Search Documents

By Y. Thibault, L. Morin, R. Cameron, D. Gould

"There are an estimated 50 to 100 million dry metric tonnes of low-grade nickeliferous pyrrhotite tailings in the Sudbury area alone, with an average nickel grade ~0.8% (plus cobalt). Pyrrhotite is a highly reactive sulphide mineral that has the potential to generate acidity; consequently, it is stored in large tailings ponds that require perpetual treatment to avoid the production of acidic drainage. Re-processing this material using bioleaching technologies has the potential to recover valuable metals, while reducing the toxicity, reactivity, and acid generating potential of the remaining residues. CanmetMINING is currently developing a stirred-tank bioleaching process to recovery nickel and cobalt from pyrrhotite-rich tailings. Stirred-tank experiments have been conducted with one tailings sample over a range of pH and temperature conditions, resulting in 80 to 90% and 70 to 80% leaching of nickel and cobalt respectively in 10 days.INTRODUCTION Sulphide tailings may represent a significant financial liability for mining companies as these wastes may produce acidic drainage under some disposal conditions. As a result, the companies must post financial bonds large enough to ensure there are sufficient funds for perpetual management of these wastes. At the same time, there are billions of dollars in metals incorporated into these mining wastes waiting to become valorized. Many sulphide tailings are amendable to bacterial oxidation for metal extraction. Re-processing of tailings using bacterial leaching has the potential to recover valuable metals from waste; and reduce the toxicity, the reactivity, and the acid generating potential of the remaining residue. By reprocessing these wastes there is an opportunity to significantly reduce liabilities and financial assurance bonds, while recovering metal values. There are an estimated 50 to 100 million dry metric tonnes of low-grade nickeliferous pyrrhotite-rich tailings in the Sudbury area alone with an average nickel grade ~0.8% (Peek et al., 2011) plus cobalt and copper. Pyrrhotite is separated from pentlandite concentrates by magnetic separation and flotation. It is already finely ground and has often been segregated from other tailings material, making „mining? relatively inexpensive. This represents roughly (> $100/ton) in contained value, with negligible mining costs. This paper reports on the development of a stirred-tank bioleaching process for recovering nickel and cobalt from pyrrhoitite-rich tailings, which is currently underway at Canmet MINING."

Jan 1, 2017

By G. T. Lapidus, A. Garcés, O. J. Restrepo

"Colombian nickel laterites have historically been processed by pyrometallurgy. However, due to the depletion in ore grades, alternative processes are required. Hydrometallurgical processes, such as pressure acid leaching, have been proposed as alternatives to extract nickel from deposits with suitable characteristics. Such a leaching process requires high concentrations of acid to achieve acceptable extractions, and is not selective. In this study, an alternative aqueous alkaline glycine system has been employed to evaluate the leaching behaviour of a Colombian nickel laterite which contains 1.15% Ni, 0.12% Co and 41.1% Fe. Additionally, the effect of the addition of chloride ions, the use of a reducing agent and the application of a pre-treatment to improve the extraction of nickel were evaluated. Extractions of 4.63% Ni, 42.16% Co and 0.33% Fe were obtained using a 1M solution of glycine at pH 9. In addition, an increase in nickel extraction from 4.63% to 25.68% was achieved by applying a pre-treatment to the sample. The results show that even though nickel dissolution was much slower than in acid leaching, it was selective over other metals such as iron, proving the proposed method to have potential as a process for the extraction of nickel from Colombian laterites.INTRODUCTION Before 2010, most of the industrial operations used pyrometallurgical processes for the extraction of nickel, mainly in saprolitic regions of deposits, with greater contents of the metal. Nevertheless, due to the gradual depletion of such deposits, different hydrometallurgical processes have been studied as alternatives to process those nickel laterites with low grade and those which present problems of refractoriness due to the presence of acid consuming materials (McDonald & Whittington, 2008; Oxley & Barcza, 2013; Wang et al., 2012). However, such leaching processes require high concentrations of acid to achieve acceptable extractions and they are not selective. Facing lateritic nickel ore deposits containing high levels of acid consuming materials, an alkaline leaching medium becomes an advantageous alternative over acidic media, due to the increase in selectivity and decreased corrosiveness and reagent consumption (Tanda, Eksteen, & Oraby, 2017). Unlike conventional acidic reagents used for metal recovery, alkaline reagents can selectively dissolve the desired metal, leaving in the solid residue other elements such as iron, magnesium and aluminum, which are problematic in subsequent stages of metals separation and recovery. Furthermore, there are no serious corrosion problems associated with alkaline leaching, even at higher reagent concentrations, or at elevated temperature and pressure (Ntumba Malenga, Mulaba-Bafubiandi, & Nheta, 2015)."

Jan 1, 2017

By B. Drew, K. Budna, C. Wenzl, D. Gregurek, A. Spanring

"The metallurgy of nickel and cobalt and of copper is closely interlinked when processing sulfidic Ni-Co ores and Cu-Co ores. The respective furnaces are typically lined with magnesia-chromite refractories, which are exposed to multiple and complex stresses. The selection of the processing route, furnace type and slag system will be dictated by the specific ore type available, this will determine the individual refractory wear mode. This paper evaluates the common refractory wear mechanisms, namely infiltration, spalling and chemical attack by various slag systems, as well as sulfur attack, as observed when processing primary sulfidic ores. All these wear parameters, which are discussed in this paper, lead to a severe degeneration of the brick microstructure and a decreased lining life. Therefore, a detailed investigation and understanding of the wear mechanisms through “post mortem studies” is an important prerequisite for the refractory producer. Based on such research results, combined with specific process knowledge, appropriate brick lining solutions for nickel and cobalt processing furnaces can be recommended.INTRODUCTION The metallurgical production of cobalt and nickel and of copper is closely interlinked to the mineralogy of the respective ores: cobalt is found in African Cu-Co ores as well as in Co-rich nickel ores (laterites and sulfides). Also, Co-bearing secondary raw materials contain the mentioned elements in different contents. In pyrometallurgical processing of sulfidic ores, cobalt is generally recovered as a by-product during the production of copper and nickel, whereas it is normally not recovered separately during the processing of nickel laterites but remains in the FeNi product. Besides various hydrometallurgical production routes, the pyrometallurgical processes involved comprise smelting (i.e., production of a Cu-Ni-Co-Fe matte in electric or flash furnaces), converting and refining (i.e. removal of Fe and S as well as other elements from matte by oxidation). The ongoing trend to use higher oxygen enrichment in process air enables higher intensity processes but also increases the oxidation potential in the vessel. Therefore, during smelting and especially during the oxidative treatment in converting and refining, some amounts of valuable metals are also transferred to the slag in their oxides form. A subsequent slag treatment is then applied for recovering valuable metals from the slag, namely allowing an economic material stream handling and minimizing metal losses. This is often done in a slag reduction furnace. Additionally, copper and nickel are very good collectors for precious metals and platinum group metals (PGMs) - therefore, depending on the content of these metals, an additional refining process is used to recover these valuable metals from the matte or metal phase (Elvers et al., 1997; Davenport et al., 2002; Crundwell et al., 2011)."

Jan 1, 2017

"The last thirty years have seen enormous changes in all aspects of the gold industry, from the technologies of mining and extracting gold to the role it has played in the fiscal policies of nations. In this time, the market price of gold has increased ten fold and mine production has more than doubled. However, the cost of mining and extracting gold has also increased exponentially, and the industry has struggled with declining ore grades and increasingly refractory ore bodies.With the major economic powers of the world shrugging off the uncertainties of the post cold war era and moving into a period of unprecedented political stability, economic growth and low inflation, gold is also losing its lustre as a hedge against inflation and a backing for national currencies. Consequently, countries that had accumulated and hoarded gold for decades are now disposing of these non-performing assets, resulting in major swings in supply of the metal. Fortunately, this has coincided with the end of communism in many parts of the world and a tentative move to free market economies in most of the developing nations. As a result, people are becoming wealthier, and this is creating more demand for gold, principally in the form of jewelry.On balance, the shift in the role of gold, from one in which a significant portion of new gold production lay dormant in bank vaults as insurance against political or fiscal instability, to one in which most new gold is now freely traded as an industrial commodity, responding to normal market forces of supply and demand, has had a negative impact on the price of gold over the last fifteen years. In that time, the gold price has declined from a peak of $850/oz in 1980 to an average price of about $400 through the rest of the l 980's, to a price of -$320/oz today (1997). In large measure, this has been due to the enormous inventory of gold metal that was held by central government banks in vaults around the world, and which has been dumped on the market as soon as the price has started to trend upwards. Even today, after ten years of fairly steady selling by central banks, about 3 0, 000 tons of gold (or -8 years' supply at the present rate of consumption) is still retained in vaults (Murray et al., 1997).The downward pressure on the price of gold has created exciting opportunities for the development and implementation of new technology. Increasing the efficiency of gold recovery from more and more refractory ore bodies, whilst at the same time lowering production costs, have become critical to survival in this industry. These challenges have been met by the development and implementation of new technologies such as heap leaching, carbon in pulp, resin in pulp and the sulphide ore pre-treatment process of pressure leaching, bacterial leaching and fluid bed roasting. For an industry that saw very little technological change in the first seventy years of the twentieth century, the pace of change over the last thirty years must have seemed bewildering at times."

Jan 1, 1998

By R. H. Fett

T HE APPROACH to maintenance must always be ?completely positive: there must be no question of putting off difficult problems until it is more convenient to tackle them. By this it is meant that a piece of machinery or equipment which, by experience, is known to be due for a check should not, merely because it appears to be operating satisfactorily, be left until it reaches a critical .condition and breaks down. The mentality of the Maintenance Manager must be completely orderly and methodical and he should, in fact, possess a ledger-book mind, having a debit and credit outlook. The debit side would be that applying to time out of service, cost in wages, material, personnel involved, etc., and the credit side that relating to continuous operational time of the locomotive and therefore to the ultimate benefit of the mine and the personnel who work there. The Maintenance Manager is not concerned with design problems, and although he and the personnel under his jurisdiction are not engaged in productive work, he and his staff do, nevertheless, add greatly to or detract from the overall efficiency of the organization. Provided the machinery placed in his care is good to start with, he must take the best steps he possibly can to keep it running. However, he may, on occasion, be forced to improvise and this is where the ingenuity of a clever man rises to the occasion.

Jan 1, 1956

By S. H. Logan

The present discussions throughout the civilized world on the subject of gold for monetary purposes may seem due to general economic conditions during the past year. But for some years previously a small group of authorities had warned the world against the continued disregard of an equitable distribution of existing gold reserves, and had urged the necessity of keeping the supply of new gold equal to the monetary demand, which, according to world production and trade figures, increases on the average about 3 per cent per annum. In 1927, Sir John Aird, the President of The Canadian Bank of Commerce, stated that the United States could spare a billion dollars of the supply it then held, 4 ½ billion dollars. About a year and a half ago the Professor of Banking and Currency in the University of London, Mr. T. E. Gregory, said, "If the world finds it impossible to modify its habits so far as to make an organized effort to economize gold seem less Utopian, it must be prepared to pay for its bad habits, in this and other respects, by a possible loss of material welfare." These clear-cut statements were not heeded, perhaps for one reason because most countries were in the flush of prosperity, and making such great demands upon the mining fraternity for industrial materials as to distract attention, at least to some degree, from gold mining. Now the world knows it faces serious problems, first, of making? fully effective its present monetary reserves, which, although badly distributed, are as a whole ample for the needs of the present, and secondly, of preventing a shortage in the supply of new gold, one that may come within the next few years if the present sources of supply are not enlarged, and if there is no marked change in the technique of gold production.

Jan 1, 1931

By Osvaldo A. Bascur

Industrial complexes rely on measurements of flow rates, qualities, and concentrations for monitoring and optimizing their operation. Corporations use the data from the various sensors and measurements to make business decisions, which affect the profitability of the operation. However, gross errors, due to a variety of reasons like faulty sensors, bad instrument calibration, or incorrect process models may corrupt the actionable information supplied to operations, quality managers, and maintenance personnel. The solution is to use the sophisticated new tools to model the process, sift through the available data to locate the gross errors, and use statistical data reconciliation to validate the sensors and instruments. In this way the data are unified to give the most accurate plant information for use by the monitoring and decision making processes. Most mining and metallurgical plants use predictive maintenance policies based on statistical analysis and special techniques, like vibration analysis, and oil and lube analysis for critical equipment. Process control strategies are installed in several metallurgical sites. All of these depend on reliable and accurate data. The data unification methods validate the individual measurements by using the concept of balances and statistical techniques where each instrument is no longer independent of the other measurements in the facility. This paper refers to the data unification and analysis methods required for profitable plant operations. Continuous improvement and monitoring of the measurement system at the plant and analysis of the reconciled data provide the best information for the decision-making process. On-line gross error detection and elimination methods are required to ensure efficient evaluation of process performance and process optimization. An open discussion of the new methods for gross error detection and data unification will be presented.

May 1, 2001

By Joerg Hammerschmidt, Marcus Runkel, Steffen Haus

Given the limited number of new plant construction, focus is turning to the optimization of existing metallurgical roasting plants. To meet the goals of high process efficiency with limited capital expenditure, plant owners are looking for new strategies, including digitization and expert support. As a supplier for numerous roasting, gas cleaning and sulfuric acid plants, Outotec has intensified its effort in recent years to develop solutions to accommodate increasing customer need. This article presents a short review on how Outotec is applying advanced control tools for the fluidized bed industry. Focus will be given on how to transfer the existing technology (used in selected Zinc roasting plants for over a year now) to copper roasting. Outotec has developed the Pretium Roaster Optimizer, a system based on heat and mass-balanced simulation models. Direct experience with this technology will be shared and will highlight similarities to the Partial and Sulfate Copper roasting processes. Pretium detects equipment and plant bottlenecks and provides consistency in process development. The Pretium program combines 24/7 advanced online digitalization tools, along with expert personal support when required. INTRODUCTION Fluidized bed reactors have been used for commercial-scale zinc and copper roasting since the 1950s. While the principles of roasting remain unchanged, over time, the technology has advanced to improve process control of roasting plants. In the past, environmental and safety standards were the driving forces for improvement of equipment and plant design. Today, the emphasis is on plant efficiency and optimization. Another change has come in process control philosophy. While plant control and operation have traditionally been the responsibility of owner/operators, they have now shifted to include both integrated digital tools and specific know-how from engineering companies. This can be seen from the earliest design stages through commissioning and into production, as evidenced by zinc roasting plants in Mexico, Brazil and Turkey.

Jan 1, 2019

By Sylvain Castonguay, Sylvain Pilon

"Operator competency is an important factor in the safe and successful operation of today’s complex processes. Competent process unit operators deliver superior performance and results. In greenfield projects, operator competency is particularly critical, as the lack of specific operations experience must be offset with proven practical knowledge and skills to avoid mistakes that can cost millions in terms of start-up delays, production losses and equipment damage. It is, therefore, important to know precisely what competencies are required for a project or site, and what any gaps in operator competency need to be addressed and improved. The success of plant commissioning, start-up and sustainable operations is directly tied to operator competency. The significant investments required for new projects, the exploitation of more challenging ore bodies, and the increasing complexity of plant operations have placed renewed emphasis on the need for competent operators. Furthermore, many large capital projects are being developed in remote regions, often with ties to the delivery of social benefits for the local population in terms of jobs, training and other development opportunities. While automation and processing technologies have helped do more with less, indicators now point to a bottleneck in human performance limiting operational results.Automation industry development in managing abnormal situations, including solutions for simulation and operator training, has produced applications to provide customized and flexible training methods. This paper will discuss tools to automate the operator competency process in order to guide trainers to effectively teach, measure, control, provide feedback, and monitor operator skills. Today’s competency management solutions can be effectively applied throughout the course of an operator’s professional life, as a guide to hiring new operators, for developing competencies to support operations, and also to develop and refine best practices and share lessons learned."

Jan 1, 2016

By G. D. Hibbard

New regions of material property space can be accessed by combining microstructural design at the nm-scale with architectural design at the µm- or mm-scale. In the first case, large strength increases associated with grain size reduction to below 50 nm have driven extensive research efforts into the development of nanocrystalline materials [e.g. 1-3]. For many potential structural applications, however, the density of a nanocrystalline material is just as important as its strength. In fact, reducing the density is more important than increasing the strength for certain weight specific materials performance indices, and it is especially critical for applying structural nanomaterials in the aerospace and automotive sectors. We have developed a new type of structural nanomaterial wherein the effective density of the parent metal is reduced by more than an order of magnitude by incorporating an internal periodic cellular architecture of open space. In one example a low density cellular nanocrystalline material was created by electroforming nanocrystalline Ni around a rapid-prototyped acrylic photopolymer microtruss, Figure 1 [4]. Microtruss materials have periodic cellular architectures that are specifically designed to undergo stretching-dominated deformation as opposed to the bending-dominated deformation in conventional open cell metal foams [5,6]. This new cellular nanocrystalline hybrid material combined the structural efficiency of microtruss architectures with the ultra-high strength that can be achieved by grain size reduction to the nm-scale. Although it played a critical role as a cathode support during the initial stages of nanocrystalline electrodeposition, the polymer core did not contribute significantly to the inelastic buckling resistance of the composite metal/polymer struts and it may therefore be desirable to remove it post deposition by means of chemical dissolution or thermal decomposition [4]. Nanocrystalline electrodeposition can also be used to reinforce conventional cellular metals (Figure 2), creating new types of cellular composites such as metal/metal microtruss hybrids [7-10] and metal/metal foam hybrids [11,12]. For example, nanocrystalline Ni-Fe alloy sleeve thicknesses of up to 400 µm were used to reinforce an aluminum alloy microtruss that had been fabricated using a stretch-bend approach; the nanocrystalline sleeves had the effect of increasing the microtruss strength by up to a factor of twelve and the specific strength by a factor of three [8]. Alternatively, much thinner sleeves can be electroplated to produce structural coatings. In one example, a nanocrystalline Ni coating was designed to provide both corrosion protection and inelastic buckling resistance [10]. Because the ultra-high strength material was optimally located at the furthest distance from the neutral bending axis, only a thin coating of 50 µm was needed to double the inelastic buckling resistance of the 1.13 mm x 0.63 mm cross-section plain carbon steel struts [10]. Overall, the mechanical performance increase that can be obtained through electrodeposition depends on a complex interaction between the starting cellular architecture and the nanocrystalline sleeves.

Jan 1, 2010

By F. Rojas, M. Sanchez, J. Palacios, O. Pavez

Copper sulfide is the main mining resources in Chile, and most of this metal is obtained via pyrometallurgical extraction in seven copper smelter plants, which extends from the northern Atacama desert to the central part of the country. In 2002, 1,522,000 metric tons of fine copper were produced, with a notorious environmental impact due to the large amount of slag generated, including transportation and disposing problems. Therefore, there is a great interest in finding alternative uses in order to give additional value to the slag. This is a total project development concept, which consider residues as new resources where new components could be obtained, improving sustainability in mining activities and also ensuring clean production processes. Thus, the present work shows a review of copper slag characterization as well as several ways of utilization, including compact material for road and railway installation, part of admixtures in concrete.

Jan 1, 2004

By Ron Doucet

Industry today is now more than ever dependent on its assets and on the standard of maintenance. Changes in technology, environmental regulations, a continually improving focus on safety and global competitiveness has made maintenance a key activity in sustaining safe, financially viable and environmentally integral operations. Maintenance used to be looked upon as a cost centre with a sole focus of fixing equipment to attain high availability. Maintenance today affects all aspects of the business: safety, environmental integrity, energy efficiency, productivity, costs, and product quality. These new demands on the function of maintenance requires us to think vastly differently about what maintenance is all about, even to the point of contradicting old beliefs. In the following paragraphs we will examine some of the changed thinking that has evolved over the last 50 years. These new concepts will lay the foundation for the implementation of 21st century best practice maintenance.

May 1, 2003

By J E. McMynn

The development of the Granduc mine presents a number of problems which are peculiar to its location and surrounding terrain. Because the development tunnels portal onto an area which is covered by an extensive glacier, and the mountain-side is subjected to dangerous snow slides, it was decided to construct an underground powerhouse to supply the necessary electric power and compressed air. This paper deals with the special problems inherent in the design and -construction of an underground plant. It involves the installation of diesel-electric generating equipment having an aggregate capacity of 1,050 kw.,and of air compressors with a total capacity of 2,400 cfm. Items dis-cussed include the selection of equipment to meet site conditions, the ventilation and cooling of the underground room, and the protection of personnel and equipment from explosions and fire. A short discussion on the automatic supervisory and alarm installation is also included. THE Granduc mine is located 135 miles north of Prince Rupert and 25 miles north of Stew-art. This seems quite accessible, mileage-wise, but, due to mountains,

Jan 1, 1963

By Michael Moser, Brighty Dutta, David Dreisinger

"Molybdenum is widely used in the industries as an alloying element in the manufacture of steels and super alloys. The widespread use of the element encourages a growing need to develop extraction processes for recovery from both primary and secondary sources. The Solvay Group has developed a solvent extraction reagent named CYANEX®600 for the recovery of molybdenum from acidic solutions originating from both low grade (e.g. copper solvent extraction raffinates, smelter dusts and slags) and high grade (molybdenite) molybdenum sources. CYANEX®600 is a purified form of CYANEX®272 with the active component bis(2,4,4- trimethylpentyl)phosphinic acid. The extraction behavior of CYANEX®600 towards molybdenum in sulphuric acid medium was evaluated. The uptake of molybdenum increased with the increase in concentration of CYANEX®600. The approximate stoichiometry of the extracted complex was: Mo: CYANEX®600 = 1:2. Efficient back-extraction could be achieved with 0.1 M disodium EDTA and 0.1 M (NH4)2CO3, thus providing the option of recyclability of the extractant. The detailed back-extraction studies are currently under progress to find out the possible option for complete transfer of Mo(VI) to the aqueous phase so that high purity Mo salts could be precipitated from the molybdate solutions.INTRODUCTION Molybdenum (Mo) is one of the world’s valuable metals and is highly sought after by researchers due to its versatile mechanical, thermal, chemical properties. Swedish scientist Carl Wilhelm Scheele demonstrated molybdenite to be a mineral sulfide in 1778. Peter Hjelm successfully isolated dark metal powder from the mineral sulphide and named it as ‘Molybdenum’ in 1782 (Gupta, 1992). Molybdenum is a refractory metal of silver gray appearance and is an important alloying element used in the manufacture of steels and super alloys. Molybdenum compounds are widely used in formulation of catalysts (Gupta, 1992). Molybdenum occurs in nature only in chemical combination with other elements. Several molybdenum bearing minerals have been identified, but the only one of commercial significance is molybdenite (MoS2). As molybdenum is a strategic metal for the industrial sector, its widespread use acts as a factor for depletion of the natural resources. Hence, there is growing need to develop extraction procedures for its recovery from both primary and secondary sources. United States, China, Chile, Canada, Peru, and Mexico are listed as the main producers by the U.S. Geological Survey, 2016 (U.S. Geological Survey, Mineral Commodity Summaries, January 2016)."

Jan 1, 2017

By M. A. Hardie

"CASES and mixtures of them are so common and so much a part of everyday existence that they become so taken for granted that their individual characteristics and idiosyncrasies rarely become of curiosity to others than those involved in tl1eir production, processing, treatment, transportation, and for utilization. The use of the most common and universal mixture of gases -air -is begun at birth by ail living creatures and their discontinuation of its use terminates existence. Modern man rides on air in his tires, rides through it for high-speed transportation, and uses it for his comfort in the heating and air conditioning of his domicile. It is neither the aim nor the in-tent, in the next few moments, to provide a panacea for even a portion of the problems inherent in the gas industry nor to delve deeply into any particular facet of its diversities. The purpose is primarily to touch upon some of the peculiarities and generally to consider approaches to employ in the pursuit of solutions."

Jan 1, 1959

By D. V. Krefting, D. R. Bennett

"The Cyprus Anvil Mining Corporation established a lead-zinc mine and concentrating plant at Faro in Yukon Territory in 1969. Following some 12 years of continuous operation from a single pit adjacent to the concentrator, the company decided to expand operations into two additional areas on the Vangorda Plateau. The two new deposits, known as Grum and Vangorda, are located some 15 kilometres from the existing concentrator.Confirmation of mining feasibility was followed by determination of the most practical and economical method of transporting the raw ore from the new mine sites to the existing concentrator. This analysis was carried out in two phases. The first phase reviewed the feasibility of alternative transportation systems on an 'order-of-magnitude' cost basis. This work identified systems worthy of more detailed examination. The second phase examined the preferred alternatives in greater detail.Initially, operating principles and parameters were established and catalogued. Then, based on these criteria, complete systems were developed utilizing alternative modes of transportation . In the overview analysis, some transportation modes were judged impractical and discarded, 'order-o f-magnitude' costs were developed for other systems and the most costly were eliminated . In the detailed study, the favourable systems were examined in depth which required development of accurate capital and operating costs, consideration of environ- mental impacts and an assessment of intangibles associated with the operation of a new development."

Jan 1, 1984

By Shuo Zhang, Wenying Liu

"In dump leaching, the efficiency of metal extraction from ores is strongly influenced by the mechanisms of fluid flow. Particle size distribution acts as a fundamental parameter in the determination of fluid flow properties in packed ore beds. In this study, we investigated the particle size distribution in dump leaching by using image analysis technique. The results showed that the particles in the dump varied from smaller than 2 cm to larger than 200 cm in diameter. P80 was calculated to be 200 cm, which was significantly higher than the historical data used by the operation. P25, P50 and P80 were found to increase non-linearly with increasing depth towards the toe of the dump, suggesting the segregation of fine and coarse particles. The image analysis results were verified by applying the rock fragmentation models. The model with the Swebrec function was found to be in better agreement with the image analysis results. Future research will investigate the effect of particle size distribution on the behaviour of fluid flow.INTRODUCTION Fluid flow plays an essential role in the extraction of valuable metals using heap/dump leaching (Amos et al., 2009). The rates of the chemical leaching reactions and microbial activities determine metal concentrations in the leachates and therefore the efficiency of the metal extraction. The reaction rates are influenced by two fundamental processes: transport phenomenon and reaction kinetics (Bouffard & Dixon, 2001). The transport phenomenon refers to the percolation of fluids through channels and pores in a packed ore bed, which carries lixiviants and reaction products to/from ore surfaces by convection and diffusion. The percolation rate of the leaching solution is determined by the hydraulic conductivity of the packed ore bed, which is a function of the permeability and the degree of saturation (Guzman et al., 2008). Permeability, an intrinsic property of a packed ore bed, is strongly influenced by the particle size distribution of the ore grains (Bouffard & Dixon, 2001). Hence, the objective of this study was to investigate the particle size distribution in dump leaching."

Jan 1, 2017

By G. Riveros

A new, continuous fire refining process for copper has been developed and tested at the 5 tph pilot scale. During oxidation, the blister copper flows through a packed bed of crushed refractory bricks counter-current to a hot oxygen containing gas. The resulting desulphurized copper flows then directly into a packed bed of charcoal for deoxidation. By controlling the air to natural gas ratio, both temperature and reducing conditions can be controlled. Based on extensive laboratory scale measurements of the rate of copper oxidation and reduction, the process concept was developed aided by process modeling and simulation. The industrial-pilot scale installation built at the ENAMI Paipote smelter in Chile, consists of two cylindrical, compact reactors, operating in line, with a designed capacity of 5 t/h of blister copper. The results of the industrial-pilot tests confirmed the feasibility of the new process. The blister copper processing capacity was increased to 10 t/h with satisfactory sulphur removal. The degree of oxidation as well the copper temperature was controlled with relative ease. The specially designed siphon block allowed for smooth tapping of the oxidized copper and separation of refining slag. The reduction of oxidized copper in the packed bed of charcoal appeared to be very effective while control of the degree of reduction according to the height of the bed ensured control of the oxygen content in the refined copper at the required level.

Jan 1, 2007

By N. Djilali

Many of the transport phenomena encountered in proton exchange membrane fuel cells occur intrinsically at the microscale level. Physically representative models that fully account for the salient physico-chemical and transport processes in PEM fuel cells are necessary to achieve truly predictive models that can be used with confidence to: (i) gain a better understanding of in-situ processes and couplings, (ii) explore new concepts, and (iii) support design and optimization. The development of more general, rationally based macroscale models requires use of knowledge on the microscale level to provide guidance, and to determine the required parameters and coefficients (model "constants"). In this paper we present a new membrane transport model, the binary friction membrane model (BFM2), recently developed to account for coupled protonic and water transport in polymer membranes. This general model is based on rational and physical consideration, removes several of the limitations of the empirical models used to date, and is formulated for all purfluoro-sulfonic acid membranes. The use of the BFM2 in a fuel cell model is illustrated highlighting significant performance predictions compared to existing empirical model. The second part of the paper addresses the fundamentals of two-phase transport in hydrophobic gad diffusion media. Computational and experimental visualizations resolving the microscale dynamics of water transport between the fibres of a GDL are presented, revealing transport mechanisms that are, contrary to assumptions used to date, dominated by fingering and channeling.

Jan 1, 2005

By Andrew Thrift

Overview ? Problem ? Research question ? Literature review ? Methodology ? Results ? Discussion and recommendations ? New developments Problem ? Increasingly higher expectations ? Inadequate consultation leads to conflict rather than collaboration ? Consultation practice is often weak on decision-making ? Influence of consultation on planning is Unclear Research question ? Are Structured Decision Processes (based on decision analysis) an effective methodology for involving stakeholders in consultative decisionmaking in the mining industry?

May 1, 2006