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By R. W. Macqueen

Organic matter commonly associated with Mississippi Valley-type (MVT) lead-zinc deposits may be used to assess the burial/thermal history of host rocks and sulfides. Organic matter may also have been involved in the genesis of H2S required to precipitate sulfide ores. Pine Point, Northwest Territories, Canada, provides an example. Located on the south shore of Great Slave Lake, Pine Point is an operating world class deposit which has produced 58 million tons of ore containing 3.0 percent Pb and 6.1 percent Zn from more than 40 Individual orebodies. Well-documented paleokarst features in a Middle Devonian carbonate complex are the main ore hosts. Sphalerite and galena ores are mainly open space fillings, and, from fluid inclusion studies, were deposited from saline fluids at temperatures of up to at least 100°C. Forms of organic matter occurring in the Pine Point barrier-reef complex Include indigenous organic matter, heavy oil and bitumen. Based on numerous geochemical criteria, it is clear that heavy oils and bitumens were derived locally from indigenous organic matter. The geochemical character of the Indigenous organic matter demonstrates that the barrier-reef complex is immature to marginally mature with respect to petroleum generation, and has not been heated above about 60°C maximum. Thus sphalerite with fluid inclusions that yield temperatures up to about 100°C represents former thermal anomalies. Bitumen is of two main forms at Pine Point: widespread soft, tarry material soluble in organic solvents (unaltered bitumen); and hard, brittle, glassy material that is mostly solvent-insoluble, and associated with white sparry dolomite and lead-zinc ores (altered bitumen). There are also partly altered bitumens. Unaltered bitumens have atomic H/C ratios of about 1.4, sulfur contents averaging 7.8 percent, and sulfur isotope ratios 634S) of approximately +4.6 per mil. Altered bitumens have atomic H/C ratios averaging 1.02, sulfur contents averaging 22 percent, and 634S values of about +12.9 per mil. These data and the organic geochemical character of a large suite of bitumen samples analyzed, strongly support the concept that some bitumen has been involved in the thermochemical reduction of sulfate to produce the H2S required to precipitate the ores. Mass-balance calculations indicate that the amount and degree of alteration of bitumen is more than enough to account for the reduced sulfur species deposited as metallic sulfides at Pine Point. MVT deposits, including Pine Point, seem to require the coincidence of available metallic Ions, pre-existing pore space, and a precipitating agent. A close look at organic matter in more MVT settings may outline trends in distribution or alteration which can be used as indicators of past thermal environments and processes of ore deposition.

Jan 1, 2013

By Andrew P. Gize

A petrographic approach to studying the organic matter in ore deposits is advantageous in that direct observation of sample heterogeneity can be made, organic constituents (macerals) can be identified, and valuable information about the geological history of the sample (such as thermal history, oxidation, and reworking) can be obtained. Thermally immature bitumens are compositionally and structurally heterogeneous, and optically isotropic. The end product of thermal alteration, graphite, is compositionally and structurally homogeneous, and optically an isotropic. One route by which thermally immature bitumens can approach the graphite structure Is by an aromatic intermediate phase, termed mesophase. The development of optical anisotropy and a thermal mesophase has been observed In several high temperature deposits. Textures in bitumens are described from the thermally-altered Mississippi Valley-Type deposit at Nanisivik (Northwest Territories), the silver-vein deposit at Kongsberg (Norway), and the gold deposit at Carlin (Nevada). Textural evidence for multiple generations of bitumens, supportive of a pulsing model for incoming brines, is shown. Petrological evidence for the introduction of bitumens as an immiscible phase or possibly as micelles is shown in the Carlin and Kongsberg deposits.

Jan 1, 2013

By Yuan-bo Zhang, Gui-hong Han, Yan-fang Huang, Tao Jiang, Guang-hui Li

"Under isothermal conditions, the reduction behavior of oxidized pellets balled with bentonite was investigated with CO-CO2gas mixers in the temperature range from 900°C to 1100°C. The whole reduction of oxidized pellets was followed up by means of weight-loss technique. And the swelling index of pellets was examined by visualizing physical changes of pellet in a horizontal tube furnace. The results present that the reduction rate of oxidized pellets is increased with the increase of reduction temperature. While the swelling index is firstly increased and then decreased with the increase of reduction time and reduction extent, which can be ascribed to the disruptive stresses induced during the transformation of hematite to magnetite. The maximum swelling index is gradually increased with the increase of reduction temperature and CO content.IntroductionWith the rapidly development of iron and steel industry, direct reduction iron has been considered as one kind of high quality burdens in electric furnace steelmaking [1]. At present, ""Two-step"" coal-based direct reduction process, which employs oxidized pellets as raw materials, has been used in industrial production [2]. The reduction behavior of iron ore oxidized pellets has been becoming one of the most frequently studied topics in extractive metallurgy[3]. The heat and mass transfer in direct reduction processes results in a series of stepwise reduction reaction (hematite--magnetite--wustite--iron), accompany with the volumetric swelling of pellets[4]. A lot of literatures have been reported on the reduction model of ferrous oxides and swelling behavior of pellets. A. A. El-Geassy K, et.al [5-7] revealed that the reduction process was controlled by chemical reaction at early stage by employing pure Fe203 as raw materials and CO as reduction gas. Chen Y [8] made research on the reduction kinetics of porous oxidized pellets and obtained the rate constant and activation energy of at different reduction stage. In addition, the swelling and disintegration of iron ore pellets was affected by chemical composition of pellet and reducing parameters, which have been studied by numerous investigators [3,9, 1O]."

Jan 1, 2013

By Yi Luo

Bolting the mine roof is one of the noisiest underground mining operations. The main contribution to the high noise is the drilling of the roof bolt holes, especially in hard rock. A previous research shows that the specific energy consumed in drilling the bolt holes is inversely proportional to the bite depth (i.e., penetration per drill revolution). Less specific energy at a reasonably high bite depth means less energy is wasted in the drilling process to produce heat, bit wear and noise. Therefore, control of drilling operation to achieve a higher bite depth can provide an opportunity to reduce drilling noise from its sources as a proactive noise control approach. In order to explore the feasibility and to develop the proactive technology for reducing drilling noise, drilling tests have been conducted in laboratory settings. The preliminary results show significant reduction in noise dose can be achieved by drilling in medium hard rock at a reasonably high bite depth. This paper presents the findings from the laboratory experimental studies conducted so far.

Jan 1, 2013

By C. Edwards

ABSTRACT The versatility and specificity of rare earth elements (REEs) have led to their use in an everincreasing variety of applications in new technologies; consequently, demand for REEs has increased significantly. However, separating REEs safely and effectively is a complex and expensive process. This paper presents a review of REE mineral processing technologies, providing an update on current capabilities in REE mineral processing and REE extraction from the major commercially valuable REEbearing minerals such as bastnaesite, monazite, and xenotime, as well as the ion-absorption type of REE deposits.

Jan 1, 2013

By Zhucheng Huang, Zhikai Liang, Lingyun Yi, Tao Jiang

"In this study, reduction of iron ore pellets was carried out at 800-950°C by simulating the atmosphere of typical coal gasification gas. The effects of temperature, gas composition and reduction degree on swelling were investigated respectively. Reduction degree was obtained according to the weight loss records. And volume changes of pellets during reduction were evaluated by infrared photography. Results showed that the pellet swelling increased with temperature and decreased slightly with hydrogen content in the reducing gas. The swelling peaked when reduction degree reached about 40% and then decreased to be stable finally. The microstructures of pellets during reduction were examined by reflected light microscope and relatively rational explanations were proposed for their swelling behaviors.PrefaceDirect reduction iron is an important and indispensable raw material for high-purified and high-quality steel in the electric furnace smelting. Gas-based shaft furnace direct reduction process has very strong competitative ability; however, this technique requires natural gas as reducing agent, so its development has been restricted by gas source and area. Compared with gas-based reduction method, coal based reduction method has the disadvantages of higher production cost and lower productivity. In China, coal resources are abundant and coal gasification technology is mature, and the development of coal gasification shaft furnace direct reduction process is promising. [1] The gasification methods of fixed bed method (Lurgi method), fluidized bed method (Undok method), airflow bed method (Texaco coal water slurry method and Shell dry powder coal method) have been put into use successfully. These syngas generated by different methods can meet the actual production requirement of shaft furnace. However, the compositions of the effective reduction gas in the syngas are quite different. The ratios of hydrogen and carbon monoxide (H2/CO) of Undok or Shell coal gas, Texaco coal gas and Lurgi coal gas are 0.4, 0.6~ 1.0 and 1.6~2.3, respectively. [2] In the coal gas direct reduction process, the swelling behavior of iron ore pellets is various due to the differences of the gas composition, reduction temperature and reduction degree, and it seriously affects the normal operation ofDRI production. [3-9] Therefore, the research on the swelling behavior and its mechanism of iron ore pellets in direct reduction were carried out in this paper."

Jan 1, 2013

By Osama A. Safaqah

Driven plate anchors can be used to hold in place large bridge caissons during floating construction. Their small size and simple method of installation make them a very cost effective alternative to other direct-embedment, gravity, and drag anchors. The geotechnical design of plate anchors involves the anchor geometry, embedment, drivability, and proof testing. This paper describes the experience gained with plate anchors used during construction of the new Tacoma Narrows Bridge. For this project, the anchors had to be driven in dense to very dense sands, and had to resist large forces from 7-9 knot currents.

Jan 1, 2013

By Christine E. Turner-Peterson

Pore-filling organic material concentrated uranium to form sandstone-hosted primary uranium deposits in the Jurassic Morrison Formation of the Grants uranium region, New Mexico. Petrographic observations and radiometric ages for primary ore in the Westwater Canyon Member require that the organic material was emplaced early in the diagenetic history of the host sandstone; in fact, organic material was emplaced before major compaction. This inferred early emplacement constrains models concerning the nature and origin of the organic material and thus also constrains models of ore genesis. Reconstruction of the burial history of the basin indicates that Late Jurassic-Early Cretaceous time, the interval of inferred emplacement of the organic material, was probably not a time of hydrocarbon generation and migration. Nuclear magnetic resonance analyses, elemental abundances, and isotopic studies provide further constraints on the nature of the organic material, and data from these studies are consistent with a humic acid rather than an oil origin. In addition, the overall tabular shape of primary uranium orebodies and the way these orebodies are suspended in the host sandstone mimics Recent deposits of humate, the precipitated form of humic acids. The critical clue that favors a humic acid origin for ore-related organic material is provided by the nature and patterns of postdepositional alterations that are spatially and temporally related to primary ore, specifically destruction of detrital magnetite and ilmenite (iron-titanium oxide) grains. Humic acids are implicated in the destruction of iron-titanium oxide grains because these organic acids are one of the most effective natural agents in leaching of Iron from these grains. Thus, timing constraints, chemical evidence, orebody geometry, and the nature and patterns of ore-related alterations favor a humic acid origin and suggest that an oil origin is highly unlikely. Because alteration of iron-titanium oxide grains tracks the pathways of humic-bearing solutions through the host sandstones, it is possible to trace these solutions back to their source. Alteration patterns in the Westwater Canyon Member suggest that the humic-bearing solutions originated as pore fluids in the mudflat facies of the overlying Brushy Basin Member and moved into adjacent sandstones during early dewatering of the mudstones. The humic acids precipitated, by the process of cation loading, in tabular layers. Uranium was concentrated within these tabular layers by complexation with the humic acids to form primary uranium orebodies.

Jan 1, 2013

By Joshua Hoffman, Braden Lusk, John Rathbun

A Flyrock Prevention Taskforce was established in Kentucky with the support of Kentucky's Department of Natural Resources, Kentucky's Explosives Industry, and the University of Kentucky. This paper presents the initial work of the Flyrock Prevention Taskforce towards its missions of identifying the root causes of flyrock incidents based on the analysis of previous events, and tracking the progress of flyrock elimination in the future. Work identifying root causes of flyrock events is presented through the development of a database which manages information about the blasts which caused flyrock. This data includes: blasting and seismograph records, drill logs, videos of the event when available, company notes/incident reports, and any additional information regarding probable cause. Work tracking the progression of flyrock elimination efforts is presented in this paper through the introduction of a flyrock index. Several metrics are proposed for this index, and are discussed for their appropriateness and shortcomings. In order for these indexes to be valid forms of tracking flyrock incident rates additional records must be kept and reported, such as the annual consumption of explosives by surface coal blasting. Suggestions for record keeping, flyrock investigation practices, and means of tracking flyrock incident rates are proposed in this paper.

Jan 1, 2013

By Michael A. Knott

Large lateral forces on bridge foundations due to extreme events such as vessel collisions, earthquakes, and wave forces on storm surges during hurricane events are often the controlling design condition for bridge foundations. A review of the American Association of State Highway and Transportation Officials (AASHTO) vessel collision analysis and design codes used in the United States for highway bridges will be presented. The paper includes the background and development of the AASHTO Guide Specification and Commentary for Vessel Collision Design of Highway Bridges (1991) and vessel collision provisions of the AASHTO LRFD Bridge Design Specifications (3rd Edition 2004 and the approved 2005 Interims). Experience in using the AASHTO codes will be discussed and observations on the adequacy and gaps, comparison with the European Standard Code, and recommendations for immediate and long term needs will be presented.

Jan 1, 2013

By Andriy Burbelko, Daniel Gurgul, Wojciech Kapturkiewicz, Marcin Gómy

"The mathematical model of the globular eutectic solidification in 2D was designed. The proposed model is based on the Cellular Automaton Finite Differences (CA-FD) calculation method. The model has been used for studies of the primary austenite and of globular eutectic grains growth during the ductile iron solidification in the thin wall casting. The model mentioned above takes into account, among other things, non-uniform temperature distribution in the casting wall cross-section, kinetics of the austenite and graphite grains nucleation, solute diffusion and non-equilibrium nature of the interphase boundary migration.Some aspects of stochastic nature of the solidification processes are taken into account. The results of the CA solidification modeling have been shown, that differences between cooling curves obtained in the same conditions of the casting solidification may be a result of the stochastic nature of the grain nucleation.The results of modeling were compared with the experimental microstructure. The model is well worked for thin walled ductile iron casting, for fast solidification process.IntroductionNodular graphite cast iron, also known as ductile iron (DI), has major applications in critical engineering parts due to its mechanical properties and castability. The mechanical and physical properties of this material depend on the shape and number of the graphite grains andmicrostructure of the metallic matrix.Solidification of DI was a subject of many computer modeling programs described in literature [ 1-5], in which the stationary conditions of carbon diffusion in austenite is pre-assumed. Recently, a tendency for production of thin-walled castings has been observed [ 6-8]. In this technology, the process of the fast solidification may be very far from equilibrium and steadystate conditions [9].The purpose of the present work is a two-dimension model development for simulation of the DI structure formation during the solidification in the condition of non steady-state temperature and diffusion fields in the thin-wall casting.Model of process The CA-FD is one of the known methods of the simulation ofmicrostructure formation during the solidification [ 10, 11]. In the CA microstructure modeling the outer grain shape is the result of the simulation and does not superimposed beforehand. The model development for a onephase microstructure evolution is a subject of the numerous researches [12 -23]. Model of the eutectic solidification of DI in the uniform temperature field and superimposed cooling rate is known [24]."

Jan 1, 2013

By Doug Anderson

Blast vibration seismograms are generally collected strictly for compliance with regulations. The peak levels (including dominant frequency) are typically all that are looked at. However, these records contain a lot more information about how a blast has performed. The seismogram is actually a record of explosive energy that was not used in fragmenting rock. The trick is to determine how to extract information that would be useful in analyzing blast performance.

Jan 1, 2013

By R. Franfield, W. J. Birch, L. Bermingham

Previous researchers have put forward two different theories as to the origin of air overpressure from quarry blasting. In 1980, Siskind et al postulated that the initial face movement gave rise to the displacement of air and that this resulted in the air overpressure pulse. However in 1990 McKenzie et al carried out research that indicated that the air overpressure pulse came into being as consequence of the shock wave created by the detention of the explosive charge in a blast hole, rapidly propagating through the rock and then impacting on the quarry face.

Jan 1, 2013

By Jie Ma, Shun-Li Zhao, Jian Zhao, Jie-Yu Zhang

"Microstructural morphology evolution of Ni-45wt.%Mo droplets during rapid solidification process was investigated using an advanced modified 3D cellular automaton-finite element(CAFE) model by CALCOSOFT software. The model was modified by User-defined functions (UDFs) and validated with experimental solidification microstructural morphology of Ni-45wt.%Mo droplets available in the literature. Then, the influences of convection heat transfer coefficient, superheat of the alloy droplets and droplets size were investigated during the rapid solidification process. The predictions show that microstructural morphology is obviously sensitive to convection heat transfer coefficient and droplet size. With the decrease of convection heat transfer coefficient, the grain density decreases. In addition, the decrease of the droplet size could obtain refined microstructure. However, decrease the superheat ofNi-45wt.%Mo droplets has little effect on microstructural morphology.IntroductionFor several decades, much attention has been paid to undercooled alloy droplets of rapid solidification process for which can obtain refined microstructure, decreased microsegregation and extended solubility of alloying elements [1-3]. Extensive prior work shows that solidification of droplets plays an essential role in advanced material properties [ 4]. Consequently, it is very important to investigate the microstructural morphology evolution, especially for dendrite growth during non-equilibrium solidification process, for dendrite growth reflected the kinetics of the crystal growth process."

Jan 1, 2013

By Alastair Torrance

The performance of commercial explosives is clearly influenced by the conditions under which they are used. Mining companies are supplied with Technical Data Sheets which provide details about explosive properties and its suitable application. These are generally produced using laboratory techniques which may not accurately reflect the quality and performance of the product in the field.

Jan 1, 2013

By WenFeng Li

Comparing to the coal seams in Eastern China, the coal seams in Western China usually have better geological conditions. Therefore, changes in the conventional gateroads layout are required for the Western longwalls. A case study based on a Western coal mine (LiMin) was presented to discuss the feasibility of an innovative gateroads layout. Based on the geological conditions, a 5m wide pillar between the adjacent two longwall panels, 09112 and 09113, was proposed in order to increase the recovery rate. More importantly, the entry supporting strategy of panel 09113 headgate needed to be determined and verified carefully since only 5m wide pillar was left to separate the entry from the panel 09112 gob. Three strategies with different supporting intensities in the panel 09113 headgate were evaluated by numerical modeling. The model outputs indicated that roof and rib boltings plus single hydraulic props were essential to maintain the gateroads stable. Field observation showed that under the proposed entry supporting strategy, the total roof-tofloor and rib-to-rib convergences were only 360mm and 460mm, respectively, during the service life of the panel 09113 headgate, which indicated that the innovative gateroad layout proposed in this paper is suitable for longwalls with similar geological conditions in Western China.

Jan 1, 2013

By V. B. Teffo

The aim of the project was to experimentally determine the coefficient of restitution, and static and rolling friction of Eskom-grade coal for discrete element modelling (DEM). These parameters will be used in further DEM studies to simulate the flow and behaviour of coal during conveyance. For the simulation to yield realistic results, the parameters for the different coal shapes identified in the samples were determined. DEM uses spherical particles, and it was found that the difference between the DEM default parameters and those measured is significantly different, by as much as 97%, which illustrates the importance of experimentally determining these parameters. The spherical particles in DEM can be used to construct the various coal shapes identified, and the parameters measured can be used to simulate realistic results. The conveyance system can then be optimized accordingly.

Jan 1, 2013

The AMIRA Code of Practice and Guidelines for Metal Accounting was developed in response to demand from a number of sponsor companies, including one major platinum producer. Since its publication in 2007, the Code has become widely accepted in the mining industry world-wide as a guide for best practice in metal accounting. With the changes in the structure of the platinum mining industry in South Africa over the last 10?15 years, in particular, the starting up of a number of small platinum producers who must have their concentrate smelted and the contained valuable metals refined by third parties, the need for metal accounting systems that are accurate and have an acceptable level of precision has become even more critical to the success of a platinum-producing operation. The current state of metal accounting in the industry is discussed, and possible areas for improved accounting and associated metallurgical efficiencies are identified.

Jan 1, 2013

By Shenghui Guo, Jian Chen, Hongbo Zhu, Jinhui Peng, Linqing Dai, Qianxu Ye

"Response surface method (RSM) based on mono-factor experiment was applied for the process optimization of sintering of chromite fines by microwave. In RSM analysis, effects of binder addition amount, sintering temperature and holding time on the compression strength and shatter strength of the sinter were examined. Results showed that the optimal values of the above parameters were determined as follows: binder addition amount of 1.90% (in mass), sintering temperature of 1153? and holding time of 16 min. Under the optimized conditions, the compression strength was 11155.8? and shatter strength was 95.6849%. The results show that the process was optimized by response surface methodology is stable and feasible, and provide a new way for sintering of chromite fines.IntroductionChromite ore is the main feedstock for ferrochrome, and ferrochrome can be used as steelmaking additive to produce a variety of great strength, corrosion resistant and oxidation resistant special steel, which can be widely used in the aerospace, automotive, shipbuilding, military departments[1], and it has important strategic significance. At present, among the annual world's mined chromite the number of lump ore continues to diminish with its price rising sharply, while the proportion of ore fines been always increased, and the difference in prices between ore fines and lump ore is growing[2]. Despite the low price of chromite fines, and its rich in resources, it can be only used for ferrochrome smelting after agglomeration. Thus manufacturing blocks by using cheap chromite fines is an effective measure to reduce the cost of ferrochrome production and use the chromite resources[3]."

Jan 1, 2013

By Laurentiu Nastac, Ruslan Mudryy

"This paper investigates the solidification of cast energetic materials. An active cooling and heating (ACH) technology and a mechanical vibration (MV) technology were applied to achieve unidirectional solidification during casting and to reduce cracks, gas pores, and shrinkage defects. The design parameters of these technologies were developed via Computational Fluid Dynamics (CFD) modeling and thermal stress analysis. Concerning the ACH technology, the number of cooling/heating sections and their temperature profiles and time sequences were optimized based on the thermo-physical properties of the energetic material as well as the riser and mold diameter, thickness and type. The ACH technology will also decrease the thermal stresses during casting of energetic materials and therefore minimize the formation of potential cracks that may form during the casting process. The MV technology will help to remove air entrapped during pouring process and decrease the detrimental gap size between the projectile and the solidified energetic material.IntroductionCasting processes are widely employed in the manufacture of products with intricate shapes and, in particular, in applications where the material of the final product is sensitive to machining. It is especially useful in processing of energetic materials. The cooling conditions applied in the casting process can affect the quality of the final cast in terms of void formation, residual stress distributions, and mold separation. Substantial shrinkage is also observed due to the density change upon solidification [1-3]. Residual stresses are known to be closely related to the formation of cold cracks and hot tears during casting. The formation of a gap between the mold and the cast material is of critical importance due to its deleterious effect on heat removal and on crack formation. In the casting of energetic materials all these defects can significantly impair the detonation velocity, Gurney energy, and insensitive munitions characteristics of the formulation, and lead to catastrophic accidents in explosives handling [ 4-5]. Imposition of carefully controlled cooling condition is thus critical in optimizing the cast quality that could help avoid such destructive effects."

Jan 1, 2013