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By E. Dernedde

Cell rooms of aluminium smelters have large openings in the sidewalls and in the roof. These openings provide a high ventilation rate, which removes heat and contaminants emitted by the reduction cells and thereby ensures acceptable working conditions inside the cell room. However the large openings make the airflows through the smelter building sensitive to the wind. In this study equations for the airflow through the openings of a smelter building exposed to crosswinds were developed and verified against plant measurements. The equations were then used to estimate the airflows through a two-storeyed smelter building containing VS Soderberg cells. Wind protection by wind-covers over the sidewall openings and by upwind buildings made the airflows through the building less sensitive to the wind. Physical and mathematical modelling showed that working conditions inside the wind-protected cell room would be acceptable for crosswinds at speeds up to 16 km/h. These predictions were confirmed by measurements taken in a VS Soderberg smelter.

Jan 1, 2007

By M. M. Helm

Samples sourced from the Goldstrike property in Nevada USA, have been evaluated in terms of their preg-robbing capacity and the physical structure of the graphitic carbon component in the carbonaceous gold ore. The study highlights a wide range in preg-robbing capacity between samples collected from the Betze-Post open pit and Rodeo underground mine. The physical structure of the graphitic carbon was assessed using Raman spectroscopy, and is found to play an important role in influencing preg-robbing behaviour. Differences observed in the physical structure of graphitic carbon are thought to be the result of hydrothermal events that occurred at Goldstrike.

Jan 1, 2011

By H. M. Woodrooffe

IT IS WELL KNOWN that chrysotile asbestos from various occurrences exhibits varied physical properties and certain differences in chemical corn position, both of which conditions may have an important bearing on the industrial utilization of the fibre. The usefulness of a harsh fibre in the manufacture of asbestos cement products and of low-iron fibre for certain electrical uses are examples. It is also .possible to obtain a fibre with a texture too harsh and brittle to be of economic value. Much research into the structure of the mineral and to a lesser degree observations relating the water of combination to certain physical properties have ?been reported. This paper is an attempt to show that the pyrolysis of ?chrysotile takes place in three stages and that the conditions of pyrolysis are peculiar to the fibre and may afford some clue to the variations in physical properties of asbestos fibres which affect their utilization.

Jan 1, 1956

By John B. Riddell

"AN EXCELLENT review of the status of applied geochemistry was given by Warren (1959) at last year's General Meeting of the C.I.M. The purpose of this paper is to present recent developments and trends. Several important books were announced during 1958: Ginzburg, I. I. Principles of geo-chemical prospecting. (In process of translation from the Russian by V. Sokoloff).Vinogradov, A. P. The geochemistry of rare and zvidely scattered chemical elements in soils. Consultants Bureau, N.Y. Korzhinskii, D. S. Physicochemical basis of the analysis of the paragenesis of minerals. Consultants Bureau, N.Y.In addition to these translations Mason's Geochemistry' has been revised, and Hawkes and Webb (personal communication) are publishing a book on geochemical exploration. A Symposium on Geochemistry was head in Paris in July, 1957, in conjunction with the XVIth International Congress of Pure and Al-lied Geochemistry. The abstracts of the papers presented at this Symposium were published in Geochimica et Cosmocl1imica Acta, 1958, Vol. 14, pp. 150-167."

Jan 1, 1960

This paper describes basic parameters, such as surface forces and film elasticity, affecting the stability of foams (two-phase froths). We used the thin film pressure balance (TFPB) technique to measure the surface forces in foam films stabilized with various frothers such as pentanol, octanol, methyl isobutyl carbinol (MIBC), and polypropylene glycol (PPG). The results were compared with the foam stabilities measured experimentally and the film elasticities calculated using a new model developed by Wang and Yoon (2006). It was found that at low electrolyte (NaCI) concentrations foam stability is controlled by both film elasticity and surface forces (or disjoining pressure), the relative contributions from each changing with frother type and concentration. Further, the kinetics of film thinning was studied at a high electrolyte concentration. The results obtained in the present work showed that the major role of a frother is to decrease the hydrophobic force rather than to increase the film elasticity. This conclusion is drawn from the observation that at the typical frother (MIBC) concentrations employed in flotation, frother additions cause sharp decreases in hydrophobic force while causing relatively little changes in film elasticity.

Jan 1, 2006

By R. P. Charbonnier

"To understand the operation of jigs and other separating processes based on differences in gravity, it is desirable to analyse the motion of various particles in given media under specific conditions. A summary of the earlier theories shows that they lead to unsatisfactory or excessively complicated formulae in cases such as coal jigging. By adopting a simplified theory of the motion of particles in a fluid, the size and duration of the initial accelerated motion of a particle falling in hindered settling can be calculated. Based on this mathematical analysis, examples referring to actual coal jigging practice show that it is desirable to prolong and/or repeat, as frequently as possible, the optimum conditions corresponding to an effective acceleration of the particles. The separation is then obtained according to gravity rather than to particle dimensions, as would be the case if the velocity of the particles• were allowed to approach its terminal value. To achieve this gravity separation, it is suggested that the suction phase of the jigging cycle be artificially prolonged and the frequency of pulsations increased as much as possible for washing the coals of smaller sizes."

Jan 1, 1959

By D. Berkley

Off-gas systems often become the limiting factor in production increase and environmental projects. Any upgrade or new off-gas project needs to address control instability issues, instabilities that can result in safety hazards, significant loss of system capacity and/or emissions to the environment [1]. In addition, the design engineer must optimize system configuration and equipment size for the new operating conditions, to have a technically feasible and economically viable project. Dynamic simulations can be used for addressing both the control stability and the design optimization issues. This paper illustrates how the dynamic simulation of transient processes and of their control system can be used in "real life" situations for these purposes, presenting the example of an electric furnace off-gas system design.

Jan 1, 2005

By M. Hames, K. Larmour-Ship, B. Grinbaum, E. Buchalter, R. Hackl, B. Wassink

Sodium cyanide continues to be the lixiviant of choice for gold dissolution. Many gold ore-bodies contain a significant amount of cyanide-soluble copper which increases the cost of processing due to high cyanide consumption and high cyanide destruction and disposal costs. Several cyanide destruction processes are in use today, however, there are just a few cyanide recovery plants operating. A solvent extraction process to recover cyanide has been developed which utilizes the organophosphorous extractants Cyanex 923, di-butyl-butyl-phosphonate (DBBP) or tri-n-butyl phosphate (TBP) in Bateman Pulsed Columns. Copper cyanide species are first converted to hydrogen cyanide (HCN) by acidification, with or without sulfide addition. HCN is extracted by the organic and stripped using a suitable base (eg. NaOH) resulting in a high strength cyanide solution (eg. NaCN) for recycle to the gold recovery process. Continuous pilot plant testwork on HCN extraction using a 40 mm diameter Bateman Pulsed Column demonstrated a cyanide recovery of greater than 99% with final levels of cyanide in solution of less than 10 ppm. These results illustrate the potential of this technology to recycle cyanide and to detoxify final effluent streams.

Jan 1, 2005

By W. W. Rudolph, L. N. Trevani, P. R. Tremaine

UV-visible spectroscopy, Raman spectroscopy, and vibrating tube densimetry have been used in our laboratory to determine equilibrium constants of aqueous species at temperatures as high as 325 °C. The UV-visible and Raman spectra of solutions containing metal complexes and ionized acids or bases can be used to yield formation constants by applying curve fitting methods to resolve the contribution of each species. Colorimetric pH indicators identified by Johnston and coworkers at the University of Texas (Austin) provide an alternative means of determining ionization constants and the pH of complex mixtures. High precision density measurements over the same range yield standard partial molar volumes, which are key parameters for "equations of state" for aqueous species. Examples are given for the copper-ammonia system, simple carboxylic acids, and the iron-sulphate system.

Jan 1, 2004

The Autogenous milling of ores holds an increasing attraction as the focus moves towards reducing energy usage, both direct and embodied in grinding media. However, most of the early AG mills were converted to SAG for improved stability and increased throughput. This imposes a huge penalty in steel grinding media consumption. The LKAB iron ore operations in Sweden process highgrade magnetite through fully-autogenous milling lines to a final product P80 of about 45µm. The outcomes of P9O AMIRA research surveys, covering a wide range of mill fillings and throughputs and with different feed blends, are presented. Insights are provided on operational strategies, opportunities, the influence of feed size control and balancing the blend of competent gangue and softer magnetite. Areas of importance in the successful operation and control of energy-efficient autogenous circuits are highlighted.

Jan 1, 2012

By A. H. Lang

"The great interest taken in uranium in Canada during the past few years has resulted in the discovery of a very large number of occurrences, and in much research that has added to the knowledge of the mineralogy and geology of uranium deposits. The object of this paper is to present that information in condensed form. Some of it has been published before, but the writer has been asked to bring it together and to add more recent, unpublished data. The paper therefore contains short accounts of the mineralogy of uranium and of the types and distribution of occurrences; brief regional descriptions, including information on some of the characteristic deposits; and conclusions regarding prospecting and development possibilities.The writer has access to much confidential information supplied in compliance with regulations of the Atomic Energy Control Board. He has used this only for making broad generalizations that could not affect individual interests, and only where the owners of properties have agreed to its use.Much of the information on mineralogy and geology is derived from the work of others. The writer is particularly indebted to M. H. Haycock and S. Kaiman of the Mines Branch; H. V. Ellsworth, S. C. Robinson, E. J. Brooker, H. R. Steacy, W. E. Hale, and A. M. Christie of the Geological Survey; and E.W. Nuffield, J. S. Stevenson, and other officers of provincial Departments of Mines. For information and many courtesies he is greatly indebted to so many officers of Eldorado. Mining and Refining (1944), Limited, and owners and staffs of private properties, that it is impossible to mention them individually."

Jan 1, 1950

By T. A. Utigard

To improve recoveries of Ni, Cu and Co in the Inco flash furnace, a new operating concept was investigated. By adding sufficient coke to form a supernatant coke layer, a reducing barrier would form allowing for improved reduction of descending oxidized sulfide mineral particles formed in the flame. The objective of this investigation was to study the kinetic mechanism and efficiency of the coke layer to produce a sulfur deficient matte. The mechanism and rate of carbon reduction of each of the phases formed in the flash flame, i.e. sulfides and oxysulfides were investigated by means of X-ray visualization tests. Graphite-slag reduction was also conducted for comparison purposes. In the case of slag, poor wettability and the formation of a gas film on the surface of the carbon reductant are often blamed for limiting the reaction surface area that ultimately results in poor reaction kinetics. The X-ray visualization tests confirmed that matte and oxysulfide wet coke better than slag and that the rates of reduction of matte and oxysulfide are faster than that of slag.

Jan 1, 2005

By M. Reda

Because of the adverse environmental effect of Chromate, Molybdate ions had been investigated as replacement for Chromate and the results had shown not to be encouraging. Film deposited from peroxopolymolybdate (from reaction of Molybdenum meta, with excess Hydrogen Peroxide), are more robust than that deposited from molybdate solutions. This was shown to be due to higher fraction of Mo (IV) and Mo (V) that form from Mo (VI) in the peroxopolymolybdate deposited film than the film deposited from Molybdate solutions. The peroxopolymolybdate film contains 40% un-hydrated molybdic acid, tetraperoxodimolybdate and tetra peroxo tetra molybdate. The protective properties of peroxopolymolybdate were shown to be due to the effectiveness of the un-hydrated molybdic acid.

Jan 1, 2010

By A. Klingberg, M. Svensson, N. Smolko Schwarzmayr

"Removal of silicates and carbonates from sedimentary phosphate ores by the use of new synthetic collector/formulations was investigated in a comparative study with traditionally used collector systems as references. In the direct carbonate flotation the new formulations showed higher efficiency, contributed to an improved balance of P2O5 recovery and P2O5 enrichment in the recovered material. Efficiency of the new formulations containing synthetic surfactants was 1.5–2 times better than potassium salt of fatty acid sulfonate based formulations that are traditionally used for that purpose. The new formulations also provided up to 7% increase in P2O5 recovery at the same P2O5 grade. The new synthetic collectors for removal of silicates showed extremely good selectivity towards silica bearing minerals. The selectivity factor for the flotation tests when new formulations were used was 32–52 and for the flotation tests with the traditional collectors: 20–32. The ratio between distribution of an amount of silicates (as SiO2) and distribution of phosphate in the froth (waste) is defined as the selectivity factor. The new formulations provided more than 2% decrease of the amount of SiO2 at the same P2O5 recovery.INTRODUCTIONPopulation growth and decrease of arable land are the main reasons for constant increase of consumption of apatite (phosphate ore) in the fertilization field (Lannefors, Gorochovceva, Klingberg, Lima, & Gustafsson, 2015). Fertilizers play a key role for farmers to produce more with less land. The phosphate component of the fertilizer is vital for producing healthy and large amount of crop. As a result the demand for phosphate rock is growing.The largest producers of phosphate rock are the Unites States, Morocco, Tunisia, China, Russia, and Brazil. The term “phosphate ore” includes all phosphate-bearing minerals and rocks, but only two of them are of industrial interest: apatite (igneous origin) and sedimentary phosphate (Peres, Araujo, El-Shall, Zhang, & Abdel-Khalek, 2007). The majority of the world’s phosphate deposits are of the sedimentary type. There are two different types of sedimentary phosphates: siliceous and carbonaceous which are categorized based on gangue minerals (such as quartz, carbonates, mica, and clay)."

Jan 1, 2016

By Frederic Benard

THE Ontario Refining Company, Limited, wholly-owned subsidiary of The International Nickel Company of Canada, refines the entire blister copper output of the latter's Copper Cliff smelter. Prior to 1936, the blister was cast in 460-lb. cakes at the smelter, loaded on open cars, and transported by rail to the refinery, a distance of approximately 1 1/4 miles. Here the cakes were transferred to the plant narrow-gauge system, charged to furnaces, and re-melted. This procedure necessitated the operation of holding furnaces and casting machines at the smelter -extensive re-handling-and melting down of a cold charge at the refinery. Transfer of the copper in molten form direct from converters to anode furnaces promised a considerable reduction in costs, and this possibility was investigated. As a result, a portable holding furnace, or hot-metal car, was designed and constructed. It was placed in operation in July, 1936, to be followed a year later by three additional units of slightly modified design. Figure 1 shows the original car, and Figure 2 the lacer type. With four cars in service, operations were placed on an all 'hot-metal' basis.

Jan 1, 1938

By G E. Craig, W. M. Williams

A simple, easily constructed apparatus suitable for the zone refining of iron and other reactive materials is described. After eight passes at one inch per hour, the iron produced showed a marked drop in hardness to 49 Brinell. In addition, an arbitrarily -defined recrystallization temperature was lowered by about 35°C and the rate of grain growth greatly increased. CERTAIN materials, of which iron is one, are so reactive that they cannot be zone refined in any known container without becoming contaminated. For such substances, the floating zone method ( 1) may be used. In this method, the specimen is supported vertically in an inert atmosphere and the molten zone supports itself by its own sur-face tension. The method was first applied to silicon (2) and has since been used for other reactive metals such as zirconium and titanium. Smith and Rutherford (3) have previously reported on the floating zone refining of iron; the efficiency of the method for reducing the car-bon content was demonstrated on

Jan 1, 1962

By G. Archibald, M. McSaveney, J. Wartman, M. Yetton, C. Massey, C. Holden, A. Kaiser

"The 2010/11 Canterbury earthquakes triggered many mass movements in the Port Hills including rockfalls, rock and debris avalanches, slides and slumps and associated cliff-top cracking. The most abundant mass movements with the highest risk to people and buildings were rockfalls and rock/debris avalanches. Over 100 residential homes were impacted by landslides, leading to the evacuation of several hundred residents.Volumes of rock leaving several of the larger cliffs during the earthquake sequence were determined from terrestrial laser scan change models. There were no seismically instrumented cliff sites and there was some distance between the cliffs and nearest strong-motion sites. Therefore, we synthesised free-field rock-outcrop seismograms by employing a stochastic approach controlled by source models and regional parameters derived using spectral inversion of the extensive strong motion data set. Relationships between volumes leaving cliffs during the earthquakes and site peak ground acceleration (PGA), peak ground velocity (PGV) and Arias intensity were compared for different sites. Multiple linear regression was used to analyse the variables that best predict the volumes of debris that fell from the slopes during the main earthquakes. The best correlation between the volume of debris falling per square metre of slope face and the seismic forcing parameters was for vertical PGV. The results from the multiple linear regression incorporating slope height, inclination, PGV horizontal and PGV vertical, improved the statistical relationship.Field data and results from the 2D seismic site response assessment indicate that the following factors affect dynamic performance of the modelled cliffs: 1) cliff geology—mainly material modulus, shear strength and shear wave velocity; 2) slope geometry—ridge-scale versus site-scale effects; and 3) the temporal aspects of the earthquake shaking (i.e., single acceleration peaks of large amplitude versus multiple peaks of smaller amplitude). Model results show that amplification of shaking does not increase linearly with increasing height, but instead reflects changes in the cliff geology where material strength, modulus and shear-wave velocity contrasts lead to acceleration contrasts.These factors show that the use of well documented case histories provide the basis for more certainty in seismic landslide assessments compared to those that are only empirically based."

Jan 1, 2015

By S. S. Al-Thyabat, A. M. Ghrair

"Printed circuit board (PCB) is the main part of any electric or electronic device, providing mechanical support and electric connection for the board eclectic components such as capacitors, resistors, diodes etc. PCB consists of non-conductive substrate overlaid with one or more layers of copper sheets. They also contain appreciable amounts of base metals (copper, nickel, tine, and aluminum) and precious metals (gold, silver, and rare earth elements (REE)) which end up in the landfill at the PCB end-of-life.PCB recycling E-waste in general is a profitable business; many valuable raw materials, precious and base metals, can be extracted with high purity. Approximately, one metric tonne of PCBs may contain 80-1500 g of gold and 160–210 kg of copper. The precious metals recovered from PCBs occur at concentrations higher than commercially mined minerals. Also PCB recycling is very important to our environment since many heavy metals (e.g. lead) may be leached from the landfills to the underground reservoirs. In Jordan, however, the work conducted on E-waste and PCB recycling in particular is limited; currently most of the E-waste is either exported or dumped in the landfill.In this work, a combination of physical (magnetic separation), physicochemical (flotation), and chemical methods (leaching) were used to compare metals concentrations in leach liquors produced from a concentrates resulted from a combination of these methods. It was found the leach liquor of the magnetic fraction of the PCB coarse size gave the highest concentration of Fe, Al, and Ni while concentration of Cu was higher in leach liquor of nonmagnetic sink fraction. On the other hand, metals concentration almost similar for both sink and float of the fine size fractions, indicating even distribution of metals concentrations in the fine size fractions."

Jan 1, 2016

The comminution circuit at Tarkwa Gold Mine was commissioned as a Single Stage SAG mill operated in closed circuit with hydrocyclones designed to process 4Mtpa. The circuit was later expanded by adding a secondary ball mill in closed circuit with hydrocyclones with a view to treat 12Mtpa. The change in the circuit configuration and assigning the low aspect ratio SAG mill for primary grinding application makes the Tarkwa experience unique in terms the optimisation strategy and operating philosophy. This paper reports the findings from a series of surveys performed on this plant. The surveys reported include data obtained when the SAG mill was operated as a single stage mill in closed circuit with hydrocyclones and also SABC mode under two different feed conditions. The differences in operating philosophy between the initial single stage SAG circuit and the current SAG/Ball mill circuit are discussed.

Jan 1, 2012

By V. I. Ryaboy, V. P. Kretov, I. V. Ryaboy, E. D. Shepeta

This paper studies the features of known and newly synthesized dialkyldithiophosphates and reagents with thioamide groups when separating copper-containing and arsenic-containing minerals in the flotation of skarn-scheelite-sulphide ore at the Primorskaya concentration plant. The optimization of dialkyldithiophosphate collectors was based on the study of their surface activity at the liquid-gas interface and estimated hydrophobic abilities. The flotation experiments show that the selectivity of action of the reagent increases with an increase of its surface activity and a reduction of hydrophobic ability when separating chalcopyrite and arsenopyrite. IMA-225-5 was proposed as a more efficient dialkyldithiophosphate collector, which increases the recovery of copper by 2.8% compared to the industrially used collector IMA-I413. Selection of the optimal structure for reagents with thioamide groups (derivatives of thionocarbamate and thiourea) was carried out according to their acidity and the presence of hydrophilic particles in their structure. Calculations were performed depending on the pH of the solution of chalcopyrite to determine the optimum reagent sorption and to further optimize the structures of these reagents. The tests with reagents with thioamide groups show an increase in copper recovery by 3-4% together with a significant increase of arsenic content compared to IMA-225-5. As a stronger collector with thioamide groups, it was recommended to use sample 234, which belongs to the thiourea derivatives. IMA-225-5 was recommended for industrial tests at the Primorskaya concentration plant. Thus, this study has shown that using dialkyldithiophosphate is more appropriate if it is necessary to increase the selectivity of separation of copper-containing and arsenic-containing minerals, and using reagents with thioamide groups, or their combinations with dialkyldithiophosphates, is more appropriate if it is necessary to increase the recovery of copper or the quality of copper concentrate with less selectivity of the process.

Jan 1, 2016