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By Robins R. G

The dissolution of metallic copper powder in aqueous solutions of cupric sulphate under the influence of ethylene gas was investigated. The dissolution reaction stoichiometry obtained was: Cue+(aq) + Cu(s) + 2C2H4(g) = 2(CuC2H4)+(aq) The rate of formation of the copper (I)-ethylene complex in the above reaction was studied in a laboratory autoclave and the effect pH, temperature, ethylene partial pressure and initial concentration on the dissolution rate was measured experimentally and expressed theoretically in terms of several simple conceptual kinetic models. The results led to the selection of optimum conditions for the reaction and the suggestion of an "ion-molecule reaction" mechanism to explain the very low activation energies for the reaction system. The area of application of this reaction lies in the direction of refining impure copper such as cement copper. Several experiments were performed in which an acidified solution of cupric sulphate under ethylene pressure was used to dissolve copper from the cement copper powder in the form of the copper (I)-ethylene complex, followed by the release of gas pressure to disproportionate the complex and precipitate a purer metallic copper.

Jan 1, 1987

By H P÷llmann

Calcium aluminates, calcium aluminate ferrate and calcium aluminate sulfate were synthesised by solid-state reaction, sol-gel method, a self-combustion method and by a polymeric precursor process. For chemical sintering methods the base chemicals CaO, CaSO4, Al2O3 and Fe2O3 were used. As precursors for sol-gel synthesis metal nitrate hydrates and Al2O3-Sol were used. In order to synthesise pure phases by a self-combustion reaction glycine was used as fuel and nitrates as metal components. In the polymeric precursor process metal nitrates and diluted H2SO4 were used as metal components and the resin was made using citric acid (C6H8O7) and ethylene glycol (C2H6O2). Precursor phases synthesised by these different methods were sintered step-by-step in order to investigate the crystallisation. Further on single phases were hydrated and their hydration behaviour was studied by heat flow calorimetry, X-ray diffraction and cryo-transfer scanning electron microscopy. Due to the different synthesis procedures different hydration reactions and microstructures of the phases will be shown.

Jan 1, 2008

By J Czerwinski, M Kasper, M Wyser, N Heeb

The VERT project 1993 - 1998 laid the technical foundation for curtailing the emission of fine particles from diesel engines at Swiss underground workplaces. The targeted maximum was 100 ¦g/m3 EC. Extensive laboratory and field investigations demonstrated that this specification is only attainable with modern diesel particulate filter (DPF) systems that almost eliminate particles in the entire lung penetrating size range from 20 nm to 2.5 ¦m. In January 2000, Switzerland mandated compulsory particle filters in underground workplaces, particularly in tunnelling, irrespective of engine age, size and type. After the implementation, the particle concentration in the respiratory air was below 40 ¦g/m3 EC, compared to earlier values of up to 750 ¦g/m3 EC. Deployed DPFs have proven filtration rates of 99 per cent in the entire size range of alveoli intruding particles. The DPFs are as durable as the engine, suffer no ageing and require minimal maintenance. The failure rate is below three per cent annually. Of the 6000 retrofitted construction machines in Switzerland, about 400 are deployed underground. Prerequisites for this quality are a sophisticated certification procedure, electronic monitoring of DPF operation and meticulous periodic exhaust gas inspection of the engines.

Jan 1, 2005

By Richardson G. W, Yap L. C

Friction rock stabilisers (FRS) are the most common steel-based ground reinforcement used in underground mines in Western Australia. As with any other steel-based product used in underground mines they are susceptible to corrosion, particularly under aggressive minewater and mineral conditions. Because of their thin-wall tubular construction and large surface area, the potential damage resulting from corrosion is considered to be more severe for this type of reinforcement than for other forms of reinforcement made of solid steel bars. Because of the obvious safety problems which may result from corrosion, both mine operators and regulators have raised concerns regarding the long-term effectiveness of FRS installed in underground mines in Western Australia. Although corrosion has been recognised as an important safety issue, the controls of corrosion in varied underground mining environments has not been well understood. To improve the understanding of the corrosion behaviour of FRS, the Department of Minerals and Energy has initiated a research project focused on the mechanisms and extent of corrosion attacks, and their influence on the effectiveness of the reinforcement. This paper describes the research project and presents the interim results achieved To-date.

Jan 1, 1995

Tokyo Metropolitan Government designs the stormwater storage plans in underground, as a measure of flood control in completed urban district and improvement of combined sewarage system. This time, introducing those plans, we report about IKEJIRI and SIN-KOMAZAWA STORAGE TRUNK LINEs design and construction. They are located in Meguro river basin of the Morigasaki drainage area. Both storage trunk lines have capacity to store 15O,000m3 of stormwater. They are in use for countermeasure of flood till Meguro river's strengthening (intensity 50 mm/h) is ended. And after the strengthening, they will be in use for improvement of river water quality, through the storage of combined sewage and first runoff, which, otherwise overflows weirs and flows to river in a rainy day. These storage trunk line's full length is about 5700m. Boring diameter 66140 mm (f = 2672m) and 47800 mm (I = 2866m) of these tunnels are constructed by Mechanical Shield tunnelling method. And boring diameter 3600 mm x 4000 mm (R = 180m) is constructed by NATM tunnelling method. We began works in 1983, and have a mind to complete in 1987.

Jan 1, 1987

Solution transport of gold and silver has occurred as a result of the chemical weathering of many Western Australian epigenetic gold deposits. Evidence for the remobilization of gold exists in the form of small crystalline octahedra, mustard gold, flake gold, and coatings on iron-oxide. This "secondary" gold is of high purity (low silver content). It is believed that the high chloride content of laterite profiles combined with the acid produced by the oxidation and hydrolysis (ferrolysis) of iron has caused dissolution of Au/Ag and Au/Te alloys. Gold, and less frequently silver, is subsequently reprecipitated in the profile nearby.Pyrite, which is a ubiquitous accessory of gold in vein or lode systems, is probably an important source of iron for the development of acidity. Where carbonate is abundant in the primary assemblage, neutralization directs the oxidation of sulphide to a path which produces thiosulphate, and an alternative type of Au/Ag oxidation process. Sulphide/carbonate ratios in the vein system, and adjacent wallrock are seen as important in determining the course and extent of remobilization in the oxidized zone of gold deposits.

Jan 1, 1984

The U.S. Bureau of Mines has developed a prototype cross well acoustic logging system and complementary tomogr`aphic image reconstruction software for the detection and delineation of abandoned underground mines and associated subsidence failure in relatively shallow environments. The logging system uses a piezoelectric, cylindrical bender as an acoustic source. A triaxial accelerometer assembly, designed to be rigidly locked in the borehole, is the receiver portion of the logging system. Both the source and receiver probes operate at high frequencies, thus providing short wavelengths capable of resolving small features in most rock types. A modified van with a dual-drum wireline winch, 4-channel data acquisition system, power amplifiers, and waveform generator supports field operation of the logging system. A field study was conducted at a test site in San Antonio, Texas, to demonstrate the cross well acoustic logging system. The underlying rock at the test site is similar to stratified sediments in coal measures. First- arrival travel times were interpreted by tomographic reconstruction of the velocity field in the two-dimensional cross section between the source and receiver boreholes. The resulting image correlates well with geological borehole logging data for the test site.

Jan 1, 1992

Gold mineralization belt of eastern China in the adjacent part of the northwestern Pacific rim is orientated NE to NNE and as-sociated with Mesozoic faults and igneous intrusives and Mesozoic to Cenozoic volcanism and subvolcanism extending more than 3000 km in length and 300 to 800 kni in width affected by the movement from the Pacific Plate subducted against the Asian Plate.The relative movement between the Pacific and the Asian plates give rise to two types of fracture zones, the tensional ones providing the space for the formation of fissure-filling type of auriferous quartz veins and the shear zones providing the space for the formation of hydrothermal replacement type of gold de-posits in Shandong Peninsula. The fissure filling type of quartz vein, is represented by Linglong gold deposit which is hosted in Mesozoic Linglong Granite and consists of hundreds of quartz veins filling fractures trending NE to NNE and the hydrothermal replacement type is represented by Sanshandao gold deposit which is hosted in crushed and hydrothermally altered Mesozoic Linglong Granite in contact with Archaean metamorphic complex of Jiaodong Group along a Mesozoic upthust fault zone trending NE.

Jan 1, 1990

Syferfontein Colliery, part of the Sasol group of companies which specialises in the field of petro-chemical production, was established in 1990. The mine is situated about 150 km east of Johannesburg, South Africa. Two coal seams are mined, utilising two 75 m3 draglines, shovels and a fleet of 177 ton rear dump trucks. The mine will reach its full production capacity of seven million tonnes per annum in 1992. During the planning period, prior to the establishment of the mine, management were confronted with the unstable socio-political environment in South Africa which could jeopardise the eventual success of the mine. They consequently conducted a strategic planning exercise to determine guidelines for mine planning to improve the chances of success in this unstable third world environment.The strategic guidelines formed the basis for specific actions taken during the planning and commissioning of the mine. Specific actions were taken in the field of operating cost, labour relations, working environment, logistics and the general environment. First results indicate that these actions have played a major role in the success of the mine to-date. This process can be utilised by others facing similar or even totally different uncertainties.

Jan 1, 1992

A study is presented of the theoretically possible initiation systems for outbursts and the subsequent propagation mechanism.Previous occurrences of outbursts and their correlation to the theoretical system are described. An estimation of the energy release from two energy sources, gas strain energy and rock/coal strain energy, is presented and the relative importance of each source in the severity of outbursts. Summary: The description of mechanisms of outbursting follows the examination of these phenomena at Collinsville in Bowen No. 2 mine and at Leichhardt Colliery, Blackwater. Quantitative material contained in the paper refers to Leichhardt Colliery, Blackwater. Clearly from the work carried out to date gas release has a major part to play in the out- bursting at both of these collieries. In the case of the December 1 1978 outburst at Leichhardt Colliery energy release estimates place gas strain energy release contributing eight times the energy of that from rock/coal strain energy. Even the normal outbursts at Leichhardt Colliery appear to show this trend. Estimates of energy released are for comparative purposes between gas and rock strain energy and the values obtained may be regarded as approximate.

Jan 1, 1980

By Chitombo GP

The proposed guidelines on vibration limits that have been circulated by the Australian Environmental Council, demonstrate the need for an extensive data collection and evaluation program to avoid the enacting of abritrary and costly legislation. The operational or practical influence of blast design and overall economic implications of legislation which further reduces permissible levels of ground vibration are discussed. In a typical blasting operation, blast sizes could become smaller and blasting correspondingly more frequent to meet pro- duction demands. Blasthole diameters and charge lengths could be reduced, increasing drilling costs and associated labour costs. Blast size however, is frequently controlled by factors associated with machinery, grade control, pit control, stope size, production contract levels and other factors which cannot be readily changed for operating mines. Blasthole diameters are frequently deter- mined by existing drilling equipment, length of holes (depth of ore or stope size), geological structure and other factors which are not easily changeable. Typical large scale open stoping and strip mining opera- tions are analysed as case studies. The effects of extreme leg- islative limits and the corresponding operational changes with respect to variations in production costs are discussed.

Jan 1, 1987

By Wygralk A, Hallenstein CP

On a world scale, many Mid-Proterozoic fluvial sediments are prospective for low grade, large-tonnage gold deposits. A significant area of the Northern Territory is covered by such Mid-Proterozoic sediments, the gold potential of which has been barely tested. The geological knowledge of these sediments is summarised. The Westmoreland Conglomerate, the basal Mid-Proterozoic formation of the McArthur Basin, has been subjected to detailed sedimentological studies in order to determine the paleoenvironments and to assess the possibility of paleoplacer occurrences. The results indicate that the sandstones and conglomerates of the formation were deposited by braided rivers and debris flows as an alluvial fan which originated in source areas to the north east. The formation contains several upward-fining cycles of sedimentation, which are related to repeated periods of uplift in the source areas. The formation of placer-type gold occurrences is possible in such depositional environments. Very limited heavy mineral sampling has indicated a cassiterite- wolframite-gold suite in the sediments of the Westmoreland Conglomerate. Disconformities at the base of sedimentation cycles are deemed to be the most likely sites for large-tonnage paleoplacer concentrations.

Jan 1, 1984

By Skaviniak M

Some better perspectives applying to the exploitation and dressing of polymetallic ores in the Banskfa. gtiavnica-Hod- rusea Ore District are supposed to be achieved after a suc- cessful investigation and proving there the existence of deep-seated mineralization as well as due to increasing de- mand for non-ferrous metals and consequently to higher mar- ket prices of those recently noticed. With respect to the present situation in mining and to the further technical development as well, a several times higher exploitation may be in this region expected, especially in the deeper .eated parts of the deposit. When solving the tasks of a complex economic exploitation over the whole region, consi- derable attention is paid to regional relations and impact studies (due to expected exploitation and ore dressing but also to very difficult problems of dewatering (drainage pro- blems-). It will be first of all necessary to find there an equilibrium between the consequences resulting from the re- naissance of mining industry and environmental requests un- dispensable for the city of Banska 9tiavnica and the other neighbouring towns in the vicinity of mining plants.

Jan 1, 1988

By Peng S. S

Measurement of pressure distribution under the base plate of the Hemscheidt 2-leg 800-ton shield was performed underground for two shifts using 12 pressure cells installed in two rows, one each under each split base plate. Pressure distribution was uneven depending on contact condition. In general the highest base pressure occurred at 1/3 of the base plate contact length from the rear edge. The resultant was near vertical, and the pressure under the tail side split base plate was always higher than the head side. For comparison, pressure distribution on the canopy and under the base plate was also measured under controlled conditions at the USBM's Mine Simulator Testing Facilities in Pittsburgh, PA. A total of 45 tests were conducted under several simulated contact conditions. The results showed that the actual contact area is highly dependent on the compliance of the immediate roof and floor due to the sloped canopy tip and a base lifting device under the base tip. The loading distribution tends to change in magnitude and profile as the leg pressure increases. The base lifting device exaggerates the high toe loading on the base plate characteristics of this type of shield support.

Jan 1, 1992

The exploration and mining risks are investigated and compared to the risks of smelting, secondary processing and other normal industrial activities. This study concentrates on the risk before, or at the investment decision. Internal and external risks are distinguished. Internal risks are the risks inherent in every engineering design and common to all projects. The main external risks are the financial risk, changes in prices, location problems and geological factors. Financial risks concern every capital-intensive and export-oriented project and cannot be considered as typical mining risks. Changes in prices, i.e. the market risk, concern every industry using raw materials, but the market risk is especially accentuated in the mining industry. Problems of location and infrastructure are normally more significant in mining than in other projects, and geological risks are unique to mining. All these risks associated with mining projects combine to form a risk at least twice as high as that for other normal industrial activities. Within the range of profitability of mines, which on average is the same as in the manufacturing industry, only a few highly profitable mines exist. These few mines are the sole reward for the high risks taken.

Jan 1, 1986

By Muir D. M

Highly saline process water has a number of implications for the CIP process during the leaching, adsorption and recovery of gold. The reduced oxygen solubility in saline water can seriously reduce the rate of gold leaching, while dissolved oxygen meters do not necessarily reveal actual oxygen concentrations in saline water. High levels of magnesium in the ground water necessitate operation at lower pH (-9), with the potential for greater cyanide loss via HCN stripping. In addition increasing salinity renders viscosity modifiers largely ineffective.The adsorption capacity of aurocyanide onto activated carbon is improved with increasing salinity, but misleading results can be obtained in assessment of gold loading kinetics of plant carbon samples already loaded, or partially loaded, in saline water if subsequently tested in fresh water. Elevated chloride levels in the Zadra elution process can cause severe anode corrosion in the elecuowinning cell. The Anglo elution process is tolerant to only slight increases in water salinity, but elution times can be reduced by ethanol addition. Care is required in carbon regeneration, as salts can catalyse carbon decomposition as well as increase kiln corrosion.

Jan 1, 1994

By Piga P, Sammarco O

Ventilation and the environmental climate in the Campiano mine is the subject of this re- search. The mine is located in Southern Tuscany (Central Italy), a region where geothermal gra- dients are very high (three times the average gradient of the earth). The research produced interesting indications as to the influence of surface climatic conditions on the environmental parameters inside the mine. A close correlation has been found between dry-bulb temperature and humidity ratio of the air in the mine for dif- ferent metereological conditions and for differ- ent mass flow rate values. Variations in air enthalpy, caused only by the heat exchange with the rock walls during the flowing of the air through the mine, depends on the surface temperature values. Statistical analyses have been used to ex- press air enthalpy variations on surface tempe- ratures, on the variations of the humidity ratio that the air undergoes inside the mine and on the mass flora rate. The application in practice of the results will permit the identification of correct mea- sures to be adopted so that optimal microcli- matic conditions are produced in the mine.

Jan 1, 1986

By U Dzharlkaganov, B Bekmurzayevand M

The principle conception is presented of timely planning of winning operations in complex-structural blocks and faces in week-24-hourly regime. For adequate description of complex interconnections of open cast operation in space and in time and solving of optimisation problems in timely regime it is necessary using of complex logical and calculation procedures.

Jan 1, 2003

By Hall C. E, Chrisholm J. M

Resource calculations for shear hosted deposits of any type are difficult regardless of which calculation technique is used. One of the main problems is the determination of the geometry of the mineralisation. Once this has been elucidated then the appropriate resource calculation methodology can be employed with a search distance and orientation that is relevant.

Jan 1, 1993

A unique opportunity is presented to Australia by recent developments in the Carpentaria and Mount Isa Mineral Province.Unique in two ways:The size, diversity and multiplicity of mineral finds in the region, and the continuing prospectivity.The approach being undertaken to accelerate development, increase the value generated for all stakeholders, and the value added in the region.

Jan 1, 1993