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By J. Zou

Open-cut method is most widely used for shallow utility lines installation. In urban areas, unexpected utility lines buried underground potentially turn open-cut construction into a highly risky operation, increasing the construction cost while presenting additional safety hazards. Examples include: breaking existing water main leads to flooding the downtown area; hitting an unexpected gas line causes an explosion. To prevent those accidents, the current practice is to stake out the underground utility lines before the open-cut construction based on the as-built information collected from various utility companies and government agencies. However, the as-built information is not always complete and accurate. To verify the locations of some important utility lines and protect them against damages caused by open-cut construction, new techniques and technologies are used but have their limitations in revealing underground utility lines, such as hydro vacuum method and ground penetration radars (GPR). The emerging technology of ultra-wide band (UWB) radar holds the potential to provide a cost-effective, non-destructive detection method. In this paper, a critical review of current practices and established methodologies is given. The functionality and working mechanism of UWB radar technologies are described. Application potential in open-cut construction is demonstrated by conducting lab experiments. Testing set-ups for detecting unexpected utility lines in soil along with preliminary results are presented. The effects of soil moisture content on the detection range are discussed. Research findings are summarized and constraints are discussed in conclusions.

Aug 1, 2013

By M. U. Oko

"Monitoring of all the waste streams from Falconbridge's Sudbury Operations to determine whether they meet the required standards, has been performed for many years. By 1969, however, the number of samples being collected had become so large that a complete revision of the existing systemwas necessary. Sites previously designated by name only, were numbered, clearly marked on the ground and on maps which were circulated to all concerned. The types of pollutants analyzed were determined and specified for each sampling location and a chemical analysis report form was designed. The sampling schedule has been computerized to produce a periodic listing of the samples to be taken and the analyses required.An area map showing sampling sites, chemical analysis report form, spill report and a computer print-out example are shown and explained.EVOLUTION OF FALCONBRIDGE'S WASTEWATER. MANAGMENT SYSTEMFalconbridge Nickel Mines employs some 4500 people, operates nine mines, four mills and a smelter in the Sudbury basin. The operations are geographically fragmented into four widely separated locations, the Falconbridge operations east of Sudbury and the Onaping operations in Levack Township being the two largest of the four. The Lockerby area located to the west and the Lindsley Mine just north of Sudbury are now under development. The magnitude, the diversity and nature of the operations are such that constant vigilance is needed to prevent inadvertent damage to the environment. The purpose of this paper is to describe the information system used to monitor and control waste-water disposal on Falconbridge's properties to help ensure the maintenance of effluent standards satisfactory to the Ontario Water Resources Commission (OWRC) and to the Ontario Department of Health."

Jan 1, 1971

By L. W. Vollmer

Introduction During the past three years at least fifty strings of 9% nickel steel tubing have exhibited excellent resistance .to the variably severe corrosive conditions typical of many of the sweet condensate wells in Mississippi, Louisiana, and Texas. This experience, and the characteristically outstanding performance of other ?nickel alloy steels under hydrogen sulphide corrosive conditions, dictated the selection of 9% nickel steel tubing for the second well drilled in the sour condensate Pincher Creek field of southwestern Alberta. The damaging effects of the Pincher Creek reservoir fluids on well equipment had been manifested in the discovery well by the rapid and not yet fully understood failure of API Grade N-80 tubing, stainless steel wire lines, and alloy steel fishing tools. Two very unexpected failures in the 9% nickel steel tubing, after only six days of service in production tests, instigated an extensive and continuing investigation to ascertain the probable cause of failure. This discussion presents some of the results obtained thus far which cast a little light on the perplexing behaviour of steels in hydrogen sulphide environments in general, and in sour condensate wells in particular. History of Tubing Failures Walter Marr well No. 1, in which the 9% nickel steel tubing failures occurred, produces from the Madison lime at the depth interval approximately 12,200 to 12,750 feet. The gas-oil ratio is about 26,000 and the gas contains 10.2 per cent hydrogen sulphide and 6.3 per cent carbon dioxide by volume.

Jan 1, 1952

By E. Henderson, L. K. Daneshmend

Drawpoint control is critical in determining the cutoff point for load-haul-dump mucking operations to minimize dilution. It is also necessary to ensure even mucking distribution and to prevent possible hang-up of material within a stope. A prototype production monitoring and reporting system has been developed for load-haul-dump operations in under-ground mines. The system generates accurate and timely information regarding mucked tonnages and drawpoint and ore/waste pass utilization. The monitoring system integrates a PLC-based load weighing system with a radio frequency identification (RFID) system for locating the vehicle. The system records the identification and time of entry and exit of each draw-point and ore/waste pass visited during a shift, as well as the weight of each bucket load. A trial of the system was conducted at the CAN-MET Experimental Mine near Val d’Or, Quebec. The monitoring and reporting system functioned as designed, with the exception that the maximum read range of the RFID tags under dynamic conditions was found to be a limitation. RFID systems with greater range capabilities have been identified for a second generation system. The system is the first of its type in North America to demonstrate that RFID tagscan be successfully applied to locate trackless underground equipment. Because of their ability to locate equipment and personnel within underground mines, RFID systems should be considered a key technology for future mine information and process control systems.

Jan 1, 1996

By R. S. Douglas

Introduction The operations of The Granby Consolidated Mining, Smelting and Power Company, L1mited, have always been concerned with the mining of low-grade copper ores. In the fifty years of this Company's existence, nearly 60,000,000 tons of such material has been successfully mined and treated. During these years, many changes in mining practice took place. However, at Copper Mountain, due to the large tonnages of very low grade material, it was realized that something more than changing mining methods would have to take place if these low-grade orebodies were to be mined at a profit and the Company and. its employees enjoy many years of successful operation and employment. Production costs were mounting commensurately with rising taxes and the increasing cost of supplies, labour, freight, and smelting, while the value of the product on the market was not increasing in price to compensate for the higher costs of production. A survey of the mineable ore in 1944 indicated that, of the 12,000,000 tons in the reserves, only 3,500,000 tons was now profitable ore. This reduction in the commercial ore reserves was a serious matter, as it meant that the mine had only two years of life at the profitable shipp1ng rate of 4,800 tons per day. Further, the location in the mine of the orebodies making up the 3,500,000 tons was not suitable for such high production.

Jan 1, 1950

By G. Shore

"The development of a DC resistivity instrumentation system for data acquisition in extreme topography yielded an unexpected bonus in the quality and information content of the type of raw data gathered. Not only were traditionally too-rough areas being investigated systematically for the first time, the unique high-density, multi-directional raw data were providing the opportunity to greatly expand the range of conductive and resistive signatures that could be accurately recognized. Using a true 3-D inversion algorithm, 3-D earth resistivity imagery began to show distinctive anomaly patterns for hydrothermal mineralization at the seldom-visited resistive end of the spectrum, successfully imaging epithermal gold systems in conditions that had defied conventional ground and airborne geophysics for years.The traditional mode of designing a resistivity survey to test a specific target concept was shown to be an unnecessary limitation on exploration thinking when a single sweep acquisition of dense, multi-directional 3-D raw data could effectively provide the all-targets “shotgun” coverage that would take 10 or 12 conventional surveys to duplicate. Exploration planning has the opportunity to move from single steps of trial and error geophysical testing to a mode of mapping everything at the outset, and then sorting out what might be of exploration interest in the results. Survey parameterization becomes the non-technical process of marking an outline on a map and declaring “survey here.” Operational and interpretational reasons for not testing where the exploration interest lies have all but disappeared. With any-terrain capabilities and unprecedented raw data density and overlap to support interpretation of complex conditions, that outline can be drawn through extreme rough terrain, including lakes, cliffs, industrial facilities, and grounded installations to test for generally unknown sub-surface features of potential interest.As more is learned about the larger-scale signatures of ore settings and the district-scale geo-electric imprint of hydrothermal processes on lithology, it appears that the only thing certain about ore signatures is their uncertainty. This is not bad news. New opportunities abound as the advanced 3-D technology allows a first effective look at the previously unexplorable rough terrain or complicated settings, and a second look at areas where older results may now be known to be non-definitive."

Jan 1, 2002

By R. Bainbridge

THE cinnabar deposits of the Consolidated Mining and Smelting Company's Pinchi Lake property, situated near Fort St. James, B.C., were discovered and reported on by a Dominion Government geological party in 1937. Claims were staked by a group of local prospectors and, later, the Consolidated Mining and Smelting Company of Canada, Limited, took an option on the property. By the fall of 1939, exploration work had indicated ore of commercial quantity and grade, and laboratory tests had shown that standard methods of reduction, namely, roasting of the ore, followed by condensation of the mercury vapour produced, would result in satisfactory recovery. In June, 1940, construction of a 50-ton unit arranged for wood firing was completed and operation commenced. The installation consisted of a 46 in. by 60 ft. rotary kiln (see Figure 1) followed by a 14-in. Sirocco cyclone, a cast-iron condenser unit, and a 1,700 c.f.m. fan, exhausting to a stack. Other equipment included a 9 in. by 18 in. Denver jaw crusher with the necessary bins and feeders. As the need for mercury was urgent, because of war requirements, construction of a duplicate unit was begun almost immediately. This first extension started operation in January, 1941, and the plant was then capable of treating about 150 tons of ore daily.

Jan 1, 1945

By Y. Okita

The Goro Nickel Process, developed over a ten-year period, uses a number of novel processing steps and treats two ore types, limonite and saprolite, together. Nickel and cobalt are solubilized using a 270°C pressure acid leach in sulphuric acid, which rejects the bulk of the Fe into the leach residue as hematite particles. The leach liquor, after CCD, is aerated to oxidize any ferrous iron to the ferric form and is neutralized with limestone to precipitate iron as hydroxides together with gypsum from the neutralization of the free acid. Further neutralization with lime, together with steps to remove suspended solids, reduces the iron to trace concentrations. Nickel and cobalt are directly recovered from the low-iron leach solution by primary solvent extraction using Cyanex 301® (SXl) in a high-strength hydrochloric acid solution. Nickel is subsequently separated from cobalt in a secondary solvent extraction circuit using tri-isooctylamine. A granular nickel oxide is made by pyrohydrolysis, and this allows the recycling of hydrochloric acid to SXl. The process is currently being commercialized to produce approximately 60,000 t/y of nickel as nickel oxide granules and approximately 5,400 t/y of cobalt as cobalt carbonate. This paper describes the process development to control the Fe concentration in the SX1 feed solution.

Jan 1, 2006

By Edgar A. Manker

"Today's market for columbium has only developed in the last two decades, and in this sense it is ""newer"" than molybdenum, vanadium and most other steel alloying elements. In this short period, it has assumed a very important role in steel alloying and in superalloys. From a few hundred thousand pounds of columbium in 1960, consumption has grown to nearly 30 million pounds per year, with a market value approaching two hundred million dollars.To assess the outlook for columbium, we will first consider the historical development of consumption and supply, particularly noting that all of today's major mines were developed during the last two decades. From current production, we will attempt to reasonably project the future. This future may well include new producers, particularly some producing columbium as a co-product with tantalum.The growth of current applications, and emerging new applications, will be considered with regard to future consumption and in relation to future trends in pricing.IntroductionThe nineteenth century was a busy time for the discovery and naming of new elements. Among those discovered were columbium in 1801 and niobium in 1844. Although it was later shown that columbium and niobium are the same element, the two names are still used today. Niobium has been pronounced the ""official"" name by the International Union of Pure and Applied Chemistry, but columbium is still widely used in commercial practice, and we have chosen to use columbium in this paper."

Jan 1, 1981

By J. E. Armstrong

"IntroductionT'HE PRODUCTION of gravel and sand may be considered to be the major mining operation in the Lower Fraser Valley of British Columbia. At least thirty pits are in operation with a yearly production probably in excess of two million yards and a value in excess of one million five hundred thousand dollars before crushing, washing, and sizing. The value of the finished products would probably be double the above figure.Since 1949, the writer and his co-workers have been engaged in the geological investigation of the Lower Fraser valley and adjoining Coast mountains for the Geological Survey of Canada. The study, which is not yet completed, includes both bed-rock geology and geology of the unconsolidated sediments lying above bed-rock. In a rapidly expanding industrial area, .an advance knowledge of the geology may• greatly aid in future 'planning, and in many cases may .prevent not only the wastage of large sums of money, 'but possible disaster. Some of the present and future applications in which geological information in the Lower Fraser valley should be of value are as follows: the development of domestic, irrigation, industrial, and municipal groundwater supplies; drainage for industrial sites,, roadbeds, and farmlands; flood control along the Fraser river and smaller streams in the area; the location of dam sites, of major tunnels for water supply •and sewage, of road-beds, of foundation sites for large buildings .and other engineering undertakings in which geology may aid; the evaluation of oil and gas •possibilities; the production of building stone; and the production of sand and gravel, the subject with which this paper is primarily concerned."

Jan 1, 1953

By Kevin M. Ansdell, Irvine R. Annesley, Christine L. Mckechnie

The U-Th-REE mineralization at Fraser Lakes Zone B is hosted by granitic pegmatites and leucogranites, which lie along the deformed contact between Paleoproterozoic metasedimentary gneiss of the Wollaston Group and Archean orthogneiss, approximately 25 km from the southeastern edge of the Athabasca Basin. The pegmatites/leucogranites are subcordant to concordant with the regional foliation and are concentrated within a northeast-plunging antiformal fold nose, the study area, which lies west of Fraser Lakes. The mineralized pegmatites/leucogranites in the western part of the study area (Group A) are typically enriched in U (± Th) with Th/U ~1, and contain uraninite, thorite, zircon, and allanite. Those intruding the central part of the study area (Group B) are generally enriched in Th and LREE, with Th/U >2, and contain monazite, thorite (commonly U-enriched), and zircon. The pegmatites and leucogranites in Group A tend to be slightly enriched in SiO2 and depleted in TiO2 relative to those in Group B and are interpreted to represent more evolved crustal melts. Both groups are peraluminous and show varied chemistry. Partial melting (~850ºC and 9 kbar) of a metasedimentary rock-dominated source, entrainment of accessory minerals as xenocrysts, and assimilation-fractional crystallization processes combined to enrich the granitic pegmatites/leucogranites in U, Th, and REE elements. Transfer of melt from the source region to the crystallization sites was assisted by deformation within and along major structural zones, such as the folded Archean-Paleoproterozoic discontinuity. The character of mineralization and structural control in the study area is reminiscent of the alaskite-hosted deposits at Rössing, Namibia.

Jan 1, 2013

By Shuji Owada

Scrap electrical and electronic appliances, so called "E-waste", are not a present target to be collected and recycled under Japanese regulations. This material, however, contains considerable amounts of base, precious, and rare metals and it is necessary to recover these elements for maintaining stable supply and establishing "the society of environmentally-sound material-cycle". This paper describes recent trends of rare metals recycling in Japan and technological approaches to achieve the above objective. Also a research work to concentrate rare metals from the printed wiring boards by combining brand new comminution and physical separation methods is discussed.

Jan 1, 2011

By Dao Dac Tao

The Vietnam coal industry in recent years has achieved the rapid growth. However, in the process of industrialization and modernization of the country, the demand for coal for energy is constantly increasing. This paper presents the Vietnam coal industry in the last stage: the opportunities and challenges facing the coal industry as it strives to become modern, highly effective and capable of meeting the demands of national energy security, all in harmony with socio-economic and environmental needs.

Aug 1, 2013

By Lebeau M., P. Duguay

"The cost of occupational injuries and diseases in the mining industry in Quebec was estimated for the period of 2010 to 2012. The method used takes into account the financial and human costs assumed by employers, workers, and the community. To better direct research and prevention toward issues with the most significant consequences, the results are presented in various ranking tables, which stakeholders might find useful.RÉSUMÉ Le coût des accidents du travail et des maladies professionnelles dans l’industrie minière au Québec a été estimé pour la période 2010-2012. La méthode utilisée prend en compte les coûts financiers et humains endossés par les employeurs, les travailleurs et la communauté. Afin de mieux orienter les recherches et la prévention vers les problèmes ayant les plus graves conséquences, les résultats sont présentés dans divers tableaux de classement, qui seront d’une grande utilité aux parties prenantes. INTRODUCTIONThe mining industry is much safer today than it was 30 or 40 years ago, mainly due to a more qualified workforce, the use of automated equipment, and a corporate culture more focused on occupational health and safety (OHS); however, the number and the severity of occupational injuries and diseases continue to make this industry one of the most hazardous. In the province of Quebec, the mining industry accounts for approximately 0.4% of paid workers but is the source of 4% of fatal work accidents. It is, therefore, important to continue the prevention efforts already underway in the mining industry.The difficult global economy, which has affected the mining industry in the last few years, is an opportunity to reaffirm that sound management of OHS can have a positive impact on companies’ productivity and profitability. Occupational injuries and diseases are costly for the companies concerned and for society as a whole. Reducing their occurrence makes it possible to reduce not only the size of workers’ compensation board contributions but also several other financial and human costs."

Jan 1, 2018

By R. G. Helberg, S. M. Rebelo

"Copper and cadmium are removed from the zinc sulphate solution in primary purification by cementation reaction followed by filtration. The solids are sent to the cake leach section where zinc and cadmium are recovered from the copper rich slurry. The copper solids from cake leach are filtered, bagged and sold. In order to achieve a lower cadmium copper cake, an altered process flow is suggested. It is proposed the primary purification be split into two steps for individual removal of copper and cadmium. INTRODUCTIONCopper cake is a product of primary purification, also known as copper and cadmium removal. Copper and cadmium are removed by cementation reaction in four stirred reaction tanks. The slurry is then filtered through Shriver manual plate and frame presses with the solution advancing to the next stage of purification, hot zinc purification (HZP). The solids from primary purification are further processed at the cake leach section where zinc and cadmium are separated from the copper rich slurry. Cadmium and zinc are dissolved in the cold cake leach tanks using spent electrolyte. Cadmium is recovered from this cadmium rich solution by cadmium sponging, leaching and electro-winning circuits. The residue from this cold leach step is further leached using spent electrolyte at a temperature of 85°C. The copper rich solids from hot cake leach are filtered on a drum filter and bagged in 1 ton bulk bags for shipping to buyers.Current assays of copper cake are shown in Table 1. The goal is to produce a copper cake product that is below 0.5% cadmium."

Jan 1, 2012

By D. D. Macdonald, G. Engelhardt

The accumulation of damage due to localized corrosion [pitting, stress corrosion cracking (SCC), corrosion fatigue (CF), crevice corrosion (CC), and erosion-corrosion (EC)] in complex industrial systems, such as power plants, refineries, desalination systems, etc., poses a threat to continued safe and economic operation, primarily because of the sudden, catastrophic nature of the resulting failures. Of particular interest in managing these forms of damage is the development of robust algorithms that can be used to predict the integrated damage as a function of time and as a function of the operating conditions of the system. Because complex systems of the same design rapidly become unique, due to differences in operating histories, and because failures are rare events, there is generally insufficient data on any given system to derive reliable empirical models that capture the impact of all (or even some) of the important independent variables. Accordingly, empirical models have generally failed to provide a robust basis for predicting the accumulation of corrosion damage in complex systems under realistic operating conditions. The alternative prediction philosophy is determinism, in which the development of damage is described in terms of valid, physico-electrochemical mechanisms with the output being constrained by the natural laws. The differential damage is then integrated along the corrosion evolutionary path for the system (i.e., over the future operating "history") to yield the desired integrated damage, which is the quantity that is most useful to an operator. In this paper, we review the theory of predicting corrosion damage within the framework of Damage Function Analysis (DFA), with particular emphasis on the pitting of aluminum in chloride solutions and on the accumulation of damage from SCC in Type 304 SS components in the primary coolant circuits of Boiling Water (Nuclear) Reactors (BWRs). These cases have been selected to illustrate the various phases through which localized corrosion damage occurs.

Jan 1, 2005

By J. P. Messervey

Dr. K. A. Clark: No one will doubt the statement of fact that, during drilling operations through the bituminous sand beds in the Mildred-Ruth Lakes area, the core-barrel was found to contain bitumen with minor amounts of sand instead of bituminous sand. But many will doubt the interpretation of this fact as meaning that beds of bitumen occur interstratified with the bituminous sand beds. They will prefer to hold faith in the laws of physics, which deny that sand will float on oil or that fluid under pressure will not flow away through a permeable medium, until it is proved that the appearance of the oil in the core-barrel was not due to circumstances surrounding the drilling of the bituminous sand beds. The implication of the interpretation that sand is floating on oil is clear and it is unacceptable. Bituminous sand is unconsolidated sand more' or less saturated with a viscous oil. It is as difficult to conceive of bituminous sand lying on top of a body of the viscous oil as it is to conceive of unconsolidated sand more or less saturated with water lying on top of a body of water. The only difference between the two concepts is that the oil is viscous whereas the water is fluid. Oil-soaked sand placed on viscous oil would, when released, sink through the oil slowly, whereas water-soaked sand would sink through the water quickly.

Jan 1, 1947

By V. Bazhko, V. Yahorava

The calcium sulphate waste stream of the wet phosphoric acid process, commonly called phosphogypsum (PG), contains the majority of rare earth elements (REE) initially present in the apatite feedstock. Mainly light and middle REE are present in PG and their total concentration ranges from 0.27% to 0.35% by mass. Worldwide, around 7 billion tonnes of PG have been produced to date at a current growth rate of 150-200 million tonnes per annum. In total, an estimated 21 million tonnes of REE are locked in PG waste dumps around the world. Due to the value of the REE contained in PG dumps a number of processes have been devised for their recovery. The majority of these processes applied complete or partial gypsum dissolution, but were deemed not viable due to high capital and operating costs. Mintek developed an alternative method for the recovery of REE from PG by applying Resin-in-Leach (RIL) technology. This technology was tested on PG sampled from dumps and current arisings from South African phosphoric acid production plants. The extensive testwork program included evaluation of various lixiviants and optimisation of lixiviant additions, optimisation of REE leach and adsorption conditions, batch equilibrium and kinetic adsorption tests, continuous RIL testwork and numerous variability tests. It was found that PG from different sources was highly variable, both in terms of REE recovery as well as physical properties of the material such as viscosity and filterability of the slurry. The recovery of REE varied from 15% to 80% depending on the origin of the samples. A high-level economic study indicated that at a price of >21 $/kg for mixed REE oxide product in conjunction with an overall REE recovery as low as 15% the economics of REE recovery from PG via RIL technology may already be favourable.

Jan 1, 2016

By Harry Siewert, Tom Milner, Jack Stickney

"LocationThe Gibraltar mine is located in central British Columbia (NTS 93B/9W), 362 km north of Vancouver. Access is provided by 20 km of paved road from McLeese Lake, which lies 45 km north of Williams Lake on Highway 97. Latitude and longitude of the mine are 52° 30' and 122° 16', respectively.The total area of the McLeese Lake site is approximately 1700 ha (4200 acres). This includes the orebodies, dumps, surface drainage collection system, plant site, roads and tailings ponds.Brief Description of OperationOre is mined by open pit methods and is concentrated using conventional crushing, grinding and flotation processes. Copper and molybdenum flotation occurs at an average rate of 40 000 tons per day. Tailing is discharged to an impoundment area and the water recycled as process water. Additional copper is extracted from the waste dumps using sulphuric acid as a leach solution followed by solvent extraction and electrowinning.HistoryExploration by Gibraltar began in 1964, continuing until late 1970, at which time it was announced that the property would go into production. Construction started in early 1971, with initial production in March 1972. Target capacity of 30 000 tons per day was achieved by the end of March and is currently at 40 000 tons per day.Ore reserves as of January 1, 1998 were 184 384 000 tons grading 0.31% Cu and 0.010% MoS2."

Jan 1, 2000

By Fabian Mohr

The methyl substituted binuclear cyclometallated gold(I) complexes [Au2(?-n-MeC6H3PPh2)2] [n = 4, 5 and 6] all undergo oxidative addition reactions with halogens and, in the case of the 4- and 5-methyl substituted analogues, with dibenzoyl peroxide to give metal-metal bonded digold(II) complexes [Au2X2(?-C6H3-n-MePPh2)2]. The 4- and 5-methyl substituted digold(II) compounds on warming or exposure to light undergo carbon-carbon coupling reactions to give gold(I) complexes containing the corresponding 2,2'-n,n'-biphenylyldiphenylphosphines. The 6- methyl substituted digold(II) complexes rapidly isomerise above ca. -20° C to binuclear heterovalent gold(I)/gold(III) compounds [XAu(?-2-Ph2PC6H3-6-Me)AuX{?2-(6-MeC6H3-2-PPh2)}], containing a fourmembered cyclometallated ring on a gold(III) centre. Surprisingly, no carbon-carbon coupling could be induced for any of the 6-methyl substituted compounds, even under forcing conditions. This difference in reactivity of the 6- methyl derivative, compared to that of the 5-methyl and unsubstituted analogues was studied by ab initio calculations using a series of model compounds. The results are in excellent agreement with the experimental findings and suggest that the key-step in the C-C coupling reaction is the partial opening of the Au(III)-P bond in one of the transition states. In the 6-methyl system this transition state is energetically inaccessible and hence no C-C coupling occurs.

Oct 1, 2003