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By Eugene Barsky

"At present, theoretical concepts of gravitational separation processes are mainly limited by the study of the interaction between a flow and a solitary particle. Then the main conclusions of this analysis are applied to a mass process. However, this analysis is absolutely insufficient, because some elementary phenomena such as the ingress of coarse particles into the fine product output and vice versa cannot be interpreted from its standpoint. It is also impossible to predict the results of the classification of a material with a specific granulometric composition on a specific apparatus on its basis.In the present paper, an extended model of the process is suggested. The model is based on the behavior of all the particles of a specific narrow size class, and not on that of an individual particle. Similarity criteria of the process, which were empirically derived previously, are obtained from the analysis of this model.INTRODUCTIONIn case of gravitational separation, a part of solid phase moves, as a rule, vertically upwards with the flow, while another part settles against the flow. This flow is extremely complicated and chaotic due to various random factors. Among these factors are mass interactions of particles with each other and with the apparatus walls, non-uniform character of concentration and velocity fields, turbulent vortices and local fluctuations, real particles shape difference from spherical one, etc.Particles rotation results in a transverse force (Magnus' effect). At the motion of a non-rotating particle in a non-uniform velocity field, a transverse force also arises (Saffman's effect).A great number of publications have been devoted to the account for all these factors in two-phase flows in recent decades. Very complicated models have been developed, but the problem has not been completely solved as yet [1, 3].At the same time, simplified models of the behavior of a solitary particle in a flow are being developed. Despite their schematic nature, such models often prove to be useful for establishing general laws of the process and its similarity criteria [1]."

Jan 1, 2016

By Franz Simon

Conventional fine gold electrolytes for barrel applications working electrolytically actually permit significant precious metal savings by corresponding optimizations but the most gold is still deposited on areas of the components where it is not absolutely essential for the desired bonding and soldering applications, i.e. in high current density areas. Therefore an electrolyte working electrolessly has been developed which inevitably leads to a much more uniform thickness distribution since in an electroless process there are no areas favoured by metal deposition and current distribution. The new electrolyte will be presented and its performance will be compared with conventional electrolytes as regards thickness distribution. The potential gold savings will be discussed.

Oct 1, 2003

By Matthew Novak, J. Brent Hiskey

It is well known that when chalcopyrite is put in direct contact with copper in an acidic medium a galvanic cell is created. Chalcopyrite is reduced to iron and sulfur deficient defect phases such as bornite, chalcocite, and at very low potentials to elemental copper. Galvanic conversion experiments were performed using three chalcopyrite concentrates. The first chalcopyrite contained less than 10% impurity phases. The second concentrate had a high concentration of pyrite, and the third concentrate had a high concentration of pyrrhotite. The effect of temperature, acid concentration, chalcopyrite grain size, copper grain size, and agitation on the rate of chalcopyrite conversion was studied.

Jan 1, 2014

By D. F. Zhang, X. Q. Jiang, N. Tahreen, D. L. Chen, F. S. Pan, D. Y. Li

Alloying with rare-earth elements has been proven to be an important tool for magnesium to achieve superior properties via texture randomization. The role of yttrium in texture weakening and the link between texture and formability are fairly well known. Since annealing is a vital part of metal processing which could significantly contribute to ductility, it is important to ascertain the impact of annealing in terms of texture change. Also, an understanding about texture development during pre- and post-deformation annealing is essential to improve the industrial deformation processing as texture is closely related to formability. While there is independent information in the literature regarding the effect of rare-earth addition and heat treatment on the texture formation, no systematic studies have been reported on the collective impact of yttrium addition, annealing and deformation on texture evolution. The present study was, therefore, aimed to identify the inter-relationship among texture evolution, yttrium content, heat treatment and deformation behavior in an extruded Mg-Zn-Mn-Y alloy. Annealing at 450°C for 1 hour and uniaxial compression tests at a certain amount of deformation were performed. The deformed and annealed samples were then subjected to annealing and compression test, respectively, followed by texture measurements. It was observed that yttrium addition effectively weakened the crystallographic texture in all conditions, which was evident from the changes in the microstructures and textures.

Jan 1, 2015

By K. J. K. Weglo, M. U. Savich

"At the Falconbridge Limited, Canadian Nickel Division, Sudbury Operations, we investigated the ""NO NOISE"" ear muffs model NN3-F which is a Swedish product with foam-filled sealing rings (the Hellberg Standard Volume Hearing Protector). It is used extensively at Falconbridge mines in Sudbury.The research which was carried out in the four Falconbridge mines was conducted under three different headings: manufacturer's attenuation data (psychophysical method), clamping force and head size (bizygomatic diameter), and attenuation tests (physical methods) under working conditions.Manufacturers of hearing protectors claim their products offer noise reductions of 23 decibels (NRR) or more, but they fail to point out that this reduction is obtainable only under ideal conditions. The reality of attenuation under working conditions, as several studies have found, is quite different.Methods for using short measurements to determine the noise exposure index, and for controlling muff-wearing habits, were developed at the Elliot Lake Laboratory. Measurements taken at Falconbridge on ""NO NOISE"" ear muffs revealed that they have a practical attenuation of some IO to 13 decibels. It is important to note here that measurements also revealed that clamping force (thus attenuation) was in an inverse relationship with ear muff comfort. Measuring attenuation using noise dosimeters was a difficult job. Not a single surveyor would accept these measurements (physical method) for absolute accuracy. Apart from that, it was impossible to measure, in one shift, more than two work stations. Because of this, we sought a solution: measuring head size and clamping force in relation to actual attenuations.A detailed analysis of the relationship between attenuation and head size/clamping force was done at four mines. Standard deviation ellipses (standard error ellipses) for head size versus clamping force are in close agreement with measurements that were carried out. In order to measure clamping force an apparatus was constructed and a method for measuring suspension system durability is described in Appendices Band C of this report. At the same time we sought to reduce deterioration of ear muffs in mines as well as to put in place a system whereby attenuation can be controlled and improved. The clamping force apparatus can be operated automatically. The proposed control system is quick, simple and efficient . This system is equally applicable in small and large mining operations, and it can be totally automated and the data computerized for audit of the results. This control system is a new step in controlling ear muff attenuation in working environments.From these measurements of NN3-F ""NO NOISE"" muffs it can be concluded that ear muffs are not the total solution to protect the worker from noise.As the results were evaluated folio wing measurement, Falconbridge switched from the NN3-F ""NO NOISE"" muffs to approximately 90% Mark V ""NO NOISE"" muffs and 10% Mark V MSA muffs. These new muffs showed much better head size versus clamping force relationship and can be expected to produce 14 dBA or better attenuation of noise. RESUMEUne étude des casques antibruit ""NO NOISE"" modèle NN3-F, de fabrication suédoise, avec anneaux d'étanchéité en mousse (dispositif de protection contre le bruit ""Hellberg "" pour volume ordinaire)a été effectuée Ii la Falconbridge Ltd. , Division canadienne du nickel aux installations de Sudbury . Ces casques sont largement utilisés dans les mines de la Falconbridge Ii Sudbury.Cette étude aeu lieuen milieu de travail dans les quatre mines de la Falconbridge sous trois rubriques différentes soit: les données d'atténuation du bruit du fabricant (méthode psychophysique), la force de serrage et la taille de la tète (diamètre bizygomatique), et les essais d’atténuation de bruit (méthodes physiques). Les fabricants de dispositifs de protection contre le bruit prétendent que leurs produits offrent une réduction du bruit s'élevant Ii"

Jan 1, 1986

By George Efremidis, Markos Avlonitis, Elias C. Aifantis, Avraam Konstantinidis

"Nowadays, there is an increasing interest for realistic spring-block models capable of addressing precursor phenomena in catastrophic earthquake-induced landslides. By pre-defining the constitutive law between externally applied stress and induced local strain increments, the dynamic behaviour of the rock/soil slope can be studied by means of the distribution of slip events at the interface between the soil and the bedrock. It is shown that by relaxing the assumption of constant of externally applied stress rate and local strain increments, a robust 2D spring-block model can be formulated for studying triggered landslides. A cellular automaton is built in order to examine the dynamic behaviour and the stability of rock/soil slopes during the initiation of a landslide. The type and nature of the failure plane, as well as the triggering mechanism is studied. The different dynamic evolution modes of the slope can be mapped to specific shape parameters of the corresponding distributions of the incremental displacements. The proposed spring-block model can be used in order to understand, predict and minimize the impact of catastrophic landslides triggered by earthquakes.INTRODUCTIONEarthquakes have long been introduced as one of the major cause of landslides. Earthquake induced landslides are of great importance because they can cause considerable damage and life casualties. Existing analyses can provide landslide concentration, i.e. the number of landslide sources per square kilometer of surface area, as well as the distance from the earthquake source, which is related to the strength of shaking, the slope steepness, which is connected to shear stress, and finally the rock type, which is referred to material strength (Keefer, 1984). In spite of their great importance in social and economic life, earthquake-induced landslides are still considered as an open geotechnical problem. The dependence of the number and distribution of landslides on earthquake magnitude and ground shaking intensities is a crucial factor for the description and determination of the phenomenon. The hazardous types of earthquake-induced landslides, the most susceptible geologic materials and the reactivation of landslides originally triggered by nonseismic activity are some important topics for areas affected by landslides. Most of these areas present an irregular and asymmetric shape with respect to epicenters and fault ruptures, and also show a strong correlation with magnitude (Keefer, 1984, 2000). The number of landslides caused by an earthquake generally increases with increasing earthquake magnitude. Keefer (1984) presented a magnitude scale in order to quantify the number of earthquake-induced landslides. Malamud et al. (2004) have proposed an independent landslide-event magnitude scale on the earthquakes, based on the logarithm of the total landslides number associated with an event. The aforementioned studies try to relate the landslide magnitude scale to the visible effects of the triggering mechanisms."

Jan 1, 2015

By S. Amira

In the last two decades, many new creep-resistant magnesium alloys have been developed for high temperatures applications. Their mechanical performance and corrosion behaviour were reported for various experimental conditions. However, these conditions often led to uneven comparison basis. In the present study the microstructure, mechanical properties and corrosion performance of four of these newly developed creep-resistant magnesium alloys were systematically compared. Specimens were obtained from experimental box-like components that were die-cast and thixocast in comparable conditions. Their mechanical and corrosion properties were compared using similar testing conditions. Results show that the creep resistance, strength and impact resistance of specimens are comparable but systematically lower compared to specimens cast under optimized conditions. The reduced concentration of elements such as Al, Ca, Sr and Ce lead to a decrease of the corrosion resistance of the magnesium alloys in 3.5% NaCI solution.

Jan 1, 2007

By M. Olper

Commercial copper plants utilising current best technology are tending towards ever increasing scale, the concentrate requirements of which cannot be serviced by a single mine. In such cases, raw materials are often sourced from different mines, which are often far away from the production plant and usually with very different ore compositions. These plants tend to use the traditional thermal processing steps of smelting, converting to blister, anode refining and casting to produce copper anodes that are then refined in a sulphate electrorefining operation. These thermal steps are in some cases troublesome and require the recycling of considerable quantities of material. A new process was developed taking advantage of the latest developments of the first thermal step of the classic loop, the smelting of copper concentrate to high grade matte or white metal using the well known AUSMELT Top Submerged Lancing Technology. The white metal and/or high grade matte product is converted directly to copper cathode and elemental sulphur using the ECUPREX technology. This approach provides an alternative to the traditional thermal steps of conversion to blister, thermal refining and anode casting, which, especially at small scale, can be expensive and problematic in terms of technical and environmental concerns. At first evaluation, this new process can be operated at low capacities, thereby, changing the traditional approach to copper production. Instead of taking the concentrate to the copper production plant, the copper production plant is taken close to the mine with some significant economic and technical advantages.

Jan 1, 2007

By J. H. Archibald

"In mines employing cut-and-fill stoping (sand fill), ore passes are built as mining progresses upward. These ore pass raises are generally made from timber and form a vertical ""chimney"", like a very tall log cabin. Traditionally the chimney, or raise, is square in shape and is constructed from square timbers with stepped ends as shown in Figure I. The timbered raise is thus surrounded by sandfill on its outside, leaving the centre open for passing ore down through it. Each layer consists of four timbers and rests flush on the layer below. The corners are frequently pinned or spiked.Under certain conditions in sandfilled stopes large horizontal loads may be transmined to the raise cribbing timbers, or the ""chimney's"" walls. In deep mines, where rock bursts are a problem, it can be shown that one of the conditions for rockbursts to occur is that the burst zone be stiffer and weaker than the surrounding rock(l). This allows a strain energy build-Up in the rock surrounding the burst zone, and the rate of release of this strain energy is known to be related directly to the over-all strength and stiffness of the rock in the burst zone. In stopes that are sandfilled, attempts are, therefore, usually made to increase the strength of the sandfill by the addition of large-sized waste rock and Portland cement. These measures usually achieve the desired strength of the sandfill and, consequently, the severity and frequency of rockbursts can be reduced.Problems may arise when the now chunky sandfill transmits high loads to the raise cribbing along with relatively large move- merits. This leads to heavily stressed and strained cribbing timbers the Coeur d'Alene district in Idaho, raise cribbing failures are common. A typical mode of cribbing failure is shown in Figure 2. One learns in statics that a structure shaped like the crib in Figure I is inherently unstable , at least from a structural standpoint. The crib has pivoted, in Figure 2, into a rhombi c shape and supports very little load. Soon the four-foot square raise cribbing made from 5 in. by 5 in. timbers will no longer pass ore."

Jan 1, 1991

By J. J. Jonas, G. R. Stewart, A. M. Elwazri

Two important parameters for dynamic recrystallization can be derived from the changes in the strain hardening rate: the critical strain for initiation of dynamic recrystallization and the point of maximum softening. In this work, these values are determined from the flow stress-strain data obtained in continuous compression testing in the range 900-1100°C. The resulting strains are used to calculate a kinetic model of dynamic recrystallization for two materials: 304 austenitic stainless steel and a hypereutectoid plain carbon steel. The mechanical parameters used to define the proposed model are confirmed with quantitative metallographic analysis of the recrystallized microstructure.

Jan 1, 2004

By L. I. Kiss, S. Perron, S. Poncsák, A. Perron

Aluminium industry has an increasing interest in the diminution of the energy consumption of the Hall-Heroult process by the reduction of the anode bottom covering with gas. Electrically isolating carbon-dioxide bubbles, produced at the anode, increase the ohmic resistance of the cell. As the gas production rate is determined by the applied current density, anode covering can be decreased only by a faster evacuation of the gas from the inter-electrode space. Among others, the inclination and curvature of the anode bottom promotes the release of the bubbles and thus decreases the mean value of the covering. Indeed, anode, insert in the molten cryolite bath has a square shape with horizontal bottom. However, inhomogeneous anode consumption, electro-erosion, bath circulation and the inclination of the bath-metal interface modify this shape gradually during electrolysis. Anode bottoms become inclined with rounded comers. This concentrates the gas generation to the center zone of the anode. As the bubble layer cannot be observed directly because of the hostile environment and the opacity of the bath, real scale air-water systems are used to study the impact of the anode geometry on the anode covering and the bubble induced flow. However, the physical properties of such a system are different than that we can found in the real cells. A simulator using the Lagrangian description of the bubble layer has been built and presented in earlier papers. This tool was used to investigate the effect of the anode inclination on gas covering and bath velocity, for both C02-cryolite and air-water system. Results obtained for the second system were compared to experimental data .

Jan 1, 2006

By LeRoy A. Thorssen

The use of lightweight aggregate as a constituent of concrete is not a recent development. Pumice was used by the early Romans, in pozzolana cement concretes, in the construction of many of their works. However, the recent development of manufactured lightweight aggregates, such as the expanded shales, vermiculite and perlite, has created a possible use for a whole new group of Portland cement concretes. Concrete can now be produced with unit weights ranging from 30 to 150 pounds per cubic foot and with various insulating, fireproofing, acoustical and structural properties. The tonnage of such materials being used has increased considerably in each of the past ten years, and can be expected to increase for the next several years as availability of the aggregates becomes more widespread and the properties of such concretes become more thoroughly investigated and more generally known. LIGHTWEIGHT aggregates of many types have become avail-able to the construction industry in most localities on this continent

Jan 1, 1963

By J. Gustavsson, S. Holmin, Å. Afvander, E. Rosseland, E. Zimmerman

There are numerous advantages in replacing lead-based anodes with mixed metal oxide (MMO) coated anodes in copper electrowinning; for example, lower energy consumption, improved working conditions for operators and less environmental impact. Since 2012, Permascand AB in Ljungaverk, Sweden has evaluated Permascand coated titanium anodes in copper electrowinning pilot trials at Glencore Nikkelverk in Kristiansand, Norway. The investigation has proceeded in three different steps (Phase I, II and III). In Phase I, different Permascand coatings, electrode structures and coating methods were investigated. The results showed that improved current distribution, lower energy consumption and longer service life could be obtained with expanded mesh electrode structure in a box configuration compared to rod anodes in a single-mode construction. In addition, improved current distribution and less coating wear was found when electrostatic spray coating was used instead of brush (manual) coating. It was also found that the extrapolated service life from controlled lab experiments at 200 A/m2 was much shorter compared to what was experimentally obtained in copper electrowinning pilot trials at similar current densities. This was mainly attributed to different coating failure mechanisms in lab and industrial copper production. INTRODUCTION Traditionally lead-based anodes have been used in copper in electrowinning due to lower cost. But there are many advantages in replacing lead-based anodes with mixed metal oxide (MMO) coated titanium anodes in copper electrowinning, such as lower energy consumption, higher corrosion resistance, improved working conditions for operators and less environmental impact. Still, many facilities are using lead-based anodes, although the progression of using metal oxide coated anodes in copper electrowinning has slightly increased (Robinson et al., 2012).

Jan 1, 2019

By W. Petruk

A study was undertaken to determine whether interrelations between mineral grains affect ore breakage during grinding, and to establish a correlation between ore breakage and mineral liberation. A base metal ore from the Brunswick No. 12 deposit in New Brunswick was ground for different periods of time in a laboratory ball mill, and both the unbroken ore and the ground products were analysed by image analysis. The results show that the mode of breakage is strongly influenced by the behaviour of pyrite. Similar size distributions were obtained for material from the 15 minute grind in a laboratory ball mill, for the grinding circuit discharge from a commercial mill, and for pyrite grains in the unbroken ore. This similarity indicates that a 15 minute grind breaks poorly bonded pyrite grains along grain boundaries, and represents the limit of easy breakage for the ore. Such a grind liberates both large separate grains of ore minerals and poorly bonded mineral grains that occur in interstices among pyrite. On the other hand the 15 minute grind does not separate moderately bonded mineral grains nor release moderately bonded interstitial minerals from pyrite; a 45 minute grind in a laboratory ball mill is required. It is assumed that, for Brunswick No. 12 ore, a 45 minute grind in a laboratory ball mill is equivalent to regrinding in a commercial mill. Grinding beyond 45 minutes in a laboratory ball mill breaks the ore by fracturing pyrite across grain boundaries and by chipping grain edges. Such intense grinding does not markedly increase sphalerite liberation from Brunswick No. 12 ore, because most of the sphalerite that can be released was liberated at the 45 minute grind. In contrast the intense grinding increases galena liberation because a significant proportion of the galena occurs as minute inclusions in pyrite. These findings show that ore breakage and coincident liberation depend upon size distributions, intergrowths, and mode of occurrence of the minerals in an ore.

Jan 1, 1988

By François Charette

High stress conditions in underground mines push the performance envelope of support systems to their limit. In weak rock masses these conditions lead to large deformation and breakdown of the rock material, while stress release events in hard rock mines can lead to sudden and usually violent rock and support failure. In typical support systems, a combination of different reinforcement and support mechanisms provide the required convergence control and retainment. These systems usually involve a multi-pass support installation. The advantages of a single pass support system are investigated and several bolting combinations are compared. Criteria for design are reviewed and new criteria are proposed to include cost and effectiveness in commonly used engineering approaches. Field observation and testing is used to illustrate the difference between the proposed approach and more conventional systems.

Nov 1, 2011

By B. Galy, L. Giraud

"This paper compares Canadian provincial mining safety regulations regarding the use and testing of cage safety catches, including a brief history and evolution. Regulations are similar across provinces, with only slight variations. Currently, the “Ontario-type” safety dog is the most commonly used safety catch in Canada. Performance estimation of the compensation mechanism for different safety-dog shapes and tooth angles show this shape works well and has consistent braking results, but the best efficiency is obtained for initial tooth angles greater than 10°. Miner safety is questionable for lightly loaded cages, an issue that should be addressed technically and legislatively.RÉSUMÉ Le présent article compare les diverses réglementations de sécurité minière concernant les parachutes des cages dans les provinces canadiennes ainsi que les essais qu’ils doivent subir. Il semble que les réglementations soient semblables à travers les provinces avec quelques légères différences ou divergences. Un bref historique des parachutes et de leur évolution est présenté. De nos jours, le parachute de « type Ontario » est le plus fréquemment employé à travers le Canada et il présente des résultats de freinage uniformes. Une estimation de la performance du mécanisme de compensation pour les diverses formes de taquets de sécurité et les divers angles des dents montre que cette géométrie fonctionne bien; cependant, la meilleure efficacité est obtenue pour des angles de dents supérieurs à 10°. La sécurité des mineurs est mise en jeu pour des cages faiblement chargées et ce point devrait être traité du point de vue technique et du point de vue législatif."

Jan 1, 2016

By X Dai

This paper investigated the loss of cyanide via oxidation in CIP or CIL processes by relating the cyanide oxidation to its major oxidation product, cyanate. The results showed that the oxidation of both free cyanide and copper cyanide complexes are substantially enhanced by the presence of carbon. The rate of cyanide oxidation was found to occur in the order: Cu(CN)32- > CN- > Cu(CN)2-. The cyanide oxidation rate in the presence of copper and carbon increased significantly with increasing dissolved oxygen concentration, typical of CIL vs. CIP conditions. Cyanide oxidation rate of iron, zinc or nickel cyanide complexes was minimal.

Jan 1, 2011

By M. Phylli Bray

"Concurrent with the continuing demise of many Canadian mining towns is the rise of a new method of providing remote mine sites with a workforce. This is the Long Distance Commute (LDC) which uses commuter labour and requires no permanent settlements to support the mine operation. It provides a flexible and cost effective method of operation to the industry and relieves both governments and industry of the expense of building and maintaining mining towns. However, little attention has been paid to the effect on workers or their families of the LDC work schedule whereby workers spend a fixed number of days at the site followed by a fixed number of days at home. Off-shore oil rig experience would indicate that negative social impacts may be expected. Research leading to an understanding of the problems involved seems to be indicated. One innovative suggestion has been to use already established but dying mining towns as workforce pick-up points for new LDC operations further north.BackgroundUntil recently, mine towns were considered as a necessary component of mine development. This was a natural symbiosis resulting from the need to provide workforce accommodation close to isolated mine sites. The early mine communities in Canada were often just a huddle of shacks around a head frame. Gradually mining companies began to provide housing which varied from basic duplexes and quads in grid pattern layout to professionally planned and designed towns, either model company towns or the more recent suburbs-in-the-bush, the so-called ""instant towns"" of the postWorld War II era of resource development. The improvement in accommodation reflected the need to attract a stable workforce as mine operations became more sophisticated. City amenities were expected and offered in these mine towns as a way of encouraging a permanent community of mining families. Indeed in towns like Manitouwdage, Schefferville, and others, it was not unusual to find a significant percentage of two- and three-generation families apparently providing the permanent mining communities so desired by mine operators."

Jan 1, 1991

By R. H. Brooks

Blasthole stoping methods were introduced at Birchtree Mine as an alternative to the original cut-and-fill and shrinkage stoping methods. The object was to take advantage of the ore structure and conditions, and achieve increased productivity. This paper outlines the design, operation and economics of three areas which utilized blasthole stoping. The 108areafrom 2300 level to 1500level was converted from cut-and-fill to sublevel blasthole stoping based on a block mining-and-filling sequence. The second area, the crown pillar of 110 mechanized cut-and-fill stope below 500 level, was recovered using horizontal rings drilled from raises within the ore zone. The third area, the 83 orebody from 1300 level to 1100 level, used the vertical crater retreat (VCR) method with large-diameter blastholes. Blasthole stoping has increased productivity and improved operating conditions.

Jan 1, 1979

By Laurence D. Burke

The electrocatalytic behaviour of gold in aqueous media is surprisingly complex and a novel view of gold electrode surfaces is proposed to explain the observed electrochemical responses. The metal surface is considered as a chemically (or redox) modified electrode, with equilibrated, low energy, surface gold atoms functioning as a relatively inert support and low coverage, high energy, protruding gold atoms (or minute clusters of same) functioning as electrocatalytic redox mediators. The protruding atoms are viewed as surface active sites and the complex electrocatalytic behaviour is attributed to the basic instability of the mediators, the diversity (and poor control) of same, and the acid/base (or hydrolysis) behaviour of the oxidized states of the mediators. It is assumed that major advances in the application of gold in the heterogeneous catalysis of gas phase reactions will be accompanied by similar advances in the use of gold in the electrocatalysis area; however, this will require considerable work of both a practical and theoretical nature.

Oct 1, 2003