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By John D. Godfrey

Precambrian Shield rocks, exposed in the extreme northeast corner of Alberta, provide the only possibility for a granitic building stone development in the province. Among a wide variety of granitoid rocks in the Shield, the Chipewyan Red Granite is one of the most favourable prospects. Geological mapping and exploration has revealed two prospective sites within a major pluton situated close to navigable water. Cleaned outcrop surfaces show clearly the pattern of joints and lithologic variations within the granite at prospective quarry sites. Other features include: basic dykes, quartz veins, and sheeting fracture zanes. Systematic orthogonally arranged fracture sets and the sheeting zanes are auributed to a tectonic origin. onsystematic irregular fractures are related to surface and nearsurface processes, such as decompression through unloading .

Jan 1, 1984

By C. Langer

Although the existence of precious metals, particularly those of the platinum group, in the nickel ores in the Sudbury district has been known for a good many years- almost as long as the ore deposits themselves- the Mond Nickel Company were the first to effect their recovery on a commercial scale. The precious metals values of the different Sudbury ores vary considerably, and are generally higher in the copper-rich ores. These values are so very small that a direct determination in the ores gives quite unreliable results. This is not surprising if one considers that some of the ores contain on1y one unit of total precious metals in about two million units of ore, and that this one unit will consist of seven different metals, each with a different chemical behaviour. It is only after the ores have been smelted to a Bessemer matte containing about 80 per cent combined copper and nickel that the precious metals content can be determined with some degree of certainty. From the figures thus obtained, the precious metals content of the ores can be calculated, provided the tonnage of ore used to produce one ton of matte is known. The recovery of these minute quantities of precious metals out of ?such a large amount of gangue and sulphides of iron, copper, and nickel seems at first glance a commercial and technical impossibility. Nevertheless, science has found a way to conquer all the difficulties, and quite substantial quantities of the precious metals contained in the Sudbury nickel-copper ores have been regu1arly recovered for many years by the Mond Nickel Company.

Jan 1, 1927

By A. Bauer, P. Katsabanis, M. Baker

The principal results from a previous paper presented at the Mine Accident Prevention Association of Ontario in 1987 (1) are summarized here. It is concluded that the selection of explosives in mines experiencing sulphide ignitions is important and that aluminized explosives should be avoided because of their high explosion temperatures and their detonation products. The duration of the blast is also critical and secondary blasts should not occur simultaneously with nearby priroa:ty blasts.

May 11, 1988

By D. Lopez, D. L. Doerr, T. J. Drake

Automated scanning electron microscopy has been widely used in recent years for gold and other precious metals characterization. However, application of this technology is resource intensive and in most instances needs specialized technical personnel to process the samples and information. Newmont Metallurgical Services (NMS) has recently acquired an ASPEX SEM. The ASPEX SEM offers some significant benefits/improvements in sample preparation and sample processing time. NMS and ASPEX have been working together to develop an approach utilizing this technology for the minerals processing industry and specifically for gold characterization.

Jan 1, 2011

By James F. Kelly

"Research and development on the production of liquid fuels from coal is rapidly expanding worldwide. AImost every industrialized country is engaged in coal liquefaction research and process development. In Canada, the federal government, through CANMET, is actively supporting coal liquefaction research and development in a number of areas.A review of the basic principles and some of the processes in the production of liquid fuels from coal is presented with reference to the characteristics of the Canadian coal resource base. An overview of the CANMET coal liquefaction contract program is presented and specific results from the batch autoclave studies carried out with Saskatchewan lignite and Nova Scotia high-volatile bituminous coals are discussed. The development of a laboratory-scale continuous-flow coal liquefaction unit at the Energy Research Laboratories of CANMET to investigate the co-processing of coal and bitumen/heavy oil is also described.IntroductionThe CANMET coal liquefaction program is made up of two interrelated parts. The first part consists of the research and development work being carried out at the Energy Research Laboratories near Ottawa, Ontario. The second focuses on contracted research and development as part of the Coal Conversion Program of Energy, Mines and Resources Canada. The long-term objective of the liquefaction program is to contribute to Canadian liquid fuels production through the definition, research, development and demonstration of different coal liquefaction technologies for the Canadian marketplace.In coal liquefaction, the main objective is to produce liquid hydrocarbons with a higher hydrogen-to-carbon (HIC) ratio than the coal feedstock while reducing heteroatom (S,O,N) content, removing mineral matter and minimizing gas production. Typical atomic HIC ratios for a variety of Canadian fossil fuels are shown in Figure I. Canadian coals have about 500/0 of the HIC ratio present in tar sand bitumens and heavy oils and only about 20% of the ratio available in methane. In general, the cost of synthetic fuels production is related to the cost of hydrogen and, therefore, to the increase of HIC ratio between feedstock and products. On this basis, the production of liquid fuels from coal would be expected to be more costly than liquid fuels produced from bitumens and heavy oils. However, for mined tar sands and some heavy oils this difference tends to be offset by the large sand content (>90 mass %) of tar sand bitumens and the increased production costs of viscous heavy oils. For example, it can easily be shown that for equal weights of distillate <525°C) yield, current coal liquefaction processes required between two and three times less mined coal by weight than the mined tar sand s required for the most technically advanced processes proposed for bitumen upgrading."

Jan 1, 1981

By Ali Montaser

This paper presents an experimental study conducted to facilitate the use of RFID on construction job sites. The study focuses on deployment settings to provide data acquisition with higher accuracy for indoor location sensing. It provides extension to the state-of-the-art in this field as it addresses the impact of metal media proximity to RFID tags, the reasonable duration for data capturing, number of RFID tags employed and the distance between them. Low cost passive RFID tags were used in the experiments where each tag is used as a reference point with a known location. Five hundred and forty (514) experiments were conducted in lab environment using a 3m by 3m test bed that is dynamically rearranged to generate 15 test beds and a total of 67713 data sets were collected and analyzed. The collected data were captured from nine locations for each test bed at four time intervals. Received Signal Strength Indicator (RSSI) was used as the main attribute for signal measurement to process the captured data. Results of the data analysis performed are studied under four main categories: duration, number of tags, locations of tags and metal interference. The best duration was found to be the 15 second in the test bed with the least number of tags; as the short amount of time to capture data did not allow creation of a lot of interference among the emitted signals. Within each test bed, errors occurred most at points where the received signals were not well distributed in a 360 degree vicinity of the data capturing point. It means that the center point of each test bed resulted in lowest errors and the points located on the extremities led to the highest errors. Finally, metal objects were found to have major impact on the accuracy of the captured data; to the level where reliable values for errors could not be calculated in the test beds attached to metal objects. In summary, the results of the experimental study and related findings are expected to provide guidelines to the users of RFID technology for localization in building construction.

Aug 1, 2013

By Roger Francis

There is increasing use of acid leach extraction methods at elevated temperatures and pressures by the mining industry. In many locations there are limited supplies of fresh water, and waters with higher chloride contents must be used, making conditions more corrosive. The fluids downstream of the main autoclave are hot, acidic, oxidizing and contain chlorides and present a challenge to the mining community to ensure reliable operation. Zeron 100 is a high strength superduplex stainless stee, that offers high corrosion resistance at a cost effective price. The paper presents a combination of laboratory data and service experience, particularly in the aggressive fluids found in downstream processing.

Jan 1, 2010

By E. M. De Souza

"The mining industry has developed a strong need for monitoring underground openings since bulk mining, used for increased productivity, has become the dominant mining method industry wide. The large stopes associated with bulk mining methods generally have to remain open and stable for several months, and monitoring is essential to provide an indication of ground response to mining and stope stability. The instrumentation data is also important during design optimization, which is used to maximize recovery, to minimize the dilution of ore and to minimize costs. Monitoring is essential to implement safety and is also critical in stope and mining sequence designs. The safety related aspects of monitoring include the protection of underground workers and the prevention of accidents by providing early warnings of the onset of any ground instability. The design related aspects of monitoring involve the development of data bases used for stope dimensioning and mine sequencing and timing and the monitoring of ground behaviour as a result of mining to verify the validity of the design thus allowing for remedial action during operation.Manual instrumentation data collection is, in a number of cases, economically unfeasible and, in many situations, dangerous as instrumented areas become inaccessible or extremely unstable. Also, because more and more complex instrumentation is being installed in underground operations, in several cases it becomes practically impossible to collect readings manually. The design and development of low-cost acquisition systems for mine wide monitoring would thus constitute an important step toward automation in excavation instrumentation. A unique menu-driven automatic 32-channel analog data acquisition and analysis system with a built-in rock failure warning mechanism has been designed and developed. This low cost acquisition system is capable of receiving, processing, displaying and storing the transmitted instrument data remotely and automatically. Computer software has been designed to provide data reduction and analysis immediately in the field and to automatically display results in graphical form for quick interpretation. Automatic data interpretation is used to show trends in rock mass behaviour and the system can be used to provide early warning of rock failure to the mine personnel working in there so that immediate remedial action can be safely taken."

Jan 1, 1992

By Lanny Pasternak

"This article is directed at plant production, engineering and maintenance personnel. Seldom does any industrial operation take the time to study the costs involved in the generation of what is probably their most expensive plant utility energy source.IntroductionIn the typical industrial plant in Canada, a 200 hp, 900 cfm, air compressor costs about $60,000* per year to operate (Fig. 1). In 1989 when BC Hydro embarked on their industrial energy management program Airflow Energy Ltd. were asked to spearhead the “Efficiency Compressed Air” portion of that program with a mandate to perform onsite overview surveys and physical hands-on testing of some 300 selected industrial plants throughout British Columbia for compressor efficiencies and wasteful air leaks (Fig. 2). The program duration lasted until 1995, during which time a tremendous amount of data were amassed relating to equipment types, clients’ operating habits, end-use applications and operating costs.During the past six years, Airflow Energy also performed somewhat similar surveys but on a smaller scale in Alberta, Ontario, the United States and the Republic of China. It was no surprise to find some inherent equipment concerns related to efficiency as well as neglected energy wasteful air leaks, so British Columbia was not alone and the problems appear somewhat universal."

Jan 1, 1996

By S. Rash Ahmadi

One of the most important elements in power plants is rotors and repairing the damaged rotors is very important in view point of economics. One of the most complicated problems in power plants is increasing of stiffness of the turbine rotors. This problem which occurs mainly due to thermal shock or rubbing makes to exit damaged rotor from service. These elements can be repaired effectively by heat treatment methods. Tempering heat treatment is the most common solution for straightening of damaged rotors but it requires having good knowledge about heat treatment parameters (temperature and time) and their affects on fundamental properties of rotors. In this article, a suitable method is introduced in order to modify the increased stiffness in journal part of rotors due to martensite transformation, using heat treatment tempering process.

Oct 1, 2011

While this paper is directed towards the ?Bellambie? type of rope attachment, the principles can be applied to any brand of rope fitting however, it is a only a broad outline and the specific installation and maintenance procedures can be obtained from the attachment supplier. The types of attachment to be discussed are:- ?Thimble Type rope cappel ?Wedge Type cappel ?WRC Rope Clamp ? (Rope Glands) ??Hoist and Balance Rope Sockets In each case, the assembly and stripping (disassembly) plus the basic maintenance procedures is briefly described. A guide for Risk Assessment is also included but because of his familiarity with the installation, the end-user is in the best position to draft the final version.

May 1, 2003

By Roy EI. Durr, Glen R. Davidge

"This paper presents the results of structural analyses and full-scale destructive tests conducted on liner plate culverts. The purpose of this work was to establish a design method and evaluate the suitability of using these structures in potential roof-fall areas for a rehabilitation application in lower stress and relaxed mining environments. Field evaluation of the design is currently in progress.Theoretical ultimate resistance functions were established for two different culvert shapes and were found to be representative of their experimental behaviour. The ultimate resistance function was used to determine their plastic behaviour to a rapidly increasing deflection condition, to determine the energy absorption capacity of these structures, and to predict their response to impact loading.IntroductionThe Kidd Creek mine of Falconbridge Limited is located justnorth of Timmins, Ontario. The area under rehabilitation for which this program was developed is the 2600 level of the No. I mine. The problem of effectively securing selected drifts at the 2600 level in NO.1 mine, for access to a high-grade ore block, is key to the economics of the operation. Diamond drill test holes had indicated a loosened rock mass above the 2600 level of about 7.5 m thick in response to the extensive mining operation below this level. This level forms the arbitrary boundary between the No. I and No. 2 mines, and has extensive volumes of cemented rock fill below it and largely untouched ore above it to the 2000 level in the North orebody. The walls at that level were showing relaxed ground conditions typical of de-stress: sub-horizontal joints opening up, and peeling.Due to the ground conditions, the consequent safety risks, the high grade of the ore, the potential production delays, and the likelihood of several phases of rehabilitation, regularly used drift rehabilitation employing rock bolts, cable bolting, or shotcrete was not practical. Two options were deemed possible alternatives to suit these conditions, steel sets with blocking and lagging, and liner plate culverts with backfill. Culverts were chosen."

Jan 1, 1995

By Neil Schofield

"The Pine Creek gold mineralization is associated with saddle reefs and quartz and quartz sulphide veining within the Enterprise Anticline. The anticlinal structure is complex and the mineralization was considered prior to development to be dominantly strata controlled. Gold grades vary up to 160 gin 1.5 m core samples with coefficients of variation in excess of three.The estimation of ore reserves for such a deposit must account for both the geological complexity and the extreme variability of gold grade.This paper describes the structural and variogram analysis of the gold grades and demonstrates the importance of incorporating the geological model in such an analysis. Variogram interpretation is greatly improved and greater insights into the finer geological structure areprovided. Part 2ofthis work presents the application of multigaussian kriging to reserve estimation for deposits with highly variable grade and which consequently demand highly selective mining operations. IntroductionThe Enterprise Gold Mine is situated some 220 km southeast of Darwin in Australia&apos;s tropical north. Gold is believed to have been discovered there in 1869 during the construction of the overland telegraph line.From 1894to 1915, some 75 000 ounces of gold were produced from 121 000 tonnes mined mainly by Chinese leaseholders. From 1906 to 1915, government-sponsored drilling led to the sinking of the Enterprise Shaft to 79 m and several drives were developed. Mining ceased because of war.Since late 1980, Goldfields Exploration Pty. Ltd. had explored on several mining tenements near Pine Creek under joint venture with the title holders, Enterprise Mines NL. This work culminated in the development of the current mine which opened on October 29, 1985.Feasibility studies to determine the economic viability of mining were based on ore reserves generated by project geologists using a sectional polygonal approach tuned to the interpreted geological control of the mineralization.The study motivating this two-part paper covers are-estimation of the recoverable reserve s using the geostatistical approach of multigaussian kriging developed at Stanford University, (Verly, 1984)."

Jan 1, 1988

By P. E. Weidmark

"CANMET InformationPART 1-Published PapersAsmis, H. W., ""The dynamic response of caverns in discontinuous rock""; Proc 22nd U.S. Symposium on Rock Mechanics, Cambridge, Mass, June 1981, 272-277; 1981.Austin , M.W., Bray, J.W. and Crawford, A.M., ""A comparison of two indirect boundary element formulations incorporating planes of weakness"" ; Technical Note; Int J Rock Mech Min Sci Geomech Abstr; 19:339-344; 1982.Barrett, J. R., ""Applying geotechnical theory to underground metalliferous mining""; Proc 1st Intnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of AIMMPE; 210-222; 1983.Barron, K., Wright, P.L. and Smales, T., ""Guideline s for the design of coal pillars in the No .4 seam at Mclntyre Mines Ltd ., Grande Cache, Alberta""; Proc 1st Intnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of A IMMPE; 559-578; 1983.Bauer, A., ""Wall control blasting in open pit mines""; Mining Engng; 34:155-158; 1982.Bieniawski, Z.T., "" Improved design o f room-and-pillar coal mines for U.S. conditions""; Proc 1st Intnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of AIMMPE; 19-51; 1982.Blackwell, G.H. and Calder, P.N., ""Practical aspects of wall stability at Brenda Mines Ltd., Peachland, BC""; 3rd Intnl Conf on Stability in Surface Mining; Vancouver, BC, June 1981; SME-A1ME; 3:573-608; 1982.Blake, W., ""Microseismic monitoring for underground stability "" ; Proc 1st Intnl Cont on Stability in Underground Mining; Vancouver , BC, August 1982; SME of AIMMPE; 272-294; 1983.Brawner, C.O., ""Stabilization of rock slopes"" ; 3rd Intnl Conf on Stability in Surface Mining; Vancouver, BC, June 1981; SME-AIME; 3:289-310; 1982.Bridges, M.C., ""Review of open stope mining in Australia""; Proc 1st lntnl Conf on Stability in Underground Mining; Vancouver, BC, August 1982; SME of AIMMPE; 813-828: 1983."

Jan 1, 1983

By M. Medraj, M. A. Arafin, D. P. Turner, P. Bocher

In this study, the kinetics of isothermal solidification during TLP bonding of Inconel 625 and 718 superalloys with nickel based multi-component filler alloy BNi-2 have been studied through a combination of direct experimentation and mathematical modeling in order to determine the effect of process variables and, thus, to optimize the process. The predicted isothermal solidification completion times from the boron diffusion model and migrating solid/liquid interface model were in good agreement with the experimentally determined values and, they were found to be significantly less than those of other nickel superalloys with different nickel based filler alloys. Further, significant reduction of holding time was observed with increasing bonding temperature and with decreasing joint gap. No significant grain growth in the base metals has been observed in the temperature range being investigated (1325 - 1394K).

Jan 1, 2006

By F. Urekar, R. B. Pankhurst

"Air spaces and air gaps in an explosives column are known to allow greater distribution and cushioning of explosive energy from the rock mass. This energy distribution is enhanced if the explosives &apos; gases can be confined in the borehole for as long as possible by plugging and stemming above the air space.Power Plug is an inflatable plug which can seal a borehole at any point to separate the stemming from an air gap and explosive toe load.IntroductionThis paper will discussion-going work by C-I -L Inc. and operators of two open pit mines to study the results of using Power Plugs:I. Pit wall stability - the authors have found the Power Plug effective for wall control blasting in open pit mines.2. Selective mining of coal seams - the authors work shows the Power Plug allows mining selective coal seams by predrilling underseam waste wedges.Pit Wall StabilityWall stability in an open pit mine is essential for safety. Good wall stability can be achieved with wall control blasting techniques which cushion the effect s of the explosives charge by decoupling the charges from the borehole wall. The usual method of decoupling a charge in a large-diameter rotary borehole is to load the explosives in tubes (Fig .I) . We now believe the air deck system is effective in sea ling a borehole above the explosive charge to create an air deck within the borehole which will cushion the blast.In a linear decoupled charge, an air annulus surrounds the explosives charge and cushions the effects of detonation genera ted gases on the pit wall. In an air deck, i.e. with the hole plugged at the collar, the gases genera ted by an explosive toe load are sealed in the empty borehole column. After a period of time, these trapped gases produce radial cracking between holes along the entire length of the borehole.It is common practice to employ de coupled explosive charge columns in the borehole to limit blast damage to surrounding rock. The exact mechanism of energy transfer in such blasts, however, is not well understood. Interruption of the continuous explosive column in a borehole by means of stemming, or air decks, may also be viewed as another form of decoupled blast. Decoupling of the explosive charge from the borehole wall affects both explosive energy release and explosion pressure developed in the borehole."

Jan 1, 1988

By A. J. Hyett, R. D. Reichert

"A laboratory and field research program was conducted to investigate the major factors influencing bond capacity of grouted cable bolts. The results indicate that cable bolt capacity most critically depends on the grout uniaxial compressive strength (UCS), the radial confinement, and the embedment length.In the laboratory &apos;split-pipe&apos; tests were conducted using P VC, aluminum and steel pipes to provide radial confinement, and field test sites were chosen in granite, limestone and shale rock masses. For both datasets higher capacities were obtained under conditions of higher radial confinement. A correlation between the two was obtained through a comparison of the radial wall stiffness of the laboratory pipes with that of the field boreholes as measured using a high pressure dilatometer. Cable bolt capacity was found to increase with embedment length though not in direct proportionality.The use of low water cement ratio grouts (<0.40) can increase cable bolt capacities by 50% to 75%. This effect is maximized under conditions of high radial confinement. However, the use of super thick grout paste (0.30 and less) may be both impractical and undesirable, first because of their limited pumpability and second because of their inconsistency in strength. Grouts with a water cement ratio of between 0.35 and 0.40 are recommended for practical cable bolt applications."

Jan 1, 1992

By Michel Dagbert, Mohammed Harfi

"Abstract - The Draa Sfar polymetallic deposit, at about 16 km NW of Marrakech in Morocco, is a massive sulfide zone at the contact between an underlying volcanic and an overlying clastics sequence. The mineralized body is a flat lens with schistosity and "boudinage," tilted to the west and with a strong dip to the east. The lens extends over a strike length of about 2 km and from surface to a depth of about 1 km, with thickness varying from 1 m to almost 30 m. It has been intersected by about one hundred surface drill holes and, in its south part, by about thirty underground fan holes from two exploration levels at depths of 300 m and 400 m. On these two levels, the massive sulfide zone has been channel sampled over a cumulative length of about 0.7 km. Results from drill and channel samples are used to estimate the resources of the orebody according to several methods: sections, polygons around intercepts on a longitudinal plan, grids on the same longitudinal plan with various distance weighting methods including kriging and, finally, a 3D grid with the same range of interpolators. A comparison of the various estimates delineates the important factors in deriving resources for this type of deposit. Those factors are mostly geological and related to the interpretation of the geometry of the two limiting surfaces of the zone. For the 3D gridding, the authors have devised a new and original method that constrains the interpolation of blocks from samples to a geometry of limiting surfaces. The resulting model shows internal grade variations that parallel fluctuations of zone thickness and orientation without having to re-orientate the search window in each block. Résumé - Le gisement polymétallique de Draa Sfar, situé à environ 16 km au NW de Marrakech est un horizon de sulfure massif au contact d’une formation volcano-sédimentaire de base et d’une formation détritique sur-jacente. Le corps minéralisé se présente sous forme d’une méga-lentille aplatie, schistosée, boudinée et déversée vers l’ouest avec un fort pendage vers l’est s’étendant sur une longueur de 2 km et une profondeur de près de 1 km avec une épaisseur variant de moins d’un mètre à près de 30 m. Il a été reconnu par plus d’une centaine de sondages de surface et, dans sa partie sud, par une trentaine de trous souterrains en éventail à partir de deux niveaux à des profondeurs respectives de 300 m et 400 m. Sur ces mêmes niveaux, des traçages ont permis de rainurer le minerai sur une longueur cumulée de 0.7 km. Les données de sondage et de rainurage ont servi à estimer les ressources du gisement selon plusieurs méthodes : sections, polygones sur longitudinale, grille sur longitudinale avec différentes pondérations en fonction des distances incluant le krigeage et enfin grille tridimensionnelle avec le même éventail de pondérateurs. La comparaison des estimés obtenus permet de mettre en évidence les facteurs importants dans l’estimation des ressources de ce type de gisement. Ces facteurs sont essentiellement géologiques et relatifs à l’interprétation de la géométrie des limites des corps minéralisés. Pour l’estimation sur grille tridimensionnelle, on a mis au point une technique originale qui calque l’interpolation des blocs à partir des échantillons sur cette géométrie des surfaces de contact. Le modèle résultant montre des variations internes de teneurs qui épousent les fluctuations d’épaisseur et d’orientation de la zone sans qu’il soit nécessaire de ré-orienter les fenêtres de recherche dans chaque bloc."

Jan 1, 2002

By Fidelis T. Suorineni

The conditions for rockburst occurrence are traditionally identified as: high stress, high extraction ratio, strong brittle rocks, folding, faulting, and unfavourable excavation geometry. Based on a critical review of case histories, this paper identifies oblique loading of orebodies by the major far field principal stress as a cause of rockbursts. Orebodies subjected to this loading condition are termed orebodies in shear. Orebodies in shear are subjected to compressive and shear loads. The case histories presented unambiguously show that the magnitudes of the far field principal stress alone, and a knowledge of the conventional rockburst causing factors are not sufficient for mine planning and design. The orientation of the major far field principal stress, or for that matter the driving stress relative to the orebody axis, should be recognised as one of the causes of rockbursts. It is suggested that since stress orientation is an important factor, and orientations from stress measurements are so variable, orientations from stress measurement data be complemented with underground observations from borehole and excavation breakouts to determine the actual in situ stress orientation, whenever possible. Also stress modelling for the design of critical elements (pillars) should include a sensitivity analysis on the relative critical field stress direction. The paper emphasises that special attention should be paid to or

Jun 1, 2012

By Masakazu Daté

Moisture effect has been studied for the CO oxidation over Au/TiO2, Au/Al2O3 and Au/SiO2, in the range of H2O concentration over four orders of magnitude. It has been found that the catalytic activity is generally enhanced by moisture in the reactant gas. The enhancement is as large as two orders of magnitude. Response to the moisture concentration, however, depends on the support oxide, indicating different contributions of the support to the reaction steps. The moisture effect is reversible and the activity is mainly determined by the amount of moisture absorbed by the catalyst. The apparent activation energies are not significantly influenced by moisture for Au/TiO2 and Au/Al2O3. On the contrary, non-uniform conversion curves versus temperature observed for Au/SiO2 are drastically changed, which indicates that the reaction over Au/SiO2 does not take place at low temperatures without moisture. The moisture effect may be probably attributed to the decomposition of carbonate species accumulated during the reaction, while the ?OH group might directly participate in the reaction pathways as a promoter.

Oct 1, 2003