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Electrochemical Behaviour of Massive Chaclopyrite Bioleached Electrodes in Presence of Acidithiobacillus ferrooxidans and Acidithiobacillus caldus In this work, the monitoring of bacterial and chemical dissolution of massive chaclopyrite was evaluated using cyclic voltammetry (CV); the mineral surface was examined using scanning electron microscopy (SEM) and the elements were examined by Energy Dispersive X-ray Analysis (EDAX). The electrolyte employed for the electrochemical tests was the medium used to bioleaching the electrodes (3.0 g/L (NH4)2+SO4, 0.5 g/L K2HPO4, 0.5 g/L MgSO4+7H2O and 0.1 g/L Ca(NO3)2).The results showed differences in voltagramms carried out by Acidithiobacillus ferrooxidans and Acidithiobacillus caldus: In bioleached electrodes tested in the presence of Acidithiobacillus ferrooxidans, the anodic and cathodic current signals were larger than with Acidithiobacillus caldus. The analysis of CV results allowed attributing the different peaks observed in both the direct and reverse potential scanning to the oxidation of chaclopyrite to a secondary copper mineral (bornite, chalcocite and covellite) and its reduction via different non stoichiometric copper sulphides intermediaries. Surface evidences were observed by SEM, and chemical elements evidences were also investigated by EDAX.

Sep 13, 2010

By R. A. Williams

Electrical impedance tomographic methods have been applied to a variety of mineral and chemical processes in the laboratory and on plant. This review paper surveys technical developments in measurement methods to enable quantitative extraction of key process information in the form of mapping of concentration profiles, mixture homogeneity and suspension velocity. The methods for determining velocity are summarized, since this is of especial interest when applied to opaque systems where most conventional optically based measurements fail. A recent significant development is the use of ultra-high speed measurement that now allows velocity vectors to be extracted for fast moving mixtures and fluids (up to several metres per second). New data are reported pertinent to low and high solids concentration flow in pipelines. Use of the methods offer improvements to design of such systems but also points to the use of tomographic electrical sensor as online flow measurement and fault detection. This offers new opportunities for applications and benefits in the design and monitoring of mineral slurries and sludges.

Jan 1, 2008

There are circumstances where the ordinary techniques of experimental variography in geostatistics û now in common use despite their recent origin û are not quite successful. This paper describes a new addition to the geostatisticians tool kit developed by one of the renowned leaders in the field to cope specifically with these circumstances. Possible application of this technique will be outlined when it will be seen that there are still problems remaining to be solved in its use for economic evaluation of deposits with irregular mineralisation.

Jan 1, 1984

By V. K. Kollipara

Air flow patterns in the face area of a room-and-pillar mining are critical for understanding the dust dispersion characteristics and for developing engineering controls. SIUC has previously performed a CFD study to analyze the airflow patterns in the face area when continuous miner is making a straight cut. Results from this study identified low air velocity and re-circulation zones in the face area and illustrated the significance of line curtain, and scrubber operation on the air flow patterns. This paper discusses similar analyses when continuous miner is making a right turn cut as it is considered to be the dustiest cut among all the cuts made to advance an entry through a crosscut. This paper presents results for box-cut development for a right hand turn x-cut. This paper also addresses line curtain advance and air leakage through the curtain on the airflow patterns in the face area for such a cut. Low air velocity and recirculation zones were identified by analyzing the velocity vectors.

Jan 1, 2012

By Brian P. Stapleton, Bill M. Stewart, Joel R. Warneke, Curtis C. Clark

Of the 28 accident/injury classifications listed by the Mine Safety and Health Administration, handling materials is second only to roof falls in terms of generating the highest number of reportable accidents in active underground coal mines. Two materials-handling activities that cause numerous injuries each year are the categories of “handling supplies or material, load and unload” and “moving power cables.” Mechanization and mine worker activity training are two methods that can aid in preventing these injuries. This paper describes three mechanical methods—the mobile manipulator, the in-mine hoist, and a cable-handling system—being developed and tested at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health. Two of the devices are specifically designed for loading, unloading, and moving supplies and materials, and the third device is for handling trailing cables in the confined spaces of coal mines. Also described are safety solutions developed for underground coal mines geared to showing miners safe and unsafe ways of performing various materials-handling tasks.

By Ram Avtar

High tensile thick plates (>80mm, weight ~3000 Kg) of medium carbon low alloy steel, when heat treated, manifested higher percentage of crystalline area (>20%) in fractured surface. Such problem was not encountered in thinner plates. The genesis of higher crystallinity in fracture was examined. It was observed that the thicker plate undergone slower rate (Average 0.9oC/Sec.) from soaking temperature to Ms temperature) of cooling after austenising during oil quenching and thereby quenched microstructure had upper bainites. During tempering of as quenched bainite, additional precipitation took place at the lath boundaries of bainite. This led to weakening of grain boundaries and aided easy crack propagation during fracture and resulted in formation of higher percentage of crystalline area in fractured surface. Enhancement in cooling rate (Average 1.8oC/Sec. from soaking temperature to Ms temperature) of austenised plate by switching over from oil quenching to water quenching practice resulted in complete transformation of austenite into martensite and produced ductile fracture (zero Crystallinity). Plates conformed improvement in mechanical properties between 2-5%.

Jan 1, 2009

By Y Zhuang, S La Brooy

The selection of the optimum process route for a new project has traditionally consisted of investigating existing options and ranking them in terms of cost, technical risk and environmental acceptability. With the current focus on sustainable development other factors now need to be considered. Life Cycle Assessment (LCA) of the process options can be used to extend the assessment in terms of their potential for earning renewable energy credits and in judging their ability to achieve greenhouse gas emission reductions. A rigorous life cycle assessment is demanding in terms of setting the baseline for comparisons and evaluating the elements that make up the emission profiles of the process options. However, a simplified LCA can provide a useful tool for comparing different process options. This approach can be combined with traditional assessment criteria to rank the options available to the project. GRD Minproc has been intimately involved in executing LCA calculations for different municipal waste treatment options. This paper applies a similar LCA methodology to investigate the greenhouse gas implications for different options for copper processing. The process options considered are:concentrator û sale of concentrate to smelter, concentrator û on-site mini smelter, and concentrator û leach SX/EW. The paper then goes on to consider the operating cost implications that could arise with the introduction of carbon taxes or carbon credits and how these might impact on the future choice of flowsheet.

Jan 1, 2002

By M. England

Keywords: Bi-directional tests, Osterberg cell, O-cell®, static load tests, Timeset® Static load testing, where loads are applied vertically to the top of the pile and often referred to as 'top down testing', has been used for many years and has become a 'standard' test for the world of foundation engineering. The method, although well developed, cannot be used under certain circumstances, magnitude of load being a particular issue. There is a finite limit to the load capacity that can be applied with either kentledge, the use of reaction piles or anchors, and as the loads increase, the costs escalate dramatically. A novel test method seeks to overcome all the associated problems of large scale and restrictive area "top down testing", utilising static load testing techniques. The method requires the foundation element to be divided into two or more sections and these can be loaded axially as required using a portion of the foundation element as a reaction. This paper presents some recent applications and developments in the use and application of the bi-directional testing technique using the Osterberg Cell or O-cell® and outlines some of the many advantages of the system. Recent bi-directional test loads applied to bored piles have mobilised capacities of 279 MN and with flight auger piles up to 25 MN.

Jan 1, 2006

By L. Su, S. Liu, K. Jiang, K. Xie

The reduction of iron dissolution and acid consumption is fairly important in the extraction of Ni and Co from laterite ores from both economic and efficiency perspectives. BGRIMM conducted detailed research to investigate the behavior of iron in a nickel laterite leaching process. The mineralogy of Ni and Co was studied. In limonite ore about 76% of nickel is present in goethite while in saprolite ore 79% of nickel is associated with magnesium and silicon minerals. Test work revealed that limonite can be decomposed completely with enough acid concentration during atmospheric leaching. More than 98% of Ni and Co were leached into solution while 85% of the iron was also dissolved with 130-140 g/L iron in solution. Iron precipitates as hematite in the temperature range 250-270?C without neutralization reagents. That’s why limonite is treated by high pressure acid leaching (HPAL) technology to achieve nickel extraction and iron precipitation in the same autoclave. BGRIMM’s test results indicated that the remaining acid in atmospheric leaching solution and acid released by iron precipitation at a lower temperature was enough to leach saprolite efficiently. The so-called inverse leaching technology leaches limonite at atmospheric condition and the leaching slurry combined with saprolite is pumped into an autoclave to leach saprolite at 150-170?C. In the autoclave iron precipitates as hematite without acid consumption. Total nickel and cobalt extractions in the test program were more than 90% with iron content in solution below 8 g/L. In this inverse process iron dissolves in the atmospheric leaching stage and precipitates as hematite in the low temperature leaching stage. Compared with HPAL the leaching temperature is reduced to 150-170 ºC from 250-270 ºC. Compared to atmospheric tank leaching acid consumption is reduced from 850-950 kg/t ore (atmospheric) to 550-650 kg/t ore (inverse).

Jan 1, 2016

By Ivan C. Machado

Jaguar Mining Inc. is implementing a 1.1 Mtpy, 7-year LOM gold project in the Iron Quadrangle (?Quadrilátero Ferrífero?), Brazil. Construction is on schedule and startup is programmed for Q2 2010. Mill feed grade averages 4.43 g/t and LOM gold production is estimated at 800,000 oz. The project entails two sulfide underground mines and three oxide/transition open pit mines. A state-of-the-art flotation/gravity concentration/CIP Plant has been designed based on testwork carried out by internationally recognized Canadian, U.S., and Brazilian laboratories. The mass recovery of the flotation section is only ca 10%, while its gold recovery is about 90%. Therefore, the CIP-ADR Plant will treat only 10% of the solids mass contained in the mill feed, while 90% will be fully cyanide-free material that will be partially used to feed a Backfill Plant. The leached tailings will be conveyed to a rather small tailings dam, whose 20- m3/h supernatant solution will be treated by a new electrolytic technology. The plant design contemplates a High Density Thickener for the cyanide-free rejects exceeding the backfill demand and a Regrinding Section before the Leaching Circuit. The estimated overall metallurgical recovery sits around 92%. This paper focus on the use of modern technologies to reduce costs, risks, and liabilities.

May 1, 2010

By G. Stokreef, B. R. Davis, M. Kadiyski, Alvear Montenegro, H-P. Loock, V. Montenegro

An optical probe for burner monitoring in copper flash smelting, first developed at the University of Concepcion, is being industrially tested in a collaboration between Kingston Process Metallurgy, Aurubis AG, and Queen’s University. The sensor uses fibre-optics and optical emission spectroscopy to analyze the light emitted from combusting particles in the furnace reaction shaft. Information that can be extracted from the emission spectrum includes the temperature and brightness of the flame, as well as emission lines or bands from excited atomic and/or molecular species. Laboratory proof of concept testing of the sensor was first completed in a continuously fed drop tube reactor using O2/S stoichiometric ratios between 0.8–4.0. These O2/S stoichiometries capture the industrial operating condition, which is typically less than 1. The results from lab testing justified a plant trial of the optical probe, which was done in the Aurubis Hamburg flash furnace in September 2018. From this trial, approximately 31 hours of spectral data were collected and synchronized with furnace operating data. The results from both drop tower test work and the plant trial are discussed with implications for process monitoring in the commercial furnace. INTRODUCTION Flash furnace smelting is a continuous feed, batch tap, pyrometallurgical process. It is used to treat copper sulphide concentrates and small amounts of secondary materials, such as dust generated by the process. O2 enriched air and the concentrate blend are fed into the furnace reaction shaft through the concentrate burner. As the particles fall through the reaction shaft, they heat up and ignite, causing rapid, exothermic reactions that oxidize the iron sulphide, some copper sulphide and impurities in the feed. Reacted particles fall into the settler of the furnace, melt and separate into a matte and slag, while the SO2 enriched off-gas is carried out of the furnace for heat recovery and H2SO4 production. Operation of the furnace is achieved by adjusting a limited number of control variables. The main variables are the blast feed rate, blast oxygen enrichment, SiO2 flux feed rate and CH4 combustion rate (CH4 is used when the chemical energy of the concentrate is low) all measured relative to a set feed throughput. (Davenport & Partelpoeg, 1987; Davenport, King, Schlesinger & Biswas, 2002) The batch tapping nature of flash furnaces makes operation difficult because these control variables impact each other, and product quality can only be measured when matte and slag are tapped from the furnace. This means that operation of a furnace is based on feedback control from matte and slag assays. Because of the time-delay associated with understanding product quality, there is interest in using technology to monitor the combustion reactions that happen in the furnace reaction shaft.

Jan 1, 2019

By Leith Sharp

I was confronted with a profound dilemma as an undergraduate engineering student at the University of New South Wales in Australia in 1992. I had been taught that our planetary life-support systems were in a state of alarming decline by an institution that operated as if what the faculty was teaching was irrelevant. Lights were left on in empty overcooled classrooms, recycling bins were nonexistent, lawns were maintained using pesticides and herbicides, diesel trucks spewed fumes as they passed on their way to drop off chlorine-bleached virgin paper. This disconnect was very alarming to me. While it was obvious that universities should play a leading role in teaching and researching sustainability issues, I wondered how it could be possible to make widespread institutional changes to meet the demands of environmental sustainability when it was not even being done in the very university sector where these ideas were being promulgated. If universities would not change, then who can and who will, I wondered? To a growing number of people, the idea of teaching sustainability without demonstrating it is highly problematic. It is also widely believed that the ability of the higher education sector to reform its own practices is an important indicator of humankind?s ability to address the global environmental imperative across all sectors of society. These sentiments have helped fuel what is now referred to as the campus sustainability movement, a movement dedicated to transforming our campuses into living laboratories for the demonstration and practice of environmental sustainability.

Jan 1, 2010

By R. W. Watson, H. D. Peer

"This paper outlines the history of steel linings in the Autogenous Mills, the factors influencing the decision to convert to rubber lining, and the operating and cost experience with the rubber liners to date. INTRODUCTIONSherman Mine is an open pit iron ore mining, concentrating and pelletizing operation located at Temagami, Ontario. The operation employs 392 hourly employees and 81 salaried employees and has an annual capacity of over one million L.T. of high quality iron ore pellets produced from low-grade magnetite ore.The Sherman Mine is a joint venture; 90% owned by Dominion Foundries and Steel Limited (Dofasco) of Hamilton, Ontario, and 10% owned by the Tetapaga Mining Company, a wholly-owned subsidiary of the Cleveland Cliffs Iron Company of Cleveland, Ohio. The operation and management of the mine is by Cliffs of Canada, Limited. Development of the property was started in 1965, with pellet plant production beginning on March 17, 1968. At the present time, the orebodies contain sufficient reserves to sustain operations at current production levels for 30 years. Mining was originally carried out in three orebodies, the North, South, and West pits. The North Pit has been exhausted and mining operations ceased in the spring of 1980. A fourth pit, the East Pit, will be developed during the early 1980's."

Jan 1, 1981

By Ira L. Wright

This paper describing the milling practice of the Black Hawk Consolidated Mines Co., is one of a series being prepared by the United States Bureau of Mines. ACKNOWLEDGMENTS Part of the information contained in this paper was furnished by I. H. Stanley, mill superintendent, Black Hawk Consolidated Mines Co., Hanover, M. M., and a part by the South-western Engineering Corporation, Los Angeles, Calif. The assistance of T. G. Chapman in arranging the paper for publication is also acknowledged.

Jan 1, 1930

By T. J. Driscoll

Methane-air mixtures can ignite as a result of sparking or rubbing of materials, particularly by impact involving light alloys and rusted steel where an exothermic thermite reaction can occur. This report reviews the published literature and describes a new method utilized by the Bureau of Mines for studying the processes occurring during collisions of light metals with rusted steels. The method involves measuring the spectra of sparks and explosions in methane-air mixtures using a photodiode array. Initial results obtained using magnesium and aluminum alloy 6061-T651 projectiles striking rusted steel are reported. These results indicate that the continuous parts of the spectra show a larger intensity for incendive sparks compared with nonincendive sparks, with the largest relative change in the higher energy, ultraviolet region. An unexpected shift of the intensity maximum for the continuous parts of the spectra towards the infrared region was observed for the more incendive sparks. Evaluation of rusted steel samples with electron microscopy, energy-dispersive X-ray spectrography, and Auger electron spectroscopy after they had been impacted by aluminum alloys indicated that aluminum was transferred to the steel in the form of islands that became larger as a function of increasing projectile velocity.

Jan 1, 1982

By Raymond B. Ladoo

"The name bentonite has been applied to a group or series of clay-like materials characterized by an alkaline oxide and alkaline earth content of 5 to 10 per cent, fine grain Giza, high absorptive powers, and usually very strong colloidal properties.Bentonite probably represents no mineral of fixed composition, and its physical properties vary considerably. The type material from Wyoming is light yellow or greenish yellow in color, but from other localities it may be cream colored, white, gray, pink, dark brown or even black. It is exceedingly fine grained, very plastic and highly absorbent. The appearance may be dull or powdeay, but a freshly cut surface usually has a waxy luster. Some varieties have the appearance of wax and may be cut into very thin, translucent shavings. The fracture of the type material is roughly conchoidal, that of other varieties is platey and shale-like, while still others have no typical fracture. Bentonite is highly absorbent; .hen wetted it will absorb more than three times its weight or seven times its volume of water. Some varieties when wetted with water expand to more than six times (some experimenters report eight times) their original volume. The wetted material is exceedingly smooth and soft and feels like soft soap. Unlike most clays, bentonite is easily fusible at a comparatively low temperature.Under a high-power microscope bentonite seems to consist of extremely small, more or less rounded, grains of uniform size, but the texture of most varieties is so fine that individual grains can not be distinguished.Some varieties when finely ground and thoroughly agitated with water will stay in suspension indefinitely, forming a translucent gelatinous mass. The addition of small amounts of acids or sodium chloride seems to have little or no tendency to raid coagulation or settling. Other varieties of similar analysis and appearance go into suspension more easily, but settle out again in a comparatively short time. It has been suggested that the material which stays in suspension indefinitely is a true colloid of the emulsion or lyophilic type."

Oct 1, 1921

By D. Tao, R. Honakey, B. K. Parekh

The dewatering of stable phosphatic clay suspensions generated from phosphate beneficiation in the central Florida is an issue of practical and theoretical importance. Because of its tiny particle size and surface charge, the phosphatic clay takes up to 20-30 years to settle in water and causes environmental, aesthetic, economic, and handling problems. An efficient and cost-effective dewatering/consolidation process for phosphatic clay is of great interest to the phosphate industry in Florida. In this paper, the consolidation and dewatering behavior of phosphatic clay was studied by use of anionic flocculants with and without sand addition. The effects of pH, initial polymer concentration, polymer dosage, polymer addition steps, and metal cations (K+, Ca2+, and Al3+) on the flocculation of phosphatic clay have been studied. Experimental results indicated that clay suspensions were well flocculated at pH 10.5 by DPW-1-1355 and Magnafloc 5250 flocculants acquired from Ciba Specialty Chemicals. Sand particles from phosphate flotation added to the clay slurry promoted flocculation and increased clay consolidation. K+ showed good performance to improve the flocculation characteristics by neutralizing clay surface charge. The adsorption mechanisms of flocculants on clay particles were also discussed in this paper.

Jan 1, 2006

By James H. Owen

Because of price structure, ANFO is normally considered to be the most cost effective explosive used in quarry blasting. Results indicate that bulk smulsion can be more cost effective in applications where hole sizes range up to 6.5 inches in diameter while providing the simplicity of single product loading and storage. This can be accomplished without any fragmentation and/or movement loss usually in patterns which are about twice the size of ANFO patterns, allowing the combined drilling and blasting cost to be less when using bulk emulsions. Examples are presented supporting this concept using actual field results along with some simple calculations which take into account differences in the products such as density, matrix and detonation velocity.

Jan 1, 1998

By William J. Kemnitzer

This study was made to show the growth of petroleum coking and to determine trends and characteristics of marketing and utilization of coke on the West Coast, comparing these data with those of the United States as a whole. An earlier Bureau of Mines economic survey of petroleum coke was made in 1930 before the widespread use of coking processes. Data, derived from published and unpublished literature as well as from interviews with industry representatives, show a marked increase in the production of petroleum coke since the end of World War II. This increase resulted from the need of refiners to upgrade heavy residuums for which the demand was diminishing. Increasing coke production as well as significant market shifts away from California-produced coke have created excessive stocks of petroleum coke on the West Coast. The causes of these market shifts were based mainly on (1) economic factors and (2) certain undesirable qualities of some of the petroleum coke produced in California.

Jan 1, 1965

By William J. Kemnitzer

This study was made to show the growth of petroleum coking and to deter- mine trends and characteristics of marketing and utilization of coke on the West Coast, comparing these data with those of the United States as a whole. An earlier Bureau of Mines economic survey of petroleum coke was made in 1930 before the widespread use of coking processes. Data, derived from published and unpublished literature as well as from interviews with industry representatives, show a marked increase in the production of petroleum coke since the end of World War II. This increase resulted from the need of refiners to upgrade heavy residuums for which the demand was diminishing. Increasing coke production as well as significant market shifts away from California-produced coke have created excessive stocks of petroleum coke on the West Coast. The causes of these market shifts were based mainly on (1) economic factors and (2) certain undesirable qualities of some of the petroleum coke produced in California.

Jan 1, 1965