5 upper coal were all found to be vitrinite rich coals. The coal characterisation study included petrographic analysis, proximate analysis, float-sink analysis, oxygen-containing functional groups, surface extraction, flotation release analysis and contact angle measurements. Flotation tests were used to validate expectations from the characterisation of the coal samples.RESULTSThe flotation data indicated that all of the coal samples were amendable to froth flotation. The best results were obtained with the Witbank seam 2 coal and the poorest flotation with Syferfontein seam 5 coal. The flotation tests showed that the best reagents to float all of the coal samples studied were iso-decanol and dodecene. These reagents produced flotation products that were near to the release curve, which are the optimum flotation results (obtained when using iso-paraffin as collector). Dodecene resulted in low ash products and iso-decanol in high yield products."

Jan 1, 2003

By G. Onal, E. Gock, H. Dincer

"During the conventional chromite dissolution process; chromite ore concentrates were ground to at least <90 µm using the ball mill and after adding Na2CO3 and leaning material (instead of CaCO3 also residues from the leaching process) at a ratio of e.g. 1:0.75:1.2, depending on the specific formulation, follows the digestion e.g. in a rotary kiln, heated in countercurrent. The reaction time is 3 to 8 h. The calcine is comminuted and leached with water or a thin chromate solution. Depending on the type of ore used, the yield is 75-85 %. The disadvantage of the above-described process is that it is impossible, using current technology, to achieve a complete digestion of the chromite ores and that the chromium-containing residues have to be disposed of as special waste, involving a large financial effort.The subject of this study was the investigation of the effect of vibratory milling on chromite dissolution. The impact stress in the vibratory mill causes the mechanical activation of chromite, which is characterised by lattice defects. The degree of mechanical activation can be quantified by measuring the relative X-ray diffraction intensities at the parent lattice planes of chromite. Each relative X-ray diffraction ratio correlates with a certain degree of digestion. As opposed to vibratory milling, a complete digestion of chromite using a ball mill is impossible, even at extremely long grinding times.In this investigation a chromite concentrate from Pulpinar/Kayseri with content of 44 % Cr2O3 and the Eccentric Vibratory Mill was used. In order to verify the effect of the vibrating grinding on chromite dissolution, reaction kinetic investigations on digestion and leaching were carried out."

Jan 1, 2003

By Kauko T. Ingerttilä, Jouko O. Kallioinen, Jaakko O. Leppinen, Alexander V. Lashkul, Vladimir E. Nenno

"Separation in Froth (SIF) is a process for the separation of mineral particles during their descent downwards through a moving froth layer, generated on the surface of water or some other liquid media by means of a bubble generator and frother. Due to the special operation principles of SIF it is possible to separate mineral particles that are about 10 times coarser than the optimal particle size for conventional flotation. In this paper the performance of the SIF technique is presented in the separation of apatite, calcite and silicate minerals from various industrial sources, based on tests with laboratory and pilot plant-scale SIF machines. Basic laboratory test results of the flotation of pure diamonds are also presented.It was shown that calcite, apatite and diamonds with particle size up to about 3 mm can be successfully floated with SIF at high recovery and grade, provided that the degree of liberation is sufficiently high. Coarse calcite (+0.25-2.8 mm) was concentrated with reverse SIF in one flotation step at 87% recovery with better than 99% grade. Apatite particles coarser than 0.2 mm are not well floated in the conventional flotation circuit leading to high P2O5 content in the coarse size fractions of flotation tailings. On the contrary, SIF is capable of recovering such coarse particles at high recovery. However, P2O5 content of the SIF tailings starts to increase at about 0.7 mm due to insufficient liberation of apatite. At higher particle size the lack of hydrophobicity of apatite particles is also likely to lower the recovery.The pilot plant testwork showed that SIF can be successfully used at operating plants not only for preliminary upgrading of the feed of conventional flotation, but also for producing final grade calcite concentrate (>99.5%) from the screen overflow or from the cyclone underflow in a particle size range up to 1 mm. It was particularly promising that the separation took place in one SIF flotation step, instead of several stages of the conventional flotation circuit, with over 90% calcite recovery. The specific capacity determined with the 1 m2 pilot plant unit was approximately 30 t/m2h. Simultaneously the consumption of chemicals was significantly lower than for conventional flotation."

Jan 1, 2003

By S. K. Kawatra, S. J. Ripke, T. C. Eisele

"An estimated 600,000 tons of bentonite clay are used annually in the U. S. as binder for production of iron ore concentrate pellets. Since this is a significant cost item for the plants, and the addition of bentonite to the pellets contributes undesirable silica into the finished pellets, there is considerable incentive for finding methods to reduce bentonite use. One way to reduce bentonite levels is to selectively use those bentonites that are most effective in this application, so that a lower dosage will still produce a sufficiently strong pellet. Unfortunately, there are no satisfactory methods available for accurately predicting which bentonites are actually most effective, short of using them to actually make pellets. One of the popular methods for attempting to evaluate bentonites is the “Plate Water Absorption” (PWA) test. While some plant operators accept the PWA results as indicating the relative quality of bentonites, others disagree and claim that, over a fairly broad range of values, PWA does not correlate with bentonite performance.Since both Ca+2 and Mg+2 ions are known to reduce the swelling and water absorption capacity of bentonite, it was believed that the presence of these ions in plant recycle water could be changing the bentonite performance. Since the standard PWA test uses only distilled water for its measurements, it could not detect these effects. Experiments were therefore carried out on a number of different bentonites using a modified PWA tests, with plant recycle water replacing the distilled water. These experiments showed little effect of the plant water on the PWA value, and chemical analysis of the water showed that the levels of dissolved salts were quite low.Water and accompanying salts were then extracted from a magnetite concentrate filter cake by rinsing with distilled water. Analysis of this water showed an extremely high level of dissolved salts, particularly salts of calcium and magnesium. When concentrations were compared with the recycle water from the plant filters, it was determined that levels of Ca+2 and Mg+2 retained in the filter cake were over 500 times higher than levels in the recycle water. This extreme elevation of soluble salts in the filter cake is believed to be due to adsorption of these ions into the electrical double layer of the magnetite particles."

Jan 1, 2003

By Dave Deglon

"The Western Cape Mineral Processing Facility (WCMPF) is a collaborative educational initiative between the Departments of Chemical Engineering of the University of Cape Town, the University of Stellenbosch and the Cape Technikon. The primary objective of the WCMPF is to facilitate the education, development and graduation of suitably qualified engineering graduates and diplomates for the mining industry. The WCMPF consists of academics and Technical Officers in the Departments of Chemical Engineering of the three tertiary institutions. The Technical Officers are usually metallurgists, with several years of industrial experience. The main objective of the Technical Officers is to improve the practical education of mineral processing students. In addition, the Technical Officers are responsible for organising an annual mineral processing student field trip for students from all three tertiary educational institutions. In recent years the WCMPF has embarked on a number of additional initiatives aimed at improving the quality of mineral processing education. These include the development of several new pilot plant practicals, an initiative in pyrometallurgy, the introduction of novel ‘end to end’ or ‘integrated’ practicals and the use of mineral processing simulation packages to complement the practical training.The WCMPF has been functioning for well over a decade and, by virtue of this, might be considered a successful collaborative educational initiative. The WCMPF has played a key role in the education of over five hundred mineral processing graduates and diplomates. During this time period, the WCMPF has gained a body of internal knowledge which might be of benefit to other educational institutions, viz."

Jan 1, 2003

By M. Barsky, E. Barsky

A study was conducted to elucidate the relationship between the hovering velocity and the particle settling velocity. The experiments were carried out in a water medium on five materials ranging in density from 1.070 to 4.000 kg/m3. Analysis of the results with allowance for the distribution of stream velocities over the cross section of the pipe revealed that the final settling velocity of the particles was equal to their local hovering velocity (on the stream axis), and not to the average velocity of vertical flow as is generally believed. It therefore follows that the kinetic structure of the stream must be taken into account when constructing theoretical models of the process for purposes of computation. In addition, the optimal stream velocity is not always equal to the hovering velocity and in fact is governed by other factors as well. Illustration is provided by the results of a study conducted in a vertical cascade classifier comprising eleven identical stages. The feed material was introduced at each stage successively beginning with the topmost (i* = 1 ) and ending with the lowermost (i* = 11). First, the stream velocity that yields optimum separation conditions at each stage of the cascade (i.e. k=50%, k being the yield of a given size class in the fines for a single stage) was sought. Subsequently the conditions of optimal separation for the instrument as a whole were determined (i.e. F(x) = 50%, F(x) being the yield of a given size class for the entire instrument). The results of the study are presented in the table.

Jan 1, 2003

By Zoran M. Stevic, Mirjana M. Rajcic-Vujasinovic, Zvonimir D. Stankovic

"Huge electrochemical investigations have been performed on Technical faculty in Bor (Serbia) which main goal was the clarification of the copper sulfide minerals behaviour in hydrometallurgic and flotation processes. Modeling of these processes was a part of the effort for better understanding of the reaction mechanisms.The consideration of electrical analog circuit and mathematical model of processes at interfaces copper sulfide/electrolyte (CuS/(CuSO4+H2SO4), Cu2S/H2SO4 and CuFeS2/H2SO4), based on studies of the overvoltage – time transients, will be presented. The transients were obtained using single pulse galvanostatic method and electrochemical cell with standard three electrode assembly. In that goal it was developed an original system for computer measurements that enables the application of several methods for electrochemical investigations (galvanostatic, potentiostatic, cyclic voltammetry, electrochemical impedance spectrometry etc). The system was tested and adjusted using commercial electrochemical equipment made by AMEL, Milano.In the first stage of consideration the different equivalent electrical circuits have been tested by computer programme OrCAD 9.2 in order to identify the circuit with responses equivalent in shape to experimentally obtained ones. In that way it was established a configuration of an analog electrical circuit for investigated electrochemical system. That phase enabled only very rough determination of values of circuit components and their relative ratio.In the second stage the method for determination of all elements of electrical analog circuit is described. It is based on mathematical consideration of a given circuit on one hand, and valves of the overvoltages at selected times, obtained from charging and discharging parts of galvanostatic transients, on the other."

Jan 1, 2003