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By Oliver Hall

WITH the friendly consent both of the Institution of Mining and Metallurgy, for whom this paper was written, and of the author, we had the pleasure of publishing Mr. Oliver Hall's paper on Mining at Noranda in our issue of last March and of having Mr. Hall present it at the Montreal Meeting. In the following pages we now report the discussion elicited by the paper at a meeting of the Institution in London on March 18th. The report is taken from the April, 1937, issue of the Bulletin of the Institution, to whom we again tender our thanks. THE PRESIDENT (MR. ROBERT ANNAN) said that this paper was, by arrangement with the Institution and the author, also being published by the Canadian Institute of Mining and Metallurgy for approximately simultaneous discussion. He was sorry that Mr. Oliver Hall could not be present to introduce it in person, for he was sure that the author would have had many more details to give about this most interesting mine. The paper contained a very useful account of mining operations, and personally he had been pleased to see the tri-dimensional projections of the orebody in Figs. 3 and S. It was a good illustration o the value of that method in presenting the form of an orebody such as this. While he had no desire to go into technical details, he wished to call attention to a remark in Mr. Hall's introduction, in dealing with the history of the mine and the principles on which it was run. The author had given an account of the early difficulties in solving geological problems, and later of the economic difficulties of seeing this mine through a period of intense depression in metal prices. He stated that it was clear that, to maintain income, tonnage must be increased, and, to maintain profits, costs must be decreased. It would be observed that there was no question of increasing the grade of ore. Then the author went on to say: 'Having set the house in order in the years of adversity, the higher price for gold is being used to mine to still lower limits and lengthen the life of the enterprise and the welfare of those dependent on it'.

Jan 1, 1937

By Wei Huang, Anh V. Nguyen

"Potash flotation is an industrially proven success of flotation of soluble salts, but its collector adsorption mechanism remains elusive. In this paper, specific ion effects in NaCl-KCl flotation with carboxylate collectors were investigated. Flotation recovery and contact angle were determined as a function of brine composition of NaCl and KCl. The experimental results have shown that wettability of KCl and flotation of the soluble salts with laurate collectors were dependent on brine ion composition. Specifically, adding Na+ to brines decreased hydrophobicity of KCl crystals and their flotation recovery. Both KCl and NaCl could be floated with laurate collectors. However, flotation of NaCl was greatly enhanced by adding K+ to brine whereas flotation of KCl was significantly suppressed by the presence of Na ions. The decrease in KCl recovery upon adding Na+ is attributed to the counter-ion binding in the pulp. The flotation recovery enhancement of NaCl in the presence of K+ is explained by two effects: 1) increasing K+ concentration leads to a better dispersion of collector colloids in the pulp and 2) K+ enhances the collector adsorption at NaCl crystal surfaces. The water affinity matching rule can explain the specific ion binding behaviors and supported by the SFG spectroscopic results.INTRODUCTIONPotassium is an important fertilizer. Its primary source comes from potash ores, which are a mixture of sylvite (KCl), halite (NaCl) and many other complex double salts such as carnallite (KCl·MgCl·6H2O), alkali nitrates such as KNO3 and NaNO3, and sulfates-langbeinite (2MgSO4·K2SO4) with water-insoluble minerals such as clay and carbonate minerals. Previously, these salts were recovered with a lengthy hot leaching method, with further crystallization of potassium salts from saturated saline solutions. Selective flotation has been preferred since 1940s. Various collector adsorption mechanisms have been proposed soon after the industrial introduction of potash flotation. These include the formation of the insoluble compound model (Halbich, 1933; Singewald, 1961), an ion exchange model (Fuerstenau and Fuerstenau, 1956), a heat of solution model (Rogers, 1957), the surface hydration model (Schubert, 1988), the surface charge model (Roman, 1966; Miller et al., 1992), the interfacial water structure model (Hancer and Miller, 2000) and the colloid adsorption model (Leja, 1983; Burdukova and Laskowski, 2009). Most of the early exercises attempting to propose a unified rule on collector adsorption mechanisms can be seen as heroic endeavors due to the consideration of a vast number of salts in the pulp including alkali halides, nitrates, and sulfates, even the practically insoluble heavy earth metals. Additionally, several types of surfactants with different polarization features and alkyl chain length have been employed. As for the recent models, due probably to the preferential application of long chain amines as collectors in industrial potash flotation, most researchers are only devoted to collectors with low polarization features like amines and sulfonates (Hancer and Miller, 2000; Du et al., 2014). Collector adsorption mechanisms are therefore proposed based largely on a neglect of carboxylates as collectors. However, carboxylates remain an important collector type in soluble salt flotation systems where both salt minerals can be floated using anionic collectors and cationic collectors. Fatty acid type collectors are still one of the widely used collectors for soluble salt flotation and also one of the first to be applied on an industrial scale for the separation of potash ore (Hernáinz et al., 2003; Titkov, 2004). Here we examine some recent models that are relevant to our study to reveal a long neglected specific ion binding effects in potash flotation."

Jan 1, 2016

By E. Busse, J. E. Burgener, J. G. Eacott, M. C. Robinson, P. E. Burgener

"This paper presents a preliminary assessment of the technical and economic feasibility of a caustic leach - electrowinning process for the recovery of zinc and lead from electric arc furnace baghouse dust at a mini-steelplant. Recent studies and literature are referenced briefly as they pertain to the formation and characterization of dust, toxicity considerations and alternative dust treatment and disposal options.Laboratory testwork results, published data, pilot plant experience and anticipated influences resulting from recycling residues are used for the purpose of developing a conceptual design for a caustic leach - electrowinning plant to treat 15,000 tonnes/year of dust at a one million tonnes /year capacity steelplant in Canada.Target economic studies, comprising preliminary estimates of capital and operating costs, revenues and rate of return are presented. Economic and commercial considerations concerning the relative merits of dust treatment at a centralized facility compared with an on-site plant are discussed.IntroductionThe treatment or disposal of mini-steelplant electric arc furnace (EAF) baghouse dust has been given increasing attention in recent years for two principal reasons. Firstly, the dust is now classed as a hazardous waste material under V.S. EPA regulations which prohibit its disposal in dumps other than controlled landfill sites. Secondly, the dust contains certain metal values, notably zinc and lead, which may be economically recoverable, depending on the costs associated with disposal resulting from enforcement of the EPA regulations. Other metallurgical dusts and waste materials, from both ferrous and non-ferrous operations, may require the same considerations as EAF baghouse dust.Several studies have been carried out to examine various aspects of dust treatment but few commercial plants are in operation. Technology employed uses pyrometallurgical techniques. Commercial-scale hydrometallurgical plants are not known to exist although small-scale plants are frequently more economically attractive than their pyrometallurgical counterparts which generally require economies of scale to be viable.The concentration of mini-steelplants in northeast V.S.A. and southeast Canada merits study to determine whether or not dust treatment for metals recovery is a commercially feasible alternative to disposal.This paper examines the technical and economic feasibility of a caustic leach - electrowinning process for the recovery of zinc and lead from EAF baghouse dust at an on-site ministeel plant processing carbon steel scrap and discusses economic and commercial considerations pertaining to dust treatment at a larger, centralized facility."

Jan 1, 1984

By Wei Wei

Mining induced ground movement and/or stress redistribution could cause ground instability issues. This is particularly true when the extraction of large stopes is done with one or two large production blasts. Often enough, it is the nearby mine development like haulage drifts and cross cuts that are influenced the most by production blasts. Proper and timely mitigation of ground control issues due to stress redistribution is required. This is usually done by drift rehabilitation involving the installation of secondary support system in the affected areas of the mine development which include; slashing, wire mesh, and in some cases the use of shotcrete liners. It is imperative that such rehabilitation be implemented to the mine infrastructure in a timely manner in order to avoid aggravated ground control problems and production delays. If the real time performance of the support system is captured, it would be possible to determine the timing for rehabilitation job. Birchtree Mine in Thompson, at the Vale Manitoba Operation, has begun mining the 84 Deep Orebody. One of the identified risks is the stability of the crusher room under mining induced stress redistribution. It is proposed to use the U-Cell technology to monitor the primary support system performance (rebar bolts and extension bolts) and monitor the real time performances of the bolt axial loads. The U-Cell technology is a 7-inch long, coupler load cell that is screwed onto the threaded portion of a rock bolt prior to installation. Rehabilitation in the vicinity of the crusher area where U-Cells are installed is recommended when the bolts have reached 70% of their yielding capacity. Catastrophic ground failure can be avoided by adding secondary support in a timely fashion. This paper presents a case study at Birchtree Mine in Thompson Manitoba, where the performance of primary ground support system is monitored and recorded during production.

Jun 1, 2012

By Guocheng Pan

"Although many factors play roles in the estimation of recoverable reserves, smoothing effect and conditional bias are considered major geostatistical issues in the estimation. This paper introduces measures for smoothing effect and conditional bias, and provides insights into their relation to the estimation of recoverable reserves. Both smoothing effect and conditional bias are intrinsic to the information effect and kriging estimators. For a given level of drilling information, however, it is possible to identify the optimal search radius that minimizes conditional bias. Furthermore, it is also feasible to define variance correction factor for reduction of the smoothing effect from exploration block models. Both of these components are key to the accurate estimation of recoverable reserves. IntroductionThe accurate estimation of recoverable reserves is critical to decision making in different phases of feasibility study and mine planning. Much attention for improving the methodology of estimation has been focussed on the effect of the change-of-support (Parker, 1980; Dagdelen, 1996). For example, it is essential to make a volume- variance correction to the estimate of multiple indicator kriging (Hoerger, 1992). When the size of block, b, in the geostatistical model differs from that of selective mining unit (SMU), v, a volume-variance correction is warranted for the prediction of recoverable reserves.Most mining plans and decisions are made prior to the availability of high density blast-hole samples. In most mining operations, the true SMU grade Zv is unknown at the time of selection. Instead, the selection is based on the estimate Z v**derived from high density blast-hole samples within the deposit G. Nevertheless, the estimate Z v * of recoverable reserves in the stage of mine planning is derived from exploration data. At the end, the production result must be reconciled to the estimate Z v * . In other words, the selection is based on Z v** from blast-hole samples, while the final production figures are reconciled to Z v * from exploration drilling. For a given preselected cutoff grade z0, the actual mining panels will consist of the units having the estimated grade Z v** =z0 rather than the true grade Zv =z0. The difference between Z v** and Zv is usually of less concern."

Jan 1, 1998

"THE PACIFIC CONTINENTAL MARGIN OF CANADA is de-fined, for the purposes of this paper, as the area sea-ward from the present mainland coast of British Columbia to the foot of the continental slope. It thus coincides with A. Sutherland Brown's Insular Tectonic Belt. The region is limited to the north and south by the political boundary with the U.S.A., the location of which is still in dispute.The region can be subdivided into: (1) an interior trough comprising the Queen Char-lotte, Comox and Nanaimo basins; (2) a medial uplift comprising Vancouver Island and the Queen Charlotte Islands; and (3) a marginal shelf which is extremely narrow (Jess than 5 km) west of the Queen Charlotte Islands, widens to 160 km in Queen Charlotte Sound and is about 35 km wide west of Vancouver Island, where it is underlain by the Tofino sedimentary basin, with its• extension, the Juan de Fuca Basin, at the southern end.The medial uplift consists of a highly disturbed anticlinorium of mainly Mesozoic rocks, with a core of Palaeozoic. The rocks include thick sequences of eugeosynclinal volcanics and sediments. There is strati-graphical evidence of repeated interruption in sedi-mentation. By late Jurassic, the main eugeosynclinal phase was over and a successor basin was initiated in the interior' trough. This became filled, during Cre-taceous and Tertiary time, with sediments ranging in environment from bathyal turbidites to terrestrial conglomerates and coals. West of the medial uplift, another successor basin developed in early Tertiary times and became filled with mainly deep-water marine sediments. A third effusive sequence marks the base of the Tertiary on Graham Island and over most of the Hecate Strait region and Tofino Basin."

Jan 1, 1970

By P. Morissette

Passive monitoring of support performance during rockbursts was conducted at three deep underground mines. A comprehensive database was constructed of 172 seismic events and the associated damage to support systems at 266 mine locations from January 2000 to September 2012. The majority of pertinent information was obtained through seismic system records and on-site field assessments. This work assesses the quality of collected information and evaluates the dynamic-load demand on support systems in seismically active mines.

Aug 1, 2013

By B. Nanthakumar

The impact of stockpile oxidation on chalcopyrite was studied through collectorless and collector-induced flotation conditions. In both cases, the Cu grade-recovery performance of stockpiled ore showed relatively poor concentrate grades with respect to that of a fresh sample. However, the oxidation had a minor effect on chalcopyrite recovery itself. The poor concentrate grades resulted from dilution effect primarily by excessive flotation of pyrrhotite. Size-by-size analyses indicated that for the collectorless flotation, the recoveries in the coarse and fine particle-size regions, were higher for fresh ore than for stockpile sample. A greater impact was seen in the coarse size regions for both types of sample, compared to the collector-induced case. The Cu recoveries showed a remarkable increase in the coarse size range for both samples when a collector was used. However, the case for stockpile sample was a marginally higher compared to the fresh sample. This difference has been offset by an opposite trend that was observed between these two samples in the fine size region. It is concluded that in contrast to the case with nickel-bearing sulphides, stockpiling conditions do not show a significant adverse effect on behaviour of chalcopyrite due to its strong floatability, regardless of oxidation.

Jan 1, 2007

By J. R. Bradfield

THOSE familiar with the development of the Horne mine can readily appreciate that more and more accommodation bas been required for underground labour as the mine has grown. A permanent fire-proof change house, 30ft. by 75 ft., was built in 1927 to accommodate 194 men. This was extended ro 30 ft. by 92 ft. in 1928 to accommodate 296 men, and to 30ft. by 110 ft. in 1930 to accommodate 398 men. By 1933 this building was again overcrowded and tentative plans for a new change house were drawn up. However, it was realized that future operations would be centred around No. 4 shaft and a proposed new shaft, and the decision as to the location of the new change house had to be deferred until the area which seemed most suitable for the new shaft had been thoroughly explored underground. In the spring of 1934, the basic idea was accepted of drying the wet clothes in open mesh compartments or baskets located between rows of standard steel street-clothes lockers and built so that the covers or lids would serve as seats or benches.

Jan 1, 1935

By W. E. Bawden

Situation: Creighton mine, situated about twelve miles west of Sudbury, Ont., on the Algoma Eastern railway, is owned and operated by the International Nickel Company, incorporated in the United States under the laws of New Jersey. The ore is smelted at Copper Cliff, near Sudbury, and the matte is refined at Port Colborne, Ont., on lake Erie. Geology: The ore occurs in what is known locally as 'the basin' near Sudbury (Figure 1) the central part of which is composed of the Animikie series of sediments, consisting of sandstones, slates, tuffs and conglomerates. The basin is about 16 miles wide and 36 miles long. The Animikie sediments are surrounded by a sill of norite - a gabbro rock in which the pyroxenes are orthorombic. On the outer contact of this norite the sulphide deposits occur and the Creighton deposit, similar to others, lies on the southern edge of this basin. There are two orebodies at the Creighton, the upper one called the footwall orebôdy, and the lower one the hanging-wall orebody. The hanging-wall of both of these bodies is norite, and the footwall of the upper one is granite. The two are separated by an intrusion of greenstone which forms the footwall of the lower body. The ? maximum length of the deposit is 1000 feet and the maximum width is approximately 300 feet. It narrows at the ends and is somewhat lenticular in shape. The dip is about 45 o to the west, and the strike is north and south. The orè is a mixture of three minerals - pyrrhotite, chalcopyrite and pentlandite. The pentlandite, which is distinguished by its cleavage from the other two, is apparent to the naked eye only in the lower orebody and is more finely disseminated in the upper one. The lower body contains a little higher percentage of nickel.

Jan 1, 1925

By M. Schwarze

SMS Meer GmbH with its COPPER PLANTS DIVISION produces a full line of systems and machines for the processing of copper. The product range includes: shaft melting furnaces, anode casting lines, horizontal and vertical casting lines, casting and rolling lines for copper wire rod and strip, cold pilger mills, planetary rolling mills as well as tube drawing equipment. The new designed shaft furnaces are the most economic way of copper melting. The CONTILANOD® system with hydraulic shear represents a breakthrough into higher production capacities and improved geometrical accuracy of anodes. The new generation of CONTIROD® lines with individual drives of rolling stands guarantee cost effective production of highest rod quality. A new horizontal continuous casting technology for the production of tube shells as feed stock for the copper tube manufacturing process ? directube® was developed and introduced into production. A first line for continuous vertical strip casting - called VERTICAST® - for higher production rates and improval quality of cold-rollable strips is in the final stage of commissioning. These innovative technologies increase product quality, reduce process costs and help for a wide use of copper in all sectors of life.

Jan 1, 2007

By Dougal R. McCreath, Dwayne D. Tannant, Peter K. Kaiser

The Geomechanics Research Centre at Laurentian University in Sudbury, Canada, has undertaken a five-year research program into the design of support appropriate for control-ling damage caused by rockbursts. Rockburst damage mechanisms in Canadian hardrock mines are reviewed and a support design approach is presented. Each element in a sup-port system performs a reinforcing, holding, or retaining function. The desirable load-displacement characteristics for elements in burst-resistant support systems are described, and recommended support systems are presented for a spectrum of rockburst conditions ranging from minor to severe. A support system can be designed to (a) prevent the triggering of aground fall or a rockburst; (b) deform to accommodate the large imposed deformations arising from a rockburst; or (c) absorb the kinetic energy contained in ejected blocks of rock.

Jan 1, 1996

By Trent Hamilton

Cameco ? McArthur River Operation is a high-grade uranium mine in northern Saskatchewan. Average grades mined are nearly 20%, more than 20 times higher than other operating uranium mines in the world. The significant risks involved with mining this grade has been effectively mitigated using innovative and unique controls, implemented from development and production mining through to ore processing. The types and sources of radiation are presented and protection measures are discussed. McArthur River?s strong radiation culture is evidenced by continually low radiation exposures while transitioning to new mining zones.

Aug 1, 2010

By H. J. Rowley

THERE are many varieties of limestone, but for the general purposes of the pulp and paper industry, two classifications are sufficient: (1) High-calcium stone, which should be quite free from impurities and contain not less then 90 per cent calcium carbonate. (2) High-magnesium stone, containing not less than 25 per cent of magnesium carbonate. Before proceeding with detail on the use of limestone and lime in the industry, a few words regarding the pulp products made in Canada are desirable. By far the largest tonnage is made by grinding spruce and balsam logs on rotating sandstones or on artificial abrasive stones of the Norton or Carborundum types. This mechanical or groundwood pulp finds its largest use in the production of newsprint paper, of which it comprises about 80 per cent of the total fibrous substance employed-the remaining 20 per cent being unbleached sulphite pulp. No limestone or lime is directly employed in making groundwood pulp, as contrasted with the chemically prepared pulps, all of which require one or the other form of the base for their processing. Sulphite pulps comprise the next largest tonnage group. They are produced by boiling, under pressure and at elevated temperatures, spruce and balsam wood in chip form in solutions of bisulphites and sulphurous acid. The usual bisulphites employed are those of calcium and magnesium. Sodium, potassium, and ammonium bisulphites give progressively better pulps, but to date, in the absence of efficient recovery methods, cost has precluded their use.

Jan 1, 1939

By Burrows. A.

Temperature profiles in the lead smelter sinter bed at Xstrata Zinc Mount Isa sinter plant have been measured using a wireless temperature probe. Corresponding sinter samples have been collected for characterization. The sinter peak bed temperatures were found to be in the range of 1000 - 1200 °C. Microstructures and softening temperatures of these sinters have been characterised. Strong correlations have been observed between peak bed temperature and peak hood temperature, and between mean sinter softening temperature and peak bed temperature. It was found that higher peak bed temperature results in higher sinter softening temperature. For the feed material used in the trials, to obtain sinters with mean softening temperatures above 1050 °C, peak bed temperatures above 1130 °C are required. There appears to be a direct correlation between granule size distribution in the feed and peak bed temperature attained. High peak bed temperatures are observed in sinters with narrow granule size distribution.

Jan 1, 2008

By Charles Graham

It is the general belief that the coal deposits on Vancouver Island are extremely large, and easily available. Indeed, they are frequently described by prominent public men and by writers in the press as "illimitable" and "inexhaustible." It is well that the facts that have been established as a result of seventy years of surface prospecting, underground operations and extensive diamond-drilling in this coalfield should be disclosed. HISTORY The presence of coal on the coast of British Columbia was first made known by Dr. W. F. Tolmie in 183 5. This coal was brought to him by Indians from the north-east coast of Vancouver Island, probably from Suquash. In 1850 the existence of coal at Nanaimo was announced by Mr. ]. W. MacKay. Development was started in 1852, and coal was shipped before the close of 185 3. The first operations were carried on by the Hudson's Bay Company, who operated the mines until 1861, when they sold them to the Vancouver Coal Mining and Land Company. Practically all of the operations in the immediate vicinity of Nanaimo have been carried on by this Company and its successors. In 1869, Mr. Robert Dunsmuir discovered coal about five miles north-west of Nanaimo, at Wellington. The Welling-ton Colliery Company was organized, and began to produce coal from the Wellington mines in 1871, the coal being shipped from Departure bay. This colliery was a large producer for several years, but was finally closed in 1900.

Jan 1, 1924

By Gene O. Cowie

"Zinc, which once enjoyed an unchallenged position in the field of decorative applications, has lost a substantial share of its markets to other materials, particularly plastics. This turn of events has led the zinc industry to explore new market areas, particularly those applications where the engineering properties of zinc can be utilized. This paper gives an overview of the zinc industry's efforts to develop the data base and product development technology which have enabled zinc alloys to emerge as engineering materials. It also indicates those areas in which the research facilities of the zinc industry must be employed to ensure that zinc alloys keep pace with developments in competitive materials and processes.The Materials RevolutionThe development and utilization of new materials and manufacturing processes progressed for centuries by evolution. Recently it erupted into a revolution, which may become as significant as the industrial revolution. The materials revolution has impacted upon many industries, but none has been affected more traumatically than the North American automotive industry. The plight of that industry is of great importance to us because their problems have, to a great degree, become problems to the zinc industry.Much of the impetus behind the automotive trauma came from the battery of motor vehicle regulations promulgated by the United States government in the 1970s. These regulations required that the efficiency of passenger cars, in terms of miles per gallon, be approximately doubled in ten years. In view of the fact that major changes in the automotive world require three years of lead time to implement, the industry was left with only seven years to perform the task. The automotive industry was simultaneously required to make progress in other areas, such as reduced emissions, reduced cost of repairs and increased levels of occupant safety. These added demands not only diverted some of the available resources away from efficiency goals, they often ran in direct conflict. For example, when you are required to provide a front bumper which will absorb the energy of a 5-mile -per-hour barrier collision, you must add both hardware and structure to the vehicle. This adds weight, and increased weight reduces miles per gallon."

Jan 1, 1983

By E. L. Bruce

EUROPEAN Russia is mainly a great plain, the average elevation of which is only 600 feet above sea level and the maximum elevation less than 1,200 feet (Figure 1). The main divide between the Arctic ocean and the Black sea and Caspian sea is an indistinguishable topographic feature from which the Dneiper and Don rivers flow southward to the Black sea and the Volga river to the Caspian. The valleys of these rivers are but little below the general level (Figure 2). To the south, this great, rolling plain is broken by a low ridge of Precambrian gneisses and intrusive rocks. The Crimea is an upland from which the descent to the Black Sea coast is precipitous (Figure 3). The Ukrainian Soviet Socialist Republic occupies the southern part of the plain. It is the southwestern unit of the Union, bordered by Rumania and Poland on the west and by the Crimean Soviet Socialist Republic on the south.

Jan 1, 1938

By Michel Masse

1. A battery-powered wireless mesh network for dynamic diesel machinery tracking and operating status monitoring. 2. A real-time ventilation model and fan speed optimizer. 3. An OPC server for information interchange. 4. OPC linkage to existing control infrastructure. 5. A Human Machine Interface (HMI) providing data archiving, trending and reporting. 6. Live MS-Excel to interrogate the simulation, controls and optimizer. 7. The battery-powered network mesh also provides SCADA functionality to route optimized setpointsto the fans and automated regulators not linked to PLCs.

Feb 1, 2008

By Ruan Chi, Zhenyue Zhang, Zhengyan He

In order to understand what governs the leaching of exchangeable rare earth (RE) and impurities and enhance the RE leaching process, the effects of the concentration of ammonium sulfate, pH and leaching temperature on the migration of RE and aluminum (Al) during the leaching of weathered crust elution-deposited rare earth ore was studied. The elution curves for ammonium ion (NH4 +) were also studied to reduce the consumption of the leaching agent. It was found that a high concentration of leaching agent can enhance the leaching process of RE and Al, reduce the breakthrough volume of NH4 + and more rapidly obtain the equilibrium of NH4 +. However, excessive leaching agent can both increase the cost and the burden on the environment. There is almost no variation on the elution curves of RE and Al in the pH range of 4-8 and control of the pH of the leaching agent can be omitted. It is better for the leaching work to be done in summer since higher temperatures can enhance the RE leaching process and improve the use ratio of ammonium. Using 0.1 mol/L ammonium sulfate for leaching 250 g RE ore, 95.42% RE extraction can be obtained when the volume of leachate is 102.6 mL. At this moment, only 18.17% of NH4 + is used to exchange RE and 49.22% of NH4 + is left in the leachate that can be reused as leaching agent by replenishing ammonium sulfate. The results of our studies can provide theoretical guidance for high efficiency and low consumption exploitation of RE ores.

Jan 1, 2016