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By A. E. Reschke

Optimized mine planning of the Leeville Gold Mine, Nevada, necessitated the requirement for an average of 2540 tpd of high quality cemented rockfill (CRF) in primary stoping blocks and underhand cut and fill workings. To meet this requirement, a number of innovative design features were incorporated into the overall batching plant design. Foremost is the use of a dedicated skip to transfer crushed aggregate from surface down through the ventilation shaft to twin underground storage silos. Also, the use of a high shear colloidal mixer on surface to pre-slurry a cement/flyash binder with pipeline delivery to one of two separate underground CRF mixing stations was incorporated. Finally, the binder and aggregate are combined in a 9 m3 twin shaft compulsory type mixer before loading into teleram trucks for placement.

May 1, 2007

The following briefing is intended to provide an overview of the present and future challenges associated with our access to a secure and adequate supply of electrical energy necessary to support safe, productive and sustainable mining initiatives at Musselwhite. Contents ??Site power demand vs. current available supply ??Supply technical deficiencies ?adequacy and security of present supply ??Present internal generation ??Anticipated future internal generation requirements ??Increased requirements necessary for planned expansion ?demand/security ??Goldcorp?s strategy to achieve required supply ?transmission line initiative ??Subsequent benefits to others from the Goldcorp initiative. ??Economic impact of MusselwhiteMine on the northwest region ??Anticipated economic impact of planned expansion ??Expected life cycle of MusselwhiteMine ??Comparative energy costs for similar operations in other jurisdictions ??Conclusions ??Anticipated action plan ??Energy Management Initiatives ??Site Orientation

May 1, 2009

The Boleo project is located in Mexico close to the town of Santa Rosalia on the Baja Peninsula. The Boleo deposit contains copper, cobalt, zinc and manganese values as oxides with minor sulfides. The Boleo deposit is metallurgically challenging due to: 1) the requirement to recover four separate metals; 2) the presence of high levels of clay in the deposit resulting in difficult solid-liquid separations, and; 3) the need to use seawater for the bulk of the processing. Baja Mining, Bateman Engineering and SGS Lakefield Research have collaborated to develop and test a process flowsheet to recover copper, cobalt, zinc and manganese products at Boleo. The key steps in the flowsheet are: ? Feed preparation (scrubbing and ball milling of oversize) in copper raffinate ? Ore leaching using oxidative and reductive leaching ? CCD washing using high rate thickening technology ? Copper SXlEW ? Treatment of a bleed solution for cobalt, zinc and manganese recovery The process for cobalt, zinc and manganese recovery involves iron and aluminum removal followed by cobalt/zinc bulk extraction using CSIRO's DSX solvent extraction system and selective zinc and cobalt stripping. The zinc strip solution is evaporated to produce zinc sulfate monohydrate crystals to market and cobalt is recovered via a further SXlEW process as high purity metal. Manganese is precipitated as manganese carbonate from the DSX raffinate solution. This paper will review the Boleo process flowsheet and provide detailed results from the 2006 pilot plant operation conducted at SGS Lakefield in Canada.

Jan 1, 2007

By A. A. Sirkeci, M. Tarkan, N. Acarkan, O. Kangal, G. Bulut

This investigation deals with the evaluation of the tailings of the Kirka Borax Plants. In this respect boron in the tailings was recovered and the utilization of the clayish fraction was investigated. There are five tailings ponds in Kirka four of which are used for the tailings of the borax concentrator and the remaining one is used for the tailings of the sodium penta-borax plant. Experiments were conducted with samples taken from ponds containing coarse fraction and fine fraction. Coarse fraction of Borax Concentrator were screened through a set of sieves. The fraction above 1 mm was removed with 41.5% recovery and 33.3% B203 content. Scrubbing was applied above 0.1 mm and products containing 32 to 34% B203 were obtained with recoveries around 35%. The tailings of sodium penta borax plant was also screened and it was found that 15% of boron reported to +1 mm size fraction with 35% B203 content. Sample containing fine tailings was treated by cycloning. The cyclone overflow was found to be below 6µm and it was separated to be used in the subsequent tests. The usage of cyclone overflow in paper, ceramics, glass, pigment and drilling industries was investigated. Since this fraction is mainly composed of carbonate minerals rather than clay minerals it was suggested that it may be used for construction and moulding purposes. Furthermore, the B203 content of the cyclone overflow was reduced to 2.4%.

Jan 1, 2004

By J. Gillies

"Extraction of Gold in Ketone from a suitably prepared sample of sulphide or siliceous ore or concentrate permits a rapid and accurate determination by Atomic Absorption. Mill test products and exploration development samples are acid-treated to effect complete dissolution of silver, copper, zinc, lead, molybdenum and iron present. Interferences in the determination of molybdenum are described. Results by Atomic Absorption are comparable to those afforded by other acceptable methods.INTRODUCTIONDuring recent years much has been written and discussed concerning Atomic Absorption Spectrometry as a technique for determining the concentration of metallic elements. We would, however, recommend a perusal of the paper presented by J. C. Ingles at the annual meeting of Canadian Gold Metallurgists held in Ottawa, January, 1966. The paper was published in the August, 1966, issue of the Canadian Mining Journal, and contains general information on Atomic Absorption.The purpose of our paper is to present certain specific method procedures for the determination of several precious and base metals normally present in Mine, Mill and Smelter products. Of necessity, analytical results should be as accurate as the most suitable available method permits, whether for metallurgical balance, settlement purpose, ore beneficiation programs, or exploration property development. The success of such programs is relative to the accuracy, speed and economics of the analysis. It is obvious, therefore, that in presenting our paper we consider the technique has achieved the desired evaluation."

Jan 1, 1968

By G. R. Yourt

"Generally speaking the usual approach for controlling dust is three-fold:1. Suppress the formation of dust at the source.2. Confine dust that cannot be suppressed.3. Dilute and remove dust that cannot be confined.This discussion will be concentrated on the second approach, namely, confining and disposing of dusty air.Dust BehaviourBefore delving into actual design principles a brief discussion on behaviour of dust should be helpful. For prevention of silicosis only respirable dust, ranging in size from < 0.5 to 5u needs to be controlled. As particles of this size have insignificant mass and momentum they follow air movements very closely. Consequently if contaminated air around dust sources is confined within enclosures and leakages maintained, strongly indraft dust is automatically controlled and capture velocities are of no concern.Dust SourcesAt metal mining operations ore is prepared for wet concentration by crushing it to mostly <3"" in size. This usually involves a jaw crusher, one or two cone crushers, one or more screens and several conveyors. Dust is actually produced only by the crushing action but it is liberated also when numerous fine particles contained in the ore stream are dispersed by surges and vibration at the discharge of the crushers, screens and headpulleys of conveyors. Furthermore, dust is dis¬persed when the slime adhering to the underside of the return portion of belts becomes dry and is rendered airborne by vibration and by cleaning floors especially where the slime has dropped."

Jan 1, 1971

By B. N. Church, A. R. Pettipas

"The second vertical derivative method of processing aeromagnetic data from low level helicopter surveys yields results correiatable with the known geology and may be utilized to indicate possible targets for future exploration in the Silver Queen and Equity Silver mines areas, near Houston in central British Columbia . The principal zones of alteration associated with mineralization, known from detailed mapping, are further delineated and extended in a way not possible by a cursory examination of the original magnetic data.IntroductionThe second derivative method of processing aeromagnetic data is a long established procedure used to enhance the short wavelength content of the magnetic fields. Some recent exam pies of the use of the second derivative technique have been published by Chandler (p. 385), Sun Yunsheng et al. (p. 424) and Yarger (p. 223) in Hinze, 1985. According to theory, the ""second vertical derivative"" is closely related to the rate of curvature of magnetic (or gravity) fields and is particularly useful in resolving and sharpening local anomalies. The contours on second derivative maps may coincide with important features such as lithological boundaries, faults and mineralized zones.In the Houston area, central British Columbia, aeromagnetic data supplied by local mining companies provide a ready base for analyses. Examples are data sets for the Silver Queen and Equity Silver mines centred 35 km and 34 km south and southeast, respectively, from Houston (Fig. 1), (Cochrane, 1970 and Church, 1985)."

Jan 1, 1990

By P. Au, R. Kearsey, D. Y. Seo, Patnaik. P. C.

Three nickel based superalloys (7.5%Cr+5%Co+2%Mo+1%Ti+5%Al and Ni balance (wt%)) containing different amounts of W and Re were produced in the single crystal (SX) condition utilizing the Bridgman casting process. First, the effect of different levels of Re, and W on chemical microsegregation were investigated by EPMA quantitative analysis, and eutectic phase fraction analysis. Second, in order to investigate the effect of these refractory elements addition on oxidation behaviour, isothermal oxidation testing of the SX nickel based superalloys was conducted at 1000°C for 277 hours under 3 ppm moisture content of air in a thermogravimetric analyzer (TGA). All three SX nickel based superalloys revealed an excellent SX solidification structure with a common primary dendrite arm spacing of -250 µm and a large fraction of ?/?&apos; eutectic located between the secondary dendrite arms. From the average EPMA compositional results, with the exception of Ni, elements such as Cr, Co, Re, Mo, and W all tended to segregate towards the dendrite core during solidification, while Al, Ti, and Ta were present in greater quantity in the last liquid phase to solidify, which resulted in large eutectic ?/? &apos; phases to form within the interdendritic regions. As the nominal level of Re increased, microsegreagation of Re, W, Cr and Mo increased, indicating that Re had a much greater influence on partitioning behavior compared to W. Figure la shows the specific mass gain as a function of exposure time for each alloy. An alloy with 2wt% of W and Re (Alloy B) exhibited less weight gain compared to two other alloys with either higher content of W or Re (Alloy A and C). Microstructural and compositional analyses of oxidized samples were conducted using SEM and EDS. Figure lb shows the typical surface morphologies of the oxidized Alloys A and B. It is evident that more oxide nodules (indicated by arrows in the figure) were presented in Alloy A. It is speculated that the amount of these nodules was responsible for more mass gain in Alloy A compared to the two other alloys. From the examination of the longitudinal section of the oxidized samples as shown in Figure 2, for Alloy A, nodules actually penetrated deep into the material. For Alloy B, however, a relatively uniform and continuous oxide layer was developed and deeply attacked areas were not observed. It was also found that preferential oxidized regions were located at the area between the ?/?&apos; eutectic phase and the dendrite arms where the concentration of refractory elements was relatively high. Therefore, it is plausible that the oxidation kinetics of these alloys is related to the extent of microsegregation.

Jan 1, 2004

By Ron Bradburn, Derek Perkins

"The Brenda mine is located in south central British Columbia, 22 km north west of Peachland, in the heart of the Okanagan Valley. Situated at an elevation of 1500 metres, the mine area straddles the divide between the headwaters of Trepanier Creek and Peachland Creek. These flow into Okanagan Lake, the chief valley water resource located 1100 metres below. The creeks are of great significance to the water management of the area as they constitute the water supply for the Municipality of Peachland, a thriving retirement community with a population of 5000. A location map is shown in Figure 1.The history of the Brenda Mine operation has been well documented previously. After twenty years of operation, the open pit mine shut down in June 1990 due to the depletion of its ore reserves. During the course of its life, it produced 109 million tonnes of waste rock which is thought to contain approximately 0.10% copper as chalcopyrite and 0.015% molybdenum as molybdenite stored in four rock piles around the pit. Similarly, approximately 200 million tonnes of tailings were produced grading 0.015% copper and 0.005% molybdenum. During operation, tailings were hydrocycloned to produce a coarse sand for dam building with the fine slime stored behind the dam. It is estimated that 40% of the tailings were used for the dam construction. The layout of the mine site is shown in Figure 2.The mine was operated under a zero discharge permit. This was achieved by diverting practically all surface water flowing towards the mine area around the site. Water affected by mine operations, was discharged to the tailings impoundment, and recycled to the mill for reuse. The recycle rate was 90% and seepage from the tailings embankment and saddle dam was pumped back to the tailings pond. Because acid drainage was not a problem with the low grade Brenda rock, runoff from the rockpiles was initially released to the local environment. However, due to the alkaline nature of the waste rock, dissolution of low concentrations of molybdenum in the site runoff waters became evident by the late 1970's. The molybdenum content of Peachland Lake, the water reservoir for the municipality of Peachland, approached the Canadian Drinking Water Standard of 0.25 ppm. By 1979, a series of diversion and collection ditches was completed to direct all runoff water from the rockpiles to the tailings impoundment area. This had a significant detrimental effect on the site water balance causing it to go into a considerable surplus condition. During normal operation, this oversupply was contained by the rate of tailings dam building. An economic shutdown of the mine during 1984 forced a limited discharge from the site to protect the integrity of the tailings dam."

Jan 1, 1995

By Mariam Melashvili, Chris Fleming, Rene Jackman

"A study was undertaken to develop a flowsheet for treating a high grade silver/gold ore body by cyanidation, CCD and Merrill Crowe precipitation, with tailings detoxification to meet stringent limits for cyanide and thiocyanate concentrations in the final discharge. In one of the flowsheets examined, free cyanide in the final leach liquor was recycled to the mill where it was hoped that it might react beneficially with fresh ore to reduce the cyanide makeup by an equivalent amount. However, laboratory results suggested that most of the cyanide recycled to the mill reacted with iron forming a soluble ferrocyanide complex. This would have had a negative impact on cost, not only because the cyanide recycled to the mill could not be claimed as a credit, but also because the presence of ferrocyanide in the final tailings meant copper sulphate had to be added to the SO2/air cyanide detoxification process to precipitate the iron cyanide. In an alternative flowsheet that was examined, recycling of cyanide to the mill was abandoned, and this allowed the milled slurry to be pre-aerated in a single mixing tank before cyanidation. During alkaline pre-aeration, any ferrous ions that are generated in the mill are oxidized to ferric ions, which, unlike ferrous ions, are inert in cyanide solution. This significantly reduced cyanide consumption and lowered costs in the detoxification of the tailings. In this paper, the cost implication of these two circuits is compared.INTRODUCTIONMost of the gold that is produced by hydrometallurgical processes is recovered by cyanide leaching. The reason for that lies in the superior thermodynamic stability of the gold cyanide complex and the favorable economics this confers on the process (Fleming, 2014). However, the gold in most of the gold-bearing ores processed is a very minor component, and therefore, the leaching response is often dominated by that of the host minerals.Many gold ores treated by the cyanidation process contain iron minerals. Cyanide reacts readily with some iron minerals forming ferrocyanide as one of the compounds. Ferrocyanide is stable when solutions are exposed to air and does not retard the dissolution of gold. In fact, it has been claimed that potassium ferrocyanide in the presence of oxygen is a weak solvent for gold (Hedley & Tabachnick, 1958). The main problem with the formation of this compound is the consumption of cyanide. Ferrocyanide contains six molecules of cyanide for each atom of iron {Fe(CN)64-} so the wasteful consumption of cyanide is greatly increased by its presence. Thiocyanate is also often produced during the reaction of certain iron sulphide minerals with cyanide, and contributes to the wasteful consumption of cyanide. In addition, environmental regulations in certain countries demand that thiocyanate be removed from the tailings, and this adds significantly to the cost of tailings treatment."

Jan 1, 2016

By Avinash Kandalam, Markus Reuter, Jörg Kleeberg, Michael Stelter

The Top Submerged Lance (TSL) technology has obtained significant importance in the pyrometallurgy industry for nearly four decades. One of the advantages of TSL furnace is its high reaction rate, which is caused by splashing and turbulence of the melt. In contradiction, this phenomenon stands as a barrier for conducting experimental investigations to validate the simulation models. The highly turbulent and splashing environment in the TSL furnace is caused due to the immersion of the lance into the slag layer and thus the effect of the flame structure is directly related to the splashing, turbulence, reaction kinetics and life-span of the lance. Moreover, the material properties such as viscosity, density and the surface tension will also influence the flame structure. As a first step to understand the flame structure, attempts are made to generate a stable flame of the lance in an open environment. INTRODUCTION Top Submerged Lance (TSL) technology was invented during the 1970s at Commonwealth Scientific and Industrial Research Organisation (CSIRO), Australia by Floyd and Denholm. This technology was later commercialised and currently, there are about 100 TSL plants around the world commissioned by various licence holders such as AUSMELT (Outotec) and ISASMELT (Xstrata- Glencore Technology). Copper is the most produced non-ferrous metal followed by lead and zinc, see Hunt (2005). Today, a wide range of primary, secondary, and complex recycling materials are used as a feed material in the TSL, Alvear et al. (2010), Kaye et al. (2008). The working principle of TSL technology lies on inserting and submerging a lance from the top of a vertical cylindrical chamber into the slag layer. The lance is considered as the heart of the furnace, where the air and fuel are transported through two concentric tubes and are mixed in a combustion chamber, which is approximately 7 cm from the tip of the lance (considering the pilot-scale TSL furnace at the Institute for Nonferrous Metallurgy and Purest Materials - INEMET). The TSL furnace is very flexible with the type of fuel, feed material and the air input. The fuel can be natural gas/heating oil/fine coal particles and the air could be enriched with oxygen (Figure 1). The general mechanism of the TSL furnace lies on feeding the material from the top of the furnace and the material is pulled into the molten bath due to the high turbulent atmosphere, which results in high reaction rates. The thermocouples installed in the furnace (i.e. in the ceramic linings) allow the operator to know the temperature of the melt. For example, in the case of copper production the tapped material (i.e. matte/metal) can be transported to a settler for further processing or directly used.

Jan 1, 2019

By Tong Qin, Jinxia Zhang, Fusheng Niu, Limei Bai

"The interaction between a deformable bubble and a rigid particle in viscous liquids under microgravity conditions is studied by direct numerical simulation via an Arbitrary-Lagrangian-Eulerian (ALE) method. Due to the microgravity, the bubble will stay as a sphere in the fluid without external forces and its deformation is caused by the moving particle. In this study we assume the flow field is axisymmetric and the motion of the gas inside the bubble is neglected. The particle equations and the Navier-Stokes equations for the fluid are solved in a unified finite element framework. The particle obtains an impact velocity by an external force and the impact velocity is varied over a wide range. A ‘critical time scale’ T0 was identified for the interaction process. For successful contacts between particle and bubble, the time scale of their relative motion must be less than T0.INTRODUCTIONThe particle-bubble interaction is an important process in many applied industrial domains such as water treatment, froth flotation and liquid steel purification. It is a complex three phase process in that it embraces many research areas: fluid hydrodynamics, interfacial forces, particle and bubble behaviour and solution chemistry.Derjaguin and Dukhin(1961) clarified the particle-bubble interaction by introducing three-zone model for small and medium size particles. When the particle is far away from the bubble surface, the hydrodynamic forces are dominant. The particle is driven toward the bubble surface by the particle inertial and gravity. This region is regarded as Zone 1 and the interaction in this zone is a collision subprocess. As the particle gets close to the bubble, it exits a zone where the liquid flow around the bubble surface creates a tangential stream from the upper surface of the bubble toward the rear of the bubble. This is Zone 2 which is called the diffusiophoretic zone. In Zone 3, the particle is very closed to the bubble, surface forces like van der Waals, electrostatic and structural forces are considered. Contrast to Zone 1, Zone3 can be regarded as an attachment subprocess."

Jan 1, 2016

By R. G. Achter, E. Wilson

"This paper describes the work undertaken to renovate the Pipe Open Pit drainage system, incorporating measures to improve effluent quality. It describes the technical feat of drilling an l l-inch-diameter hole from the bottom of the open pit for a distance of 1100feet to intersect an underground drift. An innovative method of checking the inclination of this hole is also described. The paper outlines the construction required on the 1500-foot level of the underground mine to facilitate water impoundment and slime settling, as well as the instrumentation for control of water flows. IntroductionThe Manitoba Division of Inco Metals Company operates two mines-an underground mine at Thompson and an open pit at Pipe. The Pipe Open Pit is located 20 miles southwest of the City of Thompson, approximately 400 miles due north of Win nipeg(Fig. 1).Surface diamond drilling of the Pipe ore body was sta rted in 1959. In 1961, a shaft was sunk to a depth o f 1,570 feet to carry out further exploration work and obtain bulk ore samples for metallurgical testing. Site preparation to mine the upper portion of the orebody as an open pit was initiated in 1966 and by late 1967, the removal of silt and clay overburden was in progress. The contractor completed the dredging in the fall of 1969. Over 12 million cubic yards of muskeg, clay and silt was removed, which in some places was 150 feet deep over the orebody. Production began in early 1971, by which time the top three benches of rock had been excavated and the orebody exposed.The Pipe No. 2 Mine main shaft was started in 1970 and completed in 1973 at a depth of 3,160 feet. Development for exploration purposes was carried out on the 1500 and 2460 levels, and permanent pumping facilities were installed.The surface dimensions of the open pit are 2,200 by 1,600 feet, with the long axis striking northeast. The walls are designed with a 45- to 50-degree slope and the ultimate design depth is 720 feet. The present depth of the pit is 520 feet and production capacity is 6,800 tons of ore per mine day."

Jan 1, 1980

By Paul G. Dunn

Safe rapid drift development results principally in reducing exposure of underground workers to the working face. This reduction in exposure is not achieved until either the rock walls have been suitably scaled or sufficient support has been put in place. Rapid drifting enables quicker access to orebodies (increasing returns), higher production rates and a resultant lower cost of mining. The Mining Innovation, Rehabilitation And Applied Research Corporation (MIRARCO) has been developing technology and a methodology for safe rapid drift development within the underground metalliferous mining industry. In terms of rock scaling for underground metal mines, there is still considerable use of manual and mechanical impact rock scaling techniques. Two main issues result from this approach. The first is that in highly stressed or highly fractured ground, a decision has to be made as to when sufficient scaling has taken place. This is not always easy to do and hence operator judgment is a crucial element in this approach. During a baseline study of current rock scaling practices, a wide range of scaling practices were observed within five different underground mining operations; this demonstrates the difficulty inherent in the rock scaling quality decision making process. The second issue is related to the exposure of workers to freshly created rock surfaces. In manual scaling techniques this is unavoidable and despite the best scaling practices, accidents still occur. In an attempt to provide an alternative scaling technology, MIRARCO has been investigating highpressure water jet scaling for removing loose rock as part of the drift advance process. This technology not only provides a means by which scaling practices can be engineered (remove the loose material you want to in a given rock mass condition), it is also quicker and easily automated. Automating the scaling process removes workers from exposure to freshly created rock surfaces and also enhances the application of spray-on liners through improved adhesion of these support types to the rock surface. This paper describes the water jet scaling technology research and methodology for safe rapid drifting within the underground metaliferous mining industry and highlights the key issues and major drivers behind their continued development at MIRARCO.

May 1, 2004

By Karim Ramji

The extractive sector today faces growing social, legal and political risks (SLPs) from so many different stakeholders including national and local governments, name and shame groups, civil society and environmental groups, and the ?Occupy? movement. Beyond these stakeholders, there are the indigenous peoples who have growing legal, social, political and economic influence which can often determine the outcome of the Project. The development curve in the extractive sector from initial exploration to mine start-up has become longer, steeper and more risky and expensive as these SLPs have grown in scope and complexity. Even if a project is permitted or starts commercial production, its ongoing development and operations are also facing these SLPs. The continuous assessment of these SLPs and the strategy to mitigate for them has now become critical for every project in the extractive sector. A project will only be successful if it is able to obtain the legal permits to operate, then withstand any judicial reviews, and then also to be able to gain and maintain the Social License to Operate (SLO). Stakeholder identification, management and engagement are key risk-mitigation tools. This paper focuses on the growing influence that indigenous peoples are now enjoying and the impacts on the extractive sector. Indigenous peoples are a unique stakeholder group because their legal rights and interests to lands and resources, their aboriginal title and rights, are gaining more recognition. When indigenous peoples form alliances with other stakeholders, this simply adds to their growing momentum and leverage, and this can become a daunting challenge for the extractive sector. More due diligence is required by companies to understand and assess the challenges posed by operating in areas claimed by indigenous peoples. There is a real need for mining companies to develop an effective indigenous engagement strategy to address these challenges in order to successfully convert risks into opportunities. Early identification and engagement with the indigenous peoples is required and the goal should be to conclude an Impact Benefits Agreement (IBA) with the affected indigenous peoples. The real objective must be to develop a real and transparent relationship between the company and the indigenous peoples so as to gain and maintain the SLO.

Aug 1, 2013

By L Thompson, R C. West, T S. Kho

In 1978, the Outotec direct to blister flash (DBF) smelting process was commercialized with the commissioning of the Glogow 2 smelting facility in Poland. Since then four further DBF facilities have been constructed, two at Olympic Dam, one in Zambia and most recently one at Glogow 1 in Poland. The DBF smelting process differs considerably from conventional smelting process in both chemistry and unit operations, presenting opportunities for flowsheet capital and operating cost savings particularly when the concentrate copper grade is high. WorleyParsons has amassed considerable expertise in the Direct to Blister process and in this paper the process is compared to the modern two stage Double Flash process. The processes are modeled, and the key operating parameters, consumables and production metrics are directly compared. Subsequent flowsheets, key equipment lists and capital costs are also presented for comparison and discussion. The results show the range of concentrates which are most economically treated by the DBF process relative to those best treated in conventional processes along with those concentrates which could be treated by either process. INTRODUCTION The Outotec Direct to Blister (DBF) process was developed and installed at Glogow in 1978 (Czernecki et al., 2006). Currently there are a total of five DBFs built on three sites: Glogow No.2, Olympic Dam No.1, Olympic Dam No.2, KCM Zambia and Glogow No.1, being the most recently constructed. The DBF process was the first flash furnace process to produce blister copper and paved the way for the subsequent development of the flash converter and other continuous converting processes. Today four flash converters are in operation taking the total number of flash furnaces producing blister copper to eight. In all DBF operations it is the unique ore and concentrate composition which made selection of the DBF process the most attractive. In all cases, the concentrate is relatively high in copper but low in iron because chalcopyrite is not the major constituent. When considering smelting options for high copper, low iron concentrates a key question is then often asked, “At what point does it become economic to switch from two stage smelting and converting process to the DBF process?”

Jan 1, 2019

By P. Mattar

The geotechnical importance of studying fluid flow through porous media and soils in particular, becomes evident when dealing with groundwater movement in surficial geomaterials that can be initiated by hydraulic gradients that develop during construction activity, groundwater extraction, impounding of reservoirs and groundwater recharge during adverse climatic events. In a geotechnical context, rocks are regarded as virtually impermeable materials, with comparatively greater resistance to flow of water through their pore structure. The importance of the permeability of rocks comes to the forefront when deep geologic formations are used in geoenvironmental activities for disposal of hazardous and toxic materials. The permeability of the rocks encountered is of critical importance to these geoenvironmental activities since the movement or transport of the hazardous materials during their eventual release will be largely governed by the permeability characteristics of the geologic formation. The estimation of the permeability characteristic of geologic formations is a non-trivial exercise since the measure of permeability can be influenced by the scale at which the measurement is made. Regional-scale and borehole-scale estimates of the permeability can be greatly influenced by the inhomogeneities, including fractures, fissures, solution channels and other anomalies that are present in naturally occurring geologic media. These anomalies are considered to be site specific and can only be determined in a reliable fashion by either conducting tests at the appropriate scale or in the regional-scale through inverse analysis of tracer movement patterns in rock masses. The estimation of the permeability of intact units of a geologic medium has important geoenvironmental applications in connection with storage of wastes since the units in which repositories will be located should be sparsely fractured and the sealing of the fractures and fissures are a prerequisite to developing an efficient solution for storage. The intact permeability of geomaterials is therefore regarded as an important property that influences efficiency and reliability of geoenvironmental solutions for deep geologic disposal. The permeability of geomaterials such as concrete and cementitious grouts are also important to many geoenvironmental and infrastructure applications where durability of structural materials in general and cements used for sealing deep boreholes and other access shafts employed in waste management endeavours is influenced by the permeability characteristics of these materials

May 1, 2009

By Dale A. Sketchley

"Abstract - Large differences in gold content between rock fragments or small volumes of unbroken rock, commonly referred to as the nugget effect, are related to sample and subsample weights, crushing and pulverizing sizes, and density, shape and size distribution of gold grains. Gy’s sampling theory, which relates gold grain characteristics to sample weight, fragment size, and error, provides a method of estimating a sampling constant that quantifies deposit characteristics that contribute to the nugget effect.Sampling control tests provide methods for determining the sampling constant. Sampling control charts, comprising nomographs that relate sample weight, error and particle size, use the sampling constant to optimize sample weights and comminution sizes, and to minimize the variability introduced by incorrect or inadequate sampling and sub-sampling procedures. The sampling constant is useful in classifying ores into arbitrary categories according to expected sampling difficulties. Spatial variations in the sampling constant can be used to aid in defining ore types for modeling geological domains, which should have unique sampling protocols. Examples that illustrate the relationship between the sampling constant and expected sampling problems, and the spatial variation of the sampling constant, are given for various deposits. Case histories of sampling programs are presented.Quality control procedures consist of monitoring sample contamination amd accuracy and precision of analytical results. Accuracy, precision and contamination are monitored by including standards, duplicates and blanks into batches of samples being analyzed. Analytical results of standards and blanks are plotted on a batch-and-time basis with control lines at plus or minus two/three standard deviations as confidence limits of the accepted round-robin value. Examples are given that illustrate a laboratory system in statistical control and the various types of problems encountered when interpreting quality control data. These include sample transcription errors, degradation, contamination, sampling errors, detection limit problems, instrumental drift, lack of statistical control, laboratory bias, procedural problems and data tampering.Where bias is negligible, precision, as a function of concentration, can be obtained from duplicates using the Thompson-Howarth precision algorithm, which also allows calculation of the practical detection limit. Examples are given that illustrate variations in precision, with grain size, for different types of duplicates, as well as mineralogical changes and sampling errors."

Jan 1, 1998

By T. Moyo

Ammoniacal solutions are attractive and effective lixiviants for the dissolution of chalcopyrite, allowing for the formation of stable ammine complexes with copper while rejecting iron. Chalcopyrite dissolution in ammoniacal solutions is reviewed from literature, and results from a recently completed study evaluating it through electrochemical and controlled leach studies are discussed. Ammoniacal leaching of copper ores dates back to 1916 in the leaching of low grade copper ores in the Kennecott leaching plant and in the Calumet and Hecla mines, followed by the commercialisation of the Sherrit Gordon process for the ammoniacal leaching of sulphide copper ores in 1948. Since then ammoniacal leaching has received intermittent focus from researchers with the development of the Anaconda’s Arbiter process and the unsuccessful Escondida process. In these leaching processes, the formation of surface deposits has historically been reported to result in the passivation of the chalcopyrite surfaces, whereas oxygen mass transfer in solutions has been the focus of process design improvements. Results of studies on high grade chalcopyrite material is presented in this paper which show that although a surface deposit was formed, it did not result in the passivation of chalcopyrite in ammoniacal solutions, and that while oxygen transfer is critical, it is not the direct oxidant in the reaction. INTRODUCTION Ammonia and its salts have been used in the hydrometallurgical treatment of non-ferrous metals such as copper, cobalt and nickel from oxide ores. Its chemistry allows for the selective dissolution of desired metals, leaving behind gangue including iron. Chalcopyrite is a copper sulphide ore known to be very stable and hence recalcitrant to many hydrometallurgical processing methods. Thus, the dissolution of chalcopyrite continues to be an attractive area of research. The dissolution of chalcopyrite in ammoniacal solutions is possible due to the stabilisation of copper(I) and copper (II) ions by ammonia in alkaline media. Ammonia has become more attractive as a lixiviant during the present socio-economic climate due to its low toxicity, relatively low cost and ease of regeneration by evaporation (Meng & Han, 1996). Ammonia processes are ideal when the gangue minerals are acid consuming e.g. with calcareous or dolomitic gangue (Paynter, 1973).

Jan 1, 2019

By Jan E. Nesset, L. Paul Staples

"High Gradient Magnetic Separation (HGMS) technology, although developed over 2 decades ago, has not been widely applied to the separation of sulphide minerals. Under conditions of strong magnetic field gradients, weakly magnetic minerals such as chalcopyrite (CuFeS2) and marmatite (Zn(Fe)S, sphalerite with iron in solid solution) behave paramagnetically and can be effectively separated from diamagnetic minerals such as galena (PbS). The application of this technology to the separation of Cu-Pb and Zn-Pb bearing streams in the treatment of fine grained complex sulphides may in some cases be more effective than separation by flotation. A 2 TPH Sala HGMS pilot plant was operated at Brunswick for a nine month period, ending in March 1995. The testing demonstrated the mechanical reliability of the technology, the consistency of operating results and the scale up from laboratory testing. HGMS is seen as a complimentary technology to flotation, best suited to performing those separations of galena (and other diamagnetics) which flotation does not do as well.IntroductionBackgroundSince the turn of the century, the magnetic character or magnetic susceptibilities of minerals have been determined with increasing precision and accuracy. Figure 1 illustrates specific magnetic susceptibilities of some common minerals. As long as susceptibility ranges do not overlap, separation is possible.In 1937, the principle of using a magnetizable matrix material in a magnetic field to increase both magnetic flux density gradients and number of capture sites for susceptible minerals was first applied (Frantz). It was not until the 1970's, however, that the genuine development of wet high gradient magnetic separation began with the introduction of very fine matrix materials to the magnetized volume of large solenoid magnets. Today, dozens of HGMS units purify, filter and separate minerals, primarily for the removal of iron stained minerals from clays used in the paper coating and china clay industries and for the recovery of fine titanium and iron oxides in the iron ore industry. Only the Garpenburg mill in Sweden is currently applying a continuous HGMS machine to separate complex sulphide minerals; upgrading a lead concentrate since 1988."

Jan 1, 1996