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By E. Ghali, N. Sorour, G. Houlachi

"The binary Fe53Mo47 and ternary Fe54Mo30P16 coatings have been electrodeposited from citrate-based electrolyte on mild steel (MS) substrates. The electrodeposition has been conducted for 6 hours at 20 mA cm-2 and 30°C. The electrochemical tests were carried out in chlorate solutions containing 300 g L-1 NaCl and 4 g L-1 K2Cr2O7 at pH 6.4 and 80°C. A number of surface characterization techniques such as SEM-EDS, XRD and EMP were used to study the microstructure of the alloys. The electrocatalytic activity of these coatings was investigated using steady-state polarization and galvanostatic technique. This study revealed that the Fe-Mo-P coating could be considered as a promising cathode material for the hydrogen evolution reaction (HER). The results showed an important decrease of hydrogen overpotential for Fe-Mo-P alloy as compared to that of Fe-Mo and especially MS which is a traditional cathode in chlorate industry. The HER overpotential for Fe54Mo30P16 at current density of 250 mA cm-2 was decreased by 30% in comparison to that of MS (1029 mV), and by 16.5% to that of Fe53Mo47 coating (857 mV).INTRODUCTIONSodium chlorate is used for manufacturing of several daily consumption products. This chemical is mainly employed for the production of chlorine dioxide (ClO2) that is a bleaching agent used in the pulp and paper industry. The ClO2 is also consumed for generation of perchlorates, chlorites and other chlorates, as an herbicide and in uranium processing (Cornell, 2002). Sodium chlorate is produced industrially via following overall formula in un-divided electrochemical cell (Nylén & Cornell, 2009):"

Jan 1, 2016

By D. Gorc, T. M. Fraser, Z. T. Nikic, R. Pesalj

"Mount Polley is an alkalic porphyry copper-gold deposit of Lower Jurassic age within the Quesnel terrane in south-central British Columbia. The silica-saturated Mount Polley intmsive complex is assumed to be coeval with volcanic rocks of similar composition in the Nicola Group in which it was emplaced. Other intmsions and some of the volcanic rocks in the Mount Polley area are silicaundersaturated and contain feldspathoids.The Mount Polley deposit is characterized by multiple intrusions that vary from diorite to crowded plagioclase porphyry to monzonite. Intmsion breccias are associated with some of the intmsive phases. Abundant hydrothermal breccias occur on the margins and above plagioclase porphyry intmsions. These breccias provide the main host for mineralization and are associated with the highest concentrations of copper and gold. The breccias are subdivided into four distinct types based on the dominant hydrothermal mineral in the matrix. Actinolite breccia is developed in an elongate zone within the core of the Central zone and grades laterally and vertically into biotite breccia to the southeast. Magnetite breccia is irregularly distributed and is relatively sparse throughout the deposit and albite breccia is dominant in the West zone. Pervasive and vein-related alteration correlates with the breccia types. The core of the hydrothermal system at Mount Polley is subdivided into three zones: actinolite, biotite and K-feldspar-albite. The margins of the core zone are overprinted by a discontinuous zone of calc-silicate minerals. This intermediate zone passes outward into propylitic alteration. Mineralization is most prominent within hydrothermal breccias and is generally present as disseminations, blebs within the matrix and abundant veins. Mineralization is associated with a chalcopyrite-magnetite-bornite assemblage in the core of the deposit passing out into magnetite-pyrite-chalcopyrite. Relatively constant copper to gold ratios suggest that both metals were precipitated under similar conditions.Hydrothermal breccias are genetically related to the emplacement of the crowded plagioclase porphyry melt. Crystallization of the melt was probably accompanied by volatile/aqueous exsolution, forming a water saturated carapace. Decompression of the chamber in response to magma withdrawal, fracture propagation and possible fault movement allowed hydrothermal brecciation to occur at the apex and margins of the intmsion. Alteration and mineralization appears to have been controlled by fluids migrating away from the plagioclase porphyry."

Jan 1, 1995

By J. P. Nicoud

"The Frog's Leg project is located in the Kundana mining centre 22 kms West of Kalgoorlie, in Western Australia. The Mines and Resources Australia (MRA) Dioro Exploration Joint Venture has had considerable exploration success centred on the high grade Frog's Leg discovery. A gold resource of 930,000 ounces has been defined. At Frog's Leg there have been three discrete resource domains recognised - Supergene, Contact, and Quartz Lodes. This paper describes the metallurgical test work undertaken.The selection of the drill core was a joint effort by the MRA Senior Geologist and Mineral Engineering Technical Services (METS) to ensure the samples were representative of the ore body. Optimisation of gold recovery was essential as both the Contact and Quartz Lodes have exceptionally high percentages of free gold as well as significantly higher grades than the typical open pit ores found in Western Australia. The metallurgical scope of work included documenting all of the metallurgical test results, establishing the comminution characteristics, determining the percentage of gravity recoverable gold, evaluating the cyanide leach characteristics and determining the tailings characteristics. These studies were used as the basis of flow sheet design to treat both ores and to discuss the advantages and disadvantages of alternative flowsheets. Investigations also included toll milling options at various plants as well as second hand and transportable plants. Considerable technical effort has been put into ore characterisation by way of test work aimed at managing the process risk at each stage of project development, including mitigation. MRA also carried out detailed mineralogical analysis of the ores."

Jan 1, 2005

By S. Setayeshgar

The identification of potential accidents on construction sites has been a major concern in the construction industry and it needs a proactive safety plan to reduce the risk of accidents. There are no efficient methods for checking if safety measures are taken properly on construction sites. Consequently, workers on site are not given enough awareness about dangerous areas. In addition, construction sites are dynamic and on-site situations are changing in terms of permanent and temporary structures and facilities. This information can be represented using Building Information Modeling (BIM). This paper proposes the integration of BIM and safety risk analysis by considering the risk levels associated with the work spaces of different construction tasks. Work spaces are generated in a BIM model according to the Work Breakdown Structure (WBS) of the project, reference objects in the BIM, and the schedule and resources of the task. Each work space is assigned to one or more tasks or functions, e.g., work spaces for specific tasks, shared spaces (paths), storage spaces, or spaces prohibited to workers. The assignment of work spaces is based on the workers, equipment and materials involved in the task. All the work spaces are associated with a specific duration according to the schedule of the project. Then risk evaluation of the construction site is applied in order to evaluate safety risks based on their severity and the degree of exposure of workers. For example, work spaces for storing hazard materials and for heavy construction equipment have higher risks than other work spaces. The results of the risk evaluation can be visualized in a 4D BIM model.

Aug 1, 2013

By V. Loya

Metallic foams (MF) are relatively new materials with a combination of attractive properties (permeability, high surface area, thermal and chemical stability, etc,), They can be produced from different materials and can be manufactured using various processes, Due to their unique properties, they find applications in different sectors of engineering, such as energy absorption, filtration, heat dissipation, etc, For many applications, the permeability is an important parameter to characterize and optimize, Most of the recent literature on the subject studied the permeability in the low velocity range. The present study was carried out to have a better understanding of permeability for greater velocity ranges, An equipment was designed and built for this purpose, Pressure drop measurements were made across the thickness of open-cell nickel foams, Pore and window sizes were measured by image analysis on SEM micrographs, The experimental results are in relatively good agreement with the Hazen-Dupuit-Darcy model (R2>98%), The permeability is affected by pore size, porosity and the normalized projected area of the connecting pores (ie. windows).

Jan 1, 2005

By Maurice Morton

THE use of organic and inorganic stains has found wide application as a means of detection and estimation of organic fibres. Such stains have enabled the analyst to distinguish between organic fibres of different type and even between wood fibres produced by different processes. Among these stains, aqueous iodine solutions have figured prominently, as in the case of the well-known Sutermeister and Herzberg stains. At the Johns-Manville laboratories, the idea of applying a stain to asbestos fibres was first considered solely as a visual aid in the microscopic examination of such fibres. The staining medium used in this work consisted of a 1 per cent solution of iodine in C.P. glycerine, the latter being used extensively here as a dispersing and mounting liquid for asbestos fibre. This iodine solution was found to have distinct staining properties when used on the local chrysotile fibres, and to improve greatly their visibility under the microscope. It was soon revealed, however, that this staining is apparently limited to the chrysotile variety of asbestos, as against other varieties. It can be readily seen that, if such were the case, the staining test would become a very useful tool in differentiating between chrysotile fibre and the other mineral fibres, without recourse to a lengthy chemical analysis. Hence this investigation was launched, with the purpose of obtaining more information as to the selectivity of this stain as well as its mechanism. The only previous work of this nature that could be found in the literature was that of Van Winsen and Graham (1, 2, 3) on the adsorption of erioviolet dye by serpentine and related magnesia minerals. However, these authors did not refer to any specific behaviour of chrysotile as against other types of asbestos fibre.

Jan 1, 1941

By A. G. Matyas

Process improvements which have reduced the lead content of slag from the Brunswick lead blast furnace are described. Microscope examination and electron microprobe analyses, supported by the results of slag settling and viscosity tests, showed that typically about 70% of the lead in the lead blast-furnace slag was present in the form of entrained prills of metallic lead. The total lead content was found to increase with the magnetic susceptibility of the slag. Measurements in the furnace settler indicated the presence of a magnetite-rich layer between bullion and slag, arising from high magnetite levels in the slag. This layer was believed to inhibit the settling of entrained lead from the slag. Tracer tests showed that the average slag residence time in the settler was less than 2 minutes. Improvements in coke quality and sizing, which led to a reduction in the slag magnetite content, and the installation of a larger settler and a continuous Roy tapper, have all contributed to a significant decrease in the slag lead content.

Jan 1, 1977

The 2-4D window shown above is the base startup window which allows you to begin a new project. ??Setting up the project is the first step ??The next step is to setup the properties to be used in this project

Feb 1, 2008

By P. Ashtari

Influence of Sr and Mn single and combined additions on the modification of the Fe-containing intermetallic compounds and mechanical properties of Fe-rich AA319 aluminum alloys have been investigated, The microstructural features e,g, morphology of the Fe compounds and eutectic Si has been correlated to the mechanical properties, It was demonstrated that modification of the Fe compounds from the platelet ß-Al5FeSi to the Chinese script a-Al8Fe2Si compound improves the UTS and elongation of the alloys by 10.3% and 83.9%, respectively. Moreover, the simultaneous modification of the Fe compounds and eutectic Si increases the UTS and elongation of the alloys by 15,3% and 116,1%, respectively.

Jan 1, 2005

By T. Patching

"A GLANCE BACK AT what has happened in the past is often a useful guide to the future, although it should be used mainly to provide a sense of direction rather than a map that must be followed. As a preamble to discussing some of the questions posed by the organizing committee it may be appropriate to briefly review the distribution and careers of the graduates of our Department since the first degree in mining engineering was awarded in 1916. An attempt has been made to keep a record of the locations and careers of the Department's 540 graduates in mining and metallurgical engineering. Almost all of those who graduated before 1930 have now retired, but a very large proportion held positions as senior executives prior to retirement. A major proportion of those who graduated before 1950 are now in what might be considered senior management positions. Those who have 10 to 20 years of experience are generally in work of senior engineering responsibility or in supervisory or junior management ranks, while those who graduated in the last ten years appear to be generally in staff engineering or junior supervisory positions. This classification is admittedly imprecise because it is difficult to determine from a job description whether duties should be considered of an engineering or management nature - a distinction between the two terms is often over-emphasized. Nevertheless, the trend from technical engineering to management responsibilities with seniority and years of experience is clear in the careers that we have been able to follow."

Jan 1, 1972

By Jochen Petersen, Jean-Paul Franzidis, Allan Nesbitt

This study presents a method for the determination of intra-particle diffusivities in ion-exchange resins for the purposes of evaluating the state of resin degradation during service. The method uses a zero length column (ZLC) in a closed circuit with variable speed pump and reservoir. The intra-particle diffusion is determined from absorption data by using the Nernst-Plank approximation along with the ‘mass transfer factor’ - which is a product of the mass transfer coefficient (kf )and the concentration of the adsorbing ion in the liquid at the surface of the resin - in a computer algorithm fitting simulated curves to experimental data.. Through this approach the changed intra-particle diffusivity, of a gel-type acid resin, over a 1000 loading and elution cycles, is shown.

Jan 1, 2014

By P. Lostritto, G. E. Agar, G. Labonte, M. Cherevaty

"A locked cycle flotation test was done on a sample from the ovoid portion of the Voisey 's Bay copper-nickel sulphide ore. The chemical conditions for this test were generated by prior independent testing. In this test work the time in each of the five separation stages was optimized prior to executing the locked cycle test. A numerical simulation of the continuous circuit material balance was done prior to the locked cycle test. The test results were not fully satisfactory because the flotation of pyrrhotite in the bulk rougher and cleaner stages was not consistent. The preliminary indication was that the samples had oxidized to varying degrees during storage.INTRODUCTIONINCO has performed batch laboratory flotation testing on ore from Voisey's Bay which is a mixture of chalcopyrite, pentlandite and pyrrhotite. Earlier, Lakefield Research was contracted by Diamond Field Resources to test the ""flotability"" of the ore, which included a pilot plant trial. INCO's J. Roy Gordon Research Laboratory has repeated many of the batch tests that Lakefield did to verify their results. Based on their own work, INCO has modified the circuit proposed by Lakefield Research. The modified circuit is based on batch test work, but no locked cycle test (LCT) was done. It is believed that this circuit will produce a copper concentrate at 29-30% copper and a primary nickel concentrate at 15-20% with recoveries of 80% or above.For several years the University of Toronto has been working with INCO to provide ""hands on"" experience for undergraduate students as an Industrial Research Project (IRP). This year, the objective for IRP was to optimize the time for each of the five separation stages for the Voisey's Bay ore then to numerically and experimentally simulate the material balance for a continuous circuit."

Jan 1, 1998

By Link. Theo A.

Introduction Since the discovery of a major oil pool at Leduc, Alberta, on February 13th, 1947, the long spell of 'oil drought' in Western Canada is now being turned into an oil and gas flood which requires immediate action to obtain the optimum economic benefits. The Woodbend, Section 9, and Okalta extensions of the Leduc field itself have been established; the Redwater pool, lying thirty-seven miles northeast of Edmonton, has been discovered and is being drilled up, and the Imperial Schoepp No. 1 or Golden Spike discovery holds promise of something phenomenal in view of the 500 feet of oil-saturated coral-reef porosity whose areal extent is not known. Imperial Stanolind Barrhead No. 1, northwest of Edmonton, revealed the presence of oil in the Madison, and just recently Gulf N.J. Ellis No. 1, some sixty miles southeast of Leduc, found commercial production in the Leduc D-2 discovery zone. In addition to these Paloeozoic discoveries, gas and oil reserves have also been established in the Upper and Lower Cretaceous, which must be penetrated by all tests on the way through the geological column to the Devonian. If ever there appeared to be an index of 'things to come' in the oil industry, this is it. However, without these recent discoveries the picture in Western Canada does and always did, look very promising indeed. A brief survey of the geological setting in Western Canada is the object of this contribution.

Jan 1, 1949

By T. Bhambhani, Mukund Vasudevan, Partha Patra, D. R. Nagaraj, P. Somasundaram

Selective Ni separation from ultramafic ores rich in serpentines has been a huge challenge in the mineral processing industry, and therefore highly inefficient. Analysis of the root causes of the challenges and consequent development of robust processing solutions were the main goals of the Cytec-Columbia. University-Vale Joint Development Program. In this context, the subject of this paper is limited to one of the key findings of this research program which is the influence of fibrous serpentines on grade-recovery characteristics. Specifically, the poor flotation behavior is characterized by an atypical reverse C-shaped grade-recovery curve.

Jan 1, 2011

By C. M. Díaz, P. J. Mackey, P. Coursol

In a recent paper [1], the present authors discussed calculated energy consumption numbers in copper sulphide concentrate smelting for four different smelting technologies. For the present study, from among these technologies, they selected the Noranda/Teniente continuous bath smelting followed by Peirce Smith (PS) converting route to investigate the impact on total energy requirement of some key process variations, such as tuyere injection of dry concentrate vs. slingering of wet concentrate over the molten bath, continuous converting vs. conventional batch PS converting and commercially proven slag cleaning alternatives. In their calculations, the authors used the same thermochemical model and methodology used in their earlier paper. This approach to explore plant design options provides an interesting basis for evaluating flowsheet modifications that could lead to significant copper smelting energy savings. The METSIM software was used in the present paper to carry out heat and mass balance computations for 8 different flowsheet configurations. The results are presented and discussed in the paper with respect to copper recoveries, energy requirements and CO2 emissions.

Jan 1, 2011

By T. H. Patching, D. F. Coates

The Sub-Committee on Rock Classification, Canadian Advisory Committee on Rock Mechanics, has evolved a classification of rocks which should prove useful in studies of rock mechanics. Considered in two stages -actual rock substance and rock mass -the five-point classification involves the geological name of the rock, the rock strength and rock deformation, and, in the second stage, the gross homogeneity of the rock mass and the formation continuity.

Jan 1, 1968

By E. Yan, M. Mankosa, E. Wasmund

"Rougher flotation in sulfide ore applications is typically performed using conventional flotation machines. The trend over the last 100 years has been for these cells to become larger in volume with cells reaching sizes of 600 m3 and in some cases even larger. The associated foundation loadings, transport and installation requirements along with building size have also increased. In an economic environment where projects must be executed with dwindling capital supply, bigger is not always better. More recently, industry is being challenged to identify new technology that allows for improved flowsheets and financial returns through efficiency gains. To meet this challenge, a novel high-intensity two-stage flotation system known as the StackCell™ was tested to potentially achieve installation volume and required retention time gains when compared to conventional flotation circuits. The results from on-site pilot scale work conducted on typical copper concentrator rougher flotation feed showed retention time gains on the order of 6 to 9 times when compared with conventional flotation equipment. This finding has the potential of reducing capital demands for rougher flotation circuit designs when incorporating the StackCell. The results from test work will be discussed in this paper showing comparative test data generated with a Denver bench batch test, pilot StackCell and large conventional cells, all receiving the same feed.INTRODUCTION Over the last few years, a number of flotation devices have been described as two-stage or multi-stage flotation units. The idea behind multi-stage flotation devices is that flotation performance can be improved by utilizing cells with multiple specialized units in series, but not all units of the same type, as is practiced in trains of multiple tank cells or columns. Instead, each unit is specially designed to provide the optimized fluid environment for each stage of the sequential flotation process. This idea has been proposed based on a study of the fundamentals of the flotation process, and the realization that the process consists of discrete sequential processes, that are each optimized with dissimilar process conditions (Finch et al, 1995), (Zhou, 1996). Instead of executing each step simultaneously in a homogeneous fluid environment, where the conditions would be a compromise between particle collection and froth recovery, the multi-stage flotation unit operates in a set of segregated process environments, each with a set of conditions optimized for that step."

Jan 1, 2018

By P. E. Cavanagh

THIS REPORT is not intended to be a ?comprehensive survey of the steel industry in Europe. For the past ten years the Ontario Research Foundation has been interested in several developments in the steel industry in Europe which it was felt would be of particular interest in Canada and might possibly find application in this country. This is an account of the present status of some of these developments. The economies of steel making in Canada are somewhat different than in the United States because of the nature of the market and the relative costs and availability of such raw materials as metallurgical coke and electric power. There are cases in Europe where a great deal of effort and money has been spent in trying to make steel profitably by methods which take advantage of locally available and cheap raw materials by modifying standard practices. ln cases wl1ere the investigations have been successful and the data are available to allow translation of the results into Canadian conditions, it is felt that such information may be of great benefit in the future in Canada and at !east should be known to all those in the steel industry in this country. The field to be covered in this report only comprises the steps from concentration and treatment of iron ores to production of iron and is only concerned with those commercially operating processes well known to us and judged to be of present interest in Canada.

Jan 1, 1957

By J. E. Hawley

Abstract Spectrographic methods for the analysis of minor constituents such as platinum-group metals, gold, silver, and silica in palladium and platinum refinery sponge are described. These involve the conversion of the sponge metals to the black form by reduction with high purity aluminum filings in either acid or alkaline media. Standards of known composition are prepared in the same manner from either refinery or spectrographically standardized sponge metals. Samples of the black metals are mounted in pellet form and a multisource spark discharge used for excitation. The range of concentrations of impurities studied are those common to refinery samples. Excellent reproducibility of intensity ratios using major constituents as internal standards, is demonstrated and two methods have noted by which the accuracy of the procedures are shown to be of the order of 3 per cent, on the basis of synthetic preparations. Introduction During the past two years an investigation has been carried out in the Spectrographic Laboratory, Queen's University, to determine the suitability of modern spectrographic techniques for the precise analysis of the platinum-group metals palladium, platinum, rhodium, iridium, and ruthenium in the form of refinery sponge analyzing about 99 per cent of the major constituent.

Jan 1, 1951

By E. Rezazadeh Azar

Dump trucks are the main mean for hauling earth material within and outside of the construction and open-pit mining jobsites. The real-time monitoring of the material transportation trips is beneficial for proactive equipment management, volume estimation, and productivity measurement. The traditional manual observation is tedious, non-real-time, and expensive; therefore remote sensing technologies, namely GPS and RFID, have been employed for this reason. Ordinary construction videos are another costeffective alternative to monitor dirt loading and hauling operations in real-time. A vision-based system has been developed to recognize and count hauling trips. This system has three modules including object detection, tracking, and action recognition. This system processes videos taken from access roads in which it recognizes dump trucks and then tracks them throughout the viewfinder. The action recognition module is designed to reject false alarms and also terminate tracking. This way, the system is able to count the number of hauling trips and also record the time between each trip. Several state of the art computer vision algorithms were employed to develop this system. Some of these algorithms were modified using spatiotemporal information to minimize the inherent errors of the vision-based methods. The experimental results showed considerable performance of the system for practical application in the construction and mining sectors.

Aug 1, 2013