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By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

Risk management has taken on renewed vigor since the economic crisis of the late 2000s. The resources of governments, individuals, and corporations are being stretched to a point where only the most promising projects move forward. Risk management is a crucial part of the decision making process, yet it remains a broad term that includes disciplines from engineering to finance. A collaborative effort will be necessary to ensure that the most auspicious and appropriate projects are the ones moving forward. Risk management can be quantified to an extent by comparing the likelihood of an instance with the result of consequence of the instance occurring. In this manner it is possible to assign risk factors to instances and ultimately, begin to associate monetary value to the instance. Carbon sequestration is an emerging field that has a number of unique challenges. Risk management and mitigation must be an integral part of the overall picture. This begins with the planning and design phase, continues through implementation and production, site closure, and does not cease until termination of liability. The ability of carbon sequestration projects to successfully assess, mitigate, and recover from leaks will be a decisive characteristic of overall success. The costs of mitigation and failure will need to be analyzed on a test level, but will still need to be reliable enough to extrapolate to a commercial level operation. This paper will build a risk management profile based on case studies and field tests in Tennessee and Virginia. These tests are scheduled to commence in late 2013 and consist of small-scale injection tests in unconventional storage reservoirs with an emphasis on enhanced coalbed methane (ECBM) recovery and enhanced gas recovery. The ultimate goal will be to provide a clear and concise direction to move carbon sequestration from the test phase to commercial scale. While it is necessary from a risk management perspective to analyze all risk points, the scope of this paper will focus on pre-injection risk assessment for carbon dioxide (CO2) leakage potential. Despite the differences between the two tests, CBM compared to shale among other differences, a framework for analysis and mitigation can be developed pertaining to leakage risk. The probability of each type of failure will be assessed and analyzed, and plans to mitigate or reduce these risks will be reviewed.

Aug 1, 2013

By B. Calver, D. J. M. Farnsworth

"As open-pit operations expanded at Pine Point, hydraulic aquifer evaluation was undertaken to establish the criteria necessary for the design of a feasible dewatering system.The extreme climate of this northern location dictated that the ore zone under extraction be rendered as dry as possible to minimize freezing effects. The design and implementation of such a system necessitated detailed hydraulic evaluation, and the problems that occurred are typical of those inherent in open-pit mining operations in northern areas.The paper describes the problem solution as approached from a mine engineering point of view, with particular reference to the practical aspects of operation and installation. The hydrological analysis used is simple and readily applicable to most open-pit dewatering problems."

Jan 1, 1969

By H. Attia, S. Engin

This paper presents a practical approach for determining the optimal spindle speed and the depth of cut in a milling operation within the ever-increasing economic and technical constrains. Analytical modeling and experimental work has been carried out to predict chatter in such operations. The stability lobes determined from this analysis were then used as a constraint in the optimization of the cutting process. The optimal cutting conditions are determined for two different objectives: maximum metal removal rate and minimum cost per unit. It is demonstrated that this approach can be generalized to impose multi-level constrains, e.g., surface integrity and machining accuracy. The approach presented in this work was examined and validated on three NC milling machines. The productivity improvement, cost reduction, while respecting part quality requirements, is demonstrated.

Jan 1, 2006

By M. Jackson, R. McDonald, T. Osken, D. Robinson

"The addition of sulphidic materials in the leaching of nickel laterites has several potential benefits that include improvements in the rheological behaviour of the blends, reductions in the sulphuric acid and steam requirements, sweetening of the nickel grade of the combined feed material, and the option of using a range of sulphidic materials. The current study examines the oxidative processing of 30% w/w blends of nickel concentrate and nickel laterite ore at 250oC. In particular, the viability of using low oxygen overpressures was examined for significant amounts of nickel flotation concentrate, up to 12% w/w. Further to this the impact of process water quality, in particular the presence of chloride, upon the kinetics of extraction and the mineralogy of the residue were also investigated. This paper will present the results of preliminary work in this area.INTRODUCTIONThe use of sulphidic ore as a source of sulphuric acid during oxidative hydrometallurgical processing is not a novel idea and can be traced back over forty years (Seidel & Fitzhugh, 1968). A series of patents pertaining to application of this approach for laterite ores can be subsequently found (O’Neill, 1973; Opratko et al., 1974; Rodriguez, 2008a, 2008b; O’Callaghan, 2010; Liu et al., 2011) and a few of articles containing published data (Ferron & Fleming, 2004; Quinn et al., 2009). The use of pyrrhotite tailings as a source of sulphuric acid has also been employed for the leaching of converter slags (Perederiy et al., 2011).It is known that hydrometallurgical operations such as the HPAL plant at Murrin Murrin have added small amounts of sulphides as either transitional (mixed sulphide/oxide) ore or non-smeltable concentrate. This can improve the rheology (Rodriguez, 2009) and provide heat credits. However these plants are generally limited in their ability to add such materials due to their reducing nature and given under highly acidic conditions that the breakdown potential of the titanium used for the autoclave lining is significantly reduced. A suitable oxidant must therefore be present to ensure the potential remains sufficiently high."

Jan 1, 2012

By Ralph V. Stewart

"The asbestos orebody is contained within ultrabasic rocks of Precambrian age, being located in the continuous permafrost zone of the Quebec Ungava Peninsula, some 300 miles north of the tree line at approximate latitude 61'49' and longitude 73°58'.The asbestos deposit is at the western tip of a folded ultrabasic sill complex which trends northeast and covers an elliptical area 4.5 miles wide by 15 miles long. Locally. the asbestos occurs in. a completely serpentinized dunite rock. The principal rock types in the vicinity of the ore-body originally consisted of dunite, peridotite and pyroxenite, all of which have experienced at least two periods of alteration, so that no fresh rock now remains.The main ore zone in the open pit is approximately one quarter mile in length, 150 to 200 feet in width, and plunges at 25 to 30 degrees in a northeast direction below surface, to a vertical depth of at least 1,200 feet, Consider¬able tectonic activity resulted in favourable structural conditions which culminated in the formation of the ore zone in its present form.The deposit consists principally of cross-fibre ""gash type"" veins which vary in length from several inches to several feet. The principal fibre vein direction is parallel to the dip of the enclosing serpentinized dunite and sill complex.Some of the problems encountered during diamond drill¬ing in permafrost are briefly discussed."

Jan 1, 1976

By C. A. Lavery

A DISCUSSION is presented of natural gas production and field processing equipment as now utilized in the gas producing areas of the United States, with reference to use of such equipment in Canadian gas areas. The scope of the paper is confined to a general description of various types and methods of using surface production equipment. The discussion is divided under two general groups: well-head production equipment, and field processing. The first will be concerned primarily with indirect heaters, separators, knockouts, and special versions of this equipment. The second major group includes the field processing equipment for handling natural gas. A delineation should be made here as to the meaning of field processing as used in this discussion. We will limit our term to mean such processing equipment as may be used in producing fields to process gas or its by products in a manner that does not require conventional plant practices either in operation or supervision. This covers such equipment as is necessary to complete preparation of gas for sale to pipeline and/ or is necessary to recover valuable components. Under this heading we will discuss glycol dehydration, solid desiccant dehydration, low-temperature separation, mechanical refrigeration, and desorbtion-stabilization. These are all processes involved in preparing gas for final sale or disposal. They do not include the more conventional and large-scale plant process systems.

Jan 1, 1956

By M. M. Williams

WESTERN CAN ADA'S coal industry has experienced a serious set-back since 1949, following a pattern well known to its counterpart in the United States. The loss in coal markets in Western Canada has been particularly severe as the discovery of large reserves of oil and natural gas and the subsequent construction of re-fineries and pipelines roughly coincided with the dieselization of both main railways. While the coal industry will have to face a further decline in markets of long standing, others with a large growth potential can be se-cured if present marketing methods are changed where needed and if fundamental and applied research programmes are actively pursued. The energy and chemical potential of Western Canada's coals will eventually find their place in the ever-growing needs of industry and electric power producers. Electric power generation would appear to offer the largest and most immediate market for coal. If the coal industry is to serve this market adequately and gain as much of it as possible, coal operators ? must have a good knowledge of certain characteristics -of the electric utility industry and its fuel requirements. This paper is prepared primarily to set out some of these characteristics, but also discusses other probable markets for coal.

Jan 1, 1958

By R. N. Chakravorty

Early detection of spontaneous combustion is of utmost importance in underground coal mining to prevent major disruptions of production and to ensure a safer working environment. This paper presents the work done in developing a suitable system for the early detection of heating in a hydraulic coal mine. Laboratory studies on the products of oxidation for Balmer 10 seam coal showed that a significant amount of carbon monoxide is produced during the early stages of heating and that detection methods based on the analysis of other gases, such as hydrogen, ethane or ethylene, are not a better alternative for this coal. The four-point carbon monoxide monitoring system recently installed at the hydraulic mine is discussed in this paper. It is believed that by studying the trend of carbon monoxide concentration in the mine air, it will be possible to detect heating at an early stage. Field tests carried out so far have indicated that infra-red technology will prove to be a powerful tool in the hydraulic mine, particularly for locating hidden oxidation or fire in cracks, fissures, underground workings and coal outcrop areas before it spreads extensively. The project is jointly sponsored by EMR, CANMET, Mining Research Laboratories and Kaiser Resources Ltd.

Jan 1, 1978

By Jehan Rondot

Les bancs de quartzite inhabituellement purs et epais decouverts lors de la cartographie geologique de la region de Charlevoix sont maintenant entres au stade de !'exploitation et se revelent etre une richesse naturelle durable pour cette region. Les etudes stratigraphiques effectuees dans cette partie (Quebecia) du bouclier canadien indiquent que la succession: lo. complexe a amphibolite et leptynite a la base, 2o. quartzite et gneiss a sillimanite, muscovite et gneiss calcosilicate et conglomeratique au sommet est constante sur de grandes distances (de Charlevoix a la Basse Cote Nord) et represente une sedimentation continentale et de plateforme, peu epaisse, du proterozotque inferieur. La purete et la grande epaisseur du quartzite s'expliqueraient par un processus de sedimentation continentale complexe ou se succedent climat tropical-humide et glaciaire-aride et transport fluviatile et eolien. Parmi la multitude de depots de quartzite qui existent dans le monde, peu sont de qualite superieure. Or, de par sa composition chimique, le quartzite de La Galette se compare avantageusement a ceux des meilleurs gisements des Etats-U ni s, de l'Europe de l'Ouest et de I' Afrique du Sud. D'acces facile pour l'exploitation, les gisements ne sont qu'a une quarantaine de kilometres de Baie Saint-Paul ou de La Malbaie, sur le SaintLaurent. L'utilisation en metallurgie du quartzite de La Galette comprend la production de silicium, de ferro-silicium et d'autres alliages de silicium . La composition du quartzite est en outre appropriee pour la production de carbure de silicium et de silicate de sodium. Les fines peuvent etre utilisees pour la fabrication du verre et comme matiere de charge.

Jan 1, 1984

By Magella Pelletier

"IntroductionDepuis une vingtaine d'année, les nombreux travaux de géochimie effectués par l'industrie privée et les milieux gouvemementaux ont permis:• de découvrir de nombreuses zones minéralisées a valeur économique;• d'identifier et de vérifier certains patrons de dispersion géochimique au-dessu s de secteurs minéralises déjà connus;• de favoriser le développernent des techniques analytiques;• de forcer le développement d'une mise en carte des résultats d'analyse, qui soit plus adéquat afin de permettre une meilleure interprétation géochimique.L'une de ces cartes géochimiques qui permet le mieux de mettre en valeur les données analytiques et qui fut instaurée au debut des années 80, est la carte d'interprétation géochimique par pondération.Cette carte numérique semi-quantitative, qui est construite à partir des données de base et de l'importance des éléments indicateurs pour une substance donnée, permet d'identifier et de définir des zones possédants de fortes probabilités pour la recherché de sources minéralisées."

Jan 1, 1987

By John H. Walsh

"ForewordThis paper is to be published in two parts in succeeding issues of the CIM Bulletin. In Part I, the problem of global climate change is explored together with a summary of the government's present policy in this field. Implications for the steel industry are examined as are possible strategic responses. Part II of the paper will present a new possibility - the joint production of iron and liquid fuels useful for transportation purposes. In the joint production case, the objective is to use carbon for more than one purpose in what might be termed a 'carbon cascading' technique. ABSTRACTIt is becoming increasingly probable that emissions of carbon dioxide from the fossil fuels will have to be reduced to deal with the threat of global warming. This issue is likely to be resolved one way or the other in the period 1995 to 2000 which does not leave much time to develop responsive options. In the intervening period, the policy of the Government of Canada is to stabilize emissions of greenhouse gases at their 1990 level by 2000, by encouraging greater efficiency in the use of energy. Should further reductions prove necessary, economic instruments would probably be employed but these would not be applied before a comprehensive international agreement is reached.There are three main themes in this paper: it is assumed that measures to control carbon dioxide emissions will in fact be necessary by the tum of the century; that there will be a rising need for liquid fuels to supply the world's steadily growing fleet of motor vehicles for many years to come, and that the future niche for Canada 's industry in such a carbon-constrained world will be the operation of the energy-intensive industries with efficiency and environmental sensitivity.The steel industry, as a large user of both coal and energy in other forms, would be significantly affected by a need to reduce carbon dioxide emissions. This paper first examines what might be called the conventional responses open to the industry in such a situation and then explores a new possibility for making better use of carbon by the co-production of iron and liquid fuels."

Jan 1, 1992

By X. W. Yi, Z. J. Li, G. W. Ma

In this paper, the compressive strength and failure patterns of reinforced cemented paste backfill (CPB) were studied aiming to promote the stability of backfilled stopes. The concept of ductile backfill was proposed and a series of unconfined compression tests were carried out on both non-reinforced and reinforced cemented paste specimens. Portland cement (3% to 5% by weight of tailings) and five different types of ductile materials (0 to 0.5% by weight of solids) were employed in this experiment for the specimen preparation. The test results showed that inclusion of ductile materials enhanced the unconfined compressive strength (UCS), reduced the post peak stress loss and transformed the failure behaviour of specimens from classical brittleness to ductility. The strength of CPB reinforced with different proportions of polypropylene fibres was compared. The stress-strain curves illustrated that both cement and fibres contributed to the increase of UCS, but higher strain values at the peak stress were achieved by fibre reinforcement. CT sliced images acquired from X-ray computed tomography (CT-scan) demonstrated that the reinforced specimen developed irregular crevices at the edge of cross sections and gained the capacity of bearing large displacements owing to the mobilised tensile strength of fibres. It leads to the potential of avoiding unexpected falling blocks of CPB when adjacent mining occurs. This finding highlights a strategy to improve the self-supporting capacity of the fill mass with less cement usage and reduce the ore dilution rates when excavating to adjacent stopes.

Jan 1, 2015

By S. Orangi

A representative sample of ramming paste from a peripheral seam in an aluminium electrolysis cell was taken in order to develop a process to fabricate ramming paste samples in the laboratory. To this end, paste material was compacted in multilayers in a mould designed to be representative of peripheral seams in Alcoa's smelters. The density distribution in the representative sample was measured ranging from 1.51-1.76 g/cm3. The density range obtained by the proposed methodology in laboratory is 1.47-1.77 g/cm3. The results demonstrate that the proposed fabrication method adequately duplicates paste density from the cell for both one and two layer compaction. Finally, preliminary results related to the compressive strength and Young's modulus of laboratory samples were obtained at various temperatures and are presented in this paper.

Jan 1, 2011

By O. Lashkari

Manipulation of pouring temperature is an efficient way to produce different microstructural features. In order to characterize the microstructure of rheocast billets due to different superheats of 615-695 °C, the parallel plate compression method was employed. Foundry 356 Al-Si alloy with different morphologies of primary a-Al particles were tested at different initial pressures of 4,8, 11,2 KPa, The resulted strain-time graphs were further treated mathematically to calculate viscosity of SSM billets. The interrelationships of viscosity, the microstructure and primary phase flow during compression are discussed, It is shown that the dendritic primary a-Al structure has the highest viscosity number which is almost three orders of magnitude greater than those for globular morphology, The current research have, for the first time, shown the validity and reliability of "parallel plate compression viscometry" method in characterizing microstructural evolution of Rheocast SSM billets.

Jan 1, 2005

By E. Godin, M. Rigaud, S. C. Panigrahy, I. Malinsky

"RésuméDes boulettes de concentres d'hématite spéculaire à basse silice ont été produites en substituant la bentonite par de la tourbe, adéquatement traitée, additionnée d'une faible quantile de soude caustique durant le boulettage. La réductibilité de telles boulettes et leur gonflement pendant la réduction ont été évacues, en utilisant quatre mélanges gazeux différents, formes de H2 - CO - N2.L'influence du pouvoir réducteur du gaz utilise, sur le gonflement des boulettes, à été mis en évidence. Quelles que soient ces conditions réductrices, les propriétés mesurées sur les boulettes liées a la tourbe sont comparables aux propriétés obtenues avec des boulettes traditionnelles liées à la bentonite.ABSTRACTAdditions of peat moss and small quantities of NaOH during balling of low silica specular hematite concentrates have eliminated the need to use bentonite as a binder. The reducibility and swelling of such pellets have been evaluated using four different gas mixtures, consisting of H2 - CO -N2. The influence of the reducing power of the gases, on the swelling behaviour of pellets has been documented. Under the different reducing conditions, this new type of pellets exhibit properties similar to the ones obtained using bentonite."

Jan 1, 1987

By C. O. Staples, J. G. Morrow

The application of cationic flotation to the upgrading of magnetic concentrates was investigated in the laboratory by both batch and continuous test procedures. It was found that the collection of coarse gangue particles with amine, heretofore considered a serious obstacle to this particular application of cationic flotation, is greatly enhanced by a drastic reduction in what might otherwise be considered normal impeller speed. Gangue flotation is in-dependent of variations in the rate of aeration. The collector and Crother additions and the impeller speed which favour the formation of a matte froth yield optimum results.

Jan 1, 1966

By Fazel G. Jahromi, Ahmad Ghahremaninezhad

Enargite (Cu3AsS4) is a major complex copper mineral and often is a carrier of invisible gold particles. Pyrometallurgical treatment of enargite is challenging due to the arsenic release to the environment. Hydrometallurgical treatment, on the other hand, appears to be a promising alternative for enargite processing. In an atmospheric enargite leaching process both the copper and arsenic from the mineral can be leached into a sulphuric acid solution and the arsenic can be simultaneously precipitated as ferric arsenate. The unlocked gold in the residue then can be recovered in a subsequent cyanidation circuit. The downside of the atmospheric enargite leaching in sulphate solutions is the slow leaching kinetics. In this study the effective parameters of the atmospheric enargite leaching process in ferric chloride media were investigated. All the experiments were carried out at temperatures below 100 °C. The process parameters that were investigated in this study included ferric, chloride, sulphate and cuprous concentrations, temperature, mixing rate and leaching slurry pulp density. It was found that the copper recovery rate increases with the addition of cupric chloride and also with raising the temperature. The highest leaching kinetics and the highest overall copper recoveries were achieved when cupric was initially added to the leach solution and at 90 ºC.

Jan 1, 2015

By W. R. Lindsay

Considerable attention has of late been given to the blasting of large amounts of ore in one operation, on account of the saving in labour and explosives and consequent low cost per ton, and also on account of the additional safety to employees. The blast here described, at the Hidden Creek mine. at Anyox, B.C., is not necessarily unique either in size or methods employed, but some interesting p10blems were encountered and the solutions of these may be of interest to others engaged in similar work. The ore consisted mainly of old scope-bottoms and sill pillars, although there also were some braces and parts of vertical pillars included. Some of the stope-bottoms were overlain by caved waste, and one of the problems was to break them in such a manner that the maximum amount of ore could be recovered without serious dilution with waste. The ore blocks, designated as the 385 silt and the 7 A-103 blocks, were under preparation for blasting for over a year, as conditions permitted. This work consisted in drilling long machine drill holes, varying in length from 14 to 20 feet. These holes were drilled with the Numa detachable bit, made locally, starting at 2~-inch diameter and bottoming at 2 inches for the longest length. The long hole drilling was used in the thinner sections of the area. For the stronger, thicker portions, powder drifts (3 ft. by 4 ft. in section) were driven for the powder charges. Reference to the plan and sections (Figures 2 co 8 inclusive) show the relative location of these, as well as the long drilling. The amount of explosives used in the powder drift charges averaged 0.25 pounds per ton of estimated burden, varying from 0.2 to 0.3 pounds per ton.

Jan 1, 1934

By L. Don Leet

Abstract Earthborne vibrations from blasting and other sources, including rock bursts, can now be recorded effectively. The nature and magnitude of vibrations from various sources have been investigated and certain applications of the knowledge thus gained have been made. Vibrations from blasting have been measured on special equipment over a range from an electric blasting cap at a few feet, through the largest quarry shot in history to date ( 1,-362,985 lb.), to the first atomic bomb, in uew Mexico on July 16th, 1945. Laws relating amount of explosive to amount of vibration at different distances have been developed and tested. Special studies have been made of the effects of vibrations on buildings, particularly from the standpoint of possible structural damage. Recorded vibrations are used to study the effects of modern short-period delay shooting. It ?has been found that short-period delay firing is extremely effective in reducing vibrations under the right conditions, but with certain limitations. In quarry shooting, there appears to be a minimum number of holes below which vibrations are not appreciably reduced by short-period delay firing. In several instances this minimum has been near 7. Vibrations in the ground from rock bursts and the effects of mining in stresesd ground have been studied both underground and on the surface in a search for a rock burst warning system. Introduction Earthborne vibrations from blasting and other sources, including rock bursts, can now be recorded effectively. Analyses of blasting records have been yielding increasing funds of information of practical as well as theoretical interest. The nature and magnitude of the vibrations have been investigated with special reference to their effects on structures.

Jan 1, 1951