Search Documents

There are interactions between different minerals from the same ore, minerals and grinding media, and the electrochemical conditions present in the system. Grinding in steel rod and ball mills is a common practice in minerals processing. It is accepted, that the electrochemical interactions between the grinding media and minerals in a grinding mill, influence the corrosive wear of balls/rods and the surface properties of the ground minerals. A complex massive sulphide, Cu-Zn, TAKNAR, Iran, was used for all the experiments. The aim of this study was to investigate the effect of grinding media (dry or wet) on the pulp chemistry and recovery of Cu and Zn in bulk concentrate. 1100 g of ore samples were milled, and mill products with d80=85 and 75 micron in wet and dry grinding methods were produced. Rougher bulk flotation experiments were performed with 550g ore samples, at 30% solids. SIPX in conjunction with Aero238 in 1:2 ratio (48 g/t), was used as mixed collector system, and copper sulphate (200g/t) and MIBC (20 g/t) were employed as sphalerite activator and frother. Lime and High purity Oxygen gas were used for adjusting pH at 8.5 and aeration. The results showed that, more positive pulp potentials were measured when the feed had been ground in a dry environment, and the difference in pulp potentials between the dry and wet ground feed was approximately 250 mV after the grinding stage. In dry grinding method, the recovery of Cu and Zn increased approximately 5 and 10%, respectively. In addition, in dry ground samples, the volume of middling and coarse particles (+100 micron) were more and Dry ground flotation feed had better agreed with using a mixture of collectors. After using copper sulphate, pulp potential increased about 50 mV in dry and 75 mV in wet grinding methods. Keywords: grinding media, pulp potential, Cu-Zn massive sulphide, bulk flotation

Sep 1, 2012

With shortage of sulfide nickel ores, laterite ore was paid more attention by scientists. Because its grade is commonly lower than sulfide nickel ores, laterite ore can not be utilized effectively be-coming the bottleneck of study. Leaching laterite ores from Yuanjing, Yunnan province, organic ac-ids show better selective than sulfide acid in nickel and cobalt recovery. Organic acid has low de-pendent on pH, keeping leaching capability even higher than 3. On the other side, when pH up to 2, sulfide acid can not leach laterite ores any more. After four kinds of organic acid leaching laterite ores, besides citrate, malate and succinate have good leaching and effectively selective capability. Especially, succinate has the best selective leaching capability of nickel and cobalt in four kinds of organic acids for latter anion purification and separation. Isolated from waste water with sugar, Aspergillus niger (zs1) has great capability to produce organic acids and vigorous growth. Laterite ores have been respectively processed by direct-leaching and indirect-leaching. Indirect-leaching gives a better result than direct-leaching. Extraction of nick-el by indirect-leaching reaches 44.3%, far more than that of direct-leaching. Moreover extraction of nickel at pulp density of 5% is higher than that at pulp density of 10%, reaching 63% in 11 days and extraction of cobalt also is 48.1% in the same period. Compared with nickel and cobalt, iron gives low extraction in solution, containing organic acids produced by Aspergillus niger .

Jan 1, 2014

In the present work, the flotation behaviours of zircon, rutile and ilmenite using sodium oleate as collector in absence and presence of depressants were thoroughly investigated. The maximum in the flotation recovery of any of the above minerals falls within similar pH ranges. A range of inorganic and polymer depressants were examined in order to improve the separation of zircon from rutile and ilmenite. Optimum values of conditioning pH and depressant concentration to achieve maximum recovery and best selective floatability of zircon were obtained. Selective flotation of zircon from Ti-bearing minerals was anticipated from single mineral experiments under different pH values, depressant and collector conditions.

Jan 1, 2014

By C. S. Gundewar

About 90% of the barytes produced the world over is used for oil and gas drilling as weighting agent in drilling mud to control pressure, prevent blow out and provide lubrication. This is because of its unique properties like high specific gravity, water insolubility and intentness. India is one of the leading producers and exporters of barites. The Mangampeth Baryte deposit in Cuddapah district of Andhra Pradesh, India being the largest single deposit in the world having a reserves of about 80 million tonnes. Approximately 50% of the total reserves of grey barites of Mangampet deposit assays less than 92% BaSO4, the minimum stipulated grade for oil and gas drilling industries. To reach and recover the high grade barite, the overlying low grade has necessarily to be mined out and removed. At present this is being stacked separately at the mine site involving lot of labour and transport cost. Considerable barites is contained in the dumps adversely affecting the conservation and creating lot of environmental hazards. IBM being the premier organization in India in the field of conservation of minerals and environmental protection in mining has recognized the importance of adverse effect of these huge dumps at site. The Ore Dressing Division of IBM, Nagpur has characterized these dumps and developed the flotation process on a sample assaying 66% BaSO4 and 23.3% SiO2. The flotation concentrate obtained assayed 93.7% BaSO4, 2.38% SiO2 with BaSO4 recovery of 80% and meets the requirement of the oil industry. The flotation concentrate being non-wetable, can not be used as such as weighting agent, and hence the collector coating on the concentrate was removed either by acid treatment or heating to make it water wetable. The concentrate was 92% -325 mesh and having a specific gravity 4.3. The barites concentrates so produced meets the size, grade and specific gravity specifications required for use in oil drilling industry. Apart from the financial benefits the process augurs well for the commercial exploitation of these huge dumps in terms of (1) additional recovery of these valuable minerals and conservation, (2) reduction in dumps value, (3) improvement in environment and offering an excellent potential for export.

Jan 1, 2014

By F. H. Wang

The Yinmao Lead-Zinc Mine Co. Ltd. has got 50 years of mining history. In recent years, the manganese grade in the flotation tailings has been continuously increasing. In order to make fuller use of the existing resources, as well as to increase the company?s economic efficiency, our company adopted the technique ?magnetic separation? and ?iron removal? to effectively recycle the manganese concentrate resources.

Jan 1, 2014

By Luis G. Bergh

Today, large size mechanical flotation cells of 100 to 300 m3 are used in rougher operation in different flotation industrial plants, in Chile and worldwide. However, in spite of the advances in fundamental research and the notable growing in equipment size, with more complete instrumentation systems, there are still a lack of reliable data for industrial flotation modeling and simulation to advance in better control systems design. In this work, a model of a rougher flotation circuit, based on operating variables and parameters fitted from industrial data, obtained in some previous work, is used to develop a set of logic rules in order to aid operating decisions. The simulator was first used to sensitize the effect of changing the froth depth profile on target variables, and then to find out the best profile to reject common disturbances coming into the plant. The flotation circuit simulator was redesigned to incorporate an expert system following the proposed control algorithm. Several tests were performed to evaluate the control responses to different correlated series of input variables, such as feed grade, tonnage, particle size distribution, and solid percentage. Control alternatives are discussed based on the circuit simulator. Keywords: modeling, industrial data, flotation control, mineral processing.

Sep 1, 2012

By Lei Wang, Qi Zheng, Xiao-kui Che

"The wastewater emitted by gold chemical industry contained vast of different heavy metal ion, such as Zn, Cu and Ni etc. Among them Zn is the main ion in the waste water which causes the serious environment pollution. A method of preparing a kind of resin which is used for the removal of Zn by magnetic adsorbent was developed and was applied in practice. This adsorbent is a chitosan made of a kind of Fe3O4-chitosan modified by epichlorohydrin. The adsorption capacity of the absorbent and it was concluded that under the laboratory conditions, the maximum adsorbing capacity of this adsorbent could be 287.58 mg/g. The absorbent was also applied in the wastewater emitted by a gold industry in Shandong province. Its performance was tested and the result showed that the concentration of Zn ion in the wastewater was reduced from 0.58 mg/L to 0.0174 mg/L. What is more, the adsorption rate could be more than 97% when the dosage was 100L/m3 after adsorbing for 1h. KEYWORDS Selective, preparation, laboratory experiments, industry experiment, comparation INTRODUCTION Currently, most gold chemistry use cyanide to leach gold ore. Many different metals participate to this reaction besides the gold ion in this processing, so that the composition of the water is very complex. The waste water emitted by gold chemistry industry contains large amount of heavy metals. Definitely, if it was discharged without any treatment, the water would threaten the environment. The recuperation of any ion in the water would mitigate the pollution. Ion exchange resin, which is an effective material to do the water treatment with low cost, became widely applicated in this field [Yu-jiao Wang,2013]. Different kinds of resin were developed and the influence factors such as pH, adsorption properties and selectivity for different ions were investigated [CA Cruz et al,2018; PawanKumar et al.2016; Y Zhang, et al,2010; and ShengingSun, Aiqin Wang, 2006;]. The waste water mentioned in this article has a high Zn concentration, so a magic resin for Zn adsorption selectively we designed was used to manage this water. And the recovery of Zn could not only contribute to pollution abatement but also a best way to settle a dispute to the short of Zn resource. So the article mainly describes the preparation and the application of a kind of magnetic adsorbent used for the removal of Zn both in laboratory and industry. The aim of this article is to compare the effect of this resin in industry and laboratory?"

Jan 1, 2018

By Jochen Petersen, David G. Dixon

"Although heap leaching may be perceived as a somewhat low-tech route for the extraction of low-grade minerals, the underlying physical, chemical and biological processes are in fact extremely complex. There has been increased interest in heap leaching of sulphide minerals in recent years with the advent of controlled bio-heap leaching, and the need to mine more marginal ore deposits.A detailed investigation into the dynamics of heap leach processes has provided much insight into the underlying complexities, and has led to the development of a sophisticated modelling tool. Some of the features include mineral kinetics, particle level effects, bacterial growth, oxidation and adsorption, gas adsorption, pore diffusion, bulk advection, gas balance and heat conservation.Two case studies are presented which illustrate specific features of the model for different applications and how these have helped to identify key areas of concern. In each case the model has proved as an invaluable tool either for the improvement of existing heap leach practice or for the development and assessment of novel applications."

Jan 1, 2003

With significant increase in steel output in the world the price of iron ores has been soaring recently. Especially, there is a strong demand for iron ores in China, leading to more attentions paid to developing low grade iron ores. In this paper mineralogy of nm-of-mine hematite ore was deter-mined, and coal-based direct reduction-magnetic concentration was successfully developed to beneficiate low grade hematite ore. Mineralogy analysis indicates that this hematite ore is a super fine refractory ore, with the main valuable mineral hematite being closely associated with quartz and distributing uniformly and mostly occurring within the size of 3~5J.lITI,leading to being difficult to beneficiate due to super fine hematite and only grading 28.83% Fetotal. This hematite ore failed to be effectively upgraded by traditional processes in trial tests, such as reverse flotation, gravity concentration, and magnetic separation, or the integration of the above processes. In contrast with adoption of the coal-based direct reduction-magnetic separation process, concentrate was produced with high iron grade and metallization degree in the present work, which provides a theoretical basis for utilization of low grade iron ores. By optimization of direct reduction conditions, such as reduction temperatures, duration and mass ratio of reductant coal to iron ore, the reduced ore with 93.72% metallization degree was prepared, and then three-stage grinding-magnetic separation of the reduced ore were conducted, the final concentrate was manufactured, assaying 69.54% Fetotal and 98.01 % metallization degree, and with low content of impurities. This iron concentrate with high metallization degree produced by this process is a superior burden for converter instead of blast furnace. This process is enviromnent friendly by directly making iron using coal and iron ores instead of coke, resulting in less emissions and low production cost.

Jan 1, 2014

By Ho-Seok Jeon

The separation in gravity concentrators is based on the density difference between valuable and gangue minerals. In addition to density, many auxiliary parameters like particle size, shape, feed rate, pulp density etc. plays an important role in the separation. The performance efficiency of gravity units is largely based on the interference of such auxiliary parameters during separation. Many gravity concentrators are used for the beneficiation of cassiterite ores and performance of which are varying with different feed material, particle size and required enrichment from the unit. Selection of gravity units is generally based on laboratory testing and data collected from the previous experience. In the present investigation cassiterite ore collected from Uljin deposit, South Korea has been subjected to various gravity units like jig, spiral, and Knelson concentrator with the intension to pre-concentrate the ore. Second stage concentration was carried out using shaking tables. The article mainly summarizes performance evaluation methods employed for gravity concentrators. Selection of gravity circuit for the beneficiation of cassiterite was made on the basis of the recovery-grade curve, and Tromp curve methods. Keywords: cassiterite, gravity concentration, recovery-grade curve, sink-float test, tromp curve

Sep 1, 2012

By P. Radziszewski

In comminution research, ore breakage and wear are usually studied independently of one another. Much of this is due to the fact that wear is usually a slow process compared to ore kage. However, the abrasion wheel test used to determine the abrasive wear contribution to total steel media wear provides the opportunity to study not only abrasive wear and friction but also ore breakage. In this paper, we will explore the use of the abrasion wheel wear test device to study abrasive wear, friction and ore breakage using standard Ottawa foundry sand. We will look into the feasibility of applying the work index as well as t10methodologies to this test set-up. We will also look at how the work index results evolve with abrasive wear and friction. We will then discuss the merits of pursuing the use of this abrasion wheel test for not only wear characterization but also breakage characterization.

Jan 1, 2014

By Boris Albijanic, Hongjuan Chen, Bogale Tadesse

"During mechanical flotation of fine liberation sized complex rare earth ores, a large fraction of ultrafine valuable mineral particles are lost to tailings. Fine gangue mineral particles can be entrapped within the froth phase and be floated together with target mineral particles. Another common challenge in ultrafine rare earth mineral flotation is the formation of a sticky froth (excessively stable froth). Thus, the improvement of the flotation of fine and ultrafine rare earth bearing minerals through appropriate cell design and reagent selection is highly desirable. The aim of this study is to investigate the performance of a pico-bubble cavitation flotation column in improving selective recovery of ultrafine rare-earth elements (REEs) bearing minerals from complex and low-grade ores. In pico-bubble cavitation column, very small bubbles are generated which are capable of attaching to ultrafine particles and consequently modifying their surface properties. The overall effect of these processes should lead to improved flotation selectivity and recovery of ultrafine RE mineral particles. In this paper, the effects of a number of flotation operating variables on recovery and grade of REE minerals was investigated using a continuous pilot scale pico-bubble column flotation. At the flotation conditions used in this study, subtle monazite upgrade was observed while gangue Fe oxide was preferentially floated even in the presence of depressants. INTRODUCTION Rare earth elements (REEs) have unique properties such as superconductivity and catalytic activity, and are in high demand for a large number of cutting-edge technologies in the modern world including the production of mobile phones, fuel cells, displays, permanent magnets for wind power generation, high-capacity batteries, green energy devices, etc (Naumov, 2008). REEs tend to be intimately associated within many minerals, and are rarely found in high concentrations in deposits for economic extraction. Up to now, among over 250 minerals containing REEs, bastnasite (Ce), monazite (Ce, Th and La) and xenotime (Y) are the three main minerals that contain sufficient grade of REEs for commercial exploitation (Zhang and Edwards, 2012). The deposits that contain bastnäsite, monazite and xenotime usually have complicated mineral compositions, with various valuable minerals of fine embedded grain sizes in association with complex gangue minerals. In order to ensure liberation of the REEs minerals, fine grinding to less than 30 µm is necessary. This fine grinding leads to difficulty in recovering a large proportion of fine and ultrafine particles in separation processes such as flotation (Trahar and Warren, 1976). Consequently, highly liberated and ultrafine fine valuable REEs particles are lost into tailings during traditional mechanical flotation. Besides, the formation of extremely sticky and stable froth inhibits the drainage of hydrophobic particles. Thus, improving flotation of rare earth bearing minerals, particularly the ultrafine size range, is highly desirable."

Jan 1, 2018

By Qidong Zhang, Yongsheng Song, Wenjuan Li, Guiying Zhou, Kun Song

"Molybdenum is a very important rare mineral resources, which exists largely in oxidized ores and sulphide ores in nature. About 99% of metallic molybdenum comes from molybdenite. The talcose molybdenum resources are abundant but the resources utilization is low, because the talc is naturally hydrophobic and the floatability of talc is similar with molybdenite, which lead to difficult separation by flotation. Talc is easy entry into concentrate in flotation which can cause the content of MgO overhigh, therefore the molybdenum concentrate grade can not meet the industrial requirements. Thus the utilization level of talcose molybdenum resources has been restricted greatly.The adsorption of water on talc and molybdenite surfaces and natural floatability of minerals were studied by density functional theory method. The results showed that molybdenite and talc were layered minerals which exhibited similar surface wettability and H2O molecule prefers to stay with water rather than the minerals surfaces. N2 is adsorbed on talc and molybdenite surfaces more easily than H2O. The interaction and flotation behavior were studied by SEM and flotation experiments. The reason why talc interferes with the flotation molybdenite has been revealed. The agglomeration between molybenite and talc was caused easily in neutral or acidity solution, and it was dispersing between molybenite and talc particles in alkaline solution. The flotation results showed that good floatability of talc was the key factor causing a low grade of concentrate in alkaline solution. Thus, it is the key factor to enlarge floatability difference between molybdenite and talc.INTRODUCTIONMolybdenum is a kind of important rare metal and strategic reserve resources (Zhitao Y et al, 2016a). Due to excellent characteristic, such as high melting point, good thermal property and et al, it’s widely used in metallurgy, machinery, chemical, aerospace, and many other areas. It has become an indispensable metal in modern industry. Molybdenum generally exist in the form of molybdenite which is a kind of mineral with excellent natural floatability. Talc is a kind of typical hydrous and layered magnesium silicate minerals (Beattie D et al,2006a), which is one of the most common gangue mineral of the platinum group metal ores and metal sulfide ores (Tao L et al,2011). Due to its good native floatability, talc is easy entry into the concentrate product with foam in the process of sulfide ore flotation (Kelebek S and Smith S, 2006b), which resulted in decreasing concentrate indexes. Not on that, the high-content MgO of concentrate will also produce a series of adverse impact to the subsequent smelting (Lotter N O et al, 2008). Therefore, it is difficult to separate talc from sulfide ore concentrate effectively."

Jan 1, 2018

By Ari Kokko

Metso has a long history supplying boilers for high ash coal firing. These boilers are based on circulating fluidized bed (CFB) technology. CFB?s biggest benefit is fuel flexibility ? it can burn fuels from high moisture content to high ash content. Metso has delivered tens of CFB boilers burning waste or high ash coal starting on 80?s. Some of the boilers have been in operation twenty years meaning that there is a long term experience from these plants available. This feedback includes boiler performance and maintenance issues of the boiler. Metso is also delivering coal washing plants to improve coal quality, i.e. reducing ash content of the coal. The idea to combine coal washing plant and CFB boiler was made up two years ago in Metso. Up-coming legislation of coal washing and restrictions for washery reject land-filling in India are good drivers for this kind of concept. Pre-study of this kind of concept led to the conclusion that coal washing process can be fine-tuned so that reject?s calorific value is only 1100 kcal/kg and that was set as a target for boiler design. Metso shipped 200 tons of washery reject to its own research center located in Tampere Finland. First a wide range of fuel characterization tests were done in lab-scale and after that one week test run in 4 MW CFB pilot boiler was done. Test run proved that 1100 kcal/kg can be fired without any support fuel with special boiler design. Test run results gave a good set of data regarding combustion efficiency, emission performance and boiler dynamic behaviour when burning this kind of fuel. These results are introduced in this paper. This paper introduces also the CFB boiler concept for washery reject firing including boiler plant, fuel and ash handling systems and flue gas cleaning system. Power plant can be integrated with coal washing plant so that boiler size matches with washing plants c

Sep 1, 2012

By Shobha Kumari

Coal is the prime source of energy in India. It now contributes to about 55% of the total power generation and will continue to have its major share in the energy mix of the country in the foreseeable future. Thermal coals of India, known for their wide variations in nature and categorized as difficult to wash due to their typical mineral matter association with the organic matrix, need suitable beneficiation technique for quality upgrade for improving the overall economics, efficiency and pollution free power generation. A non-coking high-ash coal, collected from Vasundhara open cast mine of the Ib Valley Coalfield, Orissa, has been characterized along with its different fractions obtained in the process of beneficiation for distribution of minerals using FTIR, XRD and ash analysis. The raw coal was fractionated by size as well as by density. It has been observed that ash yields and mineralogical composition (found to be mainly kaolinite and quartz) have no appreciable change in different size fractions, indicating homogeneous distribution of minerals in the coal matrix. However, for the different density fractions the mineral composition and ash yield have significant variations. The quartz content of the beneficiated coal visualized with 34% ash yield, as mandated by the Ministry of Environment and Forest (MOEF) for the use of coal in power plants is reduced to half of that of the raw coal. As quartz is the most abrasive mineral in coal, reduction of its proportion obviously signifies considerable reduction of wear of power plant machinery when beneficiated coal is fed to utility boiler for generation of power. The composition of the major minerals quartz and kaolinite as determined, also favors formation of ash of refractory nature during combustion. Keywords: IB valley coal, beneficiation characteristics,

Sep 1, 2012

By Jacek Kolacz

"Comex has carried out an extensive research work related to optimising sensor based sorting systems. The main target was to achieve efficient separation and maintain high capacity of the process. Eventually, the operating cost of the sorting process was investigated in terms of potential industrial applications and possible replacement of the existing traditional processing equipment. The study included an influence of the following factors on the separation efficiency: capacity, particle size and distribution, particle shape, material properties like colour, density and composition, as well as percentage of the rejected fraction. The above factors were also considered in the calculation models for the operating cost of the sorting process. In addition, other elements were considered like compressed air cost, cost of energy, labour cost, and necessary service and maintenance cost. All these elements were implemented into the calculation model allowing quick and effective evaluation of the major parameters for sorting applications. Finally, the study was carried out for two popular sorting principles: visible light sorting utilising differences in color, texture and shape and X-ray sorting using differences in density and chemical composition. GENERAL INFORMATION ABOUT SORTING POSSIBILITIES Application of the sensor based sorting systems, without any doubt, brings a lot of possible advantages in many mineral operations. The main advantage of the new system is related to its universality and at the same time very sophisticated image processing functions, which can be carried out in the same processing unit (Kolacz, 2014). Figure 1 shows the CXR-1000 system from Comex with 1 m belt width, in the configuration where many different analysed parameters can be used to provide particle separation. The image analysis system includes a camera installed either over the transport belt conveyor or at its discharge end. The system includes the X-ray attenuation analysis realized by the XRT system in the central part of the conveyor belt. The sorting system can be used with both optical and XRT analysis or separately depending on an application."

Jan 1, 2018

By Liu Jie

Refractory iron ore deposits in China have various genesis and complicated types, the nature of which is poor, fine-disseminated and complex. Therefore, refractory iron ore could scarcely be separated and utilized by traditional mineral processing technology at present. It is necessary to explore deep reduction technology to change the characteristics of refractory iron ore and to use effectively the iron resource. And deep reduction technology is that on the condition of higher reduction temperature than that of magnetic roasting and stronger reducing atmosphere, the iron oxides from iron ore was reduced to metallic iron particle that is easy to dissociate. And then production from deep reduction is easily separated by magnetic separation and iron powder production was obtained finally. Deep reduction technology for Lingyang iron ore from Jilin, China, as the refractory iron ore, was studied in this paper. The influences of such main factors as reduction temperature, time and coal content were investigated. The results showed that the Metallization rate of reduction product was up to more than 90% under optimum conditions, and then higher iron grade and recovery of reduction iron powder were obtained from subsequent magnetic separation. Furthermore, the deep reduction mechanism in the system was studied by the means of XRD and SEM analysis for reduction production and Physical Chemistry of Metallurgy. Analytical results indicated that during deep reduction, the size of iron particle from deep reduction materials was increasing as reduction temperature rising and reduction time extending. The growth of metallic iron particle from deep reduction production was divided into such three stages as reduction nucleation, deep reduction and growth of metallic iron particle.

Sep 1, 2012

By Z. C. Zhen

Basing on character of fine ores, and employing all the advantage of dissolved-air flotation, the study within the dissertation put forth the methods of superfine metal mineral flotation with dissolved-air flotation equipment, and constructed a full set of laboratory flotation system. Experiments both in water and in slurry were respectively carried out by means of this flotation equipment. Further study was also fulfilled on mechanism of air-dissolved released devices, and the key components of system including ejector, releaser and saturator were designed. Optimizing devices parameters were chosen by taking ideal performance of the devices into consideration, according to orthogonal experiments and tests on bubbles factors, those performance factors were called air release rate, air release efficiency. The results with some minerals are better than JJF flotation machine with 30 litres bulk. The Dissolved-air Flotation(DAF) machine shows great potentiality in treating super-fine metal mineral concentration. The research indicates the Dissolved-air Flotation(DAF) system has superiority over mechanical flotation machine in fine flotation. Air-dissolved released bubbles appear on the surface of hydrophobic minerals in priority, solving collision probability less in the tradition fine mineral separation, such that the metallurgy technology of fine metallic minerals are improved. The exploratory research is a foundation for industrial pilot, commercial test and equipment maturity in the future.

Jan 1, 2014

As a kind of collector, Xanthates are generally used to make sulfide minerals hydrophobic in flotation process. Xanthate adsorption on a galena surface has been widely studied experimentally. In this paper, DFT methods were employed to investigate the local adsorption interactions about the collectors,such as ethyl xanthate (CH3CH2OCS2?, EO) and ethyl trithiocarbonate (CH3CH2SCS2?, ES), absorbing on two different PbS clusters. From the results, it can be easily found that, on the edge or at the apex, both collectors, with two S atoms bidentate coordinating on the clusters, have surprising interaction energies, while on the surface, its interaction is relatively weak in the form of monodentate ligand. NBO analysis results reveal that there is at least a covalence bond with sulfur atom about 10% and lead atom about 90% when the absorbed lead is on the lattice edge or at apex, but, if the absorbed lead is on the lattice surface, no covalence band would be found. Meanwhile, the S-Pb bond, formed by the absorbed Xanthate and galena lattice, seems to have much more covalence characteristic than that formed in the PbS lattice inner. Furthermore, those data also imply that the difference of the collecting effect between the EO and the ES may be not notable, because of the similar distance and the interaction energy for the same interaction mode.

Jan 1, 2014

By M. S. Eygi

This study covers the investigations based on the electrokinetic and rheological properties to explain the interactions between kaolin minerals and commercially available polyelectrolyte in anionic character. Additional adsorption test were also conducted to support the interaction mechanism. Adsorption tests showed that adsorption densities decrease by increasing the solid content. In-creasing the solids contents from 1% to 30% by weight resulted in the decrease on adsorption from 2.14 mg/g to 1.85 mg/g. Because of its difficulty, the solids ratio at 70% was not studied. However, following to trend of the curve plotted adsorption density-solid ratio, an estimation was made and adsorption density at 70% solid content was extracted from the curve as 1.75~1.80 mg/g. The electrokinetic studies pointed out that the presence of polyelectrolyte increase the zeta potential of kaolin from 40 mV to 60 mV which is reasonable conditions to disperse and stabilize the kaolin slurry and lower the viscosity. When these result of the different tests are combined and considered together, 2 mg/g polyelectrolyte concentration was noted as optimal concentration where adsorption density, viscosity and zeta potential of the slurries give maxima and remain constant after this concentration.

Jan 1, 2014