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By Michael G. Zabetakis

Vaporization of a solvent into an airstream at temperatures above the flash point of the solvent is hazardous if vapor is liberated at a rate that is sufficient to produce a flammable mixture. In may operations, the formation of such a mixture is prevented by rapid diluton of the vapors with air. The minimum air requirements for the dilution process are determined by the composition of the lower limit mixture at the temperature and pressure of interest. Because limits of flammability cannot always be calculated with sufficient accuracy for a proposed operation, they .rust often be determined experimentally. The present Bureau of Mines investigation was prompted by an application in which the lower limits of flammability of a number of solvent mixtures were required over a range of temperatures at atmospheric pressure. These limits were to be used along with available solvent-vaporization-rate data to establish minimum airflow rates needed to prevent the formation of flammable mixtures in an industrial process. Lower limits of flammability were determined for a number of mixtures containing methyl ethyl ketone, tetrahydrofuran, toluene, ethyl alcohol, and ethyl acetate in dry air-at atmospheric pressure and temperatures between 16° and 200° C. The experimental values were found to be in good agreement at with those predicted by Le Chatelier's law; variations with temperature were in fair agreement with those predicted by a modified Burgess-Wheeler law.

Jan 1, 1962

By E Jak, M Shevchenko, E Nekhoroshev, D Shishin

In the field of pyrometallurgy, the presence of multiple molten phases with distinct chemical compositions, such as slags, mattes, speiss liquids, metals and molten salts, is a well-known phenomenon. These phases exhibit strongly non-ideal solution behaviour and are mutually miscible to varying degrees. To describe these complex molten liquids, the Modified Quasichemical Model (MQM) has proven effective and has been applied to numerous binary, ternary and several higher-order multicomponent systems related to pyrometallurgy. In recent decades, the complexity of high-temperature processes has escalated due to increased impurity concentrations in primary ores, the incorporation of recycled consumer products and the integration of metallurgical plants through by-product and waste exchanges. To address these issues, PYROSEARCH laboratory has been developing large 20-component thermodynamic database using a generalised CALPHAD (CALculation of PHAse Diagrams) methodology integrated with experimental investigations. Over the past decade, strategic decisions were made balancing the ability to generate experimental data, prediction power, accuracy, stability of calculations, as well as computational time, which are discussed in the paper. Examples provided for issues of >3 liquid immiscibility, non-ionic behaviour and exaggerated ‘sharp’ enthalpies of mixing in silicate slags, dealing with multiple oxidation states, as well as comparative analysis of pair and quadruplet approximation in MQM.

Aug 21, 2024

By Tuan V. Nguyen, Louis Mittoni, Murray Rudman, CSIRO Minerals, Jean D. Swift, John B. Farrow, Phillip D. Fawell

"Research projects towards developing a sound understanding of the factors controlling the performance of gravity thickeners have been conducted by the AJ Parker Cooperative Research Centre for Hydrometallurgy since 1988 through AMIRA International. The current phase of this work, the three year P266D “Improving Thickener Technology” project, has 27 sponsors comprising mineral processing companies, reagent suppliers and thickener manufacturers.These projects have resulted in the development of a range of tools and techniques to address flocculation, thickening and associated dewatering issues. A number of Computational Fluid Dynamics (CFD) models have been developed to predict likely full-scale thickener performance under various process conditions, based upon a knowledge of thickener design, plant flows and assessment of the flocculation behaviour of the feed slurry. At the same time, various laboratory and plant studies have been used to quantify important thickener processes, and to provide validation of the CFD models. These numerical and experimental capabilities have been applied to various thickener issues across a broad range of mineral processing operations, leading to significant process improvements and substantial financial benefits.This paper presents an overview of the work conducted during these projects, focussing on the research tools, the nature of the information that has been gained and the implications for thickener performance."

Jan 1, 2003

By D. R. Rathburn

Jan 1, 1962

By M. Wright, A. H. Mwale

Opportunities to promote enhanced eco-efficiency (i.e. the simultaneous improvement in economic and environmental performance) for the minerals industry exist across the whole value chain. However, given the current operational models of major companies within the industry, and their focus on refining of primary ore bodies, it is important to understand where such opportunities might lie within minerals beneficiation, as it is here that major environmental pressures are felt. This paper examines the combination of unit technologies in a minerals beneficiation train, and explores the inter-relationship between energy input and water consumption for a given mineralogy and product recovery, as these are two critical environmental issues which affect the overall viability of many minerals plants. In particular, we review constitutive relationships for each of the sub-processes of comminution, flotation, and tailings dewatering, and suggest how these might be integrated into a unified hybrid model, with particle size distribution as the key design variable. Such a model can then be used to explore the trade-offs between different performance objectives (be these technical, economic or environmental) as part of a multiple-objectives optimisation exercise. In this way, it may become practical to envision situations in which concentrate grade and recovery are sacrificed, marginally, in order to reduce energy demand in comminution, and improve overall water recovery. In addition, this work provides a useful baseline against which to analyse the potential for dry processing. This becomes more relevant as the industry commits to advancing the sustainable development agenda in the face of the increasing life -cycle costs and impacts of minerals processing operations, coupled to declining ore body grades, and the desire to maximise recovery of minor and trace elements. Some specific observations for copper are offered, supported by operational data from Zambian copper mines.

Jan 1, 2003

By Juliana Gutiérrez-Paredes

Keywords: Slag, chromium oxide, recovery, stainless steel Experimental and theoretical work was performed to estimate the effect of slag basicity and amount of reducing agents on the reduction of chromium oxide from the slag which interacted with molten steel at 1600°C. The slag system contained CaO, MgO, SiO2, CaF2 and Cr2O3 together with Fe-alloys (Fe-Si and Fe-Si-Mg). The CaF2 and MgO contents in the slags were 10 mass % each; Cr2O3 was 25%. The amount of the ferroalloys ranged from 12.5 to 50 g per 100 g of slag. The (CaO+MgO)/SiO2 ratio was held at 1 and 2. The Cr yield was determined using both Fe-alloys as reducing agents. Some estimations were made to determine the theoretical effect of temperature, slag basicity, (CaO+MgO)/SiO2, and amount of reducing agents in the slag on the chromium recovery. The FACT (Facility for the Analysis of Chemical Thermodynamics) computational package is used to determine the equilibrium between the slag and molten steel.

Jan 1, 2005

By Fred N. Kissell, Andrew B. Cecala

In This Chapter [Where methane is emitted at longwall faces Where methane accumulates at longwall faces Using the modified shearer-clearer to eliminate ventilation eddy zones Using a walkway curtain to reduce methane buildup during the headgate cutout Control of frictional ignitions and The best location for the methane monitor] The methane released along a longwall face represents only 10%–20% of the total methane emitted from the entire longwall panel. Nevertheless, in very gassy coal seams, this methane released at the face can pose a problem because the shearer is a ready ignition source. Preventing methane ignitions at longwall faces requires four actions. The first is to provide better ventilation around the shearer to eliminate the ventilation eddy zones at the drums where methane builds up. These eddy zones are eliminated by mounting additional water sprays on the shearer to direct air into them. The second action to prevent methane ignitions is to install a water spray behind each cutter bit and regularly replace worn bits. Water sprays behind each cutter bit act to quench the hot metal streak that follows a worn bit when it strikes rock. The third is to ensure that no ventilation eddy zones are inadvertently created by poor placement of water sprays. The fourth is to ensure that the methane monitor on the shearer is in the best location to detect methane accumulations. ADDRESSING METHANE ACCUMULATIONS AT LONGWALL FACES3 Cecala et al. [1985a, 1989] and Denk and Wirth [1991] studied methane emission and ventilation patterns at longwall faces to find where methane accumulations are most likely. Although not always the case, the major source of methane at longwall faces is usually the breakage of coal by the shearer. Stress-related fracturing of the coal seam at the face, called bumps or bounces, can cause the release of additional gas (Figure 4–1).

Jan 6, 2006

By S. Rupprecht

"This article addresses the prevalence of poor public reporting practices of coal exploration results, coal resources and coal reserves in southern Africa. Currently, the reporting of coal tonnage without supporting coal qualities or saleable tonnes and quality is a poor reporting practice that occurs far too often. Not all coal is equal — therefore it is extremely important that investors or potential investors are provided with the full details of both run-of-mine (ROM) and saleable coal tonnage, their associated qualities and other material and relevant information.Competent or qualified persons should note that publicly reported information should be sufficient to enable an informed reader to make a reasonable and balanced assessment of the significance of the information provided. “Companies are encouraged to provide information in their public reports, which is as comprehensive as possible (CRIRSCO, 2013).” However, too often this isn’t the case, and material matters are either not reported or inadequately disclosed.According to the South African National Standard (SANS) 10320:2014 draft document, “tonnage and coal quality that will be available for sale, either in the raw ROM state (raw saleable) at a specified moisture content, or after beneficiation of the ROM coal by processing operations to produce materials at specified qualities, size ranges and moisture contents. The assessments must demonstrate that at the time of reporting, the marketing of the products is reasonably justified. The basis of the predicted practical product yield to achieve the saleable coal reserve must be stated. The moisture basis of reporting shall be stated.” An example as to why coal qualities are so important to the public, the requirements of South Africa’s electric public utility (Eskom) power stations are detailed in the followint paragraphs. The Kendal power station, commissioned in 1988, operates at a calorific value (CV) range of 19 to 20 MJ/ kg, an ash content between 29 and 34 percent and volatiles between 20 to 21 percent. Other power stations, such as Kriel or Hendrina, may require different qualities, such as a CV range of 22 to 23 MJ/kg, an ash content between 20 and 28 percent and volatiles between 22 to 23 percent. Thus, in terms of domestic saleable coal, it is not just about reporting the coal qualities but also informing the investor as to which power station the coal is intended to be sold as “boilers are designed to burn particular qualities of coal” and “it is not always possible to transfer coal between stations because of different quality requirements at each station (Chetty, 2010).” Sulfur content is another important quality with the ideal coal content having a quality of less than 1 percent sulfur."

Jul 1, 2019

By G. R. Adhikari

Step 4: Selection of explosives and initiation system Various types of explosives are manufactured in India and a wide choice is available among them that include nitroglycerin based explosives, slurries, emulsions, ANFO (ammonium nitrate mixed with fuel oil) and heavy ANFO. The choice is also available between cartridged and bulk loading systems. In Indian mines, much importance is unduly given to the cost of explosives alone which is not conducive to optimization of blast design parameters. The concept of energy per meter of blasthole and the way in which the total explosive energy is partitioned between shock and heave is not considered in the prevailing practices. Besides, very little efforts are made to objectively evaluate the performance of explosives for a given site condition. Tailoring explosives is limited to changing the density of the bulk explosives. Cartridged explosives are still being extensively used in large operations where bulk explosives should be the preferred choice.

Jan 1, 2002

By Frank C. Townsend

Centrifugal model embankments with varying geometries and materials were constructed of- coal waste material, accelerated From 100 to 120 times earth's gravity, and subjected to various throughflow rates until failure occurred. Complementary laboratory tests were performed on the waste materials to obtain strength and permeability parameters for analytical calculations to predict observed centrifugal model behavior. Failures in the form of deep.-seated failure, or erosion and sediment transport or a combination of both, occurred in model embankments with 1V:1-1/2H and 1V:2H slopes when the phreatic surface due to seepage exited on the downstream slope: Positive seepage control, i.e., a toe drain successfully prevented sloughing and failures. Slope stability analyses agreed well, albeit conservatively, with observed model performance. Factors of safety ranged from 0.7 to 1.02 at the instant of failure for models with retrogressing slips as compared with 1.05 to 1.7 for stable embankments, These models verified existing criteria of a minimum safety factor of 1 3 and the necessity of positive seepage control.

Jan 1, 1980

By Douglas Rudenko

Have you ever had a neighbor complain about a blast one day, but says the next day’s blast was better, even though the Peak Particle Velocity (PPV) increased? How about neighbors that complain about a small trimming shot, but don’t complain about a big production shot? Have you ever reduced the pounds/delay and gotten more complaints? Mine operators are often bewildered when trying to correlate blast design parameters to homeowner complaints.

Jan 1, 2002

By Claudio Flores Martinez

The prospect of accomplishing economically and scientifically profitable deep-sea mineral mining within this decade or the next one is of particular interest to the emerging discipline of astrobiology which is concerned with the origin, distribution and future of life in the Universe. Several planetary bodies within our own Solar System such as Jupiter’s moon Europa and Saturn’s Enceladus now appear to be potentially habitable, or life-friendly, in terms of the three prerequisites for life as we know it: a sustained body of liquid water, biogenic elements (C, H, N, O, P, S) and energy sources to fuel metabolic reactions. Europa, for instance, possesses a global subsurface ocean, believed to be up to 100 km in depth, hidden beneath a kilometer-wide ice-sheet. A silicate mantle is directly interacting with a cold, aphotic ocean in which tidal forces might drive geological seafloor activity that results in the creation of hydrothermal systems. These locales are commonly hypothesized to be the cradles for an alternate origin of life on Europa. Especially alkaline hydrothermal springs, as found at Lost City, have been at the center of modeling the prebiological evolutionary dynamics preceding cellular life. Serpentinization-like reactions are also possibly fueling metabolic networks in putative microbial communities found in the oceans of the icy moos. Major space agencies around the globe are planning future space missions aimed at exploring and eventually characterizing potential life forms in these habitats. The technology needed for this exploration effort resembles the requirements for a successful deep-sea mineral mining industry: highly efficient AUVs (also equipped with biologically-oriented instrumentation), swarm robotics, landers, seafloor rovers and general high-pressure, cold temperature extreme environment engineering. Interestingly, science questions of deep-sea mineral mining and astrobiology converge too: the hypothesis of life originating at hydrothermal systems, the biogeographical distribution of species among these environments, adaptations of extremophilic organisms across the three domains of life and adequate autonomous robotic systems to assess the complexity of deep-sea biological communities. This presentation attempts to present a two-fold view of advanced planetary exploration that relates to a sustainable vision of deep-sea mineral mining: charting our oceans and developing technologies least harmful to endemic biology can propel the design and prototyping of future robotic planetary probes bound for aquatic missions on alien moons. Space industry, government and public interest towards a broadened planetary perspective on deep-sea mineral mining is promoted by addressing an astrobiological rationale of this endeavor.

Sep 1, 2014

By Zhuokun Cao

Manufacture of aluminum foams still suffer from nonuniformity and poor reproductively for there is lack of basic knowledge of foaming process. In this paper, carbon fibers are used as novel stabilizing additive for aluminum foams, and the structure evolution of aluminum foams with different fiber content was studied. A laser rangefinder was used to detect the expansion rate of different al foams. Al foam samples are solidified at different foaming time to determine its relative density and cell size distribution. Results indicate that the cell size of foams linearly increases with the decrease of density, and the slope of the line is influenced by fiber content. The relationship between expansion ratio, density and cell size of the foams is discussed. It is concluded that the density of resulting foam is influenced by the rate of gravity driven drainage, and its cell size is determined by expansion ratio and foaming time.

Jan 1, 2010

By D. Laguitton, D. Hodouin, V. K. Gupta, R. Spring

"The CANMET SPOC project aims at inducing progress in process evaluation and optimization by developing user oriented software based on state-of-the-art theory. The present work is the result of a joint effort by CANMET, Noranda Mines and Université Laval to develop two computer packages: one (RTD) to calculate the residence time distribution that best describes the material transport through the mill, the other (FINDBS) to estimate the rate of breakage and distribution function of the population balance model in a ball mill. The RTD package can handle data from various experimental methods (impulse or complex tracer feed, with or without recycling, etc...). The FINDBS package provides options for the functional description oj both model parameters Band S. The full detail of the methods and programs appears in a users guide. The program capabilities and several sample runs are presented.IntroductionSimulation of mineral dressing operations by computer has been largely contained within academic and research circles and has not yet gained a status of routine practice in the ore and coal industries. It is however a matter of time before process simulators are available on every process engineer's desk to assist process optimization tasks, flowsheet design and professional training. The CANMET SPOC project (Simulated Processing of Ore and Coal) was initiated in 1980 to assist the Canadian industry in integrating computer-based methodology for process evaluation and optimization(1). Software development, documentation and transfer is one of the main priorities of the project which will mature in 1985 by releasing a complete package of manuals and programs covering sampling, material balance computation, unit modelling, flowsheet simulation and optimization . This paper is a condensed description of a typical project element in its 1982-1983 state of development. The required methodology for ball-mill modelling and simulation was consolidated an d merged to other project elements during a joint study under contract financed by CANMET and Noranda Mines Ltd . The first part of the study dealt with documenting experimental methods and software for ball-mill computer simulation. Université Laval GRAAIM (Goupe de Recherche en Automatistion Appliquée à l'Industrie Minérale) acted as sub-contractor for this part of the study(16,17). A second part dealt with applying the model calibration techniques to a large industrial data base and is reported elsewhere(2,18,19)."

Jan 1, 1984

By P. Mokwena

Paper written on project work carried out in partial fulfilment of BSc (Hons) in Chemical Engineering Diamond synthesis has attracted a great deal of interest because of its exceptional properties and various applications. In this study, the chemical catalytic vapour deposition (CCVD) method was used to synthesize diamond films using acetylene as carbon source and hydrogen as carrier gas at a temperature of 1000°C, and their thermodynamic stability was studied. Photographic analysis revealed that these products are diamond films, Ramman spectroscopy confirmed that they are graphitic while confocal laser scanning microscopic image analyses proved that these diamonds films have structural defects due to iron impurity from the catalyst precursor. The quantity of diamonds films produced is also proportional to the acetylene to hydrogen ratio but these films are larger in size at lower acetylene to hydrogen ratio. Thermogravimetric analyses showed that transformation of these materials begins at 25°C but could not be used to determine if a temperature range below 25°C exists. The stability of these CCVD-synthesized diamonds also increases below 25°C when stored at different temperatures.

Jan 1, 2007

By W. Dziurzynski

The present article sets forward the results of field tests that made it possible to validate the mathematical model used in the VENTGRAPH ventilation engineer programmes. The case considered relates to the introduction of a new heading to the ventilation network of the mine. The utilisation of computer programmes in practice is justified by the necessity of ensuring expected performance and secure conditions in the network of mine headings, where - for example - plans are being made to utilise the transport dip-heading, taking into consideration fire and methane hazards. In the article we have presented the methodology of preparation of a database for computer programmes of the VENTGRAPH system, obtained on the basis of ventilation measurements. The next step consists in the execution of a design of the modified network and prediction, this on the basis of heading geometries, of parameters characterising the flow of air for the designed headings. Due to the fact that the heading was in the final stage of driving, following its introduction to normal operation and the stabilisation of flow values it was possible to retake ventilation measurements, which validated the results obtained through computer simulations. In order to execute measurements of the volume flow in the dip-heading, we employed a new wireless multipoint measurement system to determine the velocity field of air in the mine heading; the results are characterised by a high accuracy of measurement. As a part of fire prevention and incident management planning, a series of underground fire case studies for the a validated network flow model has been made. Results of simulations show the capabilities of the FIRE module of the mentioned software, including assessment of stability of flow directions and hints on counter and preventive measures for particular locations of fire.

Jan 1, 2009

By Steven A. Mathe, Seokbin Lim

Current analytical models can accurately predict the final velocity of explosively driven flyers and can somewhat predict the acceleration profile, but do little to address the deformation of the flyers. Explosive systems such as linear shaped charges and explosively formed projectiles, which can be described as multiple interacting explosively driven flyers, often involve interactions between the flyers that occur much before the flyers reach their predicted final velocity. In this regime, it is important to accurately understand both the acceleration profile and the deformation profile of the flyers, as both significantly affect the functioning of the explosive systems. Previous work proposed an analytical model to meet this need. As the expanding gas cloud of detonation products drives the flyers, rarefactions impinge upon the gas cloud from around the flyer edges, which produces a pressure difference across the back face of the flyer leading to deformation of the flyer. Previous research condensed the effects of the rarefactions into a single term, the pressure release ratio, ?, which was calculated based on hydrocode simulations of a block of explosive only and an assumption of isentropic expansion. This work intends to determine the value of ? for different explosive compounds. The results of this analysis were compared to hydrocode simulations of an open-faced sandwich configuration explosive/flyer system with an average accuracy of 15% across the tested compounds.

Jan 1, 2015

By A. E. M. Warner

At the Copper Cliff Smelter, Inco Limited has extensive experience in converting primary smelting mattes over a broad range of nickel/copper ratios and compositions. In the past 35 years, technology developments at Inco have reduced the number of Peirce-Smith converters in Nickel/ Bulk (nickel-copper matte) service from 13 to the current 5. This paper will discuss: ? The performance and life of ?stretch? 13.7m shells versus conventional 10.7m converters. ? Process control and information system development from the early 1980?s to view converter aisle status on a continuous basis to the recent central control of the stretch shells. ? Nitrogen cooling of finishing matte from plant testing to implementation in the early 1990?s to replace the dedicated cooling converters. ? The impact on converting of changing the smelter flowsheet in the early 1990?s. ? A current program to develop a converting strategy for the future to address environmental issues and profitability.

Jan 1, 2005

By Michel Brissette

"To recover more valuable ore and considering the complexity of minerals, the needs to grind finer is increasing. To reach the desired fine grinding targets, using the existing grinding media size, the energy consumption is increasing exponentially. As already proved at this conference, small grinding media represents the best potential to improve grinding efficiency. How do the small grinding media perform in industrial grinding mills?The use of small grinding media in regrind mills proved that finer grinding can be achieved at lower energy consumption. In ball mills, smaller grinding media versus 25 mm media generate a power saving from 10% to 44%. In vertical stirred mills, the power saving increases from 20% to 60%. More potential savings have been identified.For the same operating conditions, how a vertical stirred mill is performing compared to ball milling? In regrind application, a vertical stirred mill with small media (5-12 mm Millpebs) will require at least 62% less energy than a ball mill charged with 25 mm grinding media.INTRODUCTIONIn some mining applications, fine grinding is needed to liberate further the valuable ore. The purpose of regrind mills is to achieve the last stage of grinding before final flotation stage: the cleaners. In part because of high prices of small grinding media as well as availability, the most widely used size of grinding media is 25 mm.When calculating the recommended ball top size from Bond’s formula (Bond, 1961), the size for regrind applications is much lower than 25 mm. Today, the barrier for small grinding media is broken. They are best suited in regrind application. The size of grinding media is one of the most important variables affecting the mill efficiency (McIvor, R., 1997; Nesset, J.E., Radziszewski, P., Hardie, C. & Leroux, D.P., 2006).Conventional ball milling was discarded for fine grinding because of its very poor energy efficiency (Zheng, J., Harris, C.C. & Somasundaran, P., 1994; Yan, D.S., Freeman, M. & Dunne, R., 1995). Therefore, new technologies as stirred mills were developed to grind finer more effectively. Three fundamental questions should be asked. What is the best fine grinding technology? What should be the best media size to use? Is it possible to grind finer by using less energy with the existing regrind equipment?"

Jan 1, 2009

By B. K. Mishra

In order to maintain higher grinding efficiency in tumbling mills the mill interior and dynamics must be known. For this purpose, several different types of non-intrusive methods have been proposed and are being tried in the industry. We have made an effort to develop a diagnostic tool based on vibration signal. Here we discus results of our experiments pertaining to ball as well as SAG mill. In each case, a triaxial accelerometer was used to capture mechanical vibration generated due to the tumbling action of the charge. The vibration signal was transmitted to a remotely placed computer and the signals were analyzed by standard signal processing technique. In case of a ball mill (5m diameter), qualitative mill information could be obtained by correlating the vibration signal to feed rate and mill filling. An effort was also made to identify different motion characteristic of the charge by analyzing its vibration signal. In case of the SAG mill (10m diameter), liner wear was estimated by comparing the vibration signal emitting out of a freshly lined mill with that of a worn out mill.

Jan 1, 2011