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By B. Van den Bogaert, K. Binnemans, T. Van Gerven

Europium is one of the most critical rare-earth elements due to the limited supply of this element combined with a high demand for red lamp phosphors. Therefore, the recycling of europium from end-oflife lamp phosphors has become increasingly important. Photochemical reduction of europium(III) to europium(II) and subsequent removal from rare-earth mixtures by precipitation as EuSO4 is a very selective and efficient method to recover europium from binary europium/yttrium solutions. It is shown that full separation of europium and yttrium is feasible from laboratory prepared non-equimolar Eu/Y mixtures up to a ratio of 1/20, which reflect the composition of red lamp phosphors. Optimal conditions were determined at pH 4 with isopropanol as a radical scavenger, which is a less harmful and toxic compound than the commonly used formic acid scavenger. Europium removal efficiencies of more than 95% were achieved, with a purity of 98.5% of the EuSO4 precipitate. The irradiance of the used light source, expressed in mW/cm2, has a large impact on the illumination time needed to remove europium from the solution. It is observed that higher irradiance results in a shorter induction time, i.e. a period during which virtually no europium is removed, and a faster removal rate once the induction time has passed. The photochemical separation technique was applied to recover europium from leached industrial red lamp phosphor (YOX) powder, with a Eu/Y ratio of 1/30. Europium recovery of 50% was reached with a purity of 96%, proving the feasibility of this method for the recycling of europium from end-of-life lamp phosphors.

Jan 1, 2016

By R. Siwik, N. K. Davé

"The national reactive tailings (RATS) program is a co-operative industry-government effort to develop practical techniques for closure of reactive tailings areas. This paper summarizes the RATS program objectives and areas of research, and details the Noranda/CANMET project on the Waite Amulet tailings.Geophysical and biohydrogeochemical investigations were carried out at an inactive copper-zinc mine tailings site, Waite Amulet, in Noranda, Quebec. Geophysical investigations consisted of seismic, electromagnetic conductivity and electrical resistivity surveys to determine the thickness of the layers above bedrock and to map conductivity variations within the tailings and the immediate outlying area. Biohydrogeochemical investigations consisted of installing multilevel piezometer nests to determine groundwater flow patterns and porewater chemistry, obtaining solid core samples and characterizing for physical, chemical and mineralogical parameters, and iron oxidizing and sulphate reducing bacterial counts.The geophysical survey indicated a bedrock ridge extending under the tailings from the northeastern outcrop which may act as a porewater boundary layer. The survey also indicated a 2 to 20 m clay layer underlying the main tailings dam. Preliminary results of the saturated zone porewater chemistry have indicated three major zones of high electrical conductivity varying between 1,000 to 12,000 µs and pH between 3.4 to 8. Lower pH and high metal and sulphate concentrations were obtained in a shallow zone near the water table. With depth, the concentration of metal and sulphate ions decreased and pH increased below the water table. The underlying clay layer is relatively impervious -and most of the seepage from the tailings is probably exiting from the sides of the impoundment dam."

Jan 1, 1987

By Makarinskym F. M.

"This paper describes mechanical and operating modifications that were and are being made to current on-line flotation cells at Falconbridge Nickel Mines concentrators. Improved metallurgical performance and metal recoveries of some 3·4% over the past ten years are the end result of the modifications made. The paper acknowledges the contribution of operating, technical and maintenance personnel and the Company ""suggestion plan"" program. 1. INTRODUCTIONFalconbrirdge Nickel Mines Limited, incorporated in 1928 is a major product of nickel, copper,coba1t and other metals and minerals. The Canadian Nickel Division operating facilities in the Sudbury Area currently includes seven mines, two concentrators, and a smelter.For many years at all concentrators, improv0mcnts in metal recoveries have been continually under investigation. One area was to improve the flotation cell performance. This paper will deal with mechanical and operating modifications to the cells at the Strathcona and Falconhridge Ni-Cu sulphide concentrators, at the Sudbury Operations.One of the prime means to mineral beneficiation processing has been, and will continue to be, the basic froth flotation cell. The efficient operation of a flotation cell is the key to satisfactory metal selectivity and recovery. The essence of good design is simplicity. Changes to cell design can contribute to a significant improvement in metal recovery.Over the past 10 years, modifications to the flotation cells have contributed to an improvement of some 3-4” in mineral recovery. Providi11g tl1c initiative for improvements include operating, maintenance and technical personnel, as well as the employee suggestions submitted th1·ough the Suggestion Plan Program."

Jan 1, 1982

By Tobias Riedel, Peter Ay, University of Applied Sciences, Bianka Bade, Nicole Pausch, Bernhard Gemende, Florian Logsch, Matthias Leiker, Satyanarayana Narra, Claudia Glaser

This study focusses on the production of micro-structured agglomerates with high porosity from iron (III)-hydroxide-containing materials as adsorbent. A fractal-like structure of the agglomerates was created through a two-stage agglomeration process. Developing porous structures was necessary to increase the adsorption capacity. Various materials were used for the agglomeration experiments: i) filter cake (dry matter content 23 to 27 wt.-%); ii) FerroSorp®DGµ, a product which is already being used commercially for various applications in water cleaning. These materials in the pristine state have different characteristics such as dry matter content and particle size distribution. The desired optimised agglomerates can be achieved with the help of additives or binders, respectively. Additionally, the agglomeration process parameters play a vital role. In order to produce agglomerates with high porosity, the process was carried out in two steps. Firstly, FerroSorp®DGµ (d90 < 30 µm) was agglomerated jointly with the aforementioned filter cake in an Eirich intensive mixer (particle size range 125 µm < d90 < 500 µm). The second agglomeration step post drying was carried out in a pelletisation disc or in an Eirich intensive mixer with the addition of polymeric binders (up to particle sizes ranging from 2 to 4 mm). Agglomerates were characterised both in short and long term loading tests using phosphate as model ion. Contact times were less than 10 min, similar to practical application in percolation columns, or more than 7 days, respectively. The results show that the agglomerates produced in the two-stage pelletisation process have more advantageous properties like better accessibility of the active sites obtained by specificly influencing the particle size distribution during the two-stage pelletisation process.

Jan 1, 2016

By Lorne Roberts

"This paper describes: how Falconbridge&apos;s fire protection system meets the needs of the Lockerby Mine; why the system was chosen over other alternatives; how it is unique, but can be applied to any underground situation; details of the system; how it was installed; the role of a fire protection company; and general considerations when choosing afire-suppresant system.IntroductionIn May 1981, after about three years of searching for the best fire protection system for the re-opened Lockerby nickel mine at Whitefish, near Sudbury, Ontario, Falconbridge Nickel Mines Ltd. installed an AFFF type of fire suppression system. It was designed and supplied by the Fire Protection Systems Division of Levitt -Safety Ltd.The system protects against loss of life, equipment and/or production, and it complies with legislation should fire occur in a fuel storage area and/or scooptram garage and service bay at any or all of the three levels near Shaft No.2.About 18 months after Levitt-Safety began working with Falconbridge, the system was designed and installed at a cost considerably less than that which would be incurred if fire damage caused the loss of two days of production.The fire protection system, which overcomes a limited water supply, is a self-contained balanced pressure proportioning system. It senses the flow and automatically determines the correct concentration of foam to water. It is triggered by a release mechanism which operates a bank of nitrogen cylinders, which in turn pressurize a pressure vessel to expel the foam concentrate and water from the tanks. This solution is piped to sprinkler heads in the specific area."

Jan 1, 1982

By Garth A. Maki, Douglas M. Smith

"The largest Canadian Lamella thickener installation to date, with 13,600 square feet of effective clarification area, is being successfully operated at the Rocanville Division of the Potash Corporation of Saskatchewan. This paper describes the operational principles and design features of the Lamella thickener, the testwork leading to its specification f or the Rocanville phase two expansion project and a review of the performance of the full- size unit which was ultimately installed.IntroductionThickening equipment operating in the Saskatchewan potash industry is generally situated within the main refinery building or a separate insulated an d he a ted structure due to the harsh winter climate and the need to closely control plant brine temperatures to en sure good flotation circuit performance Because these thickeners process large volumes of slurries, conventional basin-type designs tend to be large, ranging up to 46 metres in diameter or more. As part of the general effort to minimize capital costs, the potash industry has begun investigating the use of alternate high capacity, compact thickener designs. In this regard, PCS Rocanville undertook a program in 1978 to evaluate a LamellaTM thickener and one other type of ‘High Rate&apos; thickener as alternatives to a conventional design for the phase two expansion project.This paper describes the operational principles and design features o f the Lamella thickener (manufactured by Axel Johnson lnc.), the testwork leading to the specification of a Lamella for the Rocanville expansion project and are view of the performance of the full size unit (1486 m2 of the effective settling area) which was ultimately installed and is now successfully operating in the Rocanville plant."

Jan 1, 1983

By Stephen G. Hardcastle, Michel G. Grenier

"Safety and health issues are and have been in the last decade a very high priority item with all parties involved in the Canadian mining industry. As a result of this high level of concern for workers&apos; safety and health, Canadian mines are at the leading edge of environmental control technology. For the most part, the occurrence of pollutants in mines is unavoidable. Dust from mining operations, airborne radiation, gases and heat from the strata as well as gases and particulate from diesel engine emissions will undoubtedly be found to some level in most Canadian mines. A lot of work remains to be done, however, in order to bring all Canadian mines at the same level of proficiency when it comes to safety and health. Also, more work is needed in order to maintain our status as world leaders in this field.CANMET&apos;s Mining Research Laboratories (MRL) in Elliot Lake and Bells Corners, Ontario, with the cooperation of the mining industry, have contributed to improving environmental conditions in underground and surface mining and milling operations. The extent of collaboration and efforts vary widely from long-term, multi-million dollar projects between several interested parties to smaller projects involving one laboratory and a single mining operation. This paper gives examples of such collaborative efforts and potential future directions as they apply to: mine ventilation analysis using tracer gas techniques, optimization of mine ventilation network efficiency using real-time monitoring and controlled recirculation (heat saving), respirable dust and radiation sampling and control techniques, diesel emission control using regenerative ceramic filters and, finally, the control of sulphide dust explosions and resulting sulphur dioxide production."

Jan 1, 1990

By D. Virely, M. Gasc-Barbier, J. Guittard

"The valleys of the Dordogne and the Vézère (France) have been inhabited since prehistoric times, as evidenced by the famous site of Lascaux. A few miles away, the village of La Roque-Gageac is also a very popular tourist destination (about 1.5 million tourists per year): The village is sandwiched between a massive limestone cliff and the Dordogne river. The collapse of a cave roof high above the village in January 2010 led us to characterize instability together for the cave and the whole cliff and propose a adapted instrumentation to monitor the fracture openings in the rock mass that are linked to climatic variations. Measurements have been going on and been recorded for nearly 4 years. They point out the role of thermal stress fatigue in the breakdown of the rock mass. In this paper we describe the site under study, the instrumentation and its main results. INTRODUCTIONThe phenomenon of thermal fatigue has been very little studied as far as rocks are concerned, whereas it is rather well characterized for other types of materials: Elsevier published a journal dedicated to fatigue (International Journal of fatigue). In the case of rocks, thermal phenomena and their impacts on mechanical behavior have been analyzed from a micro-structural point of view, and it is now well-known that an increase in temperature causes a dilatation of crystals (Arnould et al., 2004; Berest & Weber, 1998). This dilatation may lead to the development of inter-granular traction and compression stresses, and if those stresses are greater than fracture strength, inter-granular and intra-granular cracks may take place. On the other hand, the fatigue phenomenon (cyclic repetition of a temperature variation which is less extreme than the one that may lead to this inter-granular or intra-granular fracture) is a phenomenon which has not been much studied.The principal studies on thermal fatigue on rocks come mainly from the field of geomorphology, particularly in connection with the analysis of the evolutions of past climate that can explain the present shapes of those landforms: those studies remained essentially qualitative and not quantitative. Le Ber & Oter Duthoit (1987) proposed a thermal and thermodynamic approach to analyse the disaggregation of rock masses. This analysis is dedicated to the study of paleoclimates and was implemented to better understand the formation of slope deposits in order to propose transfer models permitting the reconstruction of the climactic conditions contemporary to their appearance. Since deterioration in the cliff only appears after several cycles, it means that it is a gradual and irreversible deterioration which leads to an increase of the « disorder ». Seen from a macroscopic system point of view, this irreversible evolution is quantified by the internal creation of entropy."

Jan 1, 2015

By B. McFadzean, I. Achaye, T. Chidzanira, J. Wiese

"Froth stability has an overriding effect on metallurgical recovery and grade for many ore types. Froth recoveries of less than 10% are common for low stability froths such as those in sparsely mineralized ores or in cells at the back end of flotation circuits. It is well known that, aside from chemical factors such as frothers and electrolytes, the mineral particles themselves have the dominant influence on froth stability. The particle properties of size and hydrophobicity are expected to have the greatest effects on froth stability. The aim of this study was to understand the effects of particle size on froth stability and to quantify these relationships.The study compared a synthetic ore of pyrite and quartz, with carefully controlled size ranges and hydrophobicity, with conventionally milled platinum-bearing UG2 ore and the bulk reverse flotation of hematite ore. A novel bench-scale continuous column flotation cell and continuous mechanical hybrid cell with large relative froth volumes, as well as a three-phase froth stability column were used to characterize the froths.It was found that froth stability could be related to the concentrate particle surface area by a Langmuir-type relationship. This is indicative that the mechanism by which particles stabilize the thin films in froths is similar to the mechanism by which surfactants lower surface tension. Different froth stabilities were found for different ores and this was thought to be the result of different particle sizes and distributions, which resulted in different packing densities in the thin films and Plateau borders. Interestingly, there was a clear relationship between the feed particle size and the froth stability even though froth stability was dependent on the concentrate particle surface area. It seems that the feed particle size is a good predictor of the surface area of particles in the concentrate. Concentrate particle size did not show a clear relationship with froth stability since it was already shown that it is both the size and the amount of the particles in the froth that contribute to the stability.INTRODUCTIONThe stability of the froth in froth flotation is important to the recovery and grade of the valuable mineral. Too stable a froth and the grade is reduced; not stable enough and the recovery may be compromised. Platinum-bearing ores with fragile, poorly mineralised froths are known to have froth recoveries that are routinely less than 10% (Crosbie et al, 2009). There are a number of chemical, physical and operating parameters that can affect froth stability, including reagent dosages, air flow rate, pulp density and particle properties. Arguably, the largest contribution to froth stability is from the particles that stabilise (or destabilise) the thin films in froths. Particle size, hydrophobicity and shape all affect froth stability to some extent."

Jan 1, 2016

By E. Ghali, W. Zhang, M. Robichaud, G. Houlachi

"The performances of six mesh and one plate dimensionally stable anodes have been investigated in the zinc electrolyte at 38oC and compared to conventional silver-lead alloy anodes. The electrochemical behaviour of these anodes was studied by cyclic voltammetry, galvanostatic, potentiodynamic, open circuit potential and electrochemical noise measurements. It was observed that at the end of 24 h of galvanostatic polarization at a current density of 50 mA/cm2 in the zinc electrolyte at 38oC, the mesh V had the lowest potential followed by mesh III, mesh VI, plate-V, mesh IV, mesh I, and mesh II electrode. When the potentials for mesh I, mesh III, mesh IV, VI and plate-V, mesh V were compared with that of the Pb-0.7%Ag anode (1920 mV/SHE), they were found to be 6%, 16%, 7% 10%, 17% lower, respectively.After 16 h decay following the 24 h polarization, the mesh III had the lowest corrosion rate (51 mS/cm2) among the seven specimens, followed by the plate-V, mesh V, VI, IV, I and II (221 mS/cm2). For the fresh surface as received, after two hour open circuit potential measurements, mesh I had the most positive (noble) potential (1382 mV/SHE) among the seven electrodes followed by the plate-V electrode, mesh V, mesh IV, mesh VI, mesh III and mesh II (751 mV/SHE). After consecutive series of electrochemical testing, mesh V, mesh III, mesh VI had lower corrosion rates (~ 343± 6 µA/cm2) than that of mesh IV, mesh I, plate-V, and mesh II (~ 644± 143 µA/cm2).INTRODUCTIONThe continued use of lead based anodes in the electrowinning process has been mainly due to their relatively low cost as compared to other materials (Msindo, Sibanda, & Potgieter, 2010). They have good electrical conductivity, stability during electrolysis, very good corrosion and wear resistance (Ivanov, Stefanov, Noncheva, Petrova, Dobrev, Mirkova, Vermeersch, & Damaerel, 2010). However, lead-based anodes give their high energy consumption and low corrosion resistance for electrowinning. To overcome these problems, Dimensionally Stable Anodes (DSAs) has been chosen (Msindo et al., 2010). Comparing to the traditional lead anodes, the DSA anodes have many advantages: (1) no contamination; (2) no loss of anode material, pure electrolyte; (3) lower gas bubble effect through special anode designs; (4) use of higher current densities (Msindo et al., 2010). The success of DSA anodes has been attributed to their chemical stability that allows them to maintain nearly constant dimensions during the life of the anode even when operating in environment with low pH values. Due to their stability, the consumption rates of DSA are as low as 1 mg/amp.y (Alfantazi & Moskalyk, 2003)."

Jan 1, 2016

By BARRY BANNATYNE

Non-swelling bentonite has been quarried in Manitoba by Pembina Mountain Clays Limited since 1941. It occurs in several thin layers near the base of the Pembina Member of the Upper Cretaceous Vermilion River Formation, and is quarried from the narrow outcrop belt along the slope of the Manitoba Escarpment. It is marketed both as natural and activated bentonite for a variety of specialized uses. Percolation of acidic water through bentonite has produced a naturally activated bentonite with good absorbent properties; these properties are enhanced by treatment with sulphuric acid to produce an activated bentonitefor decolourizing petroleum and vegetable oil.

Jan 1, 1984

Recently, renewed interest in the recovery of uranium from leach solutions has necessitated a re-examination of the hydrometallurgy methods used for uranium in the 1960?s to 1970?s. A synthesizing overview of the lessons learned in those decades together with examination of recent developments in this area is warranted. This paper considers uranium recovery chemistry from acid and alkali leach solutions using solvent extraction and resin ion exchange, and provides information on circuit selection and configuration, equipment selection and design, as well as operational considerations. The unique thermodynamics of uranium solvent extraction are also presented and discussed.

Aug 1, 2010

By J. Koike

Mg alloys for structural application have attracted much attention. However, high process cost and poor mechanical reliability are major concerns upon expanding the application to a wider area. In order to break through these barriers, better ductility is desired at lower temperature. Plastic anisotropy and peculiar twin formation appear to play key roles in the deformation and fracture mechanisms of Mg alloys. In the paper, dislocation slip and twin formation are reviewed. The effects of crystallographic texture and grain size are discussed. The results suggest that a good control of microstructure and texture can improve ductility and mechanical reliability of Mg alloys.

Jan 1, 2006

By D. J. Sapsford

This paper details results from laboratory simulation of an innovative underground bioleaching process. The underground reactors are periodic flushed with recycled leachate to remove uranium that accumulates within the reactor water. This leaching cycle has been recreated within the laboratory. This study examines the influence of varying cycle protocol on uranium leaching. Protocol variants examined include variation of flushing frequency, flush volume, leachate recycle, nutrient solution (NPK) addition to reactors and Fe(III) sulphate addition to reactors. The presented data highlight the dramatic improvements in uranium recovery that might be achievable by varying the operating protocol for the actual underground reactors.

Aug 1, 2010

By I. Zhitomirsky, X. Pang

The outstanding thermal and chemical stability, excellent mechanical properties and biocompatibility of zirconia have made this material an important candidate for fabrication of advanced protective coatings on metals, graphite, carbon fibers and biomedical implants. Nanostructured polymer-ceramic composite films containing zirconia were synthesized on metallic substrates by combining cathodic electrosynthesis of inorganic particles with electrophoretic deposition of cationic polyelectrolytes. Thick crack-free oxide and composite coatings were obtained using this newly developed technique. The deposits were studied by thermogravimetric analysis, X-ray diffraction analysis, scanning electron microscopy and atomic force microscopy. The mechanisms of deposition are discussed.

Jan 1, 2004

By A. M. Hadian

The use of dolomite refractories in steel making and cement industries has advantages over other basic products particularly in countries where this type of refractories is produced. Due to existence of high-quality dolomite deposits in many regions of Iran, there is a good potential for producing dolomite refractories in the country. This study focuses on the effect of such additives as iron oxide and alumina on hydration resistance and density of Iranian dolomite. It was found that addition of Fe2O3 is more effective than Al2O3 on increasing density as well as resistance to hydration of dolomite.

Jan 1, 2004

By Shamil Shaikhutdinov

CO adsorption on gold particles deposited on well-ordered alumina and various iron oxide films has been studied with temperature programmed desorption (TPD) and infrared reflection adsorption spectroscopy (IRAS). Structural characterization has been performed with scanning tunneling microscopy. Data show that the CO adsorption exhibits a size effect in that small particles adsorb CO more strongly. The effect generally vanishes after annealing to 500 K. For annealed samples, CO TPD and IRAS spectra are nearly independent of the particle size and supports studied. The results indicate that the CO interaction with gold surfaces is essentially similar and involves low coordinated atoms.

Oct 1, 2003

By M. Moats

World copper refining tankhouse practices have been surveyed. This survey is a supplement to previous surveys that have been carried out in the 1987, 1991, 1995, 1999, 2001 and 2003. On a world basis, process technology trends include the further installation of automated electrode handling systems including permanent cathode systems, automatic anode preparation and cathode handling machines, section switches, fully automatic cranes and polymer concrete cells. General plant process control has increased with more automation of material handling in the copper refining tankhouse. The general trend for most greenfield copper refining projects remains in eastern Asia.

Jan 1, 2007

By F. Parada L

Two copper concentrate with medium and high enargite content were leached in a 3 L autoclave reactor under conditions based on the CESL process. Copper, arsenic, sulfur and iron were checked in all the experiments and antimony, zinc and molybdenum were evaluated in selected tests. The 98% of the obtained copper extraction is agree with others authors, but the behavior of arsenic, iron an sulfur have some differences. The solid residue was characterized by chemical analysis, DRX and QEMSCAN®. Finally a comparative analysis with neutral roasting as an option for the treatment of this concentrate is done.

Jan 1, 2014

By A. Fortin, C. Fréchette, M. Kreuh

Éléonore project is a gold ore processing plant at a mine site located near James Bay, Quebec, Canada. SNC-Lavalin was mandated by Goldcorp to perform EPCM services on the ore processing plant and permanent infrastructures of the project following an internal pre-feasibility study. The project incurred considerable challenges due to fast-tracking from a pre-feasibility to detailed engineering and construction. The paper reviews how the EPCM was carried out. Some of the challenges resulting from skipping the feasibility study stage are discussed. The paper also presents how multiple offices across Canada were used for the engineering design.

Jan 1, 2015