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By I. C. Howard, E. J. Palmiere

"Heat transfer and friction in hot flat rolling have traditionally been characterised by an average heat transfer coefficient (h) and an average friction coefficient (p.). However, the presence of oxide scales and asperities at the interface question the use of such averages. The apparent irregularity and lack of pattern of interactions at the interface has prompted this present investigation to move away from averaged h and 11 values, and to study their local evolution based on probabilistic rules. The approach is based on the probability of finding the workpiece surface in a specific configuration at a particular instance of time in the roll gap. These rules are based on observations of surface phenomena such as scale behaviour during hot rolling. The model is implemented using user-subroutines integrated with the commercially available finite element program ABAQUS™. The results show the strong dependence of h and u on the local scale interactions. In particular, the effect of scale thickness, material behaviour and processing conditions on the evolution of hand 11 are discussed. Finally, the development of a Cellular Automata based Finite Element (CAFE) model is proposed to model the combined interfacial phenomenon of friction and heat transfer at the tool-work piece interface.IntroductionIntricate interactions between process variables in hot rolling of steels make it a challenge to the modelling community. For a given material and geometry combination, reducing interfacial power losses can increase the efficiency of the rolling process. The roll-strip interface, therefore, forms the critical zone and is currently the domain of intense investigation, especially to characterize interfacial frictionl • 2 and heat transfer3 • 4 . These interfacial phenomena are inter-related and cannot be studied in isolation. However, very few mathematical models4 • 5 combine an analysis of friction and heat transfer and deformation of the strip-roll interface taking into account the role of asperities and oxide scales."

Jan 1, 2001

By Zhang Chuanfu

Keywords: modified coprecipitation method, Ni-Co alloy powders, solid-solution oxalate, growth mechanism Homogeneous solid-solution oxalates of Ni2+ and Co2+ ions were synthesized by modified coprecipitation method and the composition and morphology of the fibrous solid-solution oxalates precursor were characterized by XRD, IR, DTA/TG and SEM analysis. The effects of feeding methods, pH values, precipitation temperature, reactant concentration, addition surfactant, alcohol washing and drying process on the morphology and dispersion of the precursor were investigated in detail. The experimental results showed that the coprecipitated powders have characteristics that are different from those of the mechanical mixtures with the same stoichiometry. Based on the observations of precursors growth and SEM morphology of the precursor, the oriented attachment was proposed for the well-aligned growth of the fibrous Ni-Co alloy precursor particles.

Jan 1, 2005

By K. Morsi

The interest in spark plasma sintering has been growing considerable over the past few years. This has been brought about by the unique advantages of the process, which include reduced sintering temperatures and times and the production of materials with unique microstructures and properties. Despite its current reputation as an outstanding process that has solved major problems such as nano-powder consolidation, it has so far been largely limited to the manufacture of simple shapes, due to its inherent geometric configuration. In this paper we present preliminary results on spark plasma "extrusion" that can allow the production of extended geometries via electric-current processing. Preliminary results on the processing and microstructure of spark plasma extruded aluminum are discussed.

Jan 1, 2009

By Paul W. Cleary

Keywords: Reactive pellets, CFD, Lagrangian SPH, Pyrometallurgy In several pyrometallurgical processes, reactive pellets are added to a melt. Heat is transferred to the pellets and reaction products such as gases, metal and slag are formed. For many pyrometallurgical processes traditional grid based CFD methods, such as using the Finite Element Method (FEM) and Finite Volume (or Control Volume methods), produce suitable predictions. However, the inclusion of solids in the bath represents significant challenges for these methods. Smoothed Particle Hydrodynamics (SPH), a Lagrangian simulation method, is able to simulate both the fluid component of the bath and any immersed solid materials, tracking the motion of these solids, and their interaction with the fluid, including gas generation. In this paper, we will summarize the key aspects of the SPH method and will show a series of structured examples illustrating the behavior of the different physics sub-systems that are used in the model of the overall system.

Jan 1, 2005

By WU Jian-hui

Keywords: metallic material; nickel powder; thermal decomposition; precursor; fibrillar powder; nanometer scale; passivation treatment The precursor thermal decomposition process of fibrillar nanometer scale nickel powder and passivation treatment of obtained powder are investigated, and the composition and morphology of the products are characterized by use of IR, TGA/DTA, XRD and SEM. The results show that the precursor morphology is a decisive factor to the product morphology of the nickel powder. The morphology of the product derived at low decomposing temperature is irregular. The nickel powders produced at the temperature higher than 480 coheres seriously. The product particles are reunited with the decomposition time prolong. The powder prepared under the optimal condition is fibrillar like woolen yarn; the grain diameter is less than 50nm.

Jan 1, 2005

A three?stages countercurrent fluidized bed prototipe reactor to neutralize the SO2from smelter gases has been developed. For gases with 8 vol-%SO2, at 800°C and for 4 h mean reaction time of the limestone, the capture of SO2 is 99%, with off gases with 0.07 vol-%. For 2 vol-%SO2, the total capture of SO2 can be obtained at 750°C and 4 h reaction time. The calcine obtained contain a blend of unreacted limestone and calcium sulphatewith minor amounts of residual lime.

Jan 1, 2006

By Torben Edens

Norddeutsche Affinerie?s (NA?s) primary smelter continually increased production in the past decade. The smelter?s concentrate capacity was expanded from 500,000 in 1993 to 1,000,000 t/a dry concentrate in 2000 and the goal of the present upgrade is 1,150,000 t/a. These goals were reached without erecting new equipment in the anode area, but instead by refitting the existing plant. The life-span extension of the casting moulds was absolutely necessary to increase the casting performance from 260,000 to 450,000 t anodes per year on a single casting wheel. Different mould manufacturing processes and alloys were tested in order to find the optimal mould. In the past the moulds were cast directly, now the anode mould is milled into NA copper cakes. Accompanying measures taken were the shortening of maintenance and repair times as well as improvements in the refining furnace equipment.

Jan 1, 2005

By P. N. Anyalebechi

The effects of solidification rate on the cast microstructures of aluminum alloys 6009 and 6016 have been investigated with directionally cooled laboratory-size ingots, at 0.2-10.1 K/s and 0.4- 23.1 K/s, respectively. These ranges of solidification rate are within those observed in commercial-size ingots. In both alloys, the average dendrite cell size and second phase particle size decreased with increase in average solidification rate and with a decrease in average local solidification time. However, at comparable solidification rates, the dendrite cells and second phase particles are finer in the shorter freezing range alloy 6009 than in the longer freezing range alloy 6016. This is provisionally attributed to the earlier formation of second phase intermetallics at higher temperatures during solidification and to the formation of greater amount of the relatively coarse plate-like ß -phase (Al9Fe2Si4) phases in alloy 6016. In general, in both alloys, the types and relative amounts of the second phase particles in both alloys are independent of solidification rate.

Jan 1, 2006

By Pengfu Tan

Xstrata Copper at Mount Isa in Australia has operated one copper Isasmelt furnace and four P-S converters. The phenomena of foaming occur in above 10% of converter operations. A thermodynamic model of copper P-S converter and a viscosity model of converter slag have been developed to simulate the slag blow and copper blow. The model predicts the chemistry and viscosity of copper skims during copper blow. The effects of oxygen potential, charge of dirty materials, slag carry-over, under-blowing, over-blowing, and temperature on the foaming and viscosity of copper skims have been discussed. Some improvements of the industrial operations have been presented.

Jan 1, 2006

By Omid Lashkari

Keywords: SEED, SSM materials, Microstructural evolution, Rheology, Swirling Speed SEED (Swirled Enthalpy Equilibration Device) is established itself as a new technology amongst the many Semi-Solid Metal (SSM) processes, where swirling of the mush plays an important role in modifying the dendritic structure of as-cast parts. A range of semi solid metal structures, dendritic, rosette and/or globular morphology of primary phase, can be prepared using SEED. The current article reports on the application of rheological tests in characterizing microstructural evolution during SSM processing of 356 Al-Si foundry alloy. A simple parallel plate test machine, designed and constructed at our labs, was used to determine viscosity values for each structure and identify the optimum structure with superior die filling characteristics. Such findings have important technological and economical implications during high pressure die casting of semi- solid metals. The strain-time graphs for 356 Al-Si foundry alloy indicated lower viscosity values for globular microstructure, i.e. improved die filling.

Jan 1, 2005

By Qingsheng Liu

A new method of recycling aluminum dross for preparation Al-Si-Ti alloy was studied in this paper. This was carried out in two processes. first the aluminum doss was pretreated by leaching and calcining process, the fine purity and phase of the intermediate oxide powder up to electrolysis demands, then, could be obtained when aluminum dross after washing have been leached for 2h at 100? in 20% hydrochloric acid and calcined for 2h at 1200?, which was treated by cryoite-based molten salt electrolysis. Finally, the Al-Si-Ti alloy was successfully obtained through electrochemical co-deposition in the cathode shows a typical as-cast microstructure. This new recycling method can produce high quality alloy and may bring remarkable economic and social benefits.

Jan 1, 2010

By M. Bilal Khan

Thermal stress relief by means of a typical heat treatment cycle (660oC for one hr) is compared with the one achieved through vibratory stress relief at resonant and multiple resonant frequencies for the D-406 HSLA material. Our analysis of the data is based on the microhardness profiles measured for the entire length of scales, namely, base metal, heat affected zone (HAZ) and the weld bead itself. The profiles obtained using the two techniques mimic each other, for an equivalent 70% stress relief level. The data are further qualified by impact testing wherein the zone of interest is projected in the retention groove to provide impact by the pendulum striker in the Charpy mode. Higher equivalent energy absorption in the treated specimens confirms the efficacy of the vibratory method. The present work rectifies earlier anomaly where heat treatment has been reported at 310oC for the same material.

Jan 1, 2009

By S. Y. Tan

The thermal stability of fully silicided NiSi with arsenic doping on silicon was investigated. The aims of the work were to investigate the Ni silicide phase-related issues associated with arsenic dopant and thermal annealing on Ni-FUSI/HfO2/Si and Ni-FUSI/HfSiO/Si gate stacks. It was found that arsenic-incorporation demonstrated some improvement in both morphology and phase stability of nickel silicided films at high processing temperatures regardless underlying gate dielectrics. The correlations of Ni-Si phase transformation and arsenic doapnt with their electrical and physical changes were established by sheet resistance measurements, X-ray diffraction (XRD), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) analysis. Furthermore, the modulation of the work function (WF) of Ni fully silicided gates by arsenic impurity is presented, comparing the effects of dopant (As) on the WF and silicide phases (NiSi and NiSi2). It confirmed that the work function of NiSi can be tuned by implanting arsenic dopant, but it ineffective for NiSi2 phase.

Jan 1, 2010

The effect of rare earth element Y (0-2.0at.%) on the microstructure of TiAl alloys at the as cast and rapidly solidified conditions has been investigated. The results show that the addition of Y greatly refined the microstructure of TiAl alloys at both conditions. The refinement is more significantly with higher Y content. The refinement of Y in the cast alloys is attributed to that the strip-shaped Y-rich phase locating on the grain boundaries impedes the grain growth during solidification. In the rapidly solidified alloys, Y-rich phase dispersing uniformly as spherical particles in the matrix acts as heterogeneous nucleation sites which increases the nucleation rate of ??phase during the ????phase transformation, and produces a refined initial microstructure during solidification. Higher cooling rate restricts the grain growth during subsequent cooling.

Jan 1, 2010

By Xiaodong Wang

A liquid metal flow generated by a magnetic field whose traveling direction is periodically reversed, the Reversed Traveling Magnetic Field (R-TMF) is studied. The modulation frequency ranges from 0 to 6 Hz. Ultrasonic Doppler velocimetry probes the generated fluid flow. Depending on the modulation frequency, a number of characteristic flow features are exhibited. A transition frequency (approximately 4 Hz) exists, above which the flow is no longer sensitive to the force modulation. Below this transition point, the amplitude of the velocity oscillation increases, and then below fm = 0.05 Hz, it saturates around a value close to that observed without any modulation. A theoretical model to obtain an analytical solution of electromagnetic force and to predict flow motion is developed, which is fairly in agreement with the experiments.

Jan 1, 2009

By David Norval

Water solidification of mattes, metals, alloys and certain slags with high metal entrainment has customarily not been practiced due to the belief that such processes are too dangerous and unproven in the Pyrometallurgical Industry. Slag granulation on the other hand is extensively applied, although in some cases crudely, with disastrous effects, as a result of not recognising the high heat capacities prevalent in slags. This paper will examine the most common air solidification processes and compare such processes with water solidification, mainly slag and matte granulation processes and design criteria for safe and reliable operation. Finally, purpose designed granulation and solidification processes will be discussed taking into account specific applications and the individual signatures of alloys and slags, emphasising that no slag, matte or alloy responds in similar fashion to a granulation practice.

Jan 1, 2006

By Tiezheng Li

Keywords: Laminate Composites; Mechanical Behavior; Damage Evolution The mechanical performance of Ti-6-4-Al3Ti metal-intermetallic laminate (MIL) composites synthesized by a reactive foil sintering technique was evaluated. Crack morphology of untested Ti-6-4-Al3Ti MIL composites has been characterized by optical microscopy. Mechanical tests were performed on Ti-Al3Ti metal-intermetallic laminate (MIL) composites and pure Al3Ti, and the principal mechanisms of damage initiation and accumulation were identified experimentally. The elastic properties and anisotropy of the laminates were calculated and successfully compared with Resonant Ultrasonic Spectroscopy (RUS) measurements. The effect of residual stress on the fracture toughness of the Ti-6-4-Al3Ti MIL composites was analyzed.

Jan 1, 2005

By Li Chen

A new process, i.e. Ball milling--Neural leaching--Oxidation calcinations--Chloridizing distillation--Hydrolysis, was designed to recover germanium from the vacuum furnace slag produced in Shaoguan smelter. The suitable process and operational parameters were determined for the practical production.

Jan 1, 2005

By WU Jian-hui

Keywords: metallic material, precursor synthesis, precipitation, nickel, fibrillar powder The composition and morphology of the precursor of fibrillar nanocrystalline nickel powder prepared by oxalate precipitation are characterized by XRD,IR and SEM analysis, and the effects of temperature, nickel concentration, pH, surfactant and drying process on the morphology and the dispersion of the precursor are investigated. By the experiment results, the fibrillar precursor is a complicated nickel salt. The precursor prepared in the of 60~70°C,0.6~0.8 mol/L nickel ion, pH=8.4~8.6 and with addition of PVP surfactant is well dispersive and in fiber form. The powder dried by azeotropic distillation is dispersive.

Jan 1, 2005

By T. T. Chen

Copper anodes generated from copper scrap are relatively rich in Sn, Zn and Fe. Because of the presence of oxygen, only trace amounts of Sn occur in solid solution in the copper crystals. Thus, Sn occurs mainly as SnO2, Cu-Sn-Ni oxide and Sn-Ni-Zn oxide in the copper anodes, and Zn and Fe occur mainly as minor constituents in the Sn-Ni-Zn oxide and Cu-Sn-Ni oxide. During electrorefining, these oxide species are liberated from the copper anodes and report directly to the anode slimes. The trace amounts of Sn present in solid solution in the copper crystals dissolve but reprecipitate as Sn arsenate or a Sb-As-Sn-O phase. Accordingly, high Sn contents in copper anodes do not lead to elevated Sn concentrations in the electrolyte.

Jan 1, 2010