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By Mike Dry, Mani Manimaran, Mykolas Gladkovas, Mariam Melashvili, Chris Fleming

Development of a new hydrometallurgical flowsheet requires quantitative description and optimisation of all chemical processes in each step in the process, as well as mass and energy balances across a fully integrated circuit incorporating all the unit operations. This paper covers steps leading to early modelling of a gold processing plant based on a bromine/bromide lixiviant. Research conducted at SGS Lakefield in collaboration with Albemarle provided the data that were used in the development of this model. A previous investigation in this series described the leaching behaviour of various mineral types in Stabilized Bromine reagent. This paper is concerned with the gold recovery operations associated with a conceptual bromine leaching process. The recovery of gold by different types of resin and activated carbon was studied, along with various methods of stripping the gold from the extractant. The circuit is closed by electrolysing the spent leach liquor to oxidize some of the contained bromide back to bromine that would allow recycling the regenerated leach solution back to the leach step in the process.

Jan 1, 2015

By J. Gordon Parr, D. A. Whitaker, G. A. Yorko

High purity alloys of zinc with 25 per cent to 50 per cent aluminum, have been prepared. Mechanical properties of the as-cast and heat-treated alloys have been related to constitution, determined by x-ray diffraction and microscopic methods. Investigations include the effects of aging and of small nickel additions on the properties of the alloys.

Jan 1, 1960

By Rene Cane, V. I. Lakshmanan, John Starkey, Richard May

"The Agrium Kapuskasing Phosphate Operation mines and processes up to 6,000 t/d of phosphate ore. Run-of-mine crushing to minus 6 inches is done in a toothed roll-crusher, while grinding is done in a SAG/ball mill circuit with no coarse recycle classification of the SAG mill discharge. The primary grinding mill is an 18 ft. diameter x 9 ft. EGL, 1500 HP variable speed SAG mill and the secondary mill is a 13 ft. diameter x 21 ft. long, 2000 HP fixed speed, ball mill. When hard ore was treated, the SAG mill restricted the tonnage that could be ground. When soft ore was treated, the ball mill and spiral classifier overloaded and restricted throughput.Recommendations from a plant benchmark and an ore hardness testing program, on how to better utilize installed energy in the Agrium SAG mill when treating soft ore, and how to obtain best results when treating hard ore, were checked in a pilot plant investigation in the 3 ft. diameter Starkey-PRO Pilot SAG Mill. Correlation between the ore hardness testing and the results from the 3’ Pilot SAG mill was very good. In addition, the work indicated the results that could be expected for the different ore types when using either smaller SAG discharge grates and/or a vibrating screen with 10 mesh square opening cloth.INTRODUCTIONAgrium Kapuskasing Phosphate Operation consists of a 6800 t/d open pit mine and a concentrator, near the Town of Kapuskasing in Northern Ontario. The two major ore types are sandy ore and cemented ore. Sandy ore is fine, soft and easy to grind in the SAG mill while cemented ore is harder, more blocky and difficult to grind in the SAG mill. The ratio of sandy to cemented ore in the deposit is thought to be in the order of 80:20 but can range as high as 5050, so it was important for the grinding circuit to have the ability to treat sandy ore alone."

Jan 1, 2002

By Anton Gronningsater

MR. J. R. GORDON: The authors are to be congratulated for their excellent papers on Copper-Nickel Matte Converting. Mr. Drummond's paper contains the results of a thorough and exhaustive study of a series of converter charges. Mr. Gronningsater has presented convincing arguments in favour of his claim that the converter has been neglected as a smelting machine for ore. Some of us may not be inclined to agree with his conclusions. Converting, like most metallurgical operations, is a compromise between an ideal and a practical operation. If it were possible for one to neglect entirely the matter of converter linings, I believe we would all agree that the proper flux for matte in a converter would be pure quartz. Under such ideal conditions, one would, if proper temperature were maintained, make the smallest quantity of slag containing a minimum of magnetite. Converter slags are notorious for their high metal content and must always be subjected to a further cleaning treatment before being discarded. For that reason, the tonnage of converter slag produced should be minimized. If norite is used as a converter flux, then the tonnage of converter slag would be greatly increased if the silica content is maintained at 27 per cent or higher. I cannot agree with Mr. Gronningsater's suggestion that, in con¬sidering a converter flux, the sum of the silica, alumina, alkaline-earths, and alkalis should be considered as being of value. The alkalis and alkaline-earth contents of the flux will replace iron in the silicates formed and tend to increase the viscosity of the slags. However, if the converter is to be used as a smelting machine, it will be necessary to drop the silica content of the converter slag in order to avoid production of excessive slag tonnages.

Jan 1, 1942

By J. E. Dutrizac, J. M. Zinck

Ferrihydrite is often the initial precipitate resulting from the rapid neutralization of Fe(III) sulphate solutions, and it seems to be a major constituent of zinc plant neutral leach residues. The most important parameters affecting ferrihydrite precipitaton are temperature, solution pH and the neutralization rate. Low temperatures and rapid neutralization rates yield poorly filterable ferrihydrite, whereas higher temperatures and slower neutralization rates produce readily filterable precipitates; in all instances, however, the precipitates are two-line ferrihydrite. Significant amounts of Zn are incorporated in the ferrihydrite precipitates, and the Zn contents increase with increasing Zn concentration, pH or temperature. Generally, the sulphate contents of the precipitates decrease as the Zn contents increase, and this may indicate that the Zn is adsorbed on the ferrihydrite. Discrete Zn phases were not detected. Neither Cd nor Tl is precipitated with ferrihydrite, although thallium jarosite co-precipitates with ferrihydrite at high Tl concentrations and elevated temperatures. Virtually all of the Sn added to the solution precipitates with the ferrihydrite, but the tin is believed to be present as intimately admixed amorphous SnO2.nH2O. Although selenite extensively precipitates with the ferrihydrite, selenate remains mostly in solution, likely because of the close similarity of the SeO4 2- ion to the SO4 2- ion which is present in high concentrations and saturates the available sites for anion adsorption.

Jan 1, 1998

By L. M. Scovell

The Internet and its related technologies will radically change the way that mines manage and control their maintenance, repair, and operating supply chains. The Internet is creating new distribution channels and offers new technology platforms with significant advantages over more traditional methods. Mines will have to re-evaluate both the strategies and the tactics employed in these areas. Mines will use e-commerce to integrate their maintenance, repair, and operating supply chains. The integration will extend beyond traditional trading partners to a worldwide network of communities with similar interests and goals. The changes will transform the way mines operate, lower mining costs, and thereby increase their chances of success in an increasingly competitive environment.

Jan 1, 2000

By W. R. Cowan

The Caledon Outwash is a large deposit of glaciofluvial gravel and sand located 55 km north west of down town Toronto. For the most part it was laid down in a meltwater channel fronting the Paris Moraine about 14,000 years ago. Applying the braided bar model of Eynon and Walker (1974) the principal facies present are imbricated coarse gravels (bar corefacies); crudely stratified, imbricated bar top sandy gravels; and trough crossbedded side channel sands and gravelly sands. Of lesser importance are crossbedded bar front gravels, shallow braided stream facies gravels, and stoss side facies sands and pebbly sands (rare). Lithologically these deposits are characterized by FIGURE I. Geological relationships of Caledon Outwash. Industrial Minerals in Canada up to 95% Ordovician limestone and siltstone in the gravel fraction. A siltstone content of up to 34% requires that beneficiation be carried out for the production of better quality aggregates. Resources remaining are estimated to exceed 500 million tonnes in 3000 ha of the most suitable part of the deposit. Present production is about 4.5 million tonnes per year, shared by several producers.

Jan 1, 1984

By A. M. Glendinning

"IntroductionLocationTHE PROPERTY of Aunor Gold Mines, Limited is in Deloro township, Ontario, about three miles southeast of the town of Timmins. It consists of a group of eleven claims located between those of Buffalo-Ankerite Gold Mines, Limited, and Delnite Gold Mines, Limited.GeologyThe ore zone at the Aunor mine consists of a narrow band of fine grained pillowed andesite, irregular bands of 'brown to green carbonated andesite, and lenticular bodies of quartz feldspar porphyry. The zone strikes N.80°E., dips 60 North, and has been traced for 5,000 feet across the property. It varies in width from 0 to 250 feet and is bounded on the north and south by masses of dark bluish-grey tale chlorite schist. These schist bands have widths up to 500 feet.The ore occurs in a series of parallel and branching veins confined to the limits of the zone. These veins tend to terminate and die out on the footwall schist contact, striking generally parallel with the ore zone. In wide sections of the zone, 150 to 250 feet, the veins range in width up •to 3.5 feet and may occur in two or three horizons across the width of the zone, each mineable independent of the other. They tend to dip a little flatter than the general dip of the zone. Where the zone is narrow, the veins are so closely spaced and numerous they can be mined together and in some places the complete zone has been mined from schist to schist."

Jan 1, 1953

By M. E. D. Raymont

"During the history of the sulphur industry there have been three distinct phases of production. Factors controlling supplies during these periods have shifted from demand for sulphur to demand for energy and a cleaner environment. The pattern of brimstone production is t raced through these phases and includes estimates of future supply; these indicate an involuntary excess production of some 20 million plus tons per year by 1980 unless some large-scale new uses are found. Traditional uses for sulphur, including fertilizer, chemicals, fibers, etc., are generally expanding slowly; how• ever, supply in ""by-product"" form alone will soon outstrip demand. The predicted oversupply situation can be corrected by the development of novel potential markets. Promising areas include construction materials, insulation and plastics, among others."

Jan 1, 1972

By H. D. B. Wilson

"IntroductionRECENT ADVANCES in geo-chemistry and in •our knowledge •of crystal structure provide a key which enables us to create a systematic picture of the genesis of many ore deposits. This genetic scheme may be used with confidence in assessing certain types of orebodies and may be of some aid in actual exploration, since it affords a rational explanation of the dependence of the composition •of the ore minerals on that of the rock type in which they occur with which they -are •associated. For purposes of the present paper, .the elements chosen are •chromium, vanadium, iron, and titanium. The oxides of all these metals occur in deposits of similar or related type, and it is proposed to show that, for each, the composition of the •ore mineral is related to •the composition of the enclosing :rock, and that one of the principal factors controlling the composition of the ore is the ionic size of its constituent elements.Geochemical PrinciplesThe crystals of the rock-forming silicates and of the magmatic oxide minerals are essentially ionic types. This means that they are composed •of oppositely charged ions such as Mg²+ and 0²-, which are held together by electrostatic attraction. The ions of each element are spherical, with characteristic size known as the ionic radius. Crystals are built up by the packing of these spheres in the most stable arrangement compatible with the size and the size and valence of the ions• involved.Many of the principles governing the formation of ionic crystals are •simple ,and logical."

Jan 1, 1953

"A method is described for determining the viability of hard rock orebody extraction by block caving. Using a very limited amount of geotechnical data, the procedure enhances Laubscher’s empirical stability graph method by using the complex structural modelling system (ChaSM) to assess cavability and block cave tonnages.IntroductionIn considering the selection of suitable mining methods, block caving has gained popularity over other extraction systems in recent years (Butcher, 1999). This has been ascribed to the fact that block caving is the lowest cost per ton mining method, with orebodies that were in the past considered unsuitable for caving, now being successfully mined. However, even though all orebodies will cave, a problem exists in the evaluation of economic viability — it is necessary to be able to predict both when the orebody will cave and what will be the sizes of the initial ore fragments (and the associated tonnages) that report to the drawpoints. This problem is compounded by the fact that, during the scoping study phase of a project, only limited geotechnical data may exist on which to base an assessment of whether block caving is viable or not. Empirical and numerical methods of cavability assessment do not account for the full effects of geological discontinuity trace lengths, nor for the stress regime. Those require significant geotechnical data to be available. The result is that uncertainty may exist as to whether block caving is an economic option. This uncertainty is complicated by the fact that limited experience exists with the caving of more competent orebodies.This paper describes a method for assessing cavability, and for predicting the size of initial ore fragments and the tonnages reporting to block cave drawpoints, using only the level of data normally available during a scoping study. Fragment size and tonnages are assessed by identifying potentially unstable blocks and wedges in the undercut back using statistical joint data. The effects of lateral confining stresses are accounted for by comparing the in situ stress orientations with the joint orientations. To evaluate the accuracy of the method, a back analysis exercise was conducted to predict cavability and initial tonnage for a mine in which the actual behaviour is known. The method is then applied to cavability and tonnage predictions for a hard rock orebody."

Jan 1, 2002

By Philip W. Johnson, Charles D. Haynes

"Abstract - The coalbed methane industry has become a prominent source of domestic natural gas, with its technology having evolved over the past 30 years. Whereas most coalbed methane wells are able to produce without major interruption over their economic lives, wells operating in an underground mining area are subject to being mined-through. If mine-through occurs, the productivity of the well is at least compromised, and may even be terminated. The economic consequences of mine-through may be relatively simple if mineral ownership and extraction rights are common for the coal and coalbed methane. However, if ownership is not common and a superior coalbed methane lease exists, the coalbed methane ownership must be compensated for lost production caused by mine-through. This paper presents a relatively straightforward method to calculate the value of the lost production caused by the mine-through. It uses technology from mining and petroleum engineering, as well as simple economics and financial management techniques.Sommaire - L’industrie de la production de méthane houiller est aujourd’hui une source importante de gaz naturel domestique dont la technologie a considérablement évolué au cours des trente dernières années. Bien que la plupart des puits de méthane houiller peuvent être mis en production durant l’entièreté de leur vie utile sans interruption majeure, les puits implantés en périphérie de mines souterraines sont sujets à être recoupés par ces dernières. Un tel recoupement peut compromettre, ou même mettre fin à la production d'un tel puits. Les conséquences économiques du recoupement par une mine souterraine peuvent être relativement simples quand les droits miniers et les droits d’extraction sont détenus en commun pour le charbon et le méthane houiller. Si toutefois ces droits ne sont pas détenus en commun et qu’il y a eu octroi d’une concession de méthane houiller de qualité supérieure, les détenteurs du méthane houiller doivent être compensés pour la perte de production résultant du recoupement par une mine souterraine. Cet article présente une méthode relativement simple pour calculer la valeur des pertes de production suite au recoupement par une mine souterraine. Cette méthode fait appel aux technologies de l’industrie minière et pétrolière ainsi qu’à des techniques simples d’économie et de gestion financière."

Jan 1, 2006

By T. H. Janes

"IntroductionSULPHUR is a constituent of many industrial products. It is part •of almost anything we eat, wear, or use. In fact, sulphur is so important that there has been an increasing tendency in recent years to measure industrial growth in terms of sulphur consumption.The uncertainty of obtaining adequate supplies •of elemental sulphur from the Frasch-mined domes. of Texas and Louisiana in the United States led all countries in 1950 to seek alternative sources of supply of this necessary element.Canadian industry has been supplied, for many years, with most of its sulphur requirements by United States Frasch-mined sulphur. World demand for this sulphur has necessitated the imposition of controls on its distribution, as production has not kept pace with demand. Until the third quarter of 1950, Canadian manufacturers of pulp and paper, heavy chemicals, explosives, and textiles •experienced little difficulty in obtaining their needs of elemental sulphur from the United States. However, at that time, low producers' stocks and declining reserves threatened to reduce shipments from producers, with the prospect of a continuing shortage for some time. These conditions, together with higher prices, stimulated the search for alternative sources of supply in Canada."

Jan 1, 1952

By H. Sano

Most of the dust generated from the copper smelting process in Chile has been stored after the stabilization by hydrometallurgical process because it contains high concentrations of arsenic. However, in recent years, the dust generation has increased because of degrading the quality of concentrate. In addition, the environmental regulations become stricter. On the other hand, valuable metals such as copper and zinc are contained in the dust at high concentrations and it is desirable to recover them. In this study, the effect of dust recirculation to the smelting process was examined in order not only to decrease the amount of dust but also to recover copper. Dust generation and the distribution of arsenic, lead, zinc etc. among the matte, slag and gas phases were evaluated as a function of the amount of recirculated dust, partial pressure of oxygen and temperature. It was found that the direct dust return to the smelting process was quite effective for the recovery of copper and the reduction of dust generation, but the acceptable dust amount was limited by the produced matte quality.

Jan 1, 2007

By L. E. Fischer

The background for the 630-million-dollar-plus iron ore project at Kudremukh is outlined. The system and plants for mining, crushing, concentrating, transporting via a slurry pipeline, filtering and shiploading 7.5 million metric tons of iron ore per year are fully described. The mode of operation and the problems encountered in such a transfer of North American technology to developing countries are analyzed. Difficulties encountered during construction are discussed and the progress milestones made over a two-year period are enumerated.

Jan 1, 1979

By F. M. Doyle, G. Sidhu, A. J. Dussault, A. Raygani

There is a growing demand for rare earth metals for use in high strength permanent magnets, most notably Nd2Fe14B. Rare earth metals are extremely reactive, with reduction potentials around -2.5V SHE, and are conventionally produced by molten salt electrolysis. The current work was done to investigate an earlier report of electrodeposition of a neodymium ferroalloy from aqueous solution, to determine whether this approach could be an environmentally and economically competitive commercial approach for producing feedstock for permanent magnets. Such a process would be analogous thermodynamically to the Castner- Kellner process, in which aqueous sodium chloride brine is electrolyzed in cells with mercury cathodes. Metallic sodium forms an alloy (amalgam) at the cathode, thereby lowering the activity of the metallic sodium significantly below unity and making the reduction potential of sodium significantly less negative than the standard reduction potential. Here we report the effects of Nd/Fe ratio in the electrolyte, current density, temperature and two different complexing agents, glycine and cysteine, on the composition and morphology of the electrodeposits, along with current efficiency. The energy needed to produce neodymium as Nd:Fe alloys by aqueous electrodeposition was compared with values estimated for production by molten salt electrolysis and the thermodynamic energy requirement.

Jan 1, 2014

By Joanne G. Petrini

ISO 26000 Unique Process Unique Personality ?Almost 10 years in the making ?What type of standard is this? Different type of ISO Standard ISO 26000 Structure and Substance ?Principles ?Core Subjects ?Implementation Guidance ISO 26000 Impact ?Same old, same old? ?So Is there really anything NEW? ?Should I care??

May 1, 2011

By J. L. Jambor, R. W. Boyle

"The Magnet Cove barite-sulphide deposit is a raking pipe-like body that replaced and partly filled a large brecciated zone at the junction of two faults at the contact between sedimentary rocks of the Horton and Windsor Groups of Mississippian age. The principal minerals in the deposit are siderite, barite, hematite, pyrite, marcasite, galena, sphalerite, chalcopyrite, tennantite, proustite, pearceite, acanthite and stromeyerite. The mineral assemblage and textural relationships indicate that the minerals were deposited from low-temperature solutions. The source of the elements in the deposit is believed to be the enclosing sedimentary rocks, with connate or ground waters as the transporting medium, and solubility products as the governing factor controlling the abundance and order of deposition of the minerals."

Jan 1, 1966

By Michael P. Davies

Mine waste facilities, and in particular tailings impoundments, are one of the highest risk aspects of any mining venture. There are far too many recent examples of how real and/or perceived physical or environmental impact from one of these facilities has had enormous economic impact on both the specific project and the overall parent mining company. In many cases, such dramatic impacts have followed a period where a due diligence of the mine had been carried out (e.g. in an acquisition, merger or similar) or an internal or otherwise audit had taken place. Consequently, it is suggested that there is a need for an audit/due diligence framework to assist those processes in terms of assessing mine waste facilities. This paper presents a recommended framework for completing either an audit or due diligence assessment of mine waste facilities under a number of typical scenarios. The framework will be of relevance to reviews carried out prior to mine construction, during operations and for mines that have been in a care and maintenance position and are to be re-opened. Concepts of risk management are introduced as an essential part of the recommended framework. The paper should be of value to current and prospective mine owners involved in stewarding an area of significant risk to viability of their mining venture. The paper should also interest prospective lenders to these ventures.

May 1, 2007

By Gordon G. Duncan

Historical Sketch Occurrences of native copper have been known along the Arctic coast of Canada, especially in the vicinity of the. Coppermine river, since the early part of the eighteenth century (See map, Figure 2, insert). In 1769, Samuel Hearne, a clerk of the Hudson's Bay Company at Fort Churchill, was sent to explore the 'copper mines' from which natives had been reported to secure copper for tools, fishing spears, etc. After two successful attempts, he reached the Coppermine river in 1771, accompanied by Indian guides. This hazardous trip was indeed a remarkable feat when one considers the vast distance covered, a great deal of which was barren lands. At Bloody falls, (See Figure 1) on the Coppermine river, Hearne's Indians swooped down on a party of sleeping Esquimaux, who gathered there each summer to fish, and murdered the entire band encamped on that side of the river. Hence the name of the falls. Hearne's knowledge of minerals was undoubtedly limited. He reported having seen the copper mines from which the natives were securing the copper, but he failed to prove the economic possibilities of the copper occurrences or to give an accurate description of any deposit. Sir John Franklin visited the area in 1821. He and other members of his expedition, namely, Richardson, Back, Kendall, and Hood, reported native-copper float to occur in the vicinity of the Coppermine river and Bathurst inlet.

Jan 1, 1931