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By M. J. Dry, G. B. Harris

"This paper presents basic chemistry and operating conditions for the hydrolysis of ferric chloride into solid hematite and gaseous hydrogen chloride, and shows how this unit operation can be applied in chloride hydrometallurgy to regenerate strong hydrochloric acid and reject iron without also rejecting valuable metals such as nickel, copper and cobalt. Two examples are used to illustrate the hydrolysis technology and compare it to existing technology. The first is the regeneration of spent steel pickling acid, comparing hydrolysis to conventional pyrohydrolysis. The second example is the processing of a hypothetical low grade nickel laterite, comparing the novel chloride hydrolysis route to conventional sulphate HPAL technology.INTRODUCTION Whilst, in many respects, the control and removal of dissolved iron from chloride leach solutions can resemble the manner in which it is done in sulphate systems, chloride chemistry additionally offers the ability to achieve the same objectives in different ways (Harris, 2014). Conventionally, iron is oxidised to its ferric state (if necessary) and then precipitated with a base, usually magnesia where the feed is a laterite and lime where it is a sulphide, since calcium will precipitate sulphate formed during leaching. One method for controlling iron is to form FeOOH, either ß-FeOOH (akaganéite), a-FeOOH (goethite), or a mixture thereof (Fillipou and Choi, 2002). However, if akaganéite is formed, the precipitate will contain a significant chloride component (as high as 7% Cl), leading to chloride losses and difficulty in satisfactorily disposing of the residue. Washing chloride from akaganéite is almost impossible due to the propensity of the solids to undergo peptization. The conventional approach requires the addition of a base, but it is based to some extent on controlled supersaturation precipitation (Demopoulos, 2009), which produces a more uniform and crystalline material and is far more attractive than, for example, the turboaeration process proposed by Great Central Mines in their chloride copper process (Raudsepp & Beattie, 1986)."

Jan 1, 2016

By Deni Côte, Michel Dagbert, Marcel Vallée

"Greater reliability of mineral deposit and reserve estimates can be attained through better quality control of the data and information acquisition, and the estimation processes. This paper reviews the following key requirements:1. greater awareness of the significant figures of both data and estimates, and better understanding of the probabilistic aspects of the estimates, their confidence limits and margins of error;2. greater reliability of the information that supports the estimates, by more explicit and more rigorous methods and standards for data acquisition and for interpretations;3. more quantitative estimations of geological/mineral continuity, based on improved three dimensional sampling patterns and the use of geostatistics; and 4. better integration at the project engineering and mine production stages, of the mineral deposit characteristics and mining method constraints, for more efficient mineral recovery and mine quality control.RÉSUMÉUne plus grande fiabilité des estimations des gisements et des réserves minières requiert plus d'emphase sur le contrôle de la qualité de I ‘acquisition de l'information et du processus d'estimation. Les exigences suivantes sont revues:1. le respect du niveau d'exactitude des données et des estimes en n'utilisant que le nombre approprie de chiffres significatifs des observations et mesures, et en exprimant le niveau de confiance et la marge d'erreur des estimations;2. l'amélioration de fa fiabilité des données par des normes plus rigoureuses pour leur acquisition et leur vérification, et par des méthodes plus systématiques d'interprétation et de modélisation;3. l'estimation plus rigoureuse de la continuité des minéralisations dans les trois dimensions des gisements, par des patrons échantillonnages mieux adaptes awe paramètres géologiquement minéralogiques, et par l'utilisation des méthodes géostatistiques; et4. l'intégration plus poussée, particulièrement lors de la planification de l'exploitation minière, des caractéristiques des gisements avec les contraintes des méthodes d'exploitation, pour améliorer la récupération et le contrôle de la qualité en exploitation."

Jan 1, 1993

By E. M. De Souza, P. Lausch, D. O. DeGagné, J. F. Archibald

"The potential use of industrial and municipal waste glass as a partial pozzolanic replacement for Normal Portland cement in mine backfill has been investigated. Considerable quantities of glass are currently discarded into landfill sites at high cost to municipal and industrial users with no foreseeable environmental benefits being gained by such disposal. This research study was undertaken to assess the viability of using ground waste glass materials as partial binder replacement of Portland cement fractionswithin consolidated mine backfill materials. The program was implemented to review various factors that could influence successful incorporation of glass waste replacement of cement, these factors being the feasibility of glass waste procurement, determination of process economics and the physical and chemical suitability of ground waste glass materials to generate adequate backfill strength when replacing Normal Portland cement fractions. A series of laboratory assessment trials were established to evaluate backfill component characteristics and mixture strength properties for both standard Portland cement-consolidated and blended Portland cement/ground waste glass-consolidated backfill materials. Side-by-side review of the strength behaviour of various component backfill/cement mixtures was designed to permit comparative evaluation of the capabilities of ground waste glass and Portland cement products as backfill consolidating agents"

Jan 1, 1995

By J. Shen

Direct methanol fuel cells have been the subject of considerable research in the last decade. Performance levels realized in cells, stacks, and systems show that this technology is a promising power source for a wide range of portable applications. A direct methanol fuel cell (DMFC) operates directly on a methanol fuel stream typically supplied as a methanol/water vapour or as an aqueous methanol solution in liquid feed DMFCs. The fuel streams in DMFCs are usually recirculated in order to remove carbon dioxide and to re-use the diluent and any unreacted fuel in the depleted fuel stream exiting the DMFC. The concentration of methanol in the fuel circulation loop is an important operating parameter because it determines the electrical performance and efficiency of the direct methanol fuel cell system. The methanol concentration in the circulating fuel stream is usually measured continuously with a suitable sensor, and fresh methanol is admitted in accordance with the signal from the sensor. There are many factors to consider in developing a methanol sensor suitable for DMFCs. These factors include sensitivity, cost, size, simplicity, reliability, longevity, concentration range, and dynamic response. In particular, reliability and low cost should be addressed. Methanol concentration sensors measure methanol concentration by means of detecting the variations of physical/chemical properties of the solution. In this work, methanol concentration sensors based on electrochemistry, electric-capacitance measurement, infrared sensing, ultrasound sensing, and other techniques are reviewed to discuss their advantages and disadvantages.

Jan 1, 2005

By J. Duriez, L. Scholtès, F. V. Donzé

"Fracture propagation process in brittle rock is investigated by means of numerical simulations performed with an adapted formulation of the discrete element method. The progressive failure mechanism is simulated through the breaking of the bonds making up the cohesion between the elements constituting the simulated medium. The use of appropriate contact laws associated to a near neighbor interaction feature provide the model the ability to reproduce fundamental characteristics of brittle rock behavior such as, for example, high values of the tensile to compressive strength ratio. Great attention is given to accurately describe the properties of the pre-existing joints or faults in the model. A specific joint model gives the possibility to define a tailor-made behavior of the discontinuity surfaces without suffering from discretization bias.Compression test simulations are performed on pre-flawed samples and compared to experimental results in order to validate the numerical approach for describing the initiation and propagation of fractures in brittle rock under mode I+II loading. It is shown that the crack mechanical parameters can greatly influence the fracturing pattern, in particular its frictional properties. Overall, the numerical simulations reproduce fairly well the failure patterns that are obtained experimentally.The discrete model is then used to study mode I+III loading to give an insight into fracturing problems occurring at the scale of the continental crust. The ability of the model to support mechanically the physical modelings performed with wet clay or sandbox is shown. As an example, the model is used to track the development of a twist crack system (wrench fault) through the nucleation and coalescence of microcracks."

Jan 1, 2015

By BARRY BANNATYNE

Ombrotrophic Sphagnum peat bogs have a characteristic signature on both colour injrared film (750 nm to 3,000 nm response) and Daedalus injrared line-scanner images (thermal infrared 3 to 5 microns and 8 to 14 microns response). This remote sensing method was used to survey bogs in southeast Manitoba to delineate targets for surface exploration. Target bogs all have a surface growth of Sphagnum; underlying dead Sphagnum ranges from 1 to 6 m thick. Large Sphagnum reserves exist in the Caribou cluster of bogs, and in /979 a bog first identified by infrared sensing was brought into production.

Jan 1, 1984

By Wei Ye, Lei Li, Xianjian Guo, Feng He

The purpose of the paper is to study the smelting process of copper concentrate with high Cu/S ratio produced in Africa or other areas around the world and theoretically analyze the influence of slag type on the smelting process. The paper has compared the processes used successfully in smelters, including CAPEX and OPEX and other factors, to provide reference for the industry to select the best process under specific conditions. INTRODUCTION At present, a great amount of copper concentrates with high Cu/S ratio, with chalcocite being the major source of copper, have been produced or are about to be produced in the Copperbelt in Africa and other countries in the world. The copper concentrate is usually high in copper (~30–55wt.%) and low in sulfur (~10–15wt.%). The conventional processes of smelting-converting and roasting-leaching-electro-winning for treating this type of concentrate is high energy and materials consumption such as electric power\fuels\flux et al. The direct-to-blister (one-step) smelting process can be considered favorable due to a reduction in processing steps. Up to now, there are four copper smelters in the world operating with the direct-to-blister smelting process. There certainly are problems in the process such as high copper content in the slag, strict operation requirement of slag cleaning electric furnace, etc. Except technical issues, the impact of factors on economical aspect such as power and material cost needs to be considered comprehensively in process selection. In this paper the technical issues of direct-to-blister smelting process, including slag treatment process, were analyzed and the comparison to the conventional processes and economic analysis of direct- to-blister smelting process to treat high Cu/S ratio concentrate were done.

Jan 1, 2019

By X. Xe, B. Myhre, N. Zhou, B. Sandberg, Z. Chen

Effects of microsilica and reactive alumina type on flowability, flow decay and working time of Al2O3-SiC-C castables for blast furnace trough were investigated. The results show that at a targeted self flow values of (80 ± 10)%, water demand markedly decreases with increased microsilica addition. The nature of reactive alumina has a strong influence on flowability of the castables. Higher microsilica content contributes to a longer working time. The flow decays gradually until the working time and then drops abruptly. In addition, microsilica have positive effect on both cold strength and hot strength.

Jan 1, 2004

By Tracy-Lynn Humby

A recent report commissioned by the South African Chamber of Mines, Mining Vision 2030, identifies the South African mining industry?s negative legacy, its exploitation of people and the environment, as the single biggest hurdle to maximizing the industry?s impact on national development. Industry leaders have identified the need to put the past ?to rest?. With reference to three recent cases involving members of the South African mining industry, this paper points to the continuities between the past and present. It argues that the metaphor of ?multiple crossings? is more generative than the notion of putting the past ?to rest? for purposes of engaging with mining?s negative legacy.

Aug 1, 2013

By Gautier Njiekak

The current study provides an experimental approach that aims at documenting the effects of different phases of CO2 (gas, liquid, supercritical fluid) on rock seismic responses. This has implications on obtaining quantitative estimates of fluid saturations for geological storage. The ultrasonic pulse transmission technique is the underlying methodology used in this work. Unlike previous rock physics studies involving CO2 as pore fluid, care is taken to fully saturate the studied samples and also to separate pore fluid effects from pore pressure build-up effects during the experiments. This allows to record seismic effects that are solely reflective of changes in the pore fluid properties. Measurements were done on a CO2 saturated Berea sandstone. Laboratory results show P- and S- waveform variations (velocity, amplitude) in response to CO2's varying phase state. Overall, CO2 phase changes (gas to liquid and gas to supercritical fluid) are marked by a drop in velocities, with the drop being smaller and less immediate over the gas-supercritical fluid transition than over the gas-liquid transition.

Jun 1, 2012

By Y. Kocaefe, D. Bhattacharyay, D. Kocaefe

The carbon anodes used in the electrolytic production of aluminum are made of petroleum coke, recycled anodes and butts, and coal tar pitch. Due to technological advances in the aluminum production technology, aimed at increasing production and decreasing energy consumption and greenhouse gas emissions, better quality anodes are required. Presently, the anode quality is evaluated by visual inspection and the analysis of a small core taken from 1.5-2% of the anodes produced. The visual inspection is susceptible to human error and limited to surface imperfections. The analysis of cores takes time, and therefore, it is difficult to determine the existence of a problem and intervene at the right time. In addition, the core does not represent the whole anode due to the non-homogeneity of anodes. A validated online anode quality control system can highly improve the situation. In this article, an electrical resistivity measurement method developed for this purpose is presented.

Jan 1, 2014

By E. Rezaei

Glue is an animal protein that is used with other organic agent such as thiourea, in copper electrorefining. The concentration of glue has to be controlled carefully, because the electro-deposition process is often very sensitive to small fluctuation in the operating variable. This additive (glue) prevents rough and nodular copper cathode deposits. The nodular deposits may grow causing short circuits, which results in losses in production. Addition agents are effective in controlling metal growth; they modify the normal nucleation and lattice growth steps and refine the grain structure. In this research glue concentration was determined in an industrial copper electrolysis plant. A non-linear model with high capability was constructed and after optimizing its parameters, the accuracy and precision of the model were evaluated. For determination of glue concentration, electrochemical voltammograms in optimum condition (Differential pulse voltammetry technique, Hpulse=50 my, scan rate=10 mv/s) were plotted. Some information from voltammograms was transferred to the model as inputs and the calibrated model analyzed the information and the glue concentration was determined with high precision and accuracy. In this way there is no need to separate or add agents to remove interferences. This method has been successfully applied at Sarcheshmeh copper complex.

Jan 1, 2007

By Y. T. John Kwong

Abstract - To exploit an ore deposit without unduly impacting the environment is a challenge that can only be met by the concerted efforts of traditionally independent teams working on a mining project. Not only is detailed geology required of geologists to help mine engineers to develop a mine plan that assures generation of the least possible amount of mine waste, but metallurgists also have to select the most environmentally friendly mineral processing schemes, and communicate with environmental engineers with regard to complications that process chemicals may pose on proper mine waste management. Traditional ore deposit models typically emphasize the geological and mineralogical aspects of ore genesis to facilitate exploration for similar deposits. Recent research has shown that potential environmental liabilities such as acid mine drainage and metal leaching can readily be predicted according to deposit types. The choice of mining methods, mineral processing schemes, and decommissioning options are also largely dictated by the composition and setting of an orebody to be mined. Integrating such related information into traditional ore deposit descriptions would lead to the development of comprehensive environmental ore deposit models. The latter would facilitate communication among staff of the varied components of a mine project and aid with the selection of a combination of methods and strategies that would assure minimum environmental risks and impacts, reduce the overall project cost, and enhance sustainable development.

Jan 1, 2003

By Ian S. Thompson

"Exploration properties form a continuum from grass roots to those with favourable geology, geochemical and/or geophysical anomalies, mineralization, showings (prospects), and finally to those with defined mineral deposits. Often properties exhibit a composite of these categories.The most problematic to value are properties or deposits that are not economically exploitable at the time of the valuation, due to a lack of exploration, insufficient grade or tonnage, poor mining conditions, or the imposition of socioeconomic, environmental, or legal constraints.Various acceptable methods of valuing the range of all such mineral properties or deposits are reviewed. Some inappropriate methods are also discussed.BIOGRAPHYIan S. Thompson is President and Principal of Derry, Michener, Booth & Wahl Consultants Ltd. (DMBW), an independent consulting practice, specializing in exploration, ore reserve estimations, engineering and valuations of mineral properties.Mr. Thompson is a graduate in Honours Geological Sciences from the University of Toronto with over 35 years Canadian and International experience in mineral exploration and development, including the discovery of base metal. gold and uranium deposits.DMBW is affiliated with DMBW, Inc. in Colorado, and works with independent engineering and financial groups in North America, Europe, Australia and Africa.Mr. Thompson is a national member of CIM; the Associations of Professional Engineers of Ontario and British Columbia; The Geological Association of Canada; The Society of Economic Geologists; The Prospectors and Developers Association of Canada and the BC and Yukon Chamber of Mines.INTRODUCTIONThis paper is presented in response to the request of the Mineral Economics Society of the Canadian Institute of Mining and Metallurgy for a Review of Approaches to Valuation of Mineral Properties, as recommended by the TSE/OSC Mining Standards Task Force.Exploration properties with undeveloped mineral resources range from grassroots acreage without exploration history, to those containing mineralization (or a mineral resource) that is insufficiently explored, to well explored deposits which lack either continuity, or sufficient grade/tonnage, or have poor mineability or metallurgy, such that they are not currently exploitable at the time of the valuation. This does not imply that they do not have value."

Jan 1, 2003

By R. Carter, C. S. Samis

"SummaryThe results of this investigation indicate that the gold in the cyanide tailing of refractory gold cyanides is occluded in fused •particles formed during roasting. This conclusion was reached following microscopic examination of calcines produced at various furnace temperatures with different atmospheres, and a •comparison with calcines produced by decomposing samples of completely sulphated concentrate under conditions such that the maximum particle temperature varied between 6•50°C. and 1,100°C. This comparison showed that the particle temperature during a normal roast may be several hundred degrees higher than the furnace atmosphere, or that the fusion is associated with a low melting (950°C.) eutectic mixture of FeO and FeS.Because of the unavoidable particle fusion during a furnace roast, and because low particle temperatures are essential for gold extraction by cyanidation, aqueous medium oxidation under high oxygen pressures was studied. Gold recovery from calcines produced by this means was over 98 •per cent •compared with a maximum of 80 per cent from furnace calcines.IntroductionMANY arsenical gold ores are called 'refractory' because much ' of the gold cannot be satisfactorily extracted by cyaniding the raw ore or concentrate. Even when such ores are roasted to oxidize .the iron and arsenic and 'release' the gold, often 10 to 25 per cent of the gold present is lost in the cyanide residues."

Jan 1, 1952

By The Staff

"A general description of the equipment, personnel and work sequence •being used in the sinking of a circular, concrete lined, 14 foot diameter shaft which at present is at a depth of 2,484 feet. Equipping, lining and sinking of the shaft is being carried out concurrently and waste is re-moved using a mechanical mucker.INTRODUCTIONTHE BUCHANS UNIT of the American Smelting and Refining Company operates a group of mines at Buchans, Newfoundland. Buchans is in the centre of the Province (Lat. 48°47'N.; Long. 56°50'W.), five miles north of Red Indian lake at an elevation of 900 feet and is accessible by 37 miles <Jf private railway which connects with the Canadian National railway at Millertown Junction, and by 47 miles of gravel highway, which connects with the Trans-'Canada Highway at Badger."

Jan 1, 1959

By J. A. Finch

Samples of feed and product from a closed grinding circuit treating a heterogeneous lead-zinc ore were taken. The feed was subjected to laboratory batch grinding in a rod and ball mill with the objective of simulating the closed-circuit size distribution. It was concluded that the batch rod mill can closely simulate this product if only the over-all size is considered, but mineral-by-mineral large differences occur. If, as is suspected, the mineral sizes are the important factor in flotation, the differences could lead to problems in interpreting flotation results. An example of mineral recovery as a function of size is described to illustrate the potential problems.

Jan 1, 1979

By K. Sun, S. A. Argyropoulos

The assimilation and the exothermic behavior of Zn-Zr metallic powder compacts into molten aluminum was studied by measuring simultaneously the temperatures inside at the centerline of the compact, at its surface, and inside the molten aluminum bath, as well as the net downward force acting on the compact. In addition, the exothermic behavior of these compacts was also investigated in an argon protected atmosphere. The temperature rise inside the compact increases significantly with the mass ratio of zirconium in the compact and to a lesser degree with the aluminum bath temperature. Experimental results on the recovery of these compacts in molten aluminum will also be presented.

Jan 1, 2008

By G. Q. Zhou, H. C. Liang, X. D. Zhao

"This study describes the strain behavior in vertical shaft lining (VSL) embedded in thick soil deposits and its application in assessment of concrete deterioration. The observed strain in VSL continuously decreased companied by a sinusoidal fluctuation due to the influences derived from negative skin friction (NSF) and temperature. The increase in strain increment between peak and trough at each year and compressive strain level as the servicing time continued and VSL depth increased implies that the concrete strength was attenuated, and this attenuation was significantly dependent on the existing compressive strain level in VSL. The reliability of the proposed approach was validated by Schmidt Hammer Technique (SHT) – based concrete strength, and is applicable in concrete assessment and then fracturing prediction of VLSs in thick soil deposits.Concrete strength, Field monitoring, Strain behavior, Vertical shaft liningINTRODUCTIONOver 100 VSLs in Southeastern China subjected to an unpredictable fracturing as shown in Figure1, and there are over 1,000 VSLs embedded in thick alluvium su?ering from challenges of damaging and potential fracturing (Cheng, Yang, Zhou, Li, & Hu, 1993; Zhou, Cui, Lv, Huang, & Chen, 1999; Li & Li,2005). Therefore, a reliable assessment of these VSLs is significant to the normal servicing of mine shafts and the recycle of underground space when these mine shafts were closed.The continuous increasing of NSF induced by the drainage of water–saturated deposits well interpreted such extensive fracturing phenomenon, and it is universally regarded as the governing indicator to determine the VSL stabilization (Cheng et al., 1993; Zhou et al., 1999). Based on this recognition, the fracturing prediction and VSL strengthening according to the field monitoring on hydrogeological characteristics, servicing environments, and mechanical behaviors of VSL were carried out (Zhao, Zhou, Zhong, Zhu, & Liang, 2009; Liang et al., 2009; Xie, Lv, & Wu, 2014). As known, the compressive strain level in VSL and the in–situ strength of VSL concrete were the main factors to perform such fracturing prediction. However, the existing studies in literatures were limited to the strain accumulating or releasing behaviors (Zhao, Zhou, Zhao, Kuang, & Hu, 2017), and lack of considering the VSL concrete strength and its attenuation. In this reported study, the in–situ monitoring data on the strain in typical VSLs and the VSL elevations between 2004 and 2014 were initially analyzed. Then, an observed strain behaviors–based approach was developed to quantitatively evaluate the VSL concrete deterioration."

Jan 1, 2019

An optimization process is described that can be systematically applied by mine planners to produce life-of-mine schedules aligned with their strategic targets, while maximizing the net present value of the mining operation. The software tool employed uses heuristics and an evolutionary algorithm to generate life-of-mine schedules of production and development activities. Generating such schedules is typically a very difficult task due to the large number of operational constraints that must be respected, and the vast number of alternative schedules; as a result the value of the mining operation can be compromised. With an expansion at Newmont?s Leeville mine in Nevada, the mine planners were given the task of producing feasible life-of-mine schedules with significantly increased production rates. Their initial efforts indicated that it would be a considerable challenge to generate such schedules in a timely manner. By systematically applying the proposed optimization process, the mine planners were able to generate optimized life-of-mine schedules with the desired production rate.

Aug 1, 2013