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By Janne Karonen, Stephen Hughes, Mikael Jåfs, Jan Stål, Hannu Johto

End-of-life electrical and electronic scrap material attracts attention as a good opportunity for new value creation through efficient metal and energy recovery of such materials. On the other hand, the treatment of such wastes becomes important to avoid problems for society and environment. Treatment of such secondary raw materials faces multiple challenges due to their increasing complexity and evolving nature. Processing of these complex scrap materials together with recovery of a wide range of valuable metals with a combination of pyrometallurgy and hydrometallurgy using Outotec technology is discussed in this paper. One key consideration is environmental performance which needs attention when processing such complex secondary E-waste materials. Outotec has successful experience with commercial projects in the countries at the forefront of environmental and operational standards. INTRODUCTION Increasing attention has been drawn to the responsible processing of end of life Waste Electrical and Electronic Equipment (WEEE) as part of metals recycling, especially copper. It has been estimated that the amount of WEEE globally in 2016 was around the level of 46 Mtpa (Balde et al., 2017), representing a major disposal challenge but at the same time huge opportunity for resource recovery. The potential for increasing the recovery is high, because the official recycling rate of WEEE is in 2016 only 20% (Balde et al., 2017) and at the same time the estimated increase of the WEEE amount is between 3 and 5% per annum in the EU (Eurostat, 2019).

Jan 1, 2019

By Candido Bariáin

A new vapochromic material of formula [Au2Ag2(C6F5)4(bipy)2]n (bipy = 2,2´ bipyridine) has been developed and used for the detection of some volatile organic compounds as acetone either in vapour or in water solution. The material is presented in the form of powders which colour changes with acetone vapours turning from bright yellow in the absence of vapour to white in the presence of vapour. By using the sol-gel technique, the powder ? dispersed in tetraethyl orthosilicate- was easily deposited on optical fibres. In order to study experimentally the behaviour of this material for construction practical optical fibre sensors, a sol-gel material doped with the vapochromic material is deposited onto an extreme of a monomode fibre connected to a coupler. The behaviour of the material was studied for different wavelengths and concentrations of acetone vapours and acetone/water solutions. Changes up to 4dB in the reflected optical power were detected. Optical fibre sensors have many advantages over conventional ones, such as electromagnetic interference immunity, passivity behaviour, possibility of using multiplexation techniques, low weigh and little size, etc. Actually, there is an increasing interest in developing optical fibre sensor for vapour detection in the chemical industry and in fact many sensor had been developed [1]. Some are based on the deposition of a sol-gel-based material either over the core of an optical fibre [1] or onto the thinner zone of a biconically tapered optical fibre [2]. Others are based on Fabry-Perot interferometers [3]. Also there are sensors based on the reflection of the light on films, on the fluorescence of dye-doped polymer cladding in fibre, on colorimetric reagents in the core of a silica fibre or on surface plasmon [4]. The possible materials for the construction of such sensor should be colorimetric reagents able to change the colour or refractive index in the presence of same organic vapours. There are not many metallic complexes with these properties, although same interesting examples have been reported in the chemistry of palladium and platinum as [Pt(p-R-C6H4NC)4][Pd(CN)4] described by Nagel [5] and Mann [6], which reported the construction of some LEDs. We recently reported the preparation of a novel vapochromic material (Fig 1) [7] which can be used for the construction of optical fibre tapered environmental sensors [8,9] of vapour organic compounds (VOC´s). Also we reported other nickel and palladium derivatives which present this type of behaviour [10]

Oct 1, 2003

By Dougla McDonald, Richard Poulin

"Most mine managers in Canada today will agree that one of the keys to mining efficiency and productivity is their human resources. A5 a result, many mines develop some sort of incentive designed to tap their employees' capabilities to the fullest extent. Historically, the most common plans used have been ""piece-rate"" plans, where individual or small groups of miners are paid a financial bonus based on some measure of their productivity. Recently, however, incentive plans that take a more team-based approach have been developed in some Canadian mines. One such plan will be defined in this paper, and its popularity in the industry today discussed.Gainsharing PlansThere are two primary components to a gainsharing plan. The first is a cash incentive, which is paid to all employees and based on factors that are highly correlated with employee productivity, and key to the profitability of the mine. For example, the typical gainsharing cash incentive is based on the cost/unit of metal produced. Management (in consultation with employees in some cases) will establish the budgeted cost per tonne, and any savings in this amount is shared between the company and the employees. The second is a management philosophy and associated communication network, which is designed to foster an environment that encourages information exchanges, communication, participation, and trust between employees and management. The typical gainsharing communication network consists of two tiers of committees. The first, operational committees, include all employees working in the same department or departments which frequently interact. The employees meet monthly with management personnel to discuss problems encountered and brainstorm for solutions. In most cases, these committees will nominate a person in the group to structure the meeting to maximize its efficiency. The second, the screening committee, is a single group consisting of representatives from the various operational groups, whose primary job is to ensure that the plan is effective, and the objectives and results generated by the plan remain consistent with the mine objectives. In short, gainsharing plans tell employees that their bonus depends upon performance and then gives them the opportunity and incentive to affect that performance. The opportunity is provided by a communication network and positive management practices, and the incentive comes in the form of ""intrinsic"" rewards of participation and the ""extrinsic"" rewards of the bonus payments. Figure I will clarify the relationship between the intrinsic and extrinsic rewards."

Jan 1, 1995

By M. Celikin, M. Isac, R. I. L. Guthrie, S. Ge

Horizontal Single Belt Casting (HSBC) is a near-net-shape casting process in which molten metal is directly cast into thin strips, at high cooling rates (order of several 100°C/s), with the potential for high volume, friction-free, continuous production of metal strips. This casting process was used in the present work to produce strips of Al-Mg alloys in the AA5000 series, with additions of Sc and Zr. Such aluminum alloys show exceptional potential as a structural material for transportation/aerospace applications. To demonstrate the suitability of the HSBC process to manufacture competitive strip products of Al-Mg-Sc-Zr, the mechanical properties and microstructures of the strips produced using the HSBC process were compared with conventionally cast products. The effects of annealing on the mechanical properties of the strip-cast Al-Mg-Sc-Zr alloys were also investigated.

Jan 1, 2014

By P. E. Cavanagh

THE Ontario Research Foundation has developed a family of dry magnetic concentrators which, when used in conjunction with a dry grinding mill such as an Aero-fall mill, will allow the production of a completely dry magnetite concentrate. Previous experience with extrusion of iron ore and with pelletizing of fine iron concentrates suggested that it might be possible to develop a method particularly suited to the agglomeration of completely dry concentrates which might have some practical advantages over other methods of agglomeration. Pelletizing is the preferred method of agglomerating very fine iron ore concentrates. Magnetite concentrate is fod to the pelletizing equipment in the form of a moist filter cake. Binders and plasticizers may be added if necessary, and the moisture content must be increased or adjusted to the percentage necessary to give good balling action and satisfactory green strength in the resulting moist pellets. The moist ore with a closely controlled water content of about 7 to 12 per cent moisture may be rolled into pellets by a snow-balling action in a pelletizing drum, a Lurgi pan, or a Mac-Dowell disc pelletizer. The resulting green pellets are fired by one of several alternative processes to produce a hard pellet which has sufficient strength to withstand handling and shipping.

Jan 1, 1957

By Robert A. Gault, T. Scott Ercit, Mehmet F. Taner

"Abstract -Vanadium mineralization occurs in oxide-rich horizons within the layered gabbro zones of the upper parts of the Bell River Complex, Matagami, Québec and the Lac Doré Complex, Chibougamau, Québec. The vanadium-rich horizons are well defined on the ground and in aeromagnetic surveys by their high magnetic susceptibility; consequently, magnetic susceptibility can be an indicator of vanadium mineralization. The main oxide minerals are ilmenite and titanian magnetite, containing 20% to 70% of volume and the ratio of titanian magnetite to ilmenite is relatively constant, ranging from about 1:1 to 2:1. Their sizes are less than 5 µm to greater than 1 mm to 2 mm, occurring as coarse- to medium-grained subhedral crystals intergrown with cumulate silicate minerals (plagioclase, pyroxene, etc.). Electron microprobe analyses indicate that the ilmenite grains are mineralogically and compositionally homogeneous and have low V contents (average 0.18% equivalent V2O5). In contrast, the titanian magnetite grains are inhomogeneous, consisting of trellisworks of ilmenite lamellae in Ti-poor, V-rich magnetite [less than 2 wt% TiO2, and 1.41% equiv. V2O5 (1.16% V2O3) for 20 analyses]. Thus, the magnetite is the principal ore mineral of vanadium; it hosts vanadium in the form of V3+, not V5+, as is commonly and erroneously reported. We have also devised a flowchart for the beneficiation of vanadium-titanium ores. Sommaire - La minéralisation de vanadium se trouve dans des horizons riches en minéraux oxydés de la partie supérieure des zones de gabbros lités des Complexes de la Rivière Bell, Matagami, Québec et du Lac Doré, Chibougamau, Québec. Des horizons riches en vanadium ont été bien définis sur le terrain et dans les levés aéromagnétiques par leur susceptibilité magnétique élevée; conséquemment, la susceptibilité magnétique est l’indicateur directe du contenu en vanadium. Les principaux minéraux oxydés sont l’ilménite et la magnétite titanifère, contenant 20% à 70% du volume et le rapport de magnétite titanifère à ilménite est relativement constant, allant d’environ 1:1 à 2:1. Leur dimension varie de 5 µm à plus grande que 1 mm à 2 mm, apparaissant sous forme de cristaux subidiomorphes, de grains grossiers à médiums, intercroissant avec la gangue silicatée (plagioclase, pyroxène, etc.) de la texture de cumulat. Les analyses à la microsonde électronique montrent que les grains d’ilménite sont minéralogiquement et chimiquement homogènes avec un faible contenu en V (moyenne 0.18% équiv. V2O5 ). Contrairement, les grains de magnétite titanifère sont hétérogènes, contenant des lamelles d’ilménite en "trellisworks"; ces grains sont pauvres en Ti et riches en V pour la portion magnétite de la magnétite titanifère [surtout contenant moins de 2 wt. % TiO2, et en moyenne 1.41% équiv. (1.16% V2O3) pour 20 analyses]. Ainsi, la magnétite est le principal minerai de vanadium; elle renferme du vanadium sous forme de V3+ et non de V5+, tel qu’il a été communément et à tort rapporté. Nous avons aussi défini un "flowchart" pour la bénéficiation des minerais de vanadium-titanium."

Jan 1, 1998

By A. J. Hyett

Due to the ongoing revolution in electronics and communications more cost-effective geotechnical instruments can be manufactured using digital technology. This new generation of digital instruments have embedded microcontrollers that provide highly accurate and reliable measurement of geotechnical behaviour in real world units that can be immediately interpreted. Digital measurements can be transmitted across existing mine-wide wireless communication networks, interfaced directly with infra-red enabled PDA?s or PC?s, and parsed to memory by low-cost data-loggers.

Apr 1, 2005

By J. W. Smith, J. G. Eacott, D. H. Napier

"Three hydrometallurgicat processes (Noranda chloride leach, B. C. Research biological leach and Sherritt-Cominco activated oxygen leach) and the Noranda pyrometallurgical process have served as the basis for design projects in the final year of the chemical engineering program at the University of Toronto. Each member of a team of five or six students devotes about 200 hours to the project and the final report is expected to include an economic analysis.None of the processes has been developed to full- scale plant, nor, in the case of the B.C. Research and Noranda processes, were pilot plant data available. Nevertheless, the designs developed provide a useful basis for a preliminary estimate of capital and operating costs and for a preliminary assessment of project feasibility.This paper discusses the approach used in the design projects with respect to engineering and economic aspects, and outlines the educational features and benefits of such a program as well as some of the problem areas that arise.IntroductionAs part of the undergraduate degree course in chemical engineering at the University of Toronto, students devote some 200 hours to a design project in their final year. Hydrometallurgical processes, not yet proven at the commercial scale, have been selected for study. The students are required to develop laboratory and / or pilot scale results into a conceptual plant design, using sound engineering principles. Capital and operating costs are then determined and a preliminary feasibility study and economic analysis are carried out."

Jan 1, 1986

By L. Mohammadi

Outline ?Background on the accident at the Sullivan Mine No.1 Waste Dump ?Holistic approach to understand the reason for accidents (Atmospheric) ?Specific hazards at reclamation sites ?Regular atmospheric risk assessment at reclamation sites ?Fuzzy risk assessment ?Managing risk at legacy sites

May 1, 2010

By W. N. B. Armstrong

CORROSION of metals, for the purpose of this talk, may be divided into two general classes, namely, atmospheric and chemical. Atmospheric corrosion is caused by the natural agents -water, air, salt, and temperature -as well as by the agents arising from industrial operations which pollute the atmosphere. Chemical corrosion affects metals in refineries and chemical plants where severe conditions exist due to .acids, alkalies, salts, solvents, gases, ?steam, etc. A special condition is encountered on road equipment and motor vehicles due to the large amounts of corrosive salts which are used on our roads in the winter. Exposure to corrosive conditions such as those referred to above causes metal to be destroyed and, therefore, it has to be protected. The non-metallic or organic coatings used to protect the metal are themselves destroyed ultimately by these same conditions. Since all types of organic coatings do not have the same kind and degree of resistance to degradation, a particular kind of -coating must be used for a particular set of conditions in order to obtain the maximum benefit. In ?addition to the above mentioned agents, organic coatings are degraded ?by sun-light, which is probably the severest single factor in the breakdown of organic coatings exposed outdoors. We can divide organic coatings, in a general way, into the following classes: (1) Conventional coatings, and (2) Special coatings.

Jan 1, 1958

By M. Behrouz

Thermal power plants convert thermal energy due to nuclear reactions or the combustion of coal, gas, heavy oil, or some other hydrocarbon to electrical energy. They consist of a variety of equipment, such as boilers, turbines, generators, cooling towers, and auxiliary equipment. Any factor that affects the equipment efficiency affects the overall efficiency. Analysis of the cooling tower and raw water using the Langlier Saturation and Ryznar Stability Indices showed that the cooling water at Sarchesmeh was slightly scaling with respect to silica. Cold lime softening was found to be a cost-effective method to produce cooling water with adequate properties to reduce the cooling water make up from 85 to 70 m3/h and blow down rate from 35 to 20 m3/h.

Jan 1, 2007

By F. K. McKean

THE task of establishing a new corrosion testing laboratory is more difficult than it need be because there is very little information on the subject available in the literature. Many articles describing tests and results may be found, but a wide search will unearth only passing remarks on the different types of equipment that may be selected for accelerated corrosion tests. An article describing some of the apparatus needed in a corrosion laboratory should be of help to those interested in building a new unit or in making additions to an old one. In May of this year, the writer was given the assignment of equipping a laboratory for general corrosion testing, to form a part of the new Physical Metallurgy Research Laboratories of the Department of Mines and Resource~ at Ottawa. With the help of senior members of the staff, along with what could be gathered from other sources, a list of necessary equipment was compiled and a plan for arranging it in the rooms was decided upon. Where possible, the apparatus was constructed in the excellent machine shops at the disposal of this Department, while the rest was placed on order with the manufacturers.

Jan 1, 1945

By Z. Bibak, S. Banisi, A. Ghasemi, E. Nematollahi

"The major importance of liners in grinding is their role in providing an appropriate trajectory for the charge. Since it is not possible to study the charge movement by direct observation in operating industrial mills, this task is accomplished by physical (laboratory), and/or, mathematical (software) methods. Because of the high cost and a longer time required for a physical analysis, mathematical simulations have become more common. Simulation of the effect of liner shape on the charge movement has provided a means to select a proper design based on the operational objectives and conditions. Furthermore, the liner shape changes due to wear and impact during operation, which will influence the charge trajectory. This adds more of an incentive to use simulation. These changes in liner could be predicted through liner profile measurements during operation and/or simulation. In this research, an inhouse developed DEM software called KMPCDEM © was used to simulate the charge movement in industrial plant SAG mills. A geometrical method of implementing the shell liners on SAG mills at the Sarcheshmeh (9.75×4.87 m) and the Gole-E-Ghohar (9×2.05 m) operations facilitated the software simulation. Point by point implementation of the measurements of liner profiles of these mills enabled the study to trend the change in the charge movement as the liners wear. Comparison of the simulation to a laboratory mill (1 m diameter) showed that the difference between the measured and predicted charge impact point, shoulder angle and toe angle were 6, 4 and 3°, respectively.INTRODUCTIONComminution is the most energy intensive operation constituting the major portion of operating and capital costs of a mineral processing plant. In the last decade, a vast number of research was aimed at studying various aspects of grinding with the aim of performance improvements (Davis, 1919; Mishra & Rajamani, 1990; kalala, Breetzke, & Moys, 2008). Mill liners transfer the input power to the charge and play a significant role in affecting the motion of the charge (Mclvor, 1983; Mishra & Rajamani, 1990; Radziszewski, 1997; Van Nierop, Glover, Hinde, & Moys, 2001; kalala et al., 2008). Lifters are usually used with mill liners to extend their life and to enhance the grinding and impact breakage efficiency. Mill lifters are used to raise the grinding media and ore to transfer the energy from the mill to the load (Rezaeizadeh, Fooladi, Powell, & Weerasekara, 2010)."

Jan 1, 2016

By J. E. Carter, D. P. Wall

"This paper details the highlights of the open-pit and underground operations of Mclntyre Mines Limited in the Smoky River area of Alberta. Mining methods, operating equipment and manpower are outlined, followed by a discussion of reclamation and environmental control.IntroductionMcintyre Porcupine Mines Limited was incorporated in 1911 and for many decades was known primarily as a gold producer in the Porcupine district of northeastern Ontario. The company, however , has held coal leases in the Smoky River area, near Grande Cache, Alberta, since 1921. Preliminary studies were carried out in the region from 1959 to 1963. In 1964, Mitsubishi, a leading Japanese trading company, (on behalf of Mcintyre), investigated the area as a possible source of coal for the Japanese steel industry. The initial report concluded that Smoky River coal was of high quality, comparable with some of the best metallurgical coals in the world."

Jan 1, 1981

By Paul Guliov

Potash dominates the industrial mineral scene in Saskatchewan accounting for 44% of total provincial mineral production in 1981. More than 7 million tonnes of potash have been produced annualy in recent years; ten underground mines are presently (1983) active. Sodium sulphate and cement are also important mineral products. Construction aggregates, clay products, bentonite, salt, peat moss and sulphur complete the list of industrial mineral products.

Jan 1, 1984

By Larry G. Twidwell, Corby G. Anderson, Camille M. Fleuriault

"The selective precipitation of iron as ammonium jarosite is a well-established industrial technology in base metals hydrometallurgy. It is a key technology in minimizing iron tenors which would be disruptive to downstream processing. It also provides a more readily filterable iron solid to better facilitate materials handling. This paper elucidates the fundamentals behind industrial iron precipitation. Then, the details of the successful optimization of an industrial ammonium jarosite circuit are presented.HYDROMETALLURGICAL IRON REMOVAL FUNDAMENTALS Iron is the fourth most abundant element in the Earth’s crust (5% by weight) and is often found in complex ores such as sulphide-bearing formations. Iron represents an issue though during leaching, a technology which is widely used for the treatment of this type of ore: •,Iron has the particularity of forming hydroxides when leached under certain conditions. Iron hydroxides form a viscous gel, which is difficult to filter and traps valuable elements such as silver. •,Iron is solubilized along with other metals and interferes with the subsequent extraction steps. As a result, purification of the pregnant leach solutions is required to achieve economical extraction of base metals. In the 1960s, metallurgists developed iron precipitation processes for solution purification (Habashi, 1999). Nowadays, precipitation of iron bearing species, such as goethite, hematite or jarosite, has become one of the most common methods used in the industry to purify leach liquors. To be suitable, the precipitate has to be readily filterable and thus must not be too fine of particle size. Precipitation can take place in autoclaves at medium to high temperatures, under an oxygen or air overpressure (Tourre, 1984, Fleuriault 2016, Fleuriault Anderson Shuey, 2016))."

Jan 1, 2016

Purpose of TSUG Continuous Improvement in Mining Share Best Practises Exchange Ideas Network for Frontline Supervisors and Middle Management Meetings ? Two per Year -Spring and Fall ? Thirty Five to Forty Attendees ? Rotate Between Host Properties ? Host Mine Provides ? Meeting Room for One Day Tour of Mine and Maintenance facilities on Second Day

May 1, 2010

By R H. Hallam

The Mattagami mining district encompasses a favour-?able belt of folded Keewatin-type rocks, with intercalated sediments and intrusives of late Keewatin age. This environment has been subjected to periods of basic and acidic intrusion. The orebodies lie within the fold structure and are associated with faulting and shearing of considerable magnitude. The No. 1 orebody contains 60 to 70 per cent massive sulphides. The minerals, in their order of abundance, are generally: pyrite, sphalerite, pyrrhotite, magnetite and chalcopyrite. It is evident that the broad geological structure of the district is amenable to ore deposition. There are two ? prominent linear expressions which comprise this broad structure. Both strike directions lie at the edge of, or are related to, a complex gabbro-anorthosite-peridotite zone. The fact that eleven of the ore zones discovered to date coincide with the broad structure indicates its over-all importance. It is estimated that the production from Mattagami Lake Mines will be in the range of 600 to 700 tons of zinc concentrate and 70 tons of copper concentrate per day.

Jan 1, 1964

By M. C. Ethier, A. L. Laramie

"The Granisle and Bell Copper mines were officially put into production in 1966 and 1972, respectively. The Granisle Mine was purchased in late 1979by Noranda and the two operations were amalgamated as one division. Both mines were closed in 1982after sustaining heavy financial losses during a period of low copper prices beginning in 1981.This paper describes the resumption of operations at the Bell Mine in 1985 after its shutdown period of three years and the dramatic and sustained improvements in productivity and efficiency realized as a result of a commitment by employees and management to the application of Participative Management and Employee Involvement principles. After a general description of the effects of such a philosophy on the operation as a whole, and a comparison to the operation's last full year as a producer, it deals with the practice of this philosophy in the maintenance department at the Bell Mine and the superb results realized.IntroductionThe Bell Copper deposit was discovered in 1963 and came onstream as a 10000 ton s per day open pit mine in the fall of 1972. Identified reserves at that time were 46 million tons of ore containing 0.50% copper. The mine shared facilities of the townsite of Granisle with the nearby Zapata-Granby mine which had established the community six years earlier.Because of easy grinding ore and improvements to milling circuits, Bell's throughput rate was increased to 17 000 tons per day by the late 1970s. In the open pit, improvements resulted in mining of additional reserves with higher stripping ratios. At startup, a half ton o f waste was mined for every ton of ore processed.By the end of 1982, with 48.2 million tons already mined, the Bell Mine had identified additional mineable reserves of 39.4 million tons containing 0.52% Cu.In November 1979 the Granisle Mine was purchased from Zapata-Granby. The two mines, with a total of 700 employees, were operated under common management as the Babine Division until 1982 when low copper price s forced the closure of both for an indefinite period.The outlook for copper prices remained bleak and only 50 people were retained on the payroll to maintain the two plants, most of them working on a part-time schedule.The population of the Village of Granisle dwindled from over 1500 inhabitants to under 500, as people moved away to seek other employment.Prior to the shutdown, the Bell Mine employed 370 people and pit extraction averaged nearly 50000 tons per day of which 16000 tons was mill feed, and the remainder waste. Total cost to produce a pound of copper was C$1.36 in 1982."

Jan 1, 1990

By D. E. Salman, R. R. Maclachlan, R. J. Barclay

"There is a considerable resource of data for spherical charge cratering, both as single charges and in row-of-charge geometr(1). The data are. however, based on cratering performance to a single free planar surface.In practice. the more common circumstance involves an angular surf ace geometry. such as occurs at the toe of a bench or the wall of a stope. It is for the purpose of investigating this circumstance that the described test work was conducted.The test objectives were: (1) to observe the change in single-charge cratering performance between planesurface and angle geometry; (2) to identify the optimum performance of single charges cratering to a plane surface. cratering from a bench sub-grade position and cratering from a condition of zero sub-grade or stope wall geometry; and (3) to observe the performance of row-of-charges cratering to an angular surface at various row burials and spacing. The row charge burial and spacing dimensions were to be expressed in simple numerical multiples of single-charge depth-of-burial data."

Jan 1, 1981