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By V. T. Panayotov, M. I. Panayotova

Wastewater from mining and mineral processing activities is often polluted by anion forming metals, such as molybdenum and chromium. Low cost materials, including zeolites, are studied for removing heavy metals from wastewater. It is widely accepted that natural zeolites are not effective in removing metals in anionic form. The paper presents study on use of metal modified natural clinoptilolite to remove Mo (VI) and Cr (VI) ions from model soft wastewater. Modification with Pb, Fe(III), Zn and Ba increases clinoptilolite uptake capacity with respect to Mo(VI) at low pH values of the water subjected to treatment, the efficiency decreasing in the order Pb > Fe(III) > Zn > Ba. Only lead-modified clinoptilolite shows high uptake of Mo(VI) in acidic, neutral and slightly alkaline conditions. Modification with Pb, Ba and Fe(III) increases zeolite uptake capacity with respect to Cr(VI) from neutral water. The effectiveness of Ba-modified zeolite decreases in slightly acidic water. Over 90 % uptake of initially available Cr(VI) is achieved by lead-modified clinoptilolite both under neutral and slightly acidic conditions. Increasing the initial pollutant concentrations increases the removed amount both of Cr(VI) and Mo(VI) for Pb-modified clinoptilolite. The findings could be a basis for using the natural clinoptilolite to remove in consecutive steps: firstly Pb(II) and/or Fe(III) ions and then loaded zeolite to be used for Mo (VI) and/or Cr(VI) removal. The kinetics of Mo(VI) uptake by CL-Ba, CL-Fe(III), CL-Pb, and CL-Zn is best described by the pseudo-first order kinetic equation. The kinetics of Cr(VI) removal by CL-Ba, CL-Fe (II), CL-Fe (III) and CL-Zn is best described by the pseudo-first order kinetic equation. Kinetics of Cr(VI) removal by CL-Pb obeys the equation for the first order irreversible reactions. Finding way to remove anions-pollutants from the mineral processing wastewater will render this industry more environmentally friendly and socially acceptable.

Jan 1, 2016

By I. M. M. W. R. Jones

"THE OBJECT of these notes is to initiate a discussion among the members of our Institution on the connotation of the term 'ore', and to arrive, if possible, at an acceptable definition of the term in the light of its current use by our leading mining engineers, metallurgists, •and geologists.The majority of •authors of well-known modern text-books on subjects dealing with mineral deposits define 'ore' in words which convey the meaning that it is an aggregate of minerals from which one or more metals can, under favourable conditions, be extracted profitably.Many eminent members of the Institution, and of mining and metallurgical institutions in other countries, consider that the term should not be restricted to metalliferous mineral •deposits but can also be applied correctly to certain non-metallic deposits. They believe that the growth, during the twentieth century, in the industrial importance of non-metallic minerals, and the progress made in the mining and the milling of deposits containing such minerals by methods similar to those used for metalliferous mineral deposits, no longer justify the academic restriction of the term to deposits worked for their metal content only."

Jan 1, 1954

By W W. Moorhouse

A survey of recent literature indicates that sulphides occur in the volcanic rocks of the Archean, or in sedimentary rocks intercalated with the volcanic rocks. The thick sedimentary sections are generally poor in sulphides. Thus, the widespread pyrite and pyrrhotite mineralization in the Archean may be largely of volcanic origin. Introduction I N this paper, commercial base-metal deposits will not be considered, as they are dealt with in other papers of the Symposium. Instead, attention will be focused on those sulphides, often associated with graphitic argillites or tuffs, which have appeared in such embarrassing abundance in electromagnetic surveys of Archean areas. The data on which the paper is based are drawn from recent reports of the Ontario Department of Mines, the Quebec Department of Natural Resources and the Geological Survey of Canada. The information available from these sources is unfortunately limited, because sulphides commonly occur in sheared rocks, such as black argillites and tuffs, which rarely form conspicuous outcrops, and may not be exposed at all. Thus, in the absence of geophysical information, even detailed mapping may fail to reveal the presence of sulphide-rich rocks.

Jan 1, 1965

This growing dependence of Canada upon foreign mineral commodities, just referred to, applies particularly in the direction of the United States. There is, in fact, no more significant feature of Canada's mineral trade than the manner in which it affects the Dominion's commercial standing with that country. Our heavy adverse balance of trade with the United States is perhaps not a matter of such wide concern or frequent comment as was the case two or three years ago. It is, of course, a well-known fact that the Dominion each year buys from the States a volume of goods to a value enormously in excess of our sales to that country. And it has come to be accepted as a ?normal, though not altogether satisfactory, feature of our international commerce that a huge portion of the bill incurred by our American purchases must be met, not by our American sales, but by the proceeds of our sales to other countries, not-ably Great Britain. It is a three-cornered situation in which our trading deficit with the United States is covered largely by our trading surplus with the United Kingdom. In this situation the mineral trade plays a remarkable part. If one delves into the details of our transactions with the United States it will be found that, in one sense, the mineral trade is entirely responsible for the huge annual balance against the Dominion. In fact, Canada gets decidedly better than an even break on Canadian American trade, if one leaves out of account the three mineral groups, "iron and steel", "non- metallic minerals", and "non-ferrous metals".

Jan 1, 1924

By H. A. Hamza, J. Visman

"This is a report on the combined application of ""long-chain"" flocculants and classifier cyclones in the field of slimes treatment, with emphasis on the simultaneous thickening and clarifying of industrial effluents, at low cost. The principle of the process described below involves: (1) the formation of small floes of relatively great strength, by sequential dispersion and conditioning, with average floe size of about 1501 microns; (2) the floes being of sufficient strength to withstand the shearing forces operating within a cyclone and consequently behaving as solid particles with an equivalent diameter (Stokes) that exceeds the size cutpoint of the classifier cyclone; (3) the removal of flocculated solids by means of a classifier cyclone the size cutpoint of which permits effective separation of these solids from the water. Results of test work to date indicate that a broader use of cyclones in industry is possible with the above types of flocculants because the submicron particles and colloidal material are readily collected and clear water is produced, with the attendant advantages of compact construction and low cost that are characteristic of centrifugal separation. The process generally permits classifier cyclones of medium throughput capacity (e.g. 12-in. diam.) to be used for clarifying effluents that contain minus 10-micron particles."

Jan 1, 1973

By I. Soosaiprakasam

This work investigated inhibition performance of copper carbonate (CuCO3), which is less toxic than conventional heavy-metal corrosion inhibitors in amine treating plants, The investigation was experimentally carried out in a bench-scale electrochemical corrosion cell under an atmospheric pressure, The inhibition performance of CuCO3 in an aqueous solution of monoethanolamine (MEA) was examined under a wide range of operating conditions and reported as a function of process parameters including inhibitor concentration, temperature and solution velocity, The results show that CuCO3 functions as an anodic inhibitor. The addition of CuCO3 decreases corrosion rate of carbon steel but might induce pitting corrosion/

Jan 1, 2005

By T. T. Tigert

INTRODUCTION THE PURPOSE of this article on methane is to present the simple basic facts of the characteristics, detection, occurrence, and control of this natural gas in metal mines, so that operators and .safety men may deal with it with some degree of confidence. Fortunately, although methane has been noted at many metal mines throughout Canada, the occurrences usually are small flows of short duration, and the ignitions experienced have, in most cases, had minor consequences. However, methane does present a hazard that can be of serious proportions, and ?any complacent attitude toward this gas that might exist in the minds .of people engaged in underground mining operations should be dispelled when it is ,pointed out that, in Ontario alone, ignitions of this gas have resulted in at least four fatalities, and eight men seriously injured and burned, during the past three years. lt is well-known that liberation of methane can and does .occur suddenly, often in mines where no gas has been found before, and that many ignitions and explosions have occurred in so called non-gassy mines. In view of this, it is apparent that no mine can, with any degree of certainty, be classified as non-gassy. CHARACTERISTICS OF METHANIZ The characteristics of natural gas encountered in most of the Ontario mines indicate that methane is the chief constituent. Methane (CH4), commonly termed 'marsh gas', and by the coal miner 'firedamp', is a colourless, odourless, and non-poisonous gas considerably lighter than air, and is the explosive gas frequently found in coal mines. Its physiological effects, closely resemble those resulting from nitrogen.

Jan 1, 1951

By H. C. Gunning

Introduction Considerable attention has of late been attracted to the area surrounding Nimpkish lake, on northern Vancouver island, by the discovery of important rich copper deposits. In less than two years some 200 mineral claims have been staked in a small area, and at least two groups have very promising surface showings. During the summer of 1929, the writer spent one month investigating the general geology and mineral deposits of the region, and, although no detailed work has as yet been done in the field or in the laboratory, the importance of the mineral discoveries and the lack of geological information available to the public warrants a preliminary paper on the district. The district is, from a mining viewpoint, very accessible. Boats from Vancouver call at Englewood, in Beaver cove, four times a week. From Englewood, a first-class logging railway, operated by the Wood, .English Company, extends to the northeast corner of Nimpkish lake. The fifteen-mile trip from the north to the south end of the lake is made by boat, two tugs being maintained by the logging company. The whole trip from Englewood can easily be made in one day. The known mineral deposits lie immediately east of the southern part of the lake, four miles or less from the shore. A fair trail, four miles ? long, leads from the lake to the Nimpkish Copper group. Apart from this trail and an old logging railway grade which follows the east side of Klaanch river for several miles, no trails exist on the southeast side of the lake.

Jan 1, 1930

By T. L. McCall

CHANGES in mining practices have evolved so quietly and unobtrusively that perhaps we scarcely appreciate how truly startling these changes are unless we cast our minds back so as to compare the past with the present. Such retrospection is, indeed, necessary when attempting to forecast the future, for it is only by carefully reviewing the past that we can hope to obtain an indication of what the future may hold in store. In this instance, it is not necessary to delve into the very early history of . coal mining, as our purpose will be served if the last three or four decades are reviewed, a period that is still fresh within the memory of many of us. These earlier days might be termed the selective period of mining, for at that time the coal resources of the world had not been tapped to anything like the extent they are at present and this condition enabled the owners and operators to exercise selective powers and only mine such seams of coal as could be most easily reached an worked at the lowest possible cost and which, at the same time, would suit the requirements of the market. Carrying this thought of selective mining still further, the miner, who was then an artisan skilled in all the branches of his calling, was able to select or discard such parts of the seam he was working that the co al sent out of the mine was acceptable to the consumer with just the barest minimum of preparation. Compare these conditions with the? conditions prevailing today, when coal seams of medium height, good quality, and readily accessible have been largely depleted and the operator has been compelled either to carry on his operations under much greater depths of cover where the coal is more costly to win, or else to work seams of lesser height or of poorer quality.

Jan 1, 1938

By B. R. Richards, B. G. W. Robinson

"This paper shows how metal values can be profitably won from a comparatively small and remotely located but high-grade orebody. To do so is not uractical for a large mining company, with its necessarily high overhead of services and organization essential to a large producer.To evaluate, develop and profitably exploit a limited but defined ore deposit becomes only a problem of determining the dollars required to win the dollars available. This paper will record how this was carried out during 1965 and at the same time describe the history, development and production plant of this property."

Jan 1, 1966

By O. D. Maurice

"This paper will essentially update the information that is already known and published on the limestones of the Province of Quebec. The excellent report by M. F. Goudge (1935)m is difficult to improve upon and the areas of limestone quarrying are generally the same as they were at the time of Goudge's report. Our knowledge of the limestones of Quebec has been improved considerably in recent years by the publications of T. H. Clark, 2 who, since 1938, has been mapping and reporting on these lime-stones and has discussed their stratigraphy, their structural features, their history and their economic value. One economic aspect is the presence of natural gas in these formations and the possible occurrence of oil. A total of 150 test holes had been drilled to a depth of more than 500 feet by the end of 1967 and, in addition, at least 256 more shallow holes had been put down in the St. Lawrence Lowlands. The information from these test holes has greatly improved our knowledge of the thickness and extent. of the various formations of Paleozoic limestone and shale in Quebec.This paper will then review briefly the limestone occurrences in Quebec, using the old as well as the more recent reports as principal references"

Jan 1, 1970

By Tony Szwilski

Using Unity 3D as a collaborative multi-user virtual on-line environment, an interactive virtual underground mine platform (IVUMP) is being developed to provide on-line access to mine safety preparedness training with a focus on mine emergency response exercises (MEREs). Communication and information flow among MERE participants and their actions can be monitored, recorded and evaluated. A mine ventilation simulation utility VFIRE is being incorporated to enhance the realism and interactive nature of the ?in-world? exercises as well as extend its functionality to include training in real-time ventilation and fire control.

Aug 1, 2013

By E. G. Leonardon

The question of geophysical prospecting is one that is beginning to occupy a pre-eminent place in the minds of those actively concerned in the discovery and exploitation of ore deposits. This is in marked contrast to the reception accorded such ideas when the Junior author, six and a half years ago, began introducing electrical prospectii1g to the mining fraternity on this continent. Happily, the mention of geophysics no longer evokes the sceptical and pitying smiles that it did in those days. A little reflection will show that modern geophysical methods are merely a logical development from pre-existing technique. In the study of geological problems, is it not logical to use all possible physical properties of matter? The study of crystal form and cleavage, the examination of thin sections of minerals by means of polarized light or ordinary light, in fact, utilize physical properties of minerals for the benefit of the geologist. These are, of course, laboratory methods, and the extension of the study of similar properties into field work was inevitable. This began with the magnetometric surveys, used as early as 1760 in New Jersey to locate iron ores. Eighty-four years later, John Locke's work in the United States resulted in pointing out relationships between the terrestrial magnetic field and main tectonic features of the earth's crust.

Jan 1, 1928

By M. D. Lawton, P. Steen

"Drilling results from the established levels at AngloRouyn Mines Limited had indicated inadequate tonnages to meet the planning schedule. It was decided to develop the main zone of the orebody below the bottom working level of the mine. The orebody dips north at an average of 50 degrees and plunges to the west at about 10 degrees. Due to the need for rapid development of this area, a decision was made to use trackless equipment.This paper describes the method used and highlights the use of small 5-ton diesel trucks as carriers for the 2-cu.yd LHD machine. The method achieved advances of about 1,000 feet per month, at a dip of 12 degrees over a length of close to 2,000 feet, using as few as 20 men per day."

Jan 1, 1971

By R. J. Mitchell

"High narrow backfills of significant strike length approach the stress conditions associated with a free standing wall but this lower bound design approach is not considered efficient for earth structures. This paper considers the design of high narrow backfills using upper bound limit analysis, retaining wall theory with backfill arching and centrifuge model tests. Complex toe support situations pertaining to operational factors at Falconbridge's Lockerby Mine are investigated. It is shown that the susceptibility of high narrow fills to toppling is much lower than anticipated from the retaining wall analysis and that toppling can be avoided by a suitable toe support. It is also concluded that adhesion between the fill and an adjacent pillar can markedly increase the stability of the fill. INTRODUCTIONFalconbridge's Lockerby Mine pillar projects will expose cemented tailings backfills to heights (H) up to 55 m. The exposed backfills may have strike lengths (L) greater than the heights but are relatively narrow, having widths (w) of up to 12 m. The bulk cement content of the fills varies from 8.3% (12.1 T:C) to 3.0% (33.1 T:C). Exposed faces may have up to a metre of overhang due to stope overblasting, as shown in Figure 1. These fills have a solids specific gravity of close to 3.0 and were placed at a pulp density of about 68%. The tailings have a fairly uniform grain size with 32% less than 0.075 mm (200 sieve) and about 12% slimes (less than 0.02 mm sizes). The fill exposed by early pillar removal will be backed by adjacent, near vertical, ore pillars. Future pillar removal may expose similar fills which are not supported by an adjacent ore pillar but which will be backed by either an open void or by uncemented backfill. Furthermore, these fills may be undercut when the pillar slot is driven, further reducing stability (case 3, Fig. I) or a wedge could be left to help support the fill (case 2, Fig . 1). This paper presents limit equilibrium analyses for these various backfill conditions in a 22: 1 T:C fill and com- pares the results to data from centrifuge model studies at a scale factor of A= 157 as indicated in Figure I. Prototype fills have a 6 m deep cone plug of 16:1 T:C which is accounted for in the comparison of centrifuge model test with analytical results."

Jan 1, 1989

By Ivor da Cunha

Ontario Mining Association (OMA) represents 57 members that are engaged in exploring, producing & processing mineral resources in an environmentally responsible manner. Conservation Bureau at the Ontario Power Authority (OPA) develops, coordinates and stimulates commitment to electricity conservation and demand management programs ? OMA selected compressed air optimization for high impact cost savings and energy efficiency potential ? Ontario Power Authority (OPA) provided $218k funding for $532k project ? Commenced summer 2006, Final Report June 2007 ? Three representative sites participating: ? Williams, CVRD Inco & FNX McCreedy ? Different levels of energy management ? Small, medium and large mining operations ? Different corporate practices and culture

May 1, 2007

By L. Chunpongtong

The mining limit in oil sands is regulated by the ratio of total mining volume (ore, interburden, and overburden) one has to mine per volume of bitumen in place (TV/BIP). This paper presents a mathematical solution for creating the most economical pit outline where the TV/BIP ratio upper limit is 12, by combining mining economic theory and the Lerchs-Grossmann (LG) algorithm.

Jan 1, 2014

By Neillm Alastair S.

"This paper looks at what has happened in the past decade in the rare earth industry, particularly for those companies outside China trying to develop alternative projects to the Chinese dominated supply chain. The rare earth industry has gone through a metamorphosis over the past decade. The industry was basically unknown outside China until overnight it became the next hot topic on the financial streets of Canada and Australia. Suddenly various junior miners shifted from uranium and other out-of-favor commodities to rare earths as funds were easy to access from an investment community that did not understand the complexities of the space. The initial funding was done on traditional junior mining metrics of grade and deposit size. This has morphed over time to:1) Lights versus heavies2) Making a concentrate3) The importance of separation4) Off-take agreementsAt the peak of the market frenzy certain flagship operations were built using the “Not Made in China” moniker. Unfortunately certain errors were made during implementation, which are finally coming to the surface and making the rest of the pack wondering what will happen next. A review and update of some of the mistakes made and lessons learned will be discussed.BACKGROUNDAbout ten years ago awareness started to form around the rare earth industry and various groups recognized that because of the closure of Molycorp, Mountain Pass, and the dominance of China, there was a risk of uncertainty of reliable supply. This was not news for those active in the industry like Rhodia (now Solvay), the Japanese, South Koreans and other key consumers but to others it was like a light went on and rare earths became the new “.com” trend for investment banks, investors and some mining companies looking for the next hot topic.In the late 1990’s Molycorp accounted for around 20-25% of the world’s supply of rare earths, mostly lights (La, Ce, Pr and Nd), with small amounts of heavies from other sources. Then environmental issues forced the closure of the operation at Mountain Pass. Within six months China had increased production to plug the gap in supply. Around that time China was developing a strategy to leverage their position in rare earths and implemented a series of regulations to increase the value added component of rare earths inside China."

Jan 1, 2016

By S. A. Pence, A. I. McCallum, V. de Korompay

"Special salt protection rings containing a water-swell• able, polymeric sealant are in successful operation in Canadian potash shafts. Installed above the Prairie Evaporite salt formation at a depth of 3,000 feet, the sealant is preventing formation water migration into the salt and pressure build-up on the concrete lining of both production and service shafts. The salt protection rings are not under the hydrostatic pressure of the formation water.The chemical sealant in use has the unique property of imbibing water and swelling. •Therefore, any water at• tempting to flow by the seal ring actually produces a tighter seal.The purpose of this paper is to discuss the sealant and its properties and uses. Installation of the material and its operation in two Canadian mine shafts is described."

Jan 1, 1971

By Zhibao Li, Lanmu Zeng

The behavior of dicalcium silicate in NaOH-NaAl(OH)4-Na2CO3 solution is of significance for controlling the silica level in the production of alumina via the sintering process. Dicalcium silicate samples were obtained through a twostep approach: coprecipitation of calcium and silicate from CaCl2-Na2SiO3-NaOH solutions; and calcination of the hydrated precursor at 1200°C for 4 hours. The optimization of the synthesis parameters including temperature, solution concentrations and aging time was also investigated. Xray diffraction (XRD) and chemical analysis show that the calcined solids include dicalcium silicate with trace amounts of wollastonite. The solubility of the synthesized dicalcium silicate in HCl, NaOH, mixed NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was determined. It was found that the solubility increases with increasing HCl and NaOH concentration. The effect of temperature on the solubility in HCl solutions is limited, but the solubility decreases with increasing temperature in NaOH solutions. The solubility of dicalcium silicate in NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was shown to increase with increased temperature, Al(OH)3 and Na2CO3 concentration. The BromleyZemaitis model for the aqueous electrolyte system was selected to predict the solubility of dicalcium silicate. The model’s predictions yielded certain success compared with experimental solubility data.

Jan 1, 2014