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By M. J. Nicol, R. P. Colborn

An investigation into the kinetics and mechanism of the oxidation of iron (11) by oxygen in aqueous chloride solutions By R. P. COLBORN Pr. Eng., Ph.D. (Natal) and M. J. NICOLt B.Sc. Hons., Ph.D. (Rand) A reaction mechanism for the oxidation of ferrous chloride by molecular oxygen is developed. and the appropriate constants are evaluated. The effect of a number of cations and anions on the rate of oxidation has been tested.

By B. J. Madden

The formula developed by Salamon and Munro in 1967 has been used for the past 22 years in the design of bord-and-pillar workings in South African collieries. This paper re-assesses the formula In the light of Its past performance and examines the effect of mining method on coal-pillar strength. An account is given of the extension of the formula so that it can be applied beyond the empirical range for which it was derived, and the advantages of the extended formula (the squat-pillar formula) are described.

Jan 1, 1991

By C Smit

SYNOPSIS A prototype collimated radiometric face scanner was tested in the Harmony Gold Mine. The results obtained during the pilot study indicate that in situ radiometric uranium assays are statistically indistinguishable from those obtained conventionally from channel chip samples. In addition, the study demonstrated that reasonably reliable gold estimates can be deduced from the radiometric measurements, by use of the ratio of gold to uranium within a mine. The instrumentation, calibration procedures, and background determination are described briefly.

Jan 1, 1985

By J. H. Venter

The accuracy of estimation from samples of ore in bulk By J. H. Venter Published in the Journal April 1972. ERRATA: Equation (1) should read... Equation (3) should read .... line following "Duscussion" Delete" .... Insert... above "References" "Discussion". Replace .... tenth DISCUSSION M. DA VID Professor Venter has proposed a formula to compute the variance of the estimated grade of a lot of broken ore, and interesting comments on the relevance of the formula and suggestions for developments are made by P. R. Janisch.

Jan 4, 1972

By J. Githiria, D. Wachira

The conventional truck and shovel haulage system has become expensive to operate in most mines due to current strict environmental conditions, increase in depth and size of open-pit mines, increase in labour costs, and fuel costs. These factors have motivated the search for alternative material haulage options in open-pit mines. In-pit crushing and conveying (IPCC) system has been regarded as a plausible alternative in material haulage systems. However, usage of IPCC has been limited to a few mines due to limited knowledge of IPCC performance, and other technical factors of the system. This paper investigates, and evaluates the productivity performance of four types of IPCC systems (fixed, semi-fixed, semi-mobile, and fully mobile IPCCs) using mine productivity index (MPi). Using a model developed by MATLAB, the MPi for the four systems is computed using input variables such as availability, utilisation, performance and number of trucks and shovels in a limestone quarry. The mine productivity index for fixed, semi-fixed, semi-mobile, and fully mobile IPCC is obtained as 67.13%, 69.02%, 70.52%, and 71.52% respectively. In conclusion, the fully mobile in-pit crushing and conveying system is the most appropriate IPCC in the quarry, due to its better productivity performance compared to the other three IPCC systems and the truck and shovel system currently in use.

Sep 1, 2021

By L. D. Robbins, M. L. Murphy, A. C. Campbell, L. Murphy

This paper reports on what appears to be the first discovery of prehistoric mica-schist mining in southern 4frica. The mine concerned was found in a location very rich in rock art that is one of the most important archaeological sites in the Kalahari. The authors conclude that the oval pieces of mica schist that were found at the mine site were used by Khoisan peoples to scrape fatty tissue from hides that were to be cured. Radiocarbon datings seem to indicate that such ovals were used for at least 20 000 years.

Jan 1, 1994

By B. K. Cross

This paper, which adopts a philosophical approach, attempts to analyse the contribution that the computer is capable of making in geological analysis, financial evaluation, and mine project control. Also examined are some reasons for non-utilization of these capabilities. As with most computer associated problems, the cause is primarily human and not mechanical. The paper gives one numerical example of the analysis of geological data and one of the evaluation of mine-design data. The values used in the examples are intended only to emphasize certain points and are not necessarily reproducible.

Jan 1, 1980

By H. A. D. Kirsten

SYNOPSIS This paper describes simple calculations to evaluate the stability of hangingwall and footwall strata at the work¬ing face and in backfilled areas. It shows that the benefits of support provided by backfill can best be realized when the fill is placed as close to the face as possible. The main beneficial effects of fill are that it reduces the stope span, at the same time providing a damping effect on vibrations, and prevents the fall-out of blocks in filled areas, thus maintaining the competence of the strata.

Jan 1, 1988

By M. B. Cortie

An account is given of the development of ferritic stainless steels since their discovery in the early years of this century. The alloys became very widely used in the 1950s, the market during that decade being driven strongly by a demand for automobile trim made of ferritic stainless steel. The production of ferritic stainless steel declined as a proportion of the total at the end of the 1950s as consumer preferences changed. However, the market is now growing strongly again, this time driven by a demand for oxidation-resistant alloys for motor-vehicle exhaust systems. The tonnages produced, applications, and market shares of the various alloys are discussed and compared. Trends in world stainless-steel production, product forms, technological development, and usage are examined.

Jan 1, 1993

By H. Ruthert

An understanding of wear in systems conveying solids is extremely important from the standpoints of design and economics. The lifetime of any bulk solids-handling system depends on the type of solids present and the operating parameters of the transportation system. The relationship between wear in backfill pipelines on South African gold mines and the transportation system's operating parameters is well understood. However, the effect of the transported solids on the pipe wear is less well understood, because of an inability to characterize particle sharpness. The sharpness of the particles, together with their size and hardness, is responsible for the aggressivity of particles, or their ability to cause damage and wear. This paper presents a novel method for the characterization of particle sharpness. The results presented rank particles according to the sharpness of their surfaces.

Jan 1, 1993

By F. H. Deist, H. D. Small, J. D. Austin, L. F. Duvel

The development and application of a Computer System to aid in the planning of production in mines By F. H. Deist, L. F. Duvel, J. D. Austin, H. D. Small A computer system to aid in the planning of production in mines and its application to a complex colliery are descrIbed, The system consists of three phases, the data base maintenance program the 'production simulator' and the report generation facility, In the first part of the paper the categories of information kept on the data base and the functions of the simulator are described in general terms. The application of the system to a multi-product colliery operating a variety of mining methods in a number of superimposed seams is described m the second part. In conclusion some comments are made on further applications and intended future developments.

By R. Koen, H. Visser, A. Roodt

"SynopsisThe tetraethylammonium salt of the mono-anionic coordination compound mer-oxidotrichlorido(thenoyltrifluoroacetylacetonato- K2O,O’)niobate(V) (NEt4)[NbOCl3](ttfa)], has been prepared under aerobic conditions and characterized by single-crystal X-ray diffraction. (NEt4)[NbOCl3](ttfa)] crystallized in the monoclinic P21/c space group, with a = 11.483 (5), b = 12.563 (5), c = 17.110(5) Å, and ß = 100.838 (5)o. The complex structure exists in a 50.0% (NbA) : 50.0% (NbB) positional disorder ratio.IntroductionComplexes containing organometallic type ß- diketone ligands with O,O and O,N donor atoms are used widely in coordination chemistry and have applications in catalysis, radiopharmaceuticals, etc. (Schutte et al., 2011; Roodt, Visser and Brink, 2011; Brink et al., 2010; Otto et al., 1998). These ligand systems are very useful because of their highly coordinative nature, high solubility, and also due to their ability to be functionalized with various substituents on the carbonyl carbon atoms (Schutte et al., 2011).Only a small number of ß-diketonate ligands have successfully been coordinated to a Nb(V) metal centre, with only a select few being characterized by X-ray crystallography (Viljoen, 2009; Bullen, Mason and Pauling, 1965; Preuss, Lamding and Mueller-Becker, 1994; Funk, 1934; Davies, Leedlam and Jones, 1999; Allen, 2002. The synthesis and crystal structure determination at room temperature of mer-oxidotrichlorido (thenoyltrifluoroacetylacetonato- k2O,O’)niobate(V) {(NEt4)[NbOCl3(ttfa)]} was first reported by Daran et al. in 1979. Accordingly, for this current investigation, (NEt4)[NbOCl3(ttfa)] was re-evaluated at 100 K to determine if the structural features might change with temperature."

Jan 1, 2015

By B. M. Munyungano

Rössing Uranium Mine operates a recovery circuit with continuous ion exchange followed by solvent extraction. Serious organic degradation problems were encountered during 1985/6, 2000 and 2005 in the solvent extraction plant. The preferential loss of the tertiary amine extractant was observed during the above-mentioned period. Previous investigations revealed that the tertiary amine was breaking down to nitrosamine, which cannot take part in the exchange reaction with U3O8. A reduction in the redox potential of the solvent extraction plant feed to below 500 mV halted this preferential loss. A lot of effort has been made to try and understand the actual mechanism for nitrosamine formation. Current understanding for the degradation is that formation is due to high nitrates on the strip side of the circuit emanating from nitrates from the precipitation process using ammonia. It is the current belief that pH lower than 3.7 on the strip side results in loading of nitrates onto the solvent. If oxidizing conditions prevail on the extraction side of the solvent extraction circuit, the tertiary alamine will then degrade into nitrosamine. This phenomenon is yet to be established and verified. It has, however, been established that the above process is brought about the following conditions ?High redox potential greater than 550 mV predominately caused by a high Fe3+/Fe2+ratio (4:1) ?Perception that if Fe2+<0.5 g/lit will contribute to high redox ?High concentrations of NO-3 in the conc eluate (feed to SX)/ammonium sulphate (NO-3> 4 g/l based on historic values) ?Presence of Mo as a catalyst ?Tests also have proved that the presence of nitrous acid in a concentration of 1 g/lat 550 mV leads to formation of nitrosamines from alamine.

Jan 1, 2007

By E. J. Magri

Consideration is given to the problem of the estimation, from limited data, of the likely grade and tonnage for a new mining property that is to be exploited by the selective mining of two metals that have substantial contributions to make to the total revenue. In particular, the case of a new gold and uranium mine in South Africa is analysed as follows. (I) The applicability of the underlying lognormal bivariate model for different support (i.e. ore unit) sizes is examined. (2) The necessary parameters for the bivariate lognormal models for different block sizes are estimated from abundant chipsampling data from a section of the Hartebeestfontein Gold Mine using alternative approaches, and the results are compared. (3) A method is given for obtaining the necessary parameters for a tonnage-grade relationship relative to a joint pay limit from the very limited information likely to be available at the end of the exploration stage of a gold mine, and the results are compared with those obtained from the large volume of data available from a minedout area.

Jan 1, 1982

By F. H. Guise-Brown

Raise-boring experiences in the gold mines of the Anglo American Corporation Group by J. W. WILSON and P. C. GRAHAM Published in the Journal, October, 1972. Discussion by F. H. Guise-Brown., B.Sc. (Min. Eng.) (Member) INTRODUCTION Messrs J. W. Wilson and P. C. Graham are to be congratulated on an excellent paper containing several thought-provoking remarks. The concept of allocating a machine and equipment valued initially at some R300 000 on an experimental basis is courageous, and the results obtained could be of interest to the mining industry as a whole. The Gold Fields of S.A. Group approached this problem differently. In pioneering the start of this work in South African gold mines, they considered that expenditure of this magnitude would be warranted only if the proposition was viable right from the start. To this end, a Robbins R41 was purchased expressly to assist in the duplication of part of the No. 1 shaft system of the Doomfontein Gold Mine. Mr M. J. Koortsl has summed up the initial results of this work and given some preliminary costing, but inflation since that period has made these figures somewhat out of date.

Jan 10, 1972

10th COMMONWEALTH MINING AND METALLURGICAL CONGRESS-CANADA, 1974 The Commonwealth Council of Mining and Metallurgical Institutions has received and accepted an invitation from The Canadian Institute of Mining and Metallurgy for the 10th Commonwealth Mining and Metallurgical Congress to be convened in Canada in April, 1974, immediately following the Annual General Meeting of The Canadian Institute of Mining and Metallurgy. It is proposed that the Congress centre will be Montreal and that, after technical sessions, tours of operations will be arranged. Further information will be issued in due course by The Canadian Institute of Mining and Metallurgy and enquiries should be addressed to the Executive Director of the Institute, 906-1117 Ste. Catherine Street West, Montreal 110, P. Quebec. NOTICE TO ALL STUDENT MEMBERS OF THE SOUTH AFRICAN INSTITUTE OF MINING AND METALLURGY The Institute offers each year for competition among Student Members of the Institute a prize, or prizes, should entries so warrant it, of up to the value of R100 to be awarded to the Student Member or Members who submit the best paper or dissertation on a topic appropriate to the interests of the Institute. In the case of Student Members who are in full time study at a university the dissertation or thesis which they may have to write in part fulfilment of their university curriculum may be accepted provided it is presented in a manner and on a topic suitable for publication in the Journal. The closing date for the receipt of papers shall be 31st December each year.

By D. J. Shields

The U.S. Bureau of Mines has developed a microcomputer-based mineral modelling system that enhances analytical capabilities of the agency. It draws upon the extensive data base previously developed for the Bureau&apos;s Availability studies. The model is first formulated as a generalized network flow optimization problem, the optimal flows from which are fed into a transportation algorithm. The goal of the modelling system is first to fulfill prespecified demand at the minimum opportunity cost and second to identify feasible, optimal trade patterns. The system facilitates the analysis of policy issues on a real-time basis and supports the Bureau&apos;s mission to assess mineral resources.

Jan 1, 1987

By M. Balamurali, K. M. Seiler

Modelling stockpiles is a key factor of a project’s economics and operation in mining, because not all the mined ores are not able to mill for many reasons. Furthermore, the financial value of the ore in the stockpile needs to be reflected on the balance sheet. Therefore, automatically tracking the boundaries of the stockpile facilitates the mine scheduling engineers to calculate the tonnage of the ore remaining in the stockpile. This paper suggests how the dynamic of stockpile shape changes caused by dumping and reclaiming operations can be inferred using polygon models. The paper also demonstrates how the geometry of stockpiles can be inferred in the absence of reclaimed bucket information, in which case the reclaim polygons are established using the digger’s global positioning system (GPS) positional data at the time of truck loading. This work further compares two polygon models for creating 2D shapes.

Sep 1, 2021

By H. A. D. Kirsten

The structural competence of mesh- and fibre-reinforced shotcrete was investigated in two series of tests on full-scale panels. It was found that uniformly distributed loading was marginally less demanding than point loading, mesh reinforcement was superior to fibre reinforcement, Dramix fibre and Melt Extract fibre were similar in reinforcing characteristics, and 30 mm to 35 mm was an optimum fibre length. Furthermore, the consistency of the fibre content could not be assured on practical mining sites, and an average fibre content of about 1,5 per cent was the maximum that could be obtained for fibre lengths not exceeding 35 mm. Also, owing to its greater flexibility, shotcrete reinforced with diamond mesh was preferable to fibre-reinforced shotcrete in mining excavations subject to squeezing conditions. In view of the difficulties associated with assuring the consistency of the fibre content in mining applications, it appears that the sophisticated attributes of fibre-reinforced shotcrete can be effectively exploited only in civil-engineering applications in which quality assurance is subject to explicit contractual control. Load-deflection curves, together with measurements of compressive stresses in the surfaces of some of the panels, enabled the ultimate flexural strength of reinforced shotcrete to be rigorously formulated, and rigorous design procedures for shotcrete subject to bending and direct thrust to be developed. The application of the procedures is demonstrated in a practical design case in which the moments and thrusts in a tunnel lining are determined in a numerical analysis of the interaction between the lining, the surrounding rock, and the rock-reinforcing system.

Jan 1, 1992

By P. J. Bartlett, H. A. D. Kirsten

A two-dimensional numerical scheme for the simulation of the plastic stress-strain properties of rock, and the various components of rock reinforcement and shotcrete, was used to rigorously determine the characteristics of tunnel support under squeezing conditions. D-shaped tunnels varying in size from 2,8 to 6,5 m in height and width were considered. The four main mining stages in the BAS block cave on Premier Mine were simulated as alternative sets of field stresses. The rock reinforcement comprised 1,8 m long fully grouted rockbolts and 6,0 m long fully grouted cable anchors at various spacings, and of various tensile and bond strengths. Various thicknesses of shotcrete and footwall support configurations were also considered. It was found that shotcrete and rock reinforcement, owing to inherent differences in stiffness, do not function in unison. As monolithic application, shotcrete has an overriding avidity for the imposed loading and destructs itself unless of extraordinary thickness. Under squeezing conditions, it accordingly supports the excavation surface while the rock reinforcement contains on-going convergence. The loads in the various support components can be determined only by simulation of the shotcrete as a stress-relieved medium to represent its broken condition in the field. The loads in the rock reinforcement vary around a tunnel and are the largest in the sidewalls. The loads increase with an increase in tunnel dimensions, the increase in load in the sidewall due to an increase in height being larger than that in the hanging- and footwalls due to an increase in width. Depending on the strength of the rock, the loads in the rock reinforcement become prohibitively large beyond a certain size of tunnel. The reinforcement of footwall rock can be omitted without adversely affecting that in other walls, provided the tensile and bond strengths of the reinforcement are not limited. The resulting footwall heave may, however, result in undermining of the reinforcement in the adjoining walls. A relative depth of anchor of 1,37 provides adequate bond strength in the larger sizes of tunnel, whereas, in smaller tunnels, anchor length is determined by the allowable convergence. The lack of fun column grouting adversely affects the efficiency of rock reinforcement to a major extent. The loads in rock reinforcement are very sensitive to the strength of the rock. Owing to a lack in refinement and calculational rigour, empirical classification systems are an inappropriate means for the design of tunnel support in squeezing conditions and, as a result, grossly unclear-estimate the support requirements.

Jan 1, 1992