Search Documents

By Mei-Yan Yang, Qiu-Ying Wang, Ltd. Yunnan Yuntong Zinc Co., Guo-Mu Chen, Meng-Yang Huang, Peng Zeng, Guo-Feng Li

"Historically, alot of jarosite was found in the leaching residue when leaching indium from secondary zinc oxide materials. The reasons for the formation of indium bearing jarosite were theoretically analyzed. The influence of controlling the acidity and the addition of reagents on the indium leaching yield during secondary zinc oxide processing was investigated. In order to increase the leaching yield of indium, a measure of controlling the creation and destruction of jarosite was proposed. The production data shows that the leaching yield of indium was increased from 60 to 96%, and the content of indium in leaching residue simultaneously decreased from 900g/t to 100–200g/t when implementing such controlling measures.INTRODUCTIONIndium does not occur as independent minerals in the earth’s crust and is mainly associated with complex sulphide minerals. Specifically some sphalerites can contain as much as 900g/t of indium. Most indium is recovered from by-products of copper, lead or zinc metallurgy. Therefore, the research on the recovery of by-products in non-ferrous metallurgy is important(Sinclair et al, 2006). The main technologies used for this objective in China include: •,pre-neutralization-reduction-precipitation indium process(Yu et al, 2008), •,countercurrent oxidizing acid leaching process and sulphation roasting-water leaching process(Cao, 2005), •,oxygen pressure acid leaching of zinc concentrate-P204 extraction process(Yang et al, 2006), •,doubleacid leaching-solvent extraction process on lead dross from a reverbatory furnace flue dust(Liu, 2003),•,an acid leaching-solvent extraction process on smelting ash(Zhouet al, 2005). Although high pressure and extreme conditions can be used to improve extraction from high iron bearing indium residues(autoclave processing), mild extraction with lower cost and lower environmental impact are preferred.This paper describes both how the indium extraction using mild conditions in a secondary zinc circuit was quite low and, how through XRD and chemical analysis jarosite formation was found as the main cause. The paper then proceeds to discuss a method for improving the leaching yield and the application of this method in industrial practice."

Jan 1, 2016

By T. Gonzales, M. Maleki, M. Caçador, B. Climenhaga, H. Ghorbani

The campaign life of furnaces in the copper making industry is greatly affected by damage caused by normal operation cycling and abnormal conditions. Proper monitoring and assessment of the existing conditions and safe remaining life of the vessels and their refractory lining is key to prevent an unplanned early replacement. This paper presents an industry-proven refractory management program as well as a typical fitness-for-service assessment of a rotary vessel shell in order to extend the campaign life of copper making furnaces and enhance safety. The furnace refractory management system involves a comprehensive audit and monitoring program which has been successfully applied to several copper flash smelting furnaces over the past 15 years. The fitness for service assessment provides a methodology to estimate the remaining life of the steel components by evaluating the existing damage and future damage rate based on the historical survey data. The above practices can provide the operator with cost savings by extending the vessel campaign life in lieu of implementing more rigorous refractory lining and shell audits. INTRODUCTION Primary copper smelting is generally divided into two categories of flash smelting and open bath smelting. There are many different types of vessels that can be used to convert the copper concentrate to blister copper including, flash, Mitsubishi process, TSL (ISA/Ausmelt), SKS Bottom Blowing, Anode and Teniente/Noranda furnaces, reactors, and Peirce Smith converters. Each vessel has its own complex and intense environment which requires careful refractory and steel design to withstand the severe thermomechanical and thermochemical attacks within its campaign life. The campaign life of furnaces is greatly affected by damage caused by normal operation cycling and abnormal conditions. Proper assessment of the existing conditions and safe remaining life of the vessels and/or refractory lining is key to prevent an unplanned early replacement. This paper presents an industry-proven refractory management program as well as a fitness-for- service assessment methodology to estimate the remaining campaign life of copper making furnaces resulting in cost savings and enhanced safety of the operating vessels.

Jan 1, 2019

By Rene A. Morin, John K. Kebe

"As explosives become more widely used in urban and other congested areas, governmental regulations pertaining to their use are becoming more pervasive and stringent. This is forcing the blasting industry to review its entire spectrum of operations. Greater attention is now being paid not only to the design and layout of blasts, but also to the monitoring and recording of their after-effects for both legal and business reasons.Current PracticesThe major users of explosives in urban areas are quarry operators and construction companies. A characteristic of both of these industries, at least in recent years, is a relatively low margin of profit. This, coupled with the fact that their use of explosives is relatively intermittent, prevents them from having the kind of professional consulting services that blasting operations really warrant in today's regulatory environment. When such services are obtained, they tend to be directed more at the design and execution of the blast than at the recordkeeping function. The records that are kept tend to be more in the form of a summary of the consultant's design data as opposed to the kind of after-effect detail that is necessary.The more experienced consultants and operators now realize that at least as much attention must be paid to the record-keeping as to the design work. Regulatory bodies at all levels of government are insisting on the availability of such records.Unfortunately, the instrumentation in use today for taking such measurements does not lend itself to the practice of intermittent consulting. Current monitoring and recording instruments are based on so-called analog technology of the type that has traditionally been applied to the monitoring of earthquakes. They require set-up and calibration procedures which must be repeated each time the instrument is moved, or the blasting parameters are changed, as well as complex total analysis of the recorded data. This can lend to confusion and a dilution of responsibility for anything other than the design work and possibly some summary reporting."

Jan 1, 1985

By J. -P. Tshibangu, M. Ramos da Silva, F. Descamps, C. Schroeder, J. -C. Verbrugge

"The mechanical behaviour of rock materials is largely influenced by the stress state and pore pressure; this needs to be considered in many applications, such as petroleum engineering, tunnelling or stability of underground excavations.Conventional triaxial tests (d2 = d 3) are generally used to assess the influence of confining and pore pressure. In this work, those tests are performed on a porous rock named Sorcy limestone, along with more advanced stress paths like triaxial extension (d 2 = d 1) and purely deviatoric tests with independent pore pressure control. Those tests are combined to a true triaxial study on the dry rock in order to investigate the effect of true triaxial stresses and, hence, build three-dimensional limiting envelopes accounting for the influence of pore pressure.Three-dimensional limiting envelopes of dry Sorcy limestone are built in meridian and octahedral planes. The shape of the octahedral sections changes with the mean stress from triangular to hexagonal and then quasi circular. At even higher mean stresses, the evolution continues towards a triangle with apexes oriented in the direction of triaxial extension stress states. In meridian sections, the deviatoric stress first increases with the mean stress. The transition between this deviatoric mechanism and the cap surface occurs at different mean pressures depending on the Lode angle.Terzaghi’s effective stress is found to govern the yield and plastic behaviour of saturated Sorcy limestone. Triaxial tests show that the limiting envelope does not depend on the loading path (conventional compression and purely deviatoric stress paths). In triaxial extension, the brittle-ductile transition is observed for a higher mean pressure than in triaxial compression, as previously found for true triaxial tests on the dry rock.Finally, it is shown that upon appropriate normalisation, the dry and saturated yield envelopes come very close one to each other. This suggests that only the size of the yield envelope changes between dry and saturated state (pore pressure = 5 MPa); its shape does not seem to evolve."

Jan 1, 2015

By Jorge Lema Patino

"The purpose of this paper is to determine the best techno-economic alternative for the treatment of tin ores, when comparing the various mining and metallurgical methods of preconcentration, concentration, volatilization (fuming) and up to the final stage of selling to the smelter. The study of the influence of the different parameters of cost, recovery and quoted prices has motivated the paper, which aims at determining the best process of ore treatment in terms of its techno-economic feasibility.Method of WorkOn the basis of head grades of 0.5, 0.75 and 1.0% tin, the following alternative methods of treatment are possible:1. Mining-Concentration-Smelting.2. Mining-Preconcentration-Fuming-Smelting.3. Mining-Concentration-Separation, with direct smelting and fuming/smelting of the two fractions produced.The calculations were carried out on the basis of existing information and publications concerning the various experimental recoveries in the operating mills of COMIBOL. In the case of concentrates containing less than 10% or more than 40% tin, extrapolation was required.The final grade of the tin concentrates and the gross weight of the concentrate were calculated on the basis of the estimated recovery curves. The costs of the preconcentration and the concentration stage s were determined per gross metric ton of material treated.The calculation of the cost of the smelting stage is similar for all the alternatives, the royalties and smelting charge varying with the grade of the final concentrate. In the fuming stage, a uniform recovery of 90% was taken in all cases so as to obtain a final concentrate grade of 65% tin, regardless of the head grade of the feed material.For the separation stage, the following considerations apply:a) Separation can be carried out by gravity separation or flotation methods.b) The cost of separation varies depending on the system used.c) The distribution of tin in the two fractions is 100% at this stage. In other words, there is no loss of tin during separation."

Jan 1, 1982

By J. L. Collins

"This paper deals with the quantitative analysis of mine maintenance records. Based on a case study of dozer engine records, the author suggests an easy method of deriving useful information for managerial decisions in a step-by-step manner.More specifically, the paper deals with the following topics:• determination of the most economical replacement time,• determination of reliability characteristics,• determination of the number of replacements, and• determination of the number of spares.IntroductionThe mining industry collects a lot of information about every aspect of its activities, an example of which appears in Table I. In Table I , the distribution describes the operating hours at failure of 56 different dozer engines used in severe applications. Besides calculating an average and possibly a standard derivation from the data, little else is derived, at least from a statistical point-of-view.More information can be obtained from these records that could help management in the decision-making process.To illustrate this point, the sample data appearing in Table I will be analyzed in detail by making use of well-known concepts in reliability engineering.Distribution of DataTable I represents a distribution obtained from the recorded hours cumulated from the operators' time cards. The operating hours have been divided into fourteen classes for each 1000 hours of engine running, e.g . all engines scoring an operating time of between 1001 and 2000 hours formed a class , those scoring between 2001 and 3000 hours another one, etc. Generally, the class interval should be a multiple of the equipment preventive maintenance check period.The minimum acceptable sample size should be large enough to ensure that the score in each class interval is at least one. Ideally, the score for each class interval should be at least five so that a chi-square test could be carried out if necessary.The average life of an engine can be found by adding the products of the frequency and the class mark (mid-point) values. Therefore:"

Jan 1, 1987

By Michel Garon

"Several years ago computer control of the flotation process was successfully implemented at the Matagami concentrator of Noranda Mines Inc. At that time this was the first computer application being installed at this operation. The last few years have seen an extensive use of programmable controllers in areas such as the copper and zinc dewatering circuits and the lime preparation system. With the aid of such instruments, these areas have attained a high level of automation and as a result, a high degree of efficiency. The controllers have proven to be very dependable and easy to use.IntroductionThe Matagarni Division of Noranda Mines Inc. operates two mines in the Matagami District of northwestern Quebec which is located about 650 km northwest of Montreal. The mines ship ores to a central concentrator whose throughput averages 95,000 tonnes of ore per month. Metal contents of the mill feed average 0.9 per cent copper and 5.0 per cent zinc. Concentrate outputs are approximately 3,200 tonnes of copper and 8,200 tonnes of zinc per month.The concentrator commenced operation in 1963. An on-stream X-ray analyzer was installed in 1968, providing analyses of several samples in the flotation circuit without the aid of a computer. In 1974, control of the circuit by computer was added to the system. As a result, zinc flotation efficiency improved considerably and reagent costs decreased through the reduction of copper sulphate consumption.In the past few years it was realized that significant improvements could also be made in other parts of the operation . Copper and zinc dewatering circuits and the lime preparation system were identified as major areas that could drastically benefit from automation. In 1982, programmable controllers were seriously considered as an attractive alternative for achieving the company 's goal. Because of their relative lowcost and their high degree of flexibility, they were selected for implementing automation and, for improving the efficiency in each of these areas."

Jan 1, 1985

By E. Ghali, W. Zhang, C. Su, N. Sorour, G. Houlachi

"Zinc electrowinning process is sensitive to the presence of metallic impurities such as lead ions that could substantially and negatively affect the power consumption and surface morphology. Effect of various concentrations of manganese ions and traces of lead ions up to 2.5 mg L-1 added to the electrolyte during electrowinning have been investigated by electrochemical polarization techniques such as galvanostatic, cyclic voltammetry and potentiodynamic. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were applied to examine the surface morphology and crystallographic orientation, respectively. Microwave plasma-atomic emission spectrometry has been used to determine the lead content in the deposit and in the electrolyte after electrodeposition. It was found that lead ions added to the zinc electrolyte led to the increase of cathodic overpotential and current efficiencies of zinc deposit. However, addition of Mn2+ into the zinc electrolyte resulted in the decrease of cathodic potential and current efficiency of zinc deposit. It can be stated as example that galvanostatic polarisation at 40?C and 52.5 mA cm-2 in presence of lead up to 0.1-0.2 mg L-1 in the electrolyte and 8-12 g L-1 Mn could be better considered as practical working parameters for electrowinning process.INTRODUCTIONApproximately 85% of the global production of zinc metal is produced by electrolytic process (Sinclair, 2005). The main goal of the zinc plant is to obtain pure zinc deposits with high current efficiencies. Smooth and pure deposits with high current efficiency (CE) are always obtained from pure electrolytes (Alfantazi & Dreisinger, 2001). The presence of metallic impurities in the zinc sulphate electrolyte is a major problem for the zinc electrowinning industry, since decreases in current efficiency, changes in deposit morphology and cathodic polarization are observed for electrolytes containing small concentrations of impurities (Ault & Frazer, 1988; Muresan, Maurin, Oniciu & Gaga, 1996). Low level concentrations as parts per million of these impurities are reported to influence negatively the zinc electrodeposition (Beshore, Flori, Schade & O'Keefe, 1987)."

Jan 1, 2016

By R. Ricketts, D. G. Vanderveer, F. Kirby

"A program of mapping, sampling and testing to determine the potential of the aggregate resources throughout Newfoundland and Labrador was commenced in 1978. A 6-km-wide corridor parallel to all transportation routes was selected as the study area.The study consisted of a preliminary surficial interpretation followed by field mapping and sampling. Granular resources were sampled at a 500-m interval and non-granular materials were sampled at a 1.5- to 2-km interval. Data were gathered on landforms and stratigraphy as well as a field description of the sample and deposit types. Particle-size and lithologic analyses of the samples were also conducted.The locations of samples and deposits were mapped on 1:50,000 topographic base maps and summarized for publication at a 1:250,000 scale. Surficial geology maps were produced at a 1:50,000 scale. A computer program is being developed for the search and retrieval of field data.The first phase of the Inventory of Aggregate Resources program is nearing completion and to date has collected information on approximately 9,500 samples throughout Newfoundland and Labrador. This data will be used to provide f or the effective management of these vital non-renewable aggregate resources.The mineral aggregate industry in Newfoundland and Labrador is very competitive, but undercapitalized when compared to other provinces. The demand for aggregates is forecasted to increase to in excess of23 million tons per annum by the year 2002.In terms of over-all mineral production, the extraction of sand, gravel and stone has a significant impact when compared to other minerals in terms of value and tonnage produced.IntroductionThe province of Newfoundland has approximately 18,000 km of coastline. A large proportion of the population lives in coastal communities where, traditionally, beaches have been a major source of construction materials. Beaches have, therefore, often been subjected to overutilization, resulting in erosion of back beach areas or adjacent headlands."

Jan 1, 1982

By J. R. Johanson, A. W. Jenike

"A solid flows out of a bin provided that the outlet is sufficiently large so that stable obstructions to flow do not develop. The geometry and surface finish of a bin and the construction of the feeder determine the type of flow pattern which then develops within the bin. The pattern, in turn, affects the uniformity and consistency of the stream, segregation, caking, degradation, live capacity and the action of level measuring devices.In most bins now in operation, material flows toward the feeder through a channel which forms within the stationary solid. This is referred to as funnel flow. If the hopper of the bin is sufficiently steep and smooth and the feeder capable of drawing material across the whole area of the outlet, all the solid flows whenever the feeder is in operation; this is referred to as mass flow. Mass-flow bins are usually far superior to funnel-flow bins; their initial cost is also usually higher.The paper describes the design criteria used in deter-mining the minimum bin outlet needed for flow and the bin geometry needed for mass flow."

Jan 1, 1970

By Paolo Farina

Slope monitoring radar has emerged in the last ten years as a leading edge tool for monitoring movements in natural and engineered slopes, thanks to its ability to rapidly measure slope movements with millimetric accuracy over wide areas in any weather conditions, obviating the need to install artificial reflectors. In recent years, slope monitoring radar has experienced significant improvements in its performances, mainly thanks to the use of different radar technology, such as Synthetic Aperture Radar (SAR), able to overcome some of the limitations of the first generation of radar and to provide higher spatial resolution, longer working distances and faster acquisition time. One of the leading applications of this technology is today represented by slope monitoring within the surface mining industry. Prominent international mining groups currently employ slope monitoring radar, based either on Real Aperture Radar (RAR) and SAR technology, for active and background monitoring of open-pit walls. The main technical features of typical slope monitoring radar based on SAR technology along with their possible applications are presented in this paper along with recent case studies of successful slope monitoring in open pit mines.

Jun 1, 2012

By Karen M. Moffitt

Developments in mining methods and rates have led to an increase in the frequency and size of waste dump failures that have not been adequately predicted or explained in terms of conventional slope stability analysis. Monitoring data and visual observations suggest a unique mode of failure responsible for large runout events. A numerical model has been developed to capture commonly observed patterns of deformation, and investigate the formation of the ensuing failure mechanism. The analyses have yielded a good correlation with observed field behaviour and have provided significant insight into the coincident stresses and deformations within the dump. Results indicate that while creep effects in the waste dump could have a significant effect on the magnitudes of displacement, the overall dump stability is governed by the strength of the foundation soils underlying the toe region. Consideration of both the stress and velocity fields leads to factors of safety for various dump heights and foundation slopes that are considerably less than predicted from limit equilibrium analysis. The results suggest that conventional limit equilibrium analysis techniques may not be adequate when assessing the stability and design of waste dumps on steeply sloping terrain.

May 1, 2001

By P. Patnaik, F. Cuneo, D. M. Wang

Microwave (MW) energy has been used widely for several decades for communications, food processing, wood drying, vulcanization of rubber and medical therapy. Recently, this technology was found to be capable of successfully sintering ceramic and metallic powder materials, with the advantages of reducing soaking times and sintering temperatures. Unlike conventional heating, MW radiation works through the absorption of the microwave energy by a material placed in an electromagnetic field within the microwave cavity. A far more efficient heating process is produced due to the unique ability of microwaves in selectively heating a pecific part of the material with desirable dielectrical properties. This exploratory research was initiated with the objective of locally sintering the thermal barrier coating of gas turbine components using MW radiation. This novel technique may allow repairing of the component without subjecting the entire piece to unnecessary elevated temperatures and reduction of process time and cost. Y ttria stabilized zirconia was used in this study and sintering was conducted using a multimodal 1.2 kW microwave facility. Three configurations of heating setup were experimented and the preliminary results will be discussed in this paper.

Jan 1, 2006

By A. D. McKay

Uranium exploration expenditure in Australia reached a record level of A$220.5 million in 2008, which has subsequently declined to A$185.2 million for the year ended 30 June 2009. Recent discoveries include: Ranger 3 Deeps east of Ranger open pit (Northern Territory), Pepegoona and Yadglin sandstone hosted deposits (South Australia), and Thunderball project (Northern Territory). Australia?s Reasonably Assured Resources recoverable at costs of <US$80/kg U at June 2009 are estimated to be 1,210,000 t U, 4% higher than the estimate for December 2008. The main additions were in the south eastern portion of the Olympic Dam orebody. The Olympic Dam Expansion is based on a large open pit and will increase output to an annual capacity of 19,000 t U3O8; 750,000 t copper; 800,000 ounces gold. The Four Mile in situ recovery project was approved in July 2009. An ion exchange facility is to be constructed at Four Mile and uranium-bearing resins will be transported to the Beverley plant to recover the uranium. Recent developments at Ranger mine, and Honeymoon, Oban and Yeelirrie projects are discussed.

Aug 1, 2010

Polymer electrolyte membrane (PEM) fuel cell has increasingly become the potential choice of zero-emission power source for portable, mobile and stationary co¬generation applications. However, technical barriers need to be overcome before its widespread commercialization; cost reduction and performance improvement including reliability are the two key areas, that can be realized through better cell/stack design and improved understanding of the transport processes occurring inside the individual cells and stacks. In this presentation, we will provide an overview of various cell/stack models that are available in the literature, their strength and weakness, and then present a comprehensive multi-species, multi-phase and multi-dimensional formulation of a single PEM fuel cell, with consistent and systematic formulation for all the regions involved, including the solid bipolar plates, gas flow channels, the electrode backing layers, the catalyst layers and the electrolyte membrane. Such a detailed approach allows us to extract sufficient information to the analysis of a stack of PEM fuel cells. Stack model will be presented that investigates the various stack designs and flow configurations, and the optimal stack design based on the present study will be described. Also some innovative cell/stack designs will be featured.

Jan 1, 2005

By Aimee Williamson

Bio-mining is a cost-effective, energy efficient and potentially environmentally protective method of exploiting a variety of ore deposits, from high-grade base metal deposits of nickel to lower-grade uranium deposits such as are found in the uraniferous quartz-pebble conglomerate beds of the Quirke Syncline, Elliot Lake, Ontario, using bacterial metabolic processes are used to enhance the solubilization of the metal(s) of interest. The cost effectiveness of bio-mining in Elliot Lake depends on the bacterially-influenced dissolution metals of economic importance, as well as on the ability to suppress microbiological activity following the release to solution of the economically important elements. This poster provides an overview of elemental recovery results and release kinetics for more than 50 elements. The data is obtained using a combination of advanced spectroscopic tools (ICPAES and ICP-MS) to analyze solutions obtained from a series of environmentally controlled biologically mediated uranium ore extraction experiments. The focus will be on rare earth elements, potential environmentally toxic elements, and metals of economic importance. Furthermore, the importance of these findings will be put into an economic and geologic context for the re-development of the mining industry of the Elliot Lake Camp.

Aug 1, 2010

By K. Murase

Potentiostatic electrodeposition behavior of dendritic copper from acidic copper(I) chloride (cuprous chloride) baths containing sodium chloride and sodium bromide was investigated. The morphology, or appearance, of copper dendrite and the sodium content in the dendrite as an impurity were both influenced by deposition potential (0 to ?150 mV vs. SHE) and bath temperature (R.T. to 60 C), while the current efficiency for the deposition was 99% or more irrespective of the deposition conditions examined. The bath pH did not affect the deposition behavior in the pH range of 0 to 2. Bath temperature was found to be the most important factor influencing the deposition current. The current density of the dendrite deposition on a titanium cathode was lower than that onto a copper cathode with the same substrate surface area. The reproducibility of the current for the dendrite deposition was poorer when an as-polished titanium cathode was used, although it was improved by surface treatment of the cathode with an HF-HNO3-H3PO4 solution before electrodeposition. The deposition behaviors were discussed with the potential-pH diagram of the Cu-Cl-H2O system.

Jan 1, 2007

By M. Lundström

The Outotec HydroCopper® process is a novel technology, developed and registered by Outotec Technology Oy, for leaching copper from chalcopyrite using cupric chloride solution. The leaching process is operated at atmospheric pressure in a stirred tank reactor, at temperatures near the boiling point of water and pH values between 1.5 and 2.5. During the leaching of chalcopyrite in cupric chloride solution, a reaction product layer forms on the mineral surface. In the present work, the formation and the composition of the reaction product layer was studied in an environment similar to that of the HydroCopper® process. The effect of the process parameters on the reaction product layer was investigated. Electrochemical measurements, including A.C. impedance spectroscopy and microscopic observations were carried out and an equivalent circuit was used to determine the surface parameters, such as the reaction product layer capacitance and the charge transfer resistance. The results suggest that, at low pH, a passivating sulfur-rich layer forms, whereas at high pH, a more porous iron-rich layer was detected. The values measured can give useful information for optimising the leaching parameters of the HydroCopper® process. Cu2007

Jan 1, 2007

By H. Saari, M. Pates, P. C. Patnaik, A. Merati

Single crystal nickel-base superalloys such as PWA1484 exhibit superior performance compared to conventional superalloys, and are used extensively in turbine blade applications requiring good high temperature properties. The life of these blades is typically limited by cracks and erosion. Due to the high cost of these blades, welding techniques are being considered to weld/repair worn components, extending their useful lives and delaying the need for expensive replacement components. However, the sensitivities for solidification cracking and post weld heat treatment cracking are relatively high in these alloys. Electron beam (EB) welding can deliver concentrated heat sources and has the potential to address these issues. Numerous welding trials and structural tests must be conducted to identify the optimum method and welding parameters. Weldability is studied over a range of material conditions, welding parameters, and directions. The influence of welding parameters on the fusion zone microstructure and resultant weldability is investigated using combination of microscopic examination and micro-hardness testing. This paper summarizes some of the results of a feasibility study conducted to understand the effects of welding parameters on localized microstructural features, cracking sensitivity, and mechanical properties of autogenously EB welded coupons of single crystal PWA1484.

Jan 1, 2004

By K. Yoo

Chalcopyrite is the most abundant copper sulfide mineral, which is normally processed using pyrometallurgical methods (i.e., smelting) to produce copper metal. Smelting has several major disadvantages, such as high gas-handling costs, high capital costs, saturation of sulfuric acid market, and inability to treat low-grade concentrates and to recover some by-products, such as zinc, nickel and cobalt. The development of hydrometallurgical processes for chalcopyrite is desirable to overcome the problems of smelting. Because chalcopyrite is refractory, the leaching rate for chalcopyrite is very low. Therefore, increasing the leaching rate has been extensively investigated, both in sulfate and chloride media, as well as in the presence of bacteria. Chloride leaching processes have shown relatively high leaching rates. The mechanism of the chloride leaching process has been investigated, but the behavior of chalcopyrite leaching in chloride solution is not clear. Therefore, the effect of the solution redox potential on the leaching rate of chalcopyrite in chloride solution was investigated. In the present study, leaching experiments were carried out using 0.1 M chloride solutions and the results indicate that high leaching rates of chalcopyrite can be achieved at relatively low solution redox potentials.

Jan 1, 2007