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By Fred H. Perfect

The thermite process, now approximately 80 years old, has heretofore been practiced in ceramic vessels. This paper outlines the successful production of several million pounds of alloy produced in zuater-cooled copper vessels. THE high temperatures necessary to produce fluid high-alumina slags have probably discouraged earlier workers from attempting to utilize water-cooled vessels. The following is a report of the successful application of this method, together with a report of the physical and chemical problems which had to be solved to make the process practical. About 1955, when Reading Alloys was more concerned with the production of ferrotungsten than with most other types of alloys, it was found to be exceedingly difficult to predict the reaction rate that one would experience from one tungsten ore to another . This difficulty was increased for two reasons: the physical state of the ore as received was seldom uniform, and the size of the mass to be reduced is a very important factor in developing the proper mix for the final reaction rate and temperature. For example, the reduction of ferric oxide with aluminum would theoretically produce temperatures of about 2600°C, and, in spite of the losses due to radiation, the energy is quite sufficient to produce a very fluid slag and iron effecting a very clean separation. On the other hand, the reduction of ferrous oxide with aluminum, while it is not as energetic as the first reaction, nevertheless should give temperatures above 2000"C, which should cause separation of alumina and iron, but, in practice, this is not the case and good fluid slag is not obtained. The heat of reaction, calculated from the thermo-dynamic heats of formation of the constituents of the reaction, offers a convenient guide to the feasibility of a thermite reaction. Thus, the values listed in Table I can be used as an approximate guide for estimating the results which may be expected in the reduction of various oxides and combinations of oxides using aluminum as the reducing agent. As a generalization, those reactions releasing approximately 600 cal per g of total mass represent the lower limit at which to expect separation of slag and metal. On the other hand, those reactions which release 1100 to 1200 cal per g are too violent to be used successfully without the addition of considerable inert material, such as lime, fluorspar, and so forth. Reaction rate is also a very important factor. This, of course, is governed very largely by the sizing and intermingling of the oxidant and reductant and by the starting temperature of the reactants. This is why those figures shown in Table I can only be a general guide. Further, it must be understood, that by adding powerful oxidizing agents, such as nitrates, chlorates or metallic oxides, such as molybdenum trioxide or chromium trioxide, certain problems respecting low temperatures are not necessarily solved. This is true in the addition of oxidants, such as sodium chlorate. By adding too high a concentration of sodium chlorate as a booster for a particular reduction, explosions are generated. Generally, they are of an intermittent type so as to give a Roman Candle effect to the reduction itself; with each surge resulting from a minor explosion more and more material is thrown

Jan 1, 1968

The Hill 50 Gold Mine is situated at Boogardie, 3 miles on a bearing of 295 degrees from; Mount Magnet township. Mount Magnet lies 300 miles north-north-east of Perth, Western Australia (Fig. 1).The older workings of the mine may be identified with those of Sirdar, Gold Mining Lease 696M The Sirdar had been worked before 1902 though no records remain, and irom 1903 to 1912 about a thousana tons at a grade of 6' 2 dwt. was extracted annually; by the end of 1918 6,225 oz. of gold had been obtained from the milling of 17,852 tons of ore. In view of these yields, and the length and width of the lode, this mine was early recognized as one of the most promising in the district. From 1919 to 1924 the ground,including G.M.L. 1282M, was held as Mt. Zion G.M.L. 1183M.The Hill 50 Gold Mine N.L. company took up the workings as Hill 50 G.M.L. 1282M in 1934 and have continued operations to the date of writing. To the end of 1956 the Hill 50 Gold Mine had yielded 982,106 tons of ore for a return of 448,'602 fine oz. of gold.The mine has been described by: J utson (1915), Feldtmann (1920), Johnson (1949), and Finucane (1953). Finucane (1953) details the mine structure to a depth of 414 ft. The author was able to examine the mine to a depth of 1305 ft. Detailed main level mapping to the 1060 level and a detailed surface examination have revealed aspects of the structure which were previously obscure.

Jan 1, 1960

This paper investigates the effects of solids concentration and the addition of Dispersant S40 on the flowability of original and ground limestone slurries. A rotational viscometer with a concentric cylinder geometry and a controlled-stress rheometer with a cone-and-plate geometry were used to characterize the rheological behaviors of limestone slurries. The rheological behavior of original limestone slurries (<100 µm) is transformed through different types of flows with increasing solids concentration. The use of Dispersant S40 can improve the slurry flowability by decreasing viscosity and eliminating Casson yield stress. It is therefore used as a grinding aid for the wet ultrafine grinding of limestone. The rheological behaviors of ground limestone slurries vary with grinding from a starting dilatant flow-ability to a resulting pseudoplastic one with an evident Casson yield stress in combination with a thixotropic character. The appearance of pseudoplastic flowability combining thixotropy is related to the fineness of a ground product and its specific surface area, which are both correlated to solids concentration and the additive amount of Dispersant S40. In addition, the accurate rheological characterization of time-dependent fluids is dependent on the instruments used and operation conditions.

Jan 1, 2007

By Jouko L. Lehtonen

Sheet pile walls can be sealed watertightly using various methods. The objective of this paper is to introduce a new innovation comprising the use of continuous cement grouting during embedding. The method has been tested on a field test site and installation and permeability features have been observed and analyzed. Installation can be carried out using traditional sheet piling machinery, merely some additional grouting equipment is needed. Installation speed of grouted sheet piles corresponds to that of conventional embedding. The permeability of the tested method is satisfactory in applications where e.g. polluted soil or water has to be isolated from the surrounding environment. In addition, this method can be used for conventional retaining walls where very low permeability is required or for reduction of soil vibration, e.g. close to a railway embankment. The new method to grout simultaneously and continuously during embedding has been developed based on respective innovations on impact driven steel piles.

Jan 1, 2006

By Harlan A. Walker

This paper on the mines of El Potosi Mining Co. is one of a series being prepared by the United States Bureau of Mines on mining practices, methods, and costs in the various mining districts of North America. Grateful acknowledgment is made of the helpful suggestions and criticisms offered by the management, together with the assistance of the mining staff in preparing maps and drawings and of C. L. Thornburg, mine geologist, in preparing the section on geology.

Jan 1, 1934

By Montaser S. EL Salmawy, Takahide Wakamatsu, Eishi Kusaka

"In conventional flotation, fluoride ions selectively would react with the aluminum site on the microcline surface and produce negative charged sites for amine to be adsorbed (Smith, 1976). According to this view, aluminum site is considered as a key feature in feldspar flotation. Generally, fluoride ion has been widely used as a modifying agent in silicate flotation. Since O'Meara's patent appeared on HF -amine reagent system to selectively float feldspar from quartz in 1942, relatively few contributions have been devoted in this issue. The reason might be that the process works very well, and accordingly there is no initiative to investigate in this area. However, due to the awareness of international community to restrict using of hazardous reagents like HF, sound engineering practice to search for alternative methods, not utilizing HF, has been launched. Inspection of literature, one can find several works dealing with this issue.In this contribution, the effect of ethoxylation of long chain alcohols on the quartz and feldspar flotation behaviors was investigated for surfactants of the octylphenol polyoxyethylene family. The tests were carried out with an average of 7.5 (Triton X 114), 9.5 (Triton X 100), 30 (Triton X305), 40 (Triton X 405) and 70 (TritonX 705) oxyethylene units. Electrokinetic and flotation studies on quartz have shown that at low pH values, quartz could be floated with polyoxyethylene octytlphenols. The possible mode of adsorption of these nonionic surfactants may be suggested to be due to hydrogen bonding between the oxygen of ether and hydrogen in the free hydroxyl groups on quartz surface. It was anticipated that the selectivity between quartz and microcline would decrease as oxyethylenic chain length increases."

Jan 1, 2003

By T. A. Sullivan

The work described in this report was undertaken to evaluate and develop techniques for determining the oxygen content of titanium and titanium alloys. Early investigations of volatilization techniques involving halogenation were unsuccessful. Later efforts were concentrated on evaluating vacuum fusion and inert-gas fusion techniques. Two vacuum fusion methods and an inert-gas fusion method were found to be satisfactory in the 0.02 to 1.00 pct., oxygen range. These methods are described in detail. The coefficient of variation by any of the three methods is approximately 5 pct, While the main portion of this paper is devoted to the vacuum and inert-gas fusion methods, a resume of other suggested methods for analyzing titanium for oxygen also is given. INTRODUCTION The Federal Bureau of Nines has conducted research on titanium metal since 1938. This research included development of the Kroll process for the production of titanium (2)4, various sodium reduction processes for making titanium metal and lower valent titanium chloride-sodium chloride mixtures (17), and a fused salt electrolytic process for Me production of high-purity titanium metal and the recovery of titanium by electrorefining from off-grade materials (20).

Jan 1, 1961

By W. Lum

In the U.S., flexible metal pipe culverts are designed by ring compression theory because the pipes are capable of deflecting and deriving side support from surrounding ground. For economy, tunnel liners are often designed as flexible structures that depend on the lateral pressure of the surrounding ground to maintain stability. In this paper, simple formulas are presented to determine the maximum deflection a concrete tunnel liner may assume and the ring compressive strength of the deflected liner. A tunnel can then be constructed to work within these limits. Similar techniques may be used to design concrete pipes.

Jan 1, 2010

During the past Two years in reef gold mining, &quot;indicators&quot; have received great attention at the hands at the Victorian gold seekers. Many years ago, what was caned the&quot; indicator lode,&quot; was struck in Ballarat East, on the course of which extremely rich deposits of gold were discovered but as to its being a .qeneral experience in reefs or leaders no one ever dreamed. Now, however, we find that these &quot;indicators&quot; are frequently to be met with, though they differ very much in different localities, making it, therefore, a difficult matter for other than a careful minel&apos; to follow them. The necessity of following &quot;indicators&quot; for the purpose of developing gold is now recognized, and the policy of following them up has been attended with much success in this field. In the case of Messrs Shaw and Sons, at Wedderburn, those gentlemen began to work on an &quot;indicator&quot; here five years ago, and immediately thereafter more by accident than anything else they being at that time inexperienced as regards &quot;indicators &quot; came upon gold bearing quartz, which continued payable so long as the&quot; indicator&quot; aud the stone were in conjunction with each other, but as soon as they parted company the stone ceasedto be of any value then, by following the&quot; indicator,&quot; as the latter intersected fresh bodies of stone they proved again more or less payable, until a fortnight or so ago the Messrs. Shaw turned out 4 tons of stone, which yielded &#163;1,825, with also profitable workingup to the present moment. Where they are now working is a mile north of their original find thus proving that &quot;indicators&quot; travel considerable distances and have something to do with the gold deposits found in reefs. On the direct course of Shaw&apos;s &quot;indicator,&quot; as high as hundreds of ozs to the ton was obtained from the stone but, just a few inches from either side in the same&quot; leader,&quot; not a colour could be got. Whatever the cause-whether by electricity or some unknown force in nature-the gold is found on the course of these&quot; indicators&quot; and nowhere else, and-as each of the Victorian Government Geologists admit-their value to the gold-seeker as a means of leading to&apos; gold cannot be over-estimated.

By Peddie F, Low K, Madgwick J, Rajoka M. I, Gutierrez N, Lim C

Percolation irrigation of low-grade quartz feldspar porphyry ore with pH 2.0 H2SO4 at 510 litres/m2/day using particle sizes 1.7 - 6.7 mm in columns measuring 5 cm dia &#215; 126 cm long was used to study effects of interrupted irrigation (&apos;rest&apos; periods) on metal ion release and leaching bacteria. Copper tenors increased approximately 16 fold and bacterial iron oxidation activity three fold following a 14 day &apos;rest&apos;. A linear relationship between copper tenor and bacterial activity demonstrated that this experimental system was effective for quantitative studies of bacterial leaching in ore colums.

Jan 1, 1981

By W. F. Watts

This report describes the Mine Inspection Data Analysis System (MIDAS) developed by the Bureau of Mines to analyze the records of industrial hygiene samples collected by the Mine Safety and Health Administration (MSHA) in metal and nonmetal mines. MIDAS is the first system capable of sorting, editing, analyzing, and reporting these data. It is also the first system designed to be used by a number of Government agencies. At present the system contains 225,000 personal and area samples for 61 contaminants in 45 industries. The records date from 1974 to early 1980, and MSHA plans to provide yearly updates to the system. This report presents preliminary analyses of dust exposures and discusses the potential uses and limitations of these data. Analysis of the dust data for 1978 and 1979 showed that bagging had the highest percentage of dust overexposure. Morn than 40 pct of the 1,536 respirable quartz dust, total nuisance dust, and total silica dust samples exceeded the MSHA exposure limit. Other dusty occupations are ranked according to their percentage of overexposure.

Jan 1, 1981

By J. G. Mitton

El uso de los flowmeters de área variable en la industria petrolera y química han simplificado algunos problemas como la alimentación exacta de productos químicos al flujo del sistema. En este sentido, el texto señala la utilidad de su empleo en la industria de flotación, así como la tardanza de su adaptación al sistema. El método de los flowmeters se adapta fácilmente a la alimentaciones de radioactivos donde el esquema es idóneo para un mineral complejo que contiene varios metales. En el caso que el mineral contiene dos metales básicos, se requiere de una mezcla intrincada de depresores para obtener una flotación selectiva o en bulk y si contiene tres metales básicos, los depresores y modificadores aumentan en número y puntos de alimentación. En 1957, como parte sus experimentaciones, la Cerro de Pasco Corporation utiilizó los flowmeters en la planta piloto de 50 toneladas cortas secas por día. Sin embargo, dicho plan presentó inconvenientes como las fallas en la correcta alimentación, errores en la calibración del alimentador de discos, órdenes a los reactivistas o derrame de radioactivos, ente otros. De otro lado, las ventajas que ofrece dicha operación está en la determinación del control de reactivos, el cual está bajo cargo de un supervisor, así como el costo de instalación se reduce a 50% en comparación con el sistema convencional de discos.

Jul 20, 1960

By Kelly E. G

NZ Steel&apos;s flushing slag typically contains 1.2 per cent V203. Extraction of vanadium from powdered slag using a salt (NaCI or Na2CO3) roast/leach process was investigated. With NaCl, optimum extraction conditions were a charge containing 10 per cent NaCI, roasting in air at 875&#176;C for 4 hours, followed by leaching in dilute H2SO4. Extractions were typically 30-50 per cent. NaCI roasting did not chemically attack the slag; the phase transformations that occurred were due to high temperature oxidation. Slag particle size had a significant effect on extraction.Optimum conditions for extracting vanadium by Na2C03 roasting were 20 per cent Na2CO3 in the charge and roasting in air for 3-4 hours at 850-875&#176;C followed by water leaching.Na2CO3 roasting involved chemical attack that resulted in the formation of perovskite (CaTiO3) and carnegieite (NaAISiO4).The extent of vanadium extraction depended on the amount of Na2CO3 added and the original slag SiO2 content.Compared to the separate roasting treatments, simultaneous treatment with NaCI and Na2CO3 gave lower vanadium extraction, while requiring considerably higher roasting times and temperatures.

Jan 1, 1982

By George A. Savanick

The objective of this research is to develop a method for measuring the tensile strength at the interface between minerals in rock. These measurements reflect the strength of the attractive forces operating at crystalline interfaces in rock. Since these forces act in opposition to the forces set up in various rock fragmentation processes, measuring their strength may help in designing more efficient methods of rock fragmentation. The method developed for measuring the strength of intergranular adhesion in rock involves separating a bicrystal from the rock and determining the tensile strength at its solid-solid interface. This technique has been successfully applied to the study of quartz-feldspar interfaces separated from massive pegmatites, graphic granite, and the Rockville granite, yielding average tensile strengths of 5.86, 8.62, and 10.65 meganewtons per meter squared (MN/m2) (850, 1,250, and 1,524 psi, respectively). The data this technique provides indicate that the members of these bicrystals are strongly adherent. Examirtation of bicrystals broken at the crystalline interfaces indicates that the bonds responsible for this adhesion operate over only a portion of the interfacial area. This work conclusively demonstrates that tensile strength tests can be conducted on small selected areas; for example, grain boundaries in rock. The small-scale zones of strength or weakness determined in this way can be related to the overall strength of the rock.

Jan 1, 1972

By Kazuya Koyama

We are studying the hydrometallurgical recycling process of indium from an Indium-Tin-Oxide(ITO) target. For this process, it is necessary to remove Sn(IV) ions from the aqueous hydrochloric acid solutions containing In(III). In this study, the removal of Sn(IV) ions by a potentiostatic electrolysis method was examined. The polarization measurements and potentiostatic electrolyses were carried out under a nitrogen atmosphere. In the Sn(IV) solution, current begins to rise at the cathode potential of -0.26 V vs. SHE, and increases with a reduction in the cathode potential. In the In(III) solution, current begins to rise at a cathode potential of -0.43 V vs. SHE. Metallic tin was electrodeposited without indium electrodeposition at the cathode potentials of -0.30 and -0.40V vs. SHE. More than 98% of the Sn(IV) was removed at the cathode potential of -0.40 V after the electrolysis for 3hrs. Both tin and indium were electrodeposited at the cathode potential of -0.50V vs. SHE.

Jan 1, 2006

By Donald F. Reed

Deposits of gray hematite occur in two districts in Talladega County, Ala., the Emauhee-Tallasechatch and Weewoka, both in the; vicinity of Wintorboro, 50 miles east of Birmingham. The deposits were investigated by the Bureau of Mines in 1945 and 1944. Approximately 15,000 feet of diamond drilling was done and 6,000 linear feet of trenches excavated and sampled.

Jan 1, 1949

By Ronald F. Balazik

[This Bureau of Mines study is intended to identify and evaluate potential effects of impending large-scale U. S. rail line closings (abandonment) on domestic nonfuel mineral industries. This is the first nationwide study of rail abandonment impacts focused on nonfuel minerals. The analyses presented is based principally on a survey of 200 rail freight records and on statistical tests that correlated 2,000 points in the Bureau&apos;s Mines Industry Location System (MILS) with 700 prospective abandonments throughout the United States. The conclusions derived from the analysis can be useful in evaluating proposed national rail abandonment policy rind legislation regarding nonfuel miner it shipping. Among these conclusions are the following: (1) Certain mineral materials (especially fertilizers) are likely to account for a large percentage of the rail traffic affected by abandonment in the next few years, but the total tonnage- involved will be small; (2) abandonment will adversely affect some mineral shippers, particularly local smart haulers; and (3 abandonment could significance reduce the opportunity to develop new resources or reopen defunct mining facilities. Despite these problems, however, the data examined in this study do not indicate that current abandonment trends will cause widespread disruption 01 domestic nonfuel mineral shipping.]

Jan 1, 1980

By Taghi Sherizadeh, Kutay E. Karadeniz, Dogukan Guner, Samuel Nowak

Seals and build-in-place (BIP) refuge alternatives (RAs) are two main underground structures to isolate an area from the active working zones with different purposes. While seals are used to prevent methane gas that seeps from coal seams and blast pressures from a possible detonation of the contained gas, RAs are used to provide a safe haven for miners who are unable to escape their working locations after an accident like an explosion or fire. The recommended BIP RA designs can be similar to seals constructed with steel-reinforced concrete. Both seal and BIP RA are constructed in different locations of the mines for a period of time, exposed to a certain convergence due to stress redistribution which can change their responses during an explosion. In this study, a steel-reinforced concrete wall to be used in such applications is simulated to examine the structural performance during an explosion for a coal mine model with different strata conditions using dynamic analysis by a 3D distinct element method (DEM) code. The main purpose of this study is to reveal any possible effects or trends on the wall deformation with changes in strata conditions by implementing different combinations of roof, seam, and floor material properties. The model is calibrated by the experiment conducted on a steel-reinforced concrete wall by the NIOSH researchers in the Lake Lynn Experimental Mine. The results show that strong adjacent rock and coal units are the least favorable condition for the survival of the wall subjected to a simulated explosion pressure. The results indicate that changes in the roof and seam conditions can have dramatic effects on the deformation characteristics of the wall when compared to the floor conditions. The results of this study might be enlightening for future BIP RA and seal applications.

Feb 8, 2023

Taking the third meridian as the eastern boundary of proved payable auriferous country, there is a stretch of country, nearly 600 miles in width, in which no appreciable amount of gold has yet been discovered. Many prospectors have attempted to .penetrate or traverse it, but comparatively few have thought it worth while proceeding with the examination.The desolate stretch of waterless desert-the very few and insignificant outcrops through the sand and the almost total absence of feed for horses have, combined, presented such a barrier as to preclude prospecting. The few who have traversed the country are eloquent in denunciation, yet their investigations, necessarily hurried, are not quite satisfactory. The absence of water utterly debars a thorough examination being made. Gold may exist in quantity, yet it would have to be extraordinarily plentiful to render its obtaining profitable. Too fantastic is the idea of its ever being a mining district; shifting sand to traverse, utter absence of wood and water render the notion absurd. Likely looking belts occur, but these in all &quot;cases are small and remote from water. Gold has been obtained from likely look ing quartz reefs, but only by fire assay, and then but a few do to the ton. Without wishing to be pessimistic, I would unhesitatingly declare that east of the third meridian, and between the parallels 25 and 30 degrees in West Australia, there is no gold in payable quantities.

Jan 1, 1901

By A. T. Robles, L. Buckingham

"When certain gold ores containing pyrite, graphite, humates and fumates or other organic compounds which are possibly adsorbed on clay minerals are treated with aqueous solution of alkali metal cyanide, the aurocyanide complex which forms is adsorbed by these ""pregrobbing"" species in the ore. Dissolution of gold proceeds until chemical equilibrium is attained between the cyanide complex adsorbed by the ore and in solution.Sodium lauryl sulfate (SLS) may be used to decrease the adsorptive activity of the prerobbing species in the ore. It has successfully improved recovery at Holt-McDermott Mine and is highly biodegradable.INTRODUCTION Precious metal-bearing ores containing preg-robbing species are poorly amenable to standard cyanidation techniques. The ""preg-robbing"" impurities with which they are associated tend to adsorb the gold cyanide complexes and carry them through the circuit to the tailings. Also, gold may be associated with these impurities in the ore and not be leached by the cyanide complexing agents used in conventional cyanidation techniques.Methods for dealing with the problem of preg-robbinq impurities in gold ores are:Carbon-in-Leach (CIL), in which granular activated carbon is added to compete with preg-robbing species for the gold cyanide complexes. This process can improve gold recovery in mildly preg-robbing ores especially when fine carbons with very high activities are used. However, with severely graphitic ore, the carbon associated with the rock may outperform the granular activated charcoal.Chemical Oxidation, in which the ore is subjected to preliminary chemical oxidation techniques to oxidize carbonaceous materials using such diverse reagents including ozone, sodium hypochlorite, calcium hypochlorite, chlorine gas, permanganates, perchlorates, chlorates and oxygen prior to subjecting the oxidized ore to standard cyanidation treatment to extract gold. This is generally a costly method and will not prove economical on a low-grade ore."

Jan 1, 1992