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By F. Hassani, E. Aflaki, M. Nokken, M. Kermani

"This paper presents and compares the physical properties of Gelfill and cemented hydraulic fill (CHF) obtained by lab experiments. Gelfill consists of tailings, different binders such as Portland cement, fly ash and blast furnace slag and an alkali activator such as sodium silicate. The CHF and Gelfill samples with various mixture designs were cast and cured for 28 days. The influence of sodium silicate concentration, pulp density and mixing time on the mechanical properties of samples were evaluated using the uniaxial strength test. Mercury intrusion porosimetery (MIP) was used to analyse the microstructure of CHF and Gelfill samples.This study concludes that: (i) The mechanical properties of CHF can be improved by the addition of appropriate amount of sodium silicate. (ii) The rate of strength acquisition in Gelfill samples is faster than CHF samples over 28 days of curing period. (iii) Mixing time strongly influences the mechanical properties of Gelfill samples but did not have any effect on CHF samples. (iv) The MIP analyses indicate that the pore size distribution and total porosity of Gelfill and CHF were different, and this did contribute to higher strength development of the Gelfill samples. INTRODUCTIONThe increased depths of mines in the Canadian Shield and the high stress associated with these depths favour a new method of mine backfill that can both meet strength requirements and help mine productivity. The mine backfill mainly consists of tailings, water and binder materials, the latter being most expensive. Gelfill is a new mine backfill material whose binder usually consists of alkali activators such as sodium silicate and other cementitious materials such as blast furnace slag and normal Portland cement. Although sodium silicate has been used in concrete manufacture, the use of this material in mine backfill is relatively new (Doucet, 2007, Razavi, 2007). Until very recently there have been only a few isolated publications, mostly out of McGill University, regarding mine Gelfill (Razavi, 2007 and Kermani et al., 2009 and 2010). These papers have investigated some of the basic mechanical properties and mechanical behaviour of Gelfill. However, the physical performance of Gelfill in various conditions has yet to be understood. Therefore, the main objective of this study was to investigate the influence of mixing time and sodium silicate concentration on the mechanical performance of Gelfill and CHF through a series of experiments. Moreover, the microstructure of the Gelfill and CHF samples was studied."

Jan 1, 2015

By F. W. Crossland

Losses of metal are often traced to incorrect pH/ORP signals in flotation, leaching, extraction, electrolysis, and precipitation processes, aggravated by pressure changes. IC Controls, a Canadian mining sensor manufacturer, developed a new superior pH/ORP sensor that stops metal losses, reduces environmental footprint and contributes to sustainability. The cause of incorrect pH/ORP signal is rooted in the reference. Reference junctions are designed to allow diffusion of reference chloride ions into the process but also allow process ions to diffuse into the reference. This development is important to mines and hydrometallurgists where sulphide, cyanide, ammonia and other poisoning ions are present in the process. These ions react with reference electrolyte components causing the signal to change, drifting from the correct process value. With fluctuating process pressure, ion in migration dilutes the electrolyte producing similar signal drifts. If process ion in-diffusion could be stopped, the pH/ORP signal would be accurate. IC Controls new pH/ORP sensor stops process ion in-diffusion, and remains accurate over long periods. New processes using higher pressure and fluctuating pressurized reactors will greatly benefit from stable pH readings. Similar to IC Controls' proven model 642 Mining pH sensor, our new model 647 contributes to sustainability through reducing disposal costs from waste reagents, lost metal and fewer used sensors.

Jan 1, 2014

By D. Chadwick, J. W. Matousek

Between 1860 and 1890 -- from the time of the American Civil War to the last decade of the 19th Century -- nickel production in North America was dominated (even monopolized) by the output of the industrial complex of the Gap Nickel Mine near Lancaster, Pennsylvania and the American Nickel Works in Camden, New Jersey. In some years, from one sixth to one third of the world's metallic nickel supply came from this enterprise. Mining and smelting were conducted at Lancaster; a matte of high iron content was shipped to Camden for pyrometallurgical and hydrometallurgical refining to produce nickel metal, copper sulfate, and cobalt oxide. The high purity nickel product was rolled into sheet for marketing, primarily for coinage, as nickel had few other uses at that time. The undertaking experienced all of the problems that face the mining and metallurgical industries of today: declining reserves, high labor and fuel costs, high transportation costs, fluctuating demand and prices, pollution concerns, and foreign competition. The technical features of the geology; the mining, smelting, and refining operations; and some of the economic aspects are assessed. The view is taken from that of the present time -- seeking those lessons from history that we are supposed to learn or face the prospect of repeating the mistakes of the past.

Jan 1, 2005

By O. Alonso-Gonzalez, F. Nava-Alonso, A. Uribe-Salas, R. Pérez-Garibay, C. Jimenez-Velasco

A current problem in gold production is the presence of copper minerals which dissolve during conventional cyanidation practice. The dissolved copper causes several problems in the different stages of the process. This issue is the base for copper elimination/recovery methods such as the Sulphidization, Acidification, Recycling, and Thickening (SART) process, which is currently used in gold production plants around the world. Even though the process is well established, new challenges appear as the composition of the solution varies from ore to ore, in some circumstances affecting the performance of the SART process. This work presents a thermodynamic study and experimental tests performed to understand the role of the initial copper concentration and sulfur addition, on the efficiency of the copper removal. For a constant cyanide concentration, an increase in the initial copper concentration causes a decrease in copper removal; high sulfur/copper molar ratios favor copper removal. We demonstrated that the cuprous sulfide formed from solutions with high ionic strength, presents better sedimentation rates than solutions with less ionic strength. For solutions with low sedimentation rates, the use of some pretreatment is necessary to facilitate the sedimentation such as addition of flocculants, particle recirculation and the used ultrasonic pretreatment.

Jan 1, 2014

By John Emery, George Wang

Research and applied utilization activities for the increased use of ferrous and nonferrous slags in construction are presented. The overall use of blast furnace slag is relatively well known for a range of construction applications from aggregates to slag cements. In contrast to blast furnace slag, which is volumetrically stable and straightforward in its construction uses, steel slag contains hydratable oxides that can result in volumetric instability that must be dealt with through appropriate steel slag aging, testing and quality control to ensure its appropriate use. Particular care must be taken to prevent potential steel slag expansive behaviour in confined applications. Quality requirements and guidelines on steel slag expansivity to further the use of steel slags, with demonstrated acceptable performance, are outlined. There is a full range of proven construction uses - from aggregate to cementitious materials - for copper, nickel and phosphorus nonferrous slag. The use of air-cooled nickel slag is presented, based mainly on practical highway construction experience. It has been shown that air-cooled, crushed nickel slag can be an excellent aggregate in granular base, engineered fill and hot-mix asphalt. There is a good potential for increased ground, granulated copper and nickel slags use as supplementary cementitious materials that is being developed, which takes advantage of the 'latent energy' content. The scope of a new technical text in preparation on the technology of slag utilization is reflected throughout to provide a practical context for the engineer.

Jan 1, 2004

By Sadan Kelebek, S. O. Fekete, Gerhard W. Heinrich, Peter F. Wells

"For many years, rejection of pyrrhotite at the milling stage has been a viable method for sulphur dioxide abatement. Pyrrhotite rejection options have included the use of selective pyrrhotite depressants in flotation; a depressant which has recently come into use is diethylenetriamine (DETA). This reagent has been the subject of recent research and development efforts in the processing of nickel-copper sulphide ores.In the present study, adsorption trends for DETA have been monitored under the dynamic conditions of flotation using a spectrophotometric method which has been adopted for this purpose at Falconbridge Limited. The results indicate that the adsorption of DETA is quite fast and in the majority of cases, accounts for the disappearance of 75-95 % of this reagent from pulp's liquid phase. The adsorption decreases linearly with an increase in the DET A dosage from 100 git to 600 git. The tailings produced in flotation tests were subjected to washing with deionized water at 60 °C to examine the desorption of DET A. These results indicate that the amount desorbed increases with increasing DETA dosage used during flotation but is less than 7 per cent of that adsorbed. It was found that adsorption of DETA alone, even at relatively high levels, does not always cause depression of pyrrhotite. A new combination of reagents identified in the metallurgical laboratories of Falconbridge Limited utilizes sulphur dioxide with DETA. These reagents together are capable of efficient depression of pyrrhotite on a consistent basis."

Jan 1, 1995

By L. Li

Iron removal is a common procedure in hydrometallurgy of non-ferrous metallic ores. Chemical precipitation and solvent extraction are currently the main methods employed for separation of iron from copper leach solution. However, chemical precipitation methods have the problem of producing large amounts of iron precipitates, and/or requiring high temperature and high pressure conditions for precipitation. The precipitates are difficult to separate from the solution. Emulsification is a general problem for solvent extraction, which causes loss of extractants and contamination of the electrolyte. A common problem for solvent extraction and chelating ion exchange processes is the difficult iron stripping process. Therefore, finding an efficient and environmentally friendly method for iron removal is of great significance. In this paper, new processes of using ion exchange resins to remove iron from copper leach solution have been investigated. Salicylic acid, amino carboxylic acid, amino phosphonic acid and hydroxy-oxime resins were employed to adsorb iron from a simulated copper leach solution containing 40 g/L of Cu2+ and 36 g/L of Fe3+. It was found that a hydroxy-oxime resin, named Z-Fe, has excellent adsorption selectivity on Fe3+. Desorption behavior of the resin was studied by two step elution using dilute H2SO4 and oxalic acid solution, respectively. After optimizing the adsorption-elution processes, the extent of removal of iron from the simulated copper leach solution using resin Z-Fe was 90%, while copper recovery could reach 100% in closed circuit processing.

Jan 1, 2016

By A. Piche, J. Nantel

"This paper describes the recent developments in Canada toward the establishment of a Canadian Centre for Mining Automation and Robotics, at McGill University and École Polytechnique in Montreal. The role of the Mining Association of Canada (MA C) and of the National Advisory Committee on Mining Automation will also be reviewed. IntroductionIn order to remain competitive, the mining industry must increase its productivity and reduce its costs. In the last two decades, this objective has been achieved through mechanization. From now on, any further improvement in productivity will be gained through increasingly more automated mining equipment.Recent international developments following the Versailles Economic Summit in June 1982, having given rise in Canada, to a renewed interest in applications of robotics and automation to mining.The mineral industry in Canada is at a crossroads. Competition in emerging from everywhere: lower grade ore bodies, increasing distances between viable mines and markets, third world massive production of certain commodities, substitution of "" space age"" materials (ceramics, plastics, composites, etc.) for metals.On the positive side, it is generally believed that present mineral commodities, i.e. base metal, gold, iron, industrial mineral s, etc ., will continue to be in high demand for centuries to come despite substitution. New applications for conventional metals will be found and the enhancement of certain properties of these conventional metals mean continued demand. For some mineral commodities, there will never exist an y substitute."

Jan 1, 1988

By William H. White

"AbstractThe value of anomalous metal contents of trees as an aid to the discovery of mineral deposits was tested under field conditions cm four known ore deposits. Results indicate that a base-metal deposit, or any deposit containing zinc or copper, casts a 'metal shadow' into the overlying soil which remains approximately positioned above the deposit, regardless of the type of overburden or the movement of groundwater.The unusually high content of zinc or copper in trees growing within the limits of this 'metal shadow' constitutes an anomaly which can be detected and ,plotted in the field The field kit and certain points of the field technique are described briefly; and the characteristics of plant anomalies and possible limitations of their use are mentioned.IntroductionRecent investigations concerning the metal content of trees indicate not only wide variations in the metal content of different species and in different parts of the same tree but, in addition, suggest that the metal content of a tree is related to that of the subjacent bed-rock. Abnormal values found by Warren, Delavault, and others in trees growing above or near orebodies suggest a new tool which may prove of considerable value in exploration work. Evaluation of this new tool must involve consideration of the following questions:(I) Is the technique one which can be used under field conditions by persons not specially trained; and can results be duplicated within reasonable limits of error? Rather than taking tree samples for subsequent laboratory analysis, it is highly desirable that analyses be made on the spot. This allows anomalous results to be checked and additional samples may be taken at key points."

Jan 1, 1950

By S. Itoh, T. Nagasaka, J. Ono

With respect to the recycling of used lead-batteries, a pure lead is required to prepare a lead-calcium alloy electrode for a new maintenance-free battery. The pure lead can be obtained by means of electrolytic and/or pyrometallurgical refining. In the lead electrorefming, antimony is concentrated in anode slime. From the viewpoint of the recycling and recovery of metal values from used lead-batteries, especially from anode slime, oxidation experiments were conducted for pure liquid antimony in the temperature range between 973 and 1373 K to elucidate the oxidation kinetics and mechanism. Furthermore, since lead anode slime generally consists of antimony, lead and bismuth, experiments have been also carried out using antimony-lead-bismuth alloy. The equation relating to the mass transfer characteristics in the gas phase was then applied to analyze the oxidation kinetics. As a result, it was found that the anode slime treatment, that is, an oxidation of antimony concentrated in anode slime followed by vaporization as antimony oxide Sb406, should be operated with higher oxygen partial pressure and sufficient amount of gas flow rate at lower temperature around 1073 K. The feasibility of the oxidation treatment for anode slime has been also discussed.

Jan 1, 2004

By G. L. Palmer

"In 1986, anomalous sampling results for heavy minerals were obtained at various sites in Namaqualand on the west coast of the Cape Province. Drilling in 1987 at Graauwduinen penetrated up to 35 meters of heavy mineral-bearing Tertiary sands which extend several kilometers inland from the coast. The heavy mineral suite includes ilmenite, rutile, leucoxene, zircon and monazite, along with gamet, pyroxene and amphibole. Three deposits are recognized, two of which comprise the resource to be mined by Namakwa Sands Limited, a recently formed Anglo American Corporation subsidiary company.Mineable reserves in excess of 500 million tonnes have been delineated, sufficient to sustain mining for over 35 years at projected production rates. During the feasibility study, on-site investigations included test mining at various sites to assess rnineability and to provide material for metallurgical testing in a pilot plant located at the site. llmenite produced at the mine will be smelted at a new facility to be built at Saldanha Bay. Saleable products comprise titania-rich slag, pig iron, zircon and rutile.During the exploration phase, company environmental guidelines were established and monitored. The feasibility study incorporated a Class 1 Environmental Impact Report, the contents of which were made public following the principles of the Integrated Environmental Management legislation."

Jan 1, 1994

By Kristie D. Tarr

Ideally, in situ monitoring would supply the input data for numerical modeling of backfill material property requirements. However, clue to production requirements and costs of conducting field tests, input data are often based on small-scale laboratory tests. The size of test samples is known to play an important role in the laboratory assessment of the behaviour of geotechnical materials, including backfill. There are observed differences between the mechanical properties of laboratory-scale samples and those of in situ materials, and these are generally attributed to the differences in scale. Various scaling factors have been proposed for converting laboratory observations to anticipated in situ conditions for soil and rock materials. With regard to mine backfill, very limited studies exist which have involved the effects of sample size on material properties. The literature indicates that reported backfill strength data are based on a variety of test sample sizes and in some cases, specimen geometries. Carefully determined laboratory scale effects could play an important role in estimating the potential backfill behaviour in the field, especially when developing new backfill systems. Laboratory studies were conducted with sample diameters ranging from 50 to 300 mm. Scale factors relating specimen size to strength were developed wherever possible, and are presented in this paper

May 1, 2008

By P. R. Goad

"Kidd Creek is a large volcanogenic base metal sulphide deposit, located near the west end of the Abitibi greenstone belt, 27 km north of Timmins, Ontario. The rhyolite geology is characterized by a NNE-striking and steeply east-dipping package of rhyolite volcaniclastics upon which has been imposed a strong ESE-striking and north-dipping structural fabric . Massive rhyolite units with grey-black. chloritic cores and yellow, sericitic margins intrude as dykes into the stratigraphic footwall and as sills higher in the stratigraphy. Massive rhyolite units positioned near the top of the felsic pile exhibit an extensive marginal development of hydraulic fracturing and are termed crackle-brecciated rhyolite.The stringer sulphide zone is positioned in a lobate blanket of crackle-brecciated rhyolite at the top of the felsic pile. The stringer sulphide zone is characterized by a mature chemical alteration, being specifically depleted in alkalis and enriched in iron-rich chlorite. with accompanying silica, sericite and carbonate alteration. A suite of trace elements characterizes this mature alteration. The massive rhyolite units, which intrude lower in the rhyolite volcaniclastics, exhibit a core of weak chlorite alteration and strong marginal sericite alteration. Tight or unfractured massive rhyolite units are essentially devoid of sulphide mineralization and exhibit a suite of trace elements characteristic of this immature alteration. It is interpreted that the massive rhyolite units intruded into an already evolving system and ""choked-off"" active conduits carrying hydrothermal fluids and subsequently acquired an immature alteration signature. Rhyolite units positioned higher in the pile developed intense hydraulic fracturing and a mature alteration coincident with the formation of the stringer sulphide zone. In summary, a model, based strictly upon the rhyolite geology, is reviewed to assist in the exploration for volcanogenic base metal sulphide deposits."

Jan 1, 1985

By N. Saracoglu, J. P. Golightly, R. H. Wallis, J. J. Brummer

"In January 1974, the Minerals Division of Canadian Occidental Petroleum Ltd. made the strategic decision to add uranium to its active exploration commodities and through compilation studies selected northern Saskatchewan as the most attractive and cost-effective exploration area in Canada. In August 1974, 100 sq. miles were staked adjacent to Gulf Minerals' Rabbit Lake deposit and east of the Esso Minerals Midwest boulder train. Initial exploration was based on geologic models of the Rabbit Lake deposit.In the summer of 1975, surface surveys delineated radon anomalies which were drilled that winter and found to overlie anomalous concentrations of uranium in the regolith which forms the upper unit of the crystalline basement. Within the crystalline basement, one hole intersected graphite and pyrite with anomalous nickel-cobalt-arsenic. Geochemical and radiometric surveys followed in the summer of 1976. Drilling in the winter of 1977 intersected several zones of graphite and also anomalous, but uneconomic, uranium abundances. Also in 1977, Dahlkamp and Tan (1977) described the coincidence of graphite and uranium at Key Lake and ground EM surveys on CanadianOxy claims detected graphite conductors beneath 250 ft of Athabasca sandstone. Inco Limited joined the project in April 1977 as a 50% partner. The project area was then surveyed using the airborne INPUT EM method, which detected 84 miles of conductors, with associated graphitic metasediments. On the ground these were located with MaxMin surveys, and follow-up drilling located the ""Tent"" Lake uranium zone.In 1978, the Midwest and Dawn Lake discoveries were announced, 7 miles and 2 miles west of the Joint Venture (J.V.) claims; and, in part for this reason, the 1979 winter drilling was concentrated on the deeper west side of the property. Exploration hole 102-79 intersected altered and uraniferous rocks, but stepout holes were barren. Drill hole 153-79 tested an under-snow three-station radon anomaly east of hole 102-79 and intersected 33 feet of 7.51 % U3O8, confirming the disco very of the McClean North zone. The geophysical grid of the McClean North conductor system was extended and detailed a strong, continous conductor to the south, called McClean South. This was drilled in January 1980and hole 1004-80intersected 22 feet of 2.95% U3O8."

Jan 1, 1983

By C. Larsen, R. A. Walker, A. Voth, C. Daoust

"The 3000 t/d mill at Hernia Gold Mines Inc. was commissioned in March, 1985. By Canadian standards the concentrator is highly automated, however, unlike the retrofit systems in many other plants, the Hernia process control system was installed during plant construction. This paper describes the Hernia control system beginning with system development (justification, architecture, start up, etc.), proceeding to current applications (crushing, grinding, leaching, etc.) and finally discusses some of the short term objectives for system improvement.INTRODUCTIONThe Hernia Gold Mines Inc. operation is located in the Marathon area of Northwestern Ontario. Controlled by Noranda Minerals Inc. (50.1 %), the cost of bringing the mine into production was nearly $300 million. A unique feature of the mine development was the extraordinarily short elapsed time of three years from Noranda's initial involvement to the start of milling operations. Additional background information on this project can be found in the trade literature (e.g. Tinter (1986). Scales (1987).)The Hernia concentrator is designed to process 3000 tpd of ore and commenced operation in March, 1985. Figure 1 provides a general plant flowsheet indicating the major circuits. Typical annual production statistics are included on the figure and these have been extrapolated from the available 1987 year-to-date data. Larsen and Tessier (1986) have previously described the operational aspects of the mill.In a metaphorical sense, the Hernia concentrator is like the traditional bride, ""wearing something old (e.g. the cyanide leach process), something new (e.g. a plant wide digital control system installed during construction), something borrowed (e.g. crushers from Gaspe) and something blue (e.g. the cladding on the surface buildings). While the prospect of fully undressing this bride is of considerable interest, here we choose to focus on something new. In particular, we choose to examine the process control system in some detail since Hernia is one of Canada's more highly autcmated gold mills. The control system is of interest because it has received suostantial credit for maximizing metal production and minimizing operating costs. With reference to the latter, it is worthy of note that Hem lo reports recent operating costs of less than $100 U.S./oz."

Jan 1, 1988

By Z. D. Hora

Limestone of economic interest is widespread in British Columbia. Triassic deposits on Texada Island are a convenient 1idewa1er source of li111es1one for cemen1 and lime for 1he Pacific orthwes1. Permian limes/one near Pavilion Lake is used for quicklime, and a deposit near Kam/oops is used for cement. Quarries at Dahl Lake and Pwrmigan Creek serve local pulp and paper needs.

Jan 1, 1984

By Jean-Pierre Birat, François Hanrot, Gérard Danloy

Global warming presents an enormous challenge to the steel industry, which is both carbon-intensive and energy efficient. Lean production can provide some short-term emission mitigation, at the level of the Kyoto requirements. In the middle term, more use of scrap will also help alleviate emissions. But to reach much larger reductions in GHG emissions, on a par with the likely targets that will be set after the Kyoto period, the steel industry will have to imagine new production paradigms, which constitutes its most formidable challenge for the years to come. Carbon capture and sequestration, processes leaner in carbon use, electricity and hydrogen from green sources will have to be added together in a patchwork of process routes, which will have to be developed at great risk in the next decade, hopefully through broad international cooperation.

Jan 1, 2004

By Michael L. Free, Shukla. Abhijeet

The short-circuiting tendency of a copper electrowinning cell (EW) based on the roughness of cathode deposits was investigated with varying parameters such as Cu concentration, guar concentration, current density, and temperature. A bench scale EW cell was set up to produce copper under conditions similar to industrial Cu EW. In addition, a statistical analysis and finite element analysis were performed to analyze the deposited thickness, surface roughness and maximum feature height. Interaction data for the cathode deposits suggest that current density and Cu concentration together affect the roughness of deposit more than the combined effect of guar and temperature. Model predictions of roughness were similar to experimental values. The predicted time to short-circuiting was similar to the measured time. This study provides an industrial relevant baseline against which new operating parameters can be compared.

Jan 1, 2014

By D. Neely

As Saskatchewan potash mines grow in age and size, mining reaches greater depths.  The stress-relief design principals which were empirically derived at shallower depths are beginning to show fault.  Nutrien Vanscoy Potash has began to encounter new ground support and panel design challenges which were previously had negligible effect.  While the initial reaction was to reduce extraction and implement distance buffers between operating machines, it eventually became clear that these would only provide short term relief and that in order to continue safely and efficiently mining broad areas, a fundamental change in the mine design would provide the long-term protection required.  Presented is a case study with an overview of the challenges encountered at Vanscoy Potash in areas of greater depth along with an account of the design changes considered, implemented and recommended for future success. 

May 4, 2025

By S. C. Ells

Introduction An investigation of the bituminous sands of Alberta was begun by the Mines Branch, Department of Mines, in 1913. This investigation was interrupted during the period 1916-19, but was resumed in 1920. Work completed in October 1924 has included detailed topographical surveys of extensive areas, examination and sampling of principal outcrops, the mining of trial shipments, laying of demonstration pavements, and a study of methods adapted to the recovery of hydrocarbons from the crude bituminous sand. Bituminous sand consists, for the most part, of clear quartz grains, cemented together by petroleum residuum or bitumen. In form the quartz grains are most irregular, varying from sharply angular to smooth, waterworn shapes. The bitumen has a specific gravity of 1.018 and has a penetration of 9.00 mm. (77° F. 100 grams 1 sec.). The percentage of bitumen associated with the sand varies from 5 to 25 per cent. A large tonnage is available in which the percentage of bitqmen is 15 per cent or over. Production Up to the present time, production has been restricted to requirements for experimental .and demonstration work. The total quantity shipped for such purposes has not exceeded 750 tons.

Jan 1, 1925