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By Z. Q. Liu, J. M. Du

"On the basis of analyzing current design and applications, the structure form, working loads and design principles of shaft sinking headframe are summarized in this paper. To overcome the insufficient bearing capacity and geometry size of the finalized shaft sinking headframe in China, a series of new large shaft sinking headframe were developed under vertical shaft construction conditions of maximum net diameter of 12.0 m and maximum depth of 1200 m. The new series shaft sinking headframe include two sets (with single sheave platform and double sheave platform), three dimensions (optimum shaft diameter <8.0 m, 8.0-10.0 m, and 10.0-12.0 m, respectively) for each set, and has innovation and optimization on structure of the sheave wheel platform (MU type) and bracing frame (REN and ZHONG type). The largest new shaft sinking headframe can arrange up to 4 hoisting equipment simultaneously and has bearing capacity more than 10000 kN. Two of the new shaft sinking headframe were successfully applied in practical engineering, such as the Hulusu auxiliary shaft, the Dahaize 1# auxiliary shaftand Sishanling auxiliary shaft. These applications showed that the new shaft sinking headframe has sufficient bearing capacity and reliable applicability. The new shaft sinking headframe could provide an effective guarantee for safety and efficiency sinking of deep-large shaft in the future.INTRODUCTIONShaft sinking headframe is one of the basic shaft sinking structures and it is mainly for hanging hoisting containers and sinking facilities in sinking a vertical shaft (Yu & Shi, 1991; Wang, Jing, & Liu, 2007). Currently, 7 types of steel pipe sinking headframe are used in China, which are mainly finalized by the Ministry of Coal Industry of China (Wang, 1988). As shown in Table 1, V-type is the largest of them and it is only suitable for sinking shaft of diameter less than 8 m and depth less than 1 000 m(Yang, 1982). However, with the increase of mining depth and scale of mineral resources in China, the diameter and depth of newly built vertical shaft are increasing continuously (Xie, Zhou, Xue, Wang, Zhang, & Gao, 2012; Qi & Pu, 2013). At present, the maximum net diameter of vertical shaft is close to 12 m, and the maximum depth is more than 1600 m (Yang & Chen, 2015; Xu, Yang, Liu, & Qin, 2015). The shaft sinking headframe has become the main restrictive factor for the development of sinking equipment, such as the height of muck discharging platform cannot meet the usage requirement of hydraulic umbrella driller, the size of sheave wheel platform is difficult to arrange the increasing hoisting and suspension equipment, the bearing capacity is insufficient to meet the needs of multiple hoisting loads in sinking a deep-large shaft, etc. Therefore, development of new shaft sinking headframe for deep-large shaft (>1000 m in depth and 8~12 m in diameter) is urgently required for China and also the whole world."

Jan 1, 2019

By Yong Kang, Bingyuan Yan, Dandan Zheng, Xiaochuan Wang, Dengfeng Su, Dongyang Li

"According to the characteristics of rock mass and the directional cutting technology of water jet, a new idea of light shock controlled blasting with water jet slotting was put forward. Based on the fracture mechanics theory and the stress wave theory, the mechanism of damping with water jet slotting was analyzed. On the basis of the above, the evolution law of the pressure wave and displacement field during the blasting were simulated by FEM software ANSYS/LS-DYNA. The result shows that: the oriented slot plays a good role in orientation during the blasting, and makes the energy generated by gas released by the explosives gather at the tip of the oriented slot, which makes it easier for the main crack to expand along the oriented slot and indirectly reduce the stress effect on the protected object. Meanwhile, the energy of the seismic wave is reduced while transmitting through damping slot. Finally, compared with the normal blasting with damping ditch, the maximum acceleration is reduced by 15.62%, the maximum velocity is reduced by 52.99%, and the maximum displacement is reduced by 68.32%. INTRODUCTIONIn recent years, with increasing demand for energy and space, an increasing number of underground projects have been under construction. Drilling-blasting method, as a traditional main method for rock excavation, is still an indispensable means in the engineering construction. As is known, blasting vibration will cause the deformation and unstable of the existing building structures, so how to reduce the influence on the existing building structures caused by the blasting vibration has become the focus. Traditional shock absorption measures mainly include three kinds: the first one is pre-splitting blasting, the second measure is to change the parameter of explosive filling, and the last one is to excavate damping ditch between the protected object and blastholes. However, engineering practices show that: the protected rock may be damaged in the process of pre-splitting crack construction by blasting, the second measure is difficult in operating, and the third measure is troubled by large work quantity (Song Guangming, 1999; Lou Jianwu, 2004; Lou Jianwu, 2005; Li Xibing et al., 2008)."

Jan 1, 2015

By X. T. Zeng, X. Z. Ding, W. R. Chen, L. R. Zhao

The effect of deposition defects in metal nitride coatings on erosion behavior is presented. AlCrN, AlTiSiN, TiSiN and TiSiN:MoS2 coatings were fabricated by reactive cathodic arc evaporation and unbalanced magnetron sputtering processes. The microstructure and mechanical properties of the coatings were characterized by X-ray diffraction, scanning electron microscopy and nanoindentation, and the erosion property was assessed by solid particle impingement testing. The erosion characteristics on the coating surface and cross section were analyzed and correlated to the defects, which played an important role by promoting formation of erosion pits.

Jan 1, 2006

By Kéiko H. Hattori, Neil T. Pettigrew

"Abstract- The Legris Lake Complex is a northeast-trending, 7.3 km long by 3.5 km wide, maficultramafic intrusive complex located in the western Wabigoon Subprovince of the Archean Superior Province. It is one of a series of mafic-ultramafic igneous complexes, the most notable of which is the Lac des Iles Complex, host to Canada’s only producing Pd mine with reserves of 93.5 Mt grading 1.53 g/t Pd as of December 2001 (North American Palladium Ltd., Annual Report 2001). Cu-Ni- PGE mineralization was first discovered in the Legris Lake Complex by a local prospector late in 1999. Shortly thereafter, the property was jointly optioned by Avalon Ventures Ltd. and Starcore Resources Ltd., who continue to discover significant Cu-Ni-PGE mineralization.One of the most notable features of the Legris Lake Complex is the occurrence of extensive brecciation caused by multiple injections of volatile-rich magma. The Cu-Ni-PGE mineralization is hosted by leucogabbro within a 2 km long by 600 m wide, highly brecciated area in the northwestern area of the Complex. The mineralized rocks contain disseminated to blebby sulfides (1 to 5 vol.%), comprising chalcopyrite + pyrite ± pyrrhotite + millerite ± pentlandite, typically surrounded by epidote. The majority of the Cu-Ni-PGE mineralization displays low ratios of Pt/Pd (~0.20) and high ratios of Cu/Ni (~2.9), which are similar to those of the Lac des Iles and the River Valley mafic-ultramafic complexes. The lithologies in Legris Lake Complex bear similarities to the heterolithic gabbro of the Twilight and Roby Zone deposits at the nearby Lac des Iles mine. However, the mineralization at Legris Lake, which is restricted to leucogabbro overlying unmineralized clinopyroxenite, is similar to that of stratiform deposits such as the Stillwater and Munni Munni complexes. The mineralization at Legris Lake is best explained by the late-stage, immiscible separation of a sulfide melt from volatile-rich parental magmas and the subsequent minor redistribution of metals by deuteric fluids."

Jan 1, 2001

By Matthew Janes

Advantages: Clean samples Low sample disturbance Very low spoil Versatile Fast Penetrates all formations Resonant Drill 100 or 150 kW Self tuning to resonance Rotation to 100 rpm Increased depth in dense soil Increased productivity Reduce water use Reduce casing plugging

May 1, 2013

By The Staff

"THE property of Red Mountain Mines Limited is located 11/2 miles north and west of the town of Rossland, in southern British Columbia. The mine is situated on the flank of Red mountain, famous in pioneer days as the site of a number of profitable gold-copper producers. Mining and milling commenced in May, 1966, and by the first of July the concentrator was treating close to its average design capacity of 400 tons per day. The following description of the property and its operations is divided into three parts, dealing respectively with geology, mining and milling.GeologyAll the known ore reserves of Red Mountain Mines occur on the Coxey claim, on the west slope of Red mountain. Although there are indications of molybdenite mineralization elsewhere on the Company's property, these have not been developed.The Coxey and adjoining areas are underlain by the Mount Roberts formation of the Rossland volca-nics. This formation consists of an interbedded series of volcanic and sedimentary rocks, mostly brecciated and silicified near the ore zone, and all intruded by igneous rocks which occur in various forms, and vary in composition from basic to acid. The country rock in the vicinity of the mineralization seems to be mostly a volcanic, approximately andesitic in composition, and possibly a surface flow. There is much banding, some of which is undoubtedly due to tuff and agglomerate layers, and some to narrow, siliceous, sedimentary horizons such as the surface exposure of the main ""A"" orebody, much of which was a thin capping of greyish banded rock that looked like quartzite. The drill holes also intersected occasional layers of black, argillaceous quartzite, sometimes altered to a greenish colour. The whole assemblage has been silicified with varied intensity, sometimes to such an extent as to have obscured or obliterated the original characteristics. The mineralized zone has also been strongly brecciated, the fragments varying in size from less than an inch up to large masses, best described as a mega-breccia. Anomalous results obtained in drilling, such as sedimentary sections that do not appear in adjoining holes, may sometimes be due to the presence of these large blocks, no longer in their original position. The whole volcanic unit is thus very complex and confusing. For practical purposes, the ore may be said to occur in a greenstone formation with minor sedimentary interbeds and considerable later igneous material."

Jan 1, 1967

In order to avoid impurity problem and enhance absorption/desorption kinetics of Mg-based compounds, nanostructured Mg-based compounds were synthesized from Mg, Ni and other elemental nanoparticles produced by hydrogen plasma-metal reaction. XRD and TEM results demonstrate that homogeneous nanostructured Mg-based compounds with less impurity were successfully synthesized by this method. DSC in hydrogen atmosphere, pressure-composition isotherm and the kinetics of hydrogen adsorption/desorption were investigated at different temperatures. The results show that the nanostructured Mg-based compounds can absorb hydrogen in a high speed at a low temperature.

Jan 1, 2005

By J. Warner, K. A. Hughes, P. E. R. Blanchard, J. Esslifie-Dughan, J. W. Reid

Tailings management plays an important role in reducing the environmental impact of Orano Canada’s uranium mining operations in Northern Saskatchewan. Uranium ores mined from Northern Saskatchewan are often associated with large amounts (10-20 wt%) of other harmful elements, such as arsenic and nickel. The JEB Tailings Management Facility (TMF) located at McClean Lake, Saskatchewan is designed to prevent potentially harmful water-soluble elements, particularly arsenic, from contaminating the surrounding environment by promoting the formation of water-insoluble minerals. It is therefore important to determine which arsenic-containing mineral species are present in the TMF and how they evolve over time. Researchers at the Canadian Light Source (Saskatoon, Saskatchewan) were successful in identifying the arsenic mineral species present in tailings samples collected from the TMF in 2013 using X-ray absorption near-edge structure (XANES) spectroscopy. XANES analysis verified that the majority of arsenic species in the TMF existed as amorphous and crystalline ferric arsenates with minor amounts of arsenite and arsenide species. Herein, XANES is again used to analyze a new set of tailings samples collected from the TMF in 2018, specifically focusing on the difference in the distribution of arsenic species in old and new tailings.

Jan 1, 2020

By Chuan-Jian Zhong

Gold-based nanoparticles in the size range of a few nm have attracted increasing interests in catalysis, sensors and biomedical applications. The study of the unique catalytic properties of nanosized gold was inspired by the pioneering work of Haruta on the nanogold-catalyzed CO oxidation (1-4). There have been a number of excellent reports discussing both fundamental and application aspects of gold nanoparticles in catalysis (3-8). Our work reported herein is aimed at investigating the preparation and application of gold and its alloy nanoparticles for potential applications in fuel cell catalysis. Fuel cells operating by electrochemical oxidation of hydrogen or methanol fuels at the anode and reduction of oxygen at the cathode are attractive power sources due to their high conversion efficiencies, low pollution, lightweight and high power density. While methanol offers the advantage of easy storage and transportation in comparison with hydrogen fuel cell, its energy density (~2000 Wh/kg) and operating cell voltage (0.4 V) are much lower than the theoretical energy density (~6000 Wh/kg) and the thermodynamic potential (~1.2 V). The poor activity of the anode catalysts and inefficient activity or issue related to "methanol cross-over" at the cathode electrode are associated with the loss of about one-third of the available energy at the cathode and the other one-third at the anode. Extensive studies have been focused on Pt-group metals (Pt+Pd+Rh+Ru+Ir (PGM)) for both anode and cathode catalysts. A major problem is the poisoning of Pt by COlike intermediate species (9,10). Recently, oxide-supported gold nanoparticles in the <10 nm size range have emerged as one of the best catalysts for CO oxidation (1-3,11), and for water gas shift reaction in reforming stage using 5 nm Au on Fe2O3 (6). Gold and its alloy with other metals in the nanosize range present new alternatives (2,12). Whether the unique properties of gold nanoparticles can be exploited for addressing these problems is a focus area of our work. The ability to harness the large surface area-to-volume ratios and the unique surface sites of nanoparticles in <10 nm size range, especially in heterogeneous catalysis, constitutes a major driving force in fundamental research and practical applications of nanoparticle catalysts. It is this size range over which the metal particles undergo a transition from atomic to metallic properties. The understanding of factors controlling the morphological and surface reconstitution associated with such a size range is of fundamental importance to the ultimate exploration of nanostructured catalysts. We have been investigating the interfacial structures and properties of core-shell types of nanoparticles consisting of gold or alloy nanocrystal cores and organic monolayer shells that were prepared by twophase synthesis (13) and processing (14) protocols. Important attributes of such nanoparticles include controllable size monodispersity, processibility, and stability towards size- and composition-tunable catalysis (15-21). Some of these attributes were studied for understanding their electrocatalytic properties in the oxidation of methanol and reduction of oxygen, which are of fundamental interest to fuel cell technology.

Oct 1, 2003

By V. ?. Chanturiya, G. P. Dvoychenkova, ?. Ye. Kovalchuk

"Several mineralogical investigations have revealed the composition of modified kimberlites and the mud generated during treatment of diamonds, which contains up to 50% clay minerals (e.g., talc, talcsaponite, chlorite-saponite, Na-saponite) and X-ray amorphous phase. We investigated the composition of the natural diamond surface in relation to the diagnosed minerals and established the sequence and conditions for mineral formation on the crystal surface under kimberlite processing conditions. This article suggests a method to destroy and further dissolve minerals on the crystal surfaces using water system electrolysis products, which makes it possible to restore the diamond hydrophobic properties. The application of chemically treated water in the foam separation cycle under the conditions of high recovery of diamonds made it possible to increase the content of the factory concentrate by 8.0%.INTRODUCTIONThe high content of the modified minerals in the kimberlite ore results in the formation of hydrophilic slicks on the surface of the crystals which decreases the diamond’s hydrophobic properties and increases the losses thereof in the process of grease and foam separation to 20-30% (Kurenkov, 1957; Chanturiya et al., 1998, 1999, 2005; Duikarev et al., 2000).The previous researches have revealed the fact that the prospective way of solving the problem of intensity of mineral impurities formation on the surface of the crystals and the increase of concentration parameters is reached due to application of physical and chemical stimulation techniques on the solid and liquid pulp (Stricland-Constable, 1971; “Improvement of the technology…”, 2006; Makarskii, Adodin & Tarasova, 2011; Chanturiya, Dvoychenkova & Trofimova, 2012). However, the main task of investigations to stipulate the objective achievement is the studying and justification of the reasons of the diamond surfaces covering by the mineral slicks"

Jan 1, 2016

By O. G. Olvera, E. Asselin, D. Rival

Particle concentration distributions in a leaching tank have been estimated using a novel experimental approach that takes advantage of the galvanic interactions that occur between pyrite (FeS2) particles and a Pt electrode. The collision of FeS2 particles with Pt changes the open circuit potential measured with the electrode due to galvanic interactions. To discern particle collisions with the Pt electrode from experimental noise a simple analytical procedure was first adopted although the use of techniques involving frequency domain analysis is also briefly presented and discussed. Although this method is still under development, it is simple to implement and can yield valuable information regarding the hydrodynamic behavior of solid particles in stirred tanks in very short times. Finally, the advantages and drawbacks of the technique are discussed.

Jan 1, 2014

By M. Mirnezami, J. A. Finch, S. Uddin

A fast, reliable and practical way of measuring zeta potential using sedimentation potential method is proposed. A cell was designed along with the instrument control software to determine the required variables simultaneously i.e. sedimentation potential, specific conductivity, volume fraction of solid as well as pH. High purity alumina and silica powders were used as test samples. Measured zeta potential using the proposed technique was comparable with the results by electrophoresis.

Jan 1, 2009

The Discrete Element Method (DEM) is a powerful tool for analysing the flow of charge, the energy consumption and the pattern of energy utilisation of a SAG mill. With the development of laser scanning measurement, the detailed internal working surfaces of a SAG mill can now be included in DEM models. Using scanned results for new and worn shell liners for a 32? (9.75 m) SAG mill, it is shown that the feed and discharge lifters have significant effect on the flow of the charge introducing significant threedimensionality. The effects of the resolution accuracy of liner geometry and the lower cut-off of the rock size distribution are explored. Finally, using a matched new and end of life worn liner and operating conditions taken from site surveys, the effect of wear on charge motion, distribution and energy utilisation are evaluated.

Jan 1, 2012

By P. Bacher, L. Dubourg, M. Jahazi, G. Dezaise

Effect of friction stir welding parameters and natural ageing on weld properties are reported. Using a Taguchi design of experiment, attempt is made to systematically examine the influences of the welding speed, tool rotation speed, forge force, tilt angle and pitch ratio on the weld size and ultimate tensile strength of FSWed joints. One millimetre thick plates of AA7075-T6 were welded in lap joint configuration. Samples were characterized by optical microscopy, hardness and tensile measurements. Trends suggested by the results and directions for further investigation are discussed.

Jan 1, 2006

By A. Taylor

This paper considers mineral processing in zero gravity dry environments typical of asteroids or comets. The electro-dynamic separation technique using pneumatic flow systems is explored. Pneumatic delivery of solids is used because of extreme temperature changes and the possible scarcity of water. The present earth-based process and how it can be modified for these conditions is examined.

May 1, 2001

By Madaah Hosseini H. R., P. Abachi, S. Miraghaei

In this study, the effects of milling time, chemical composition and heat treatment on microstructure and magnetic properties of nanocrystalline Fe-Si (6.5-25 at.% Si) alloys prepared by mechanical alloying have been investigated. The results show that increasing the milling time or the Si content, decreases the lattice parameter and increases the internal microstrain. The prepared powders mainly consist of micron-sized particles with an average grain size of less than 20 nm. The specific saturation magnetization values are slightly less than those of single crystal or conventional Fe-Si alloys and decrease as Si content increases. The coercive force values of the nanocrystalline as-milled powders are much higher than those of corresponding Fe-Si bulk alloys with a minimum at 13.5 at.% Si. The values of coercive force decreased after annealing but it seams that the residual strain developed during milling is not the major contributing factor to the higher values of coercive force in the mechanically alloyed powders and nanocrystals behave as single-domain particles without exchange interaction between them.

Jan 1, 2006

By Trygve Høy

"Important stratabound lead-zinc deposits in southeastern B. C. occur in rocks that range in age from Proterozoic Helikian to Middle Cambrian. The Sullivan deposit, and similar but smaller deposits in the Sullivan area are the only important deposits that occur in clastic rocks with little carbonate content. The highly deformed and metamorphosed Shuswap deposits, of probable Hadrynian to Helikian age, are in mixed marble, calc-silicate gneiss and pelitic schist assemblages, rocks transitional between clastics and carbonates. Deposits in younger rocks, such as the Kootenay Arc deposits in the Lower Cambrian Badshot-Reeves Formation and the Monarch -Kicking Horse deposits in Middle Cambrian dolomite, are hosted by platformal carbonate rocks.An important regional control for the distribution of deposits appears to be a northeast-trending tectonic zone that crosses the Rocky Mountains and the Purcell Mountains just south of the Sullivan area, and projects southwestward toward the Salmo camp at the southern end of the Kootenay Arc. Pronounced northeast-trending gravity and magnetic anomalies, basic volcanism of Hadrynian age (the Irene volcanics west of Creston) and a preferred alignment of Mesozoic granitic rocks indicates that the zone coincides with deep crustal structures. Within the zone are dramatic and abrupt thickness and facies changes in Hadrynian Windermere rocks and lower Paleozoic rocks, and on the east side of the Rocky Mountain Trench in Helikian Purcell Supergroup rocks, indicating that block-faulting was active intermittently within the zone from Helikian through to lower Paleozoic time. Right-lateral and reverse movements occurred on northeast-trending tear faults within the zone in Mesozoic time."

Jan 1, 1982

By Vladislava A. Ignatkina, Victor D. Samyguin

"Within the limits of two-phase approach, considering mass transfer with pulp and air streams was shown that each bubble appears to be an elementary carrier, transporting particles from the collection zone into the froth. The kinetics of flotation was described by the exponential equation in which first order flotation speed constant has to be replaced with two-phased coefficient of a mass transfer. Criteria of selectivity of two ore fractions separation, based on determination of optimum time at which maximum difference between extractions and components content in separated fractions were offered. An interrelation between optimum time of pulp residence in a flowing chamber of a flotation machine, time of bubbles mineralization and an optimum airflow has been ascertained. Cumulative criterion of mass transfer efficiency of flotation process has been ascertained to be a form of the spectrum and its position on axis of three-phase coefficient of a mass transfer.INTRODUCTIONRegularities of a mass transfer of three bearing streams: pulp stream, air stream and froth stream underlie theory of mineral complexes flotation (Samygin, Filippov, & Shekhirev, 2003)However, only description of mass transfer in pulp stream by means of kinetic equations that were simple and convenient for practical use, has gained a full distribution (Tykhonov, 2009;Rubinstein&Filippov, 1980; Saleh, 2010).Within the limits of a single-phase approach, the role of gas stream in increase of speed and selectivity of flotation, was associated with an improvement of hydrodynamic mode. An influence of particles and bubbles sizes (Rubinstein&Filippov, 1980; Rubinstein&Samygin, 1998, Samygin et al., 2003; Dai, Fornasiero,& Ralston, 2000), of pulpflow and airflow (Finch& Dobby, 1990) and turbulent energy intensity (Shubert, 1979; Massinaei, 2007) on the flotation process has been studied. It was stated that flotation selectivity is increasing by means of gradual airflow increase from first to final cameras of the impeller flotation machine (Aslan&Boz,2010; Finch, 2011) and by means of using a multizone flotation machine (Samyguin, Filippov, Matinin, Lekhatinov, &Tertyshnikov, 2013)."

Jan 1, 2016

By A. V. Lyamin, J. P. Wang, A. J. Li, Z. Qian

"For general stability analysis of rock slopes, rock mass strength and rock mass disturbance are definitely should be considered. In addition, the impact of earthquakes must be taken into account. In fact, the rock mass strength is very difficult to be assessed which causes the difficulty of analysing rock slope stability. Therefore, an empirical failure criterion, the Hoek-Brown failure criterion, has been proposed. It is one of the most widely accepted approaches to estimate rock mass strength. The rock mass disturbance is important and was found having significant influence on evaluating rock slope stability, especially for rock slope with poor quality rock mass. In the Hoek-Brown failure criterion, the disturbance factor can represent the level of the rock mass disturbance which would provide a reasonable basis for estimating rock mass strength.This research will not only discuss the slope factor of safety, but also consider the influence of the seismic force on rock slope stability assessment using pseudo-static method. In practice, only horizontal seismic coefficient is used. Various magnitudes of the disturbance factor and recommended blasting damage zone thickness are also taken into account. The blasting damage zone thickness considered ranges from 0.5 to 2.5 times of slope height. The research results have potential to be extended and then sets of comprehensive stability charts can be provided for the rock slope stability evaluations. They will be convenient tools for practising engineers. In this study, finite element upper bound and lower bound limit analysis methods are employed. Their applicability has been investigated in some previous studies. The differences between upper bound and lower bound solutions are less than ±10% which would provide reasonable and acceptable range for rock slope stability safety factor estimation."

Jan 1, 2015

By S. D. F. Rocha1, L. Katsarou, G. P. Demopoulos

"Crystalline scorodite (FeAsO4·2H2O) has been pointed out as the most stable compound to immobilize arsenic for disposal due to its good stability performance according to EPA’s TCLP test. However, in anaerobic conditions, arsenic releasing is increased to undesired levels due to scorodite reductive break down, in eh <100 mV at 5.5< pH <7 which causes contamination of groundwater. In this work, the concept of encapsulation by controlled deposition of mineral coatings immune to pH or redox potential variations is presented. Aluminum and calcium phosphates were evaluated as coatings and the release of arsenic from scorodite previously coated with phosphates was substantially decreased when compared to the VALUES (obtained from crude scorodite, both in oxic and anoxic conditions. INTRODUCTIONThe widely acknowledged hazardous properties of arsenic as a soil and natural water contaminant and its adverse health effects when present in drinking water have led to very strict environmental regulations (Mandal & Suzuki, 2002) aiming at the drastic reduction of the presence of arsenic in the effluents of the mining and metallurgical industries.In Canada, the Metal Mining Effluent Regulations (Government of Canada, 2002) dictate that the maximum monthly mean concentration in tailings for arsenic must be lower than 0.5 mg/L. At the same time the new Environmental Protection Agency’s (EPA) standard for drinking water foresees concentrations of arsenic less than 0.01 mg/L, which means that the leachability limit for the industrial waste is set at 1 mg/L arsenic (EPA, 1994; Le Berre et. al, 2007). One of the preoccupations of the mining and metallurgical industries is directed to the elimination of arsenic presence in all its effluents, especially since arsenic is commonly found in many ores mainly in the form of oxides and sulphides. After processing of arsenic-containing ores and concentrates, arsenic can be present either in solid residues and tailings, liquid effluents or in flue dusts. Several of these forms of arsenic waste materials are soluble and therefore may cause the contamination of ground water, if disposed of without further treatment."

Jan 1, 2012