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In the past ten years or so there has been a renewed interest worldwide in the processing of refractory gold ores. The Archean province of Western Australia contains both numerous and major gold deposits, and has a long history in the development and practise of treating refractory ores (eg Blaskett and Woodcock, 1953). Depletion of shallow oxidised ores in recent years has re-focused attention on deeper sulphidic ores, and as a consequence has renewed interest in treatment methods for those ores which are refractory. Mineralogical factors he at the heart of reasons as to why these ores are refractory, and are the key to designing and improving treatment options in the longer term. This paper presents an overview of mineralogical factors that are relevant to the processing of refractory gold ores in the Archean of Western Australia. It is based on a number of research projects and other work on a variety of gold deposits, mainly in the Eastern Goldfields region, carried out over the past five years or so.

Jan 1, 1991

A thick sequence of alkaline intrusions and volcanic rocks underlies a Quaternary caldera on Liliir Island. The sequence is host to a still active sub-aerial hydrothermal system and associated epithermal gold mineralisation. Sub-horizontal alteration horizons exhibit progressively increasing chondrite norma-lised (La/Lu) en and (La/Sm) cn ratios from unaltered shoshonites, to the potassic alteration zone, to the argillic altera-tion zone to the advanced argillic alte-ration zone. The increasing fractionation of HEE, and especially of LHEE, up the alteration sequence is the result of de-creasing pH, temperature and alkalinity of the hydrothermal fluids with increa-sing alteration intensity. HRE3 were especially mobile in argillic and advanced argillic alteration units characterised by acid fluid conditions and large fluid volumes. Abundant Cl, S and CO2 within the hydrothermal fluids and thus abundant REE complexing agents and large fluid volumes favoured the mobility of REE during hydro-thermal alteration of the volcanic rocks and intrusions. Steam escape, mixing of the gases with groundwater and a change from a magmatic neutral chloride hydro-thermal system to a meteoric acid sulphate system was accompanied by liquid/vapour ratio changes, pronounced alkalinity, pH and temperature decreases, and fluid/rock ratio increases. This caused the mobili-sation, fractionation and deposition of PF.F.

Jan 1, 1990

Discovered in 1896, the Sons of Gwalia orebody is located in a ductile mylonite zone within a sequence of Archaean pillow metabasalts and minor metasediments of greenschist facies which are variably sheared.The ore zone has good continuity, being 110 m wide and 500 m long, dipping 45 degrees east and plunging 70 degrees to the south to a depth of 1500 m downplunge. A strongly-developed foliation is present together with a prominent lineation paralleling the plunge. The mylonite zone consists of unmineralised chlorite schist and a 'U' shaped mineralised zone of chlorite-sericite schist with varying amounts of quartz-carbonate as veins parallel to foliation, boudins, and locally as massive quartz-carbonate. Pyrite is the dominant sulphide present.Grade control utilises RC holes on a 10 m x 10 m pattern, with infill blast rig holes 5 m deep where necessary.Some visual control of ore boundaries is present and, combined with good ore continuity and a knowledge of the structure of the orebody, enables cost-effective grade control to be achieved. To-date, over three million ounces of gold have been produced from the orebody.

Jan 1, 1993

By Ault A. R

The recent modernisation program at the Risdon electrolytic zinc smelter of Pasminco Metals - EZ (PMEZ) inyolved significant changes to the composition of cell electrolytes. The most significant were increased acidity and sulphate level, a reduction in Co level, and the replacement of 2-naphthol in the additive mixture with licorice. In determining acceptable operating ranges, a relatively large number of industrial deposition tests under controlled conditions was required. The cathode zinc deposits so produced were examined in terms of overall appearance, crystal structure according to X-ray diffraction, and a micro-roughness parameter. Beginning with typical deposits produced in the presence of an excess of one of the addition agents glue or antimony or a mist suppressant (licorice or 2-naphthol), a simple classification system was developed. In this system, the deposits are divided into the following types: Doughy, Pinholed, Compact and Stressed. There was a weak correlation between deposit type and crystal orientation. In terms of ease of stripping, observations in plant operations showed that only Compact and Pinholed were consistently acceptable. Current efficiency was normally maximised by producing a Compact deposit. Process variables such as zinc concentration, temperature and the use of strontium carbonate were found to cause changes in deposit type if the reagent mixture used was unchanged. From the knowledge gained, guidelines were developed to allow glue and antimony additions to be altered to fit new circumstances. The simple classification system was first used to expedite recovery from undesirable morphologies and then to optimise individual cell units operated under substantially different conditions. It is believed that finer control could be exercised by determining the micro-roughness of Compact deposits. However, difficulties can arise if sudden, large deviations occur and go undetected. Suggestions are given for an improved additive control system. The classification system developed has been compared with published information in the literature, and good correspondence was noted suggesting a predictable relationship between short-term, laboratory deposition tests and observable phenomena in industrial electrowinning cells run under steady conditions.

Jan 1, 1993

About 3km2 of the central Luise Caldera, in which the Lihir orebody is located, is geothermally active wit.lj gas seeps and fumaroles, and in some areas, a water table at boiling point.The proposed mine, adjacent to Luise Harbor, will be excavated to more than 200m below sea level and will extend into the geothermal system to depths at which current rock temperatures are 170¦C.

Jan 1, 1994

The history of potential large scale development at Stawell in northwestern Victoria dates back to 1914, when Great Boulder Mines Limited, of Kalgoorlie, Western Australia, took up options on some of the major mines in the Stawell Goldfield. Despite this and other attempts by various groups over the next thirty years, mining activity on the field gradually dwindled to the retreatment of old mill tailings.A static price for gold and indifferent drilling results prevented a major effort towards reopening the field until the late 1970's. A renewed exploration effort led to the discovery of sufficient reserves to justify installation of a carbon-in-leach gold treatment plant.

Jan 1, 1984

By Leach T

The Tolukuma Gold Deposit is hosted by metamorphic and volcanic rocks, and igneous intrusions. Dilatant structures for the main veining appear to be provided by post-metamorphic flexure/faulting; syn-mineralisation tectonics is recognised from the en-echelon patterns of much of the veining. A SSE trending structure containing high grade mineralisation has acted as a major dilational zone within or at the contacts of porphyry intrusions. An ESE trend has controlled numerous dilational structures splaying eastward from the SSE vein structure and containing medium grade mineralisation.Early hydrothermal activity (Stage I) is represented by unmineralised, pyrite-rich brecciation and fracturing. Associated chloritic veining is indicative of single phase neutral-chloride fluids upwelling in relatively low fracture controlled nenneahility

Jan 1, 1993

By Sneddon NW

Aberdare North Colliery is situated on the eastern boundary of the City of Cessnock in the Hunter Valley, New South Wales. Although the area is now noted for its wines and vineyards, the district has a long history based on coal mining. The richest coal seam in the Cessnock district is the Greta Seam, a low ash, high volatile steaming or gas making coal. The seam, up to 10 metres thick, extends over a large area surrounding the city of Cessnock and neighbouring townships such as Bellbird, Aber- dare, Kearsley, Neath, Ellalong, Kurri Kurri and Stanford Merthyr. The Aberdare Colliery, leases, which extend under Aberdare and Cessnock townships, were first worked in 1905 and continued developing pillar panels until the mine closed on 11 Nov- ember, 1960. Coal mining to this time consisted mainly of developing pillars to the 2.4 metre parting and, in some areas, dropping the top coal to the 6 metre parting, thus leaving the pillars intact, the top 1.8 metr-es of coal be- ing left untouched due to the high sulphur content. Aberdare North Colliery was opened in 1956 in order to recover and extract the pillar coal and tops left standing for over 40 years. During the pillar extraction phase the occurr

Jan 1, 1981

By Weller K. R, Trahar W. J

The Mount Lyell Company treats some 2.3 million tonnes of ore annually, mined from a number of orebodies on the field. Blended ore is essentially a quartz-sericite schist containing about eight per cent of pyrite and three per cent of chalcopyrite. Four-stage crushing and two-stage ball milling are followe by selective flotation for copper. Pyrite is recovered from the coarse fraction of dopper circuit tailings. A detailed survey involving examination. of 82 samples provided information on the size- by-size behaviour of the principal ore constituents throughout the grinding, copper flotation and pyrite flotation sections of the circuit. Results for the copper and pyrite flotation sections are presented in the paper, and it is shown that over half the copper reporting to the final tailing (5% of copper in the feed) is plus 100 microns and that the major pyrite loss is in the desliming cyclone overflow. These data proVide a basis for assessing potential methods of circuit optimisation.

Jan 1, 1977

Epithermal gold mineralisation was discovered at the Muyup prospect during regional reconnaissance exploration in 1986. Further exploration utilising routine techniques of stream sediment, panconcentrate, rockchip sampling and geological mapping resulted in the discovery of five auriferous vein systems located along northwest-trending fault zones. Scout diamond drilling was conducted on two of the vein systems. Mineralisation is hosted by a poorly exposed, mid-Tertiary volcanic inlier composed of intermediate and minor felsic volcanic rocks intruded by intermediate hypabyssal por- phyries. Gold is wholly contained in narrow steep-dipping hydrothermal breccias and quartz vein stockworks in which chalcedonic silica and fine grained quartz is the predominant gangue with minor adularia, carbonate, and sulphides. Alteration zoning is manifested as intense fracture-controlled silicification mantled by narrow clay-rich envelopes which in tam grade outward and downward into propylitic alteration or unaltered host rocks. Late advanced argillic alteration is superimposed on the vein-related altera- tion assemblages. Alteration assemblages and fluid inclusion data suggest that gold mineralisation occurred in response to episodic hydraulic fractur- ing and boiling of low to moderate temperature, dilute alkali-chloride fluids. The Muyup prospect represents the shallow eroded remnants of an epither- mal gold deposit enriched in Au, Ag, As, Sb and Hg. Low sulphur fugacities reflected by vein and alteration assemblages support an adularia-sericite classification (Heald et al, 1987) for this epithennal gold deposit.

Jan 1, 1991

By Nguyen G. H, Graham J

A laboratory-scale fluidised-bed roaster has been used to examine the effect of temperature and duration of roast on the morphology of the calcine produced from a pyritic gold-bearing concentrate. Two mechanisms of oxidation, which depend on the roasting temperature, have been identified. For samples roasted below 550°C, direct oxidation of the sulphide occurred to form hematite with a porous fine-grained concentrically-layered texture. The surface area of the calcine increased with an increase in roasting temperature in the range 400 to 500°C. For samples roasted above 550°C, the first reaction was the evolution of sulphur vapour to produce pyrrhotite, which underwent increasing grain growth as the roasting temperature was increased. This had the effect of decreasing the surface area of the calcine. The pyrrhotite was subsequently oxidised to produce hematite.Leaching studies using cyanide solution indicated that gold extraction around 95 per cent was achieved at temperatures of 500°C and above, with optimum extraction, taking into account rate and cyanide consumption in the range 550 - 700°C. Hence recovery did not decrease with decrease in surface area of the calcine. Observed gold in leached calcines was mainly enclosed in thin oxide walls of the hematite, with minor quantities enclosed in quartz and silicate minerals.

Jan 1, 1995

By Muir D. M

Highly saline process water has a number of implications for the CIP process during the leaching, adsorption and recovery of gold. The reduced oxygen solubility in saline water can seriously reduce the rate of gold leaching, while dissolved oxygen meters do not necessarily reveal actual oxygen concentrations in saline water. High levels of magnesium in the ground water necessitate operation at lower pH (-9), with the potential for greater cyanide loss via HCN stripping. In addition increasing salinity renders viscosity modifiers largely ineffective.The adsorption capacity of aurocyanide onto activated carbon is improved with increasing salinity, but misleading results can be obtained in assessment of gold loading kinetics of plant carbon samples already loaded, or partially loaded, in saline water if subsequently tested in fresh water. Elevated chloride levels in the Zadra elution process can cause severe anode corrosion in the elecuowinning cell. The Anglo elution process is tolerant to only slight increases in water salinity, but elution times can be reduced by ethanol addition. Care is required in carbon regeneration, as salts can catalyse carbon decomposition as well as increase kiln corrosion.

Jan 1, 1994

By Laing W. P, Neill D. M, O&apos

The Reward polymetallic massive sulphide deposit occurs 35 km south of Charters Towers, adjacent to the Highway gold deposit (Fig. 1). It is hosted within rhyolitic lavas and interlayered volcaniclastics of the Cambro-Ordovician Mt Windsor Volcanics. Reward is a "blind" deposit discovered in 1987 after a long history of exploration by various companies in the area. The main pyrite dominant massive sulphide body occurs under 100m combined thickness of Tertiary fluviatile sediments overlying deeply weathered gossanous volcanics. The exploration case-history provides a striking example of how geological and structural models can be built up almost exclusively from drill information. Four different styles and ages of mineralisation are present: 1) volcanogenic Cu+Pb+Zn+Ag+Au massive sulphides of probable syngenetic origin; 2) remobilised Cu+Au in massive pyrite of metamorphic/deformational origin; 3) supergene and 4) oxide Cu+Au mineralisation of weathering origin. The massive pyrite body, containing chalcopyrite lenses, transects the stratigraphy and is inferred to contain in excess of 5 million tonnes. Overlying the primary mineralisation a supergene chalcocite rich zone contains a measured/indicated resource of 634,231 tonnes of 6.77% Cu which includes 287,000 tonnes of 1.32 g/t Au and 18 g/t Ag. In addition a measured/inferred oxide resource of 309,000 tonnes of 5 g/t Au and 27 g/t Ag overlies the supergene zone.

Jan 1, 1989

By Zamel G. I, Zenari L. P

Technological developments in modem Tunnel Boring Machines (TBMs) and associated back-up equipment are offering significant alternatives for mining operators to consider, in the selection of equipment for coal mine development drifts, roadways, longwall gate roads as well as metalliferous mining declines and development drives.Greater flexibility in handling variable ground conditions, muck disposal and radius of turn as well as advance rates, are just some of the areas where modem TBMs can accomplish the flexibility that mine operators require to achieve cost-effective developments.Compact TBMs are achieving this acceptance because of the fundamental design of a shielded machine containing electrics and hydraulics within the forward shell, ability to achieve tight radius of curvature and grades, and ability to provide highly flexible support systems to meet all possible ground conditions.However, a single TBM design will not suit all mine developments, as each development method - while having common goals with all mine developments - will also require certain unique criteria to be fulfilled.

Jan 1, 1993

By White A. H, Vihena M. T M B

Presently, orebody modelling consists basically of fitting a mathematical model to represent spatially a certain geological variable, generally grade. An orebody model is constructed from a set of sample data obtained from various locations in the orebody, thus it is only one form of representation of the true phenomena. Checking the compatibility of the data with the modelling procedure is the most important factor when assessing confidence in the orebody model. The level of confidence in the model will depend on the adequacy of the data set and the validity of the basic assumption required by the modelling method. Fractal geometry is one way of modelling the spatial distribution of a geological variable in an orebody geometry. Fractals can be used to interpolate the Z(x) geological variable at unsampled sites. The concepts of self similarity and self affinity that form the basic assumption of fractal geometry theory which areinvestigated. The population distribution of the geological variable in question must be examined to determine the appropriateness of both fractal geometry and geostatistical modelling methods. The selection of the most appropriate method depends on the available data. A researcher or a practitioner needs to understand the strengths and limitations of the various modelling methods before choosing the most appropriate method. This study investigates the fractal properties of grade distribution using the variogram and some proposed variations as techniques to measure the fractalness. The aim is to assess applicability of fractal geometry theory to modelling ore grade distribution in a deposit. A comparison of the results demonstrates the methods which better capture the spatial behaviour of the variable under study.

Jan 1, 1995

By Zervoudis J

Limitations of current touch-up solders for galvanised steel include coating thickness control problems and poor corrosion and abrasion resistance as well as health and environmental concerns due to toxic constituents such as lead. This paper reports on progress in ILZRO-sponsored research to develop an improved touch-up solder. Encouraging results were achieved in torch soldering trials with experimental zinc-tin-based alloys. Mouldability and coating thickness control were achieved over a practical working temperature range in which the solders consisted of a viscous mixture of solid primary zinc phase particles in a liquid zinc-tin eutectic matrix. The mouldability was dependent on the microstructure of the solder sticks, and optimum structures could be obtained through control of casting solidification rates and by the addition of small amounts of copper. Hardness, abrasion resistance, adhesion and corrosion tests on experimental Zn- (40 - 50 per cent) Sn-I per cent Cu also showed improved performance over lead-tin-zinc solders and compared the effects of tin content within this range. Atmospheric corrosion testing and optimisation of alloy composition and methods of solder stick production are continuing.

Jan 1, 1993

By S Bandopadhyay

The seasonal fluctuations of the dust content in Arctic mine environments and the environmental variables affecting the intensity of dust production are qualitatively well known, but quantitative models that allow simulation and prediction of dust generation and the effects of engineering control of thermal regime on the mine environment are still non-existent. In Arctic mines, the migration of moisture in the surrounding rock mass releases fine dust by freeing it from the ice matrix allowing it to escape into mine airway. The migration of moisture is the direct cause for the production of mine dust and heat is the primary driving force. This paper examins the heat and moisture exchange between the ventilation air and the surrounding rock mass in frozen ground, placer mines in the Arctic. Based on the simulated results of a coupled heat and mass transfer problem with phase change, methods of dust control have been identified for mines in the Arctic.

Jan 1, 2005

Iron formation-hosted iron ore deposits account for the majority of current world iron ore production and consist of three classes: unenriched primary iron formation with typically 25 to 45 wt per cent Fe; martite-goethite ore formed by supergene processes, with abundant hydrous iron oxides containing 60 to 63 wt per cent Fe; and high-grade hematite ores thought to be of hypogene or metamorphic origin overprinted by subsequent supergene enrichment with 60 to 68 wt per cent Fe.Individual iron ore deposits range from a few millions of tonnes to over two billion tonnes at >64 wt per cent Fe, although most are within the range of 200 to 500 Mt. In the Hamersley Province of Western Australia, martite-goethite ores are largely developed in the Marra Mamba Iron Formation, although high (>0.08 per cent P) phosphorous mineralisation is also well developed in the stratigraphically higher Brockman Iron Formation. Whilst the vast majority of high-grade microplaty hematite ore is best developed in the Brockman Iron Formation, this paper provides the first textural evidence of locally significant microplaty hematite mineralisation in the Nammuldi Member of the Marra Mamba Iron Formation, in the Chichester Ranges at the Christmas Creek, Cloud Break and Mount Nicholas prospects. Petrographic studies have identified a high-grade Fe texture composed of nanometre scale plates of hematite in mineralised sections of primary microplaty hematite deposits in the Pilbara and elsewhere, well below the normal depth of weathering or dehydration. The population of nanometre to micrometre scale hematite plates is interpreted to represent various stages of nucleation, crystallisation and progressive growth of hematite from the primary ore-forming fluid in areas that were once iron-rich carbonates or silicates in the BIF.

Jan 1, 2005

By Butt C. R M

Resurgence in Au exploration during the past decade has been characterised by a considerable emphasis and dependence on geochemical procedures. This has been made possible, firstly, by marked improvements in analytical sensitivity over those previously available and secondly, of particular importance to exploration in Australia, by a better understanding of the distribution of Au in the regolith, which has led to the optimisation of sample media. These developments have given exploration companies the ability to seek and detect subtle and widespread geochemical signatures of concealed Au mineralisation and provided an enhanced capability to interpret the data. As a consequence, several new discoveries have been made, even in areas that have been intensively explored in the past. In the deeply weathered Yilgarn Craton (WA), and in equivalent areas elsewhere in Australia and overseas, Au has accumulated in the upper lateritic gravels and duricrusts of the regolith, probably during humid climatic periods in the Tertiary. The laterites may not only be Au ores in themselves, but research by CSIRO and CRC LEME has shown them to be very important sample media, (eg Anand and Smith, 1992). In many areas, however, the laterite has been eroded and hence is unavailable as a sample medium and chemical modification under more and conditions since the Tertiary has leached Au from the upper saprolite. This has greatly increased the difficulties of exploration, particularly where reliance was placed on sampling between 2 and 15 m of the surface. Further research, however, has demonstrated that, despite this leaching, recent remobilisation of An has caused it to concentrate in a specific soil component, pedogenic carbonate, usually in the top I - 2 m, thereby giving surface expression even to mineralisation that is concealed by over 20 in of leached overburden. Secondary carbonates, commonly referred to as calcrete, may precipitate as calcite and/or dolomite in regoliths where the average annual rainfall is less than about 600 mm. Pedogenic carbonates are those that form in unsaturated (vadose) soil horizons. They are widely distributed in the Gawler and Yilgarn Cratons. In the Yilgarn Craton south of about 30¦S ('the Menzies Line'), they are seemingly more abundant over more basic rocks and towards the south east (Figure 1). In contrast, groundwater calcretes form in saturated (phreatic) environments, typically in the axes of major drainages north of the Menzies Line. These are known to accumulate economically-significant grades of U but not, apparently, An.

Jan 1, 1997

By Allnutt S. L, Carswell J. T, Mutton A. J

The Dugald River Zn-Pb-Ag deposit occurs within the complexly deformed and metamorphosed sediments of the Middle Proterozoic Cloncurry Terrane, Eastern Succession, Mount Isa Inlier. The sedimentary sequence comprises a thick package of variably carbonatic argillitic and siliciclastic sediments of the Corella Formation, Lady Clayre Dolomite and Knapdale Quartzite. A slate and calc-argillite unit locally referred to as the Dugald River Slates is the host to the economically significant deposit. The deformational history of the Dugald River area involved three phases of ductile deformation. The present geometry of the Dugald River Main Lode is recognised as a strike extensive steep westerly dipping tabular sheet, within which a steep north westerly plunging zone of pronounced thickening is evident. This zone is interpreted to have formed during folding via remobilisation of the sulphides into a shoot-like body, the geometry of which was controlled by stretching associated with the folding. Further modification of the shoot and sulphide re-distribution has resulted from late phase transgressive shears. The sulphide mineralisation is characterised by three distinctive sulphide types, laminated, banded and breccia, the distribution of which define two broad zones. The northern zone is a narrow I - 5 m thick stratabound unit comprising finely laminated and banded sulphide mineralisation within a well bedded fine grained argillite sequence. This is part of the Lady Clayre Dolomite sequence and is a predeformational precursor form of mineralisation. The southern zone comprises the thickest development of mineralisation (up to 30 m) characterised by slate-sulphide breccias and veins derived from complex polyphase remobilisation of the sulphide mineralisation. It is this zone which forms a stratabound locally transgressive body within the high strain Dugald River Slates and which contains the main body of economic mineralisation. Sulphide mineralogy comprises sphalerite, pyrite, pyrrhotite, galena and traces of chalcopyrite, pyrargyrite, tetrahedrite, marcasite and arsenopyrite. The present resource for the Dugald River deposit stands at 38 Mt grading 13.0 per cent Zn, 2.1 per cent Pb and 42 g/t AS. The Dugald River Zn-Pb-Ag deposit is regarded as an example of a syndiagenetic stratabound sulphide accumulation which, as the result of polyphase deformation and upper greenschist to middle amphibolite facies metamorphism, has undergone extensive remobilisation and Rccrystallisation.

Jan 1, 1993