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By X Liu

The crystal chemistry of carbonate in Ca apatites, including Na-free and Na-bearing hydroxylapatite (CHAP) and Na-bearing fluorapatite (CFAP) and chlorapatite (CCLAP), has been investigated by Fourier transform infrared (FTIR) spectroscopy and single-crystal X-ray structure, using crystals synthesised from carbonate-rich melts at 1 GPa, 1400 - 1000¦C. The carbonate ion substitutes for both the X (OH, F, Cl) anion species in the apatite channel (type A carbonate) and the phosphate group (type B carbonate). The type A carbonate ion is oriented in the channel with two oxygen atoms close to the c-axis, and the type B carbonate ion is located close to the sloping faces of the substituted phosphate tetrahedron, with details varying with composition series. Sodium promotes the uptake of type B carbonate and also has a profound effect on FTIR spectra. Crystal compositions correspond approximately to the substitution formula Ca10-(y+z)Nay z[(PO4)6-(y+2z)(CO3)y+2z][X2-2x(CO3)x], with x + y up to 1.0 and z + 0.0 for CHAP, x + y + 4z + 0.4 for CCLAP, and x + y + 2z + 0.1 for CFAP, for equivalent conditions of synthesis. The sodium cation and A and B carbonate ion defects are locally coupled in all three composition series to facilitate charge compensation and minimise the effects of spatial accommodation. Synthetic Na-bearing type A-B CHAP with x + y + 0.5 has a similar chemical composition and FTIR spectrum to biological apatite.

Jan 1, 2008

By M I. Pownceby, N Karimian, J R. Manuel, M J. Peterson

The CSIRO ore classification scheme for Pilbara ores was used as a reference frame to target recognisable ore types/textures with potentially elevated phosphorus content for detailed analysis. Particles of each individual ore texture were separated from a Brockman high-P ore and each class was characterised using methods including XRF, XRD, EPMA and synchrotron-based XAS. Results were then correlated with optical microscopy and hand specimen identification to establish any relevant associated mineralogical phases and/or textures. This represents a more systematic approach to identification of high-P ore components based on particle and goethite type and texture. The information can then provide the basis for more targeted P-removal strategies factoring in the relationship between particle/ore texture and phosphorus deportment

Sep 18, 2023

By H Benzer

Grinding clinker to finished cement consumes more energy than any other comminution process. World production of cement in 2009 was 2840 million tonnes and the energy required for comminution was 40-60 kWh/tonne depending on the clinker characteristics and the fineness of the finished cement. Machines used include single and multi compartment ball mills, HPGRs, vertical roller mills, centrifugal air separators, V separators, screens and crushers. The circuit most commonly used consists of a closed circuit HPGR followed by a single compartment ball mill and an air separator, and in operation the variables are adjusted to obtain maximum throughput with no loss of quality of the separator fines.A common objective in cement plants is to reduce energy consumption without affecting the particle size in the finished cement and simulation is used as one procedure to achieve this. Models are now available for all the machines commonly used in clinker circuits and circuit optimisation studies using simulation have been carried out in many plants leading to decrease in energy consumption per tonne of cement. In this paper the models used will be discussed briefly and several case studies will be reviewed which will highlight the effect of change in ball size in a two compartment mill, the role of the HPGR in an HPGR – ball mill – air separator circuit, and the use of a high intensity vibrating mill for producing finished cement with high additive ratio.

Aug 8, 2011

By B Manda, K L. Sandvik, K Musiwa

Mining and processing of pyrite ore at Iron Duke Mine, north east of Zimbabwe, generates large quantities of acidic mine water as a result of the oxidation of iron sulfides on exposure to air and water used in the drilling and blasting operations. The acid mine drainage (AMD) contains elevated levels of dissolved Fe, Al, Mn and sulfate and has characteristic pH values ranging from about 0.50 to 3.00. Handling and disposal of such a drainage places significant impacts on the economics of the mining operation due to the corrosive nature of the drainage on infrastructure, the limitations placed on water reuse and discharge to the environment under a new law governing effluent discharge. Treated sludge at Iron Duke is chemically unstable, changing pH from ~7 to ~3 within four days after deposition in the evaporation ponds. The effluent does not meet the permitted level of neutral pH, 500 mg/l sulfate and less than 2000 mg/l total dissolved solids. Excessive acid seepage from the evaporation ponds has resulted in contamination of the ground water below the ponds area, which shows high mean annual levels of iron (368.67 mg/l), sulfate (1702.89 mg/l) and low pH (2.86) in addition to other pollutants. This poor quality seepage infiltrates into the nearby Yellow Jacket River, contaminating the public water source. Furthermore, a deterioration of the land area and vegetation adjacent to the tailings dump is also observed. Understanding the controls on the neutralisation of acidic drainage and long-term sludge stability after placement in evaporation ponds is essential to minimise costs of closure requirements and for the protection of environment and human health. This study examined the effects of the master variables pH, redox potential, acidity and alkalinity on acid neutralisation. The results indicate that ferrous hydroxides are not as stable as ferric hydroxides and that proper oxidation of iron also leads to better sludge stability, higher treatment efficiency and a manageable sludge viscosity. Metal hydrolysis and secondary mineral formation at the evaporation ponds under a wide range of pH and redox conditions is responsible for equilibrium shifts in metal reactions, resulting in high potential for metal leaching and mobility. Mechanisms of metal attenuation are also discussed.

Jan 1, 2006

The Kaltails Project is situated close to the city of Kalgoorlie-Boulder in Western Australia. Located on the south-eastern fringe of the Golden Mile, Kaltails has been in operation since June 1989. The tailings forming the reserve for Kaltails have been derived from 100 years of underground mining on the Golden Mile, but, some of the re.;erve has been retreated in the past. A map of the tailings reserves and treatment plant site is presented as Figure 1. The gold project is a joint venture between Poseidon 90 per cent and Gold Corporation (ten per cent) and is managed by Poseidon Gold Kaltails.

Jan 1, 1992

By Y L. Ma, M Chen, W Bruckard

With the extensive exploitation and gradual depletion of high-grade copper reserves, the mining industry is paying more and more attention to the hydrometallurgical extraction of copper from lowgrade and arsenic bearing copper ores. Hydrometallurgical processing, such as heap leaching, column leaching and bioleaching, provide a viable alternative to the traditional pyrometallurgy due to its harmony with the environment, moderate capital investment, and low operating costs. However, the slow leaching kinetics of enargite (Cu3AsS4) and chalcopyrite (CuFeS2) remain problematic for commercial leaching practice. The formation mechanism and the nature of the passivating layers during leaching is still a matter of debate in hydrometallurgical research. In this study, the dissolution mechanism of enargite and chalcopyrite in sulfuric acid solution was investigated using a range of electrochemical and spectroscopic analysis methods. Electrochemical oxidation of enargite demonstrated an obvious passivation region from 500 to 750 mV (Ag/AgCl). The formed passivation film was found a n-type semiconductor behaviour, which is different from the original enargite with a p-type behaviour. The results of X-ray photoelectron spectroscopy (XPS) suggested that a nonstoichiometric film Cu(3−x)As(1−y)S4 (x>>y) accumulated on the electrode surface, which accounted for the obvious decrease in current density in the passive potential region. For chalcopyrite, three important potentials of 550, 680 and 730 mV which are related to the formation and dissolution of passivation film were observed based on the cyclic voltammetry (CV) and potentiodynamic polarisation. Raman and X-ray absorption near edge structure (XANES) spectra studies of the chalcopyrite electrodes after being treated under these three potentials indicated a metal-deficient sulfide of Cu1−xFe1−yS2 (y>>x) might be responsible for the passivation phenomenon. Hence, it is concluded that the passivation of enargite and chalcopyrite are similar which are caused by metaldeficient sulfide surfaces although the compositions of the metal-deficient sulfide are different.

Aug 24, 2022

The mining industry is quite often faced with declining selling prices for its products in the face of rising prices for the input cost resources that it uses. Blasting is a key activity within the mining system and has a vital role to play within the Mine to MillTM concept. It is therefore important that blasting makes a positive contribution to mine profit and productivity. There are several variables involved in considering the profitability and productivity of blasting. The rock types and structures, the bench height, the blast hole drill rig specifications, hole diameter, spacing and burden, explosive loading and initiation and blast size fragmentation. Productivity accounting is a methodology which is used elsewhere to give additional insights into the productivity and pricing factors that drive the financial performance of a business. Miners know intuitively that productivity and pricing influence costs and profit, but only with productivity accounting can the dollars involved be calculated. Drilling and blasting are part of a chain of unit operations in a mine. For an owner-miner, drilling and blasting would be considered as cost centres and a productivity accounting cost model approach would be relevant. On the other hand a contractor is likely to consider drilling and blasting as a profit centre, in which case a productivity accounting profit model approach would be appropriate. Both of these will be explained. The paper provides a basic outline of deterministic productivity accounting and demonstrates its application to blasting. Drilling and blasting data from a mine was obtained for a two-month period. The change in productivity and prices was calculated to obtain the dollar contributions from them towards the change in cost. It was determined that although there had been productivity dollar gains these were offset by larger pricing dollar losses, the net effect being that total drilling and blasting costs increased. The productivity accounting analysis gives the facts and the mine is in a position to establish priorities based on knowing the dollar contributions of each input used.

Jan 1, 2001

By A Gerson, S Miller, R Smart, J Thomas

Environmental Geochemistry International (EGi) and the Ian Wark Research Institute (IWRI) collaborated in a three-year Australian Minerals Industry Research Association (AMIRA) research project (Project Number P387A) focussed on the prediction and kinetic control of acid mine drainage. As part of this project, single addition, and sequential net acid generation (NAG) testing was carried out on sulfide mineral samples. The test samples comprised a range of synthetic waste materials prepared using a quartz bulk and controlled quantities of the commonly occurring sulfide minerals; pyrite (FeS2), pyrrhotite (Fe7S8), arsenopyrite (AsFeS), chalcopyrite (CuFeS2), chalcocite (Cu2S), covellite (CuS), bornite (Cu5FeS4), galena (PbS) and sphalerite (ZnS). NAG test results clearly show that there are significant differences between the acid forming potential of sulfide minerals. The NAG test results for each mineral were compared with theoretical acidity values (NAPP*). The NAPP* calculation was based on stoichiometric oxidation reactions assumed for each of the sulfide minerals. Sequential NAG values for pyrite corresponds closely to predicted NAPP* values, confirming the assumption that pyrite oxidation occurs according to the stoichiometry assumed. For the pyrite sample with 5 wt per cent S, two NAG stages were sufficient for all of the sulfur to be released to solution. Since sulfides in waste materials will generally be dominated by pyrite, results also confirm the validity of including NAG testing for ARD evaluation of most waste rock. NAG testing confirms that of the sulfide minerals examined, only pyrite, pyrrhotite, arsenopyrite and chalcopyrite are acid producing, ie able to produce leachate with a pH less than 4.5. In the case of sphalerite, galena, bornite, chalcocite and covellite the pH of the final NAG solution was greater than 4.5. The significant differences between the acid forming potential of different sulfide minerals could lead to overestimation of acid producing potentials based on NAPP values calculated from total per cent S alone, ie assuming all S is present as pyrite. The oxidation of galena during the NAG test resulted in the consumption of acid. The examination of the galena surface by X-ray photoelectron spectroscopy (XPS) after oxidation in peroxide solution indicated the presence of polysulfide. The reaction of sulfide to polysulfide is acid consuming, thus explaining the net acid consuming behaviour of galena in the NAG test. This reaction pathway may provide a possible explanation for the lower than expected acid production observed for some of the other sulfide minerals examined.

Jan 1, 2003

By A Tawadrous, D S. Preece

Cave mining is of interest to the mining community as it offers a chance to extract large, deep orebodies with low operating costs and high production rates. It allows for extracting large low-grade orebodies, which may not have previously been considered for mining. Cave mining is done either top down (ie sublevel caving) or bottom up (ie block/panel caving). Both approaches rely on gravity, stresses and weakness of the rock to fracture and achieve a controlled collapse.Block caving starts at the base of the orebody. It progresses upward and across through continuous collapse of the roof. To achieve this, a critical hydraulic radius must be exceeded. This is accomplished by blasting drawbells, through which the caved ore passes to the production level. An entire level above the drawbells (undercut level) is excavated to help initiate the cave. The undercut level ensures the connection between drawbells and achievement of the required hydraulic radius.Conventionally, drawbells are generated by drilling and blasting several times from the production level as well as the undercut level. Mucking between each shot is required to generate enough void space for the rock to swell. The need for several blasts necessitates some downtime between each blast. Also, the cost of developing and maintaining the undercut level can constitute up to 35 per cent of the cost of mining the panel.A new blasting technique was developed to create the drawbells in a single blast from the production level. The technique ensures the connection of the drawbell to the neighbouring ones, thus, the critical hydraulic radius is reached and propagation of the cave achieved without the need for the undercut level. The technique has the potential to reduce the capital cost of a block caving operation, increase its feasibility and reduce time to reach the ore and consequently the payback period. This paper presents the modelling of a traditional drawbell excavation process, the philosophy of the developed technique, the modelling of that new design and its implementation.CITATION:Tawadrous, A and Preece, D S, 2015. A novel blasting technique to create drawbells and eliminate the undercut level in block cave mining, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 617–624 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

A laboratory investigation was carried out to obtain data on the explosive character- istics of selected coals mined in New South Wales. Seven coal seams were sampled and the volatile matter content of the coals tested varied between 28 and 37 percent. A mod- ified Hartmann apparatus with a volume of 1250 ml was used in the investigation. Dust clou' generation was produced by an air blast delivered radially through a mushroom type valve and the ignition source was a-continuous A.C. spark produced by a 20 000 V, 50 mA transformer. The coal dust parameters invest- igated were the maximum pressure developed, the average and maximum rates of pressure rise at dust concentrations between 200 and 1500 3 g/m.

Jan 1, 1981

By K J. Davey, J T. Woodcock

Australian steelmakers produce up to 30 000 t/yr of electric arc furnace (EAF) dust. Current disposal techniques include sending EAF dust to landfill, stockpiling, and paying zinc smelters or registered waste removalists/processors to take the dust. Many of the complex overseas pyrometallurgical and hydrometallurgical treatment routes cited in the literature are not considered economic. Governmental, environmental and social pressures on producers to consider more sustainable disposal options are mounting, and there is now a strong push to consider recovering potentially valuable or recyclable components, such as zinc and iron units, from EAF dust. As well, there remain strong economic drivers for producers to find lower cost disposal solutions. Characterisation studies undertaken at CSIRO Minerals have revealed important physical differences in the nature of the zinc- and iron-bearing phases contained in domestic EAF dusts. These differences have been exploited using simple and cheap mineral processing techniques such as water washing, wet cycloning and wet magnetic separation. This has allowed a significant upgrade in the zinc content of EAF dust to be achieved, together with a reduction in the levels of key smelter penalty elements, such as chlorides and fluorides. The zinc-rich portion of the dust is now a more attractive smelter feed while the iron-rich part of the dust could potentially be briquetted or pelletised with a reductant and recycled to recover iron, and thus close the loop on dust processing. The basis of the separations tested together with laboratory results from several Australian dust samples are presented and discussed in this paper.

Jan 1, 2006

By K J. McDonald

All commercially available zircon sands contain radioactivity sourcing from the decay of trace amounts of contained uranium (U) and thorium (Th). The fine particle size zircons of the Horsham area in the Murray Basin region of Victoria, Australia, contain significantly more (about twice) Th+U than those commercial zircon sands. The marketability of these fine-grained zircon sands is likely to rely on the removal of these radioactive impurities. CSIRO Minerals have been working for some time to develop processes for the removal of the radioactive impurities from zircon. It is generally agreed that it is quite impossible to leach U and Th from zircon, however, the Heat and Leach (HL) process, described in detail in Aral and McDonald (1999), reduces the radionuclide levels significantly. The identified (HL) process aims to leach uranium and thorium selectively from a decomposed zircon. The novelty of the process is that a large part of the leached product can be reconstituted to a low radiation zircon by a subsequent heat treatment. The HL process uses a flux mixture of sodium carbonate and calcium borate to decompose the zircon at relatively low temperatures (900 to 1150¦C) and a weak acid (0.5M HNO3; 80¦C/0.5 h; pulp density ten per cent) to leach the radionuclides selectively. The process leaves the major components (ZrO2 and SiO2) behind with little loss. The HL process for example lowers the U+Th content of a Murray Basin zircon from 1000 ppm to 400 ppm U+Th. Among the radionuclides more U progeny is removed than the Th series radionuclides. This is very significant as the radioactivity of U series is 2.5 times more that from the Th series. Therefore the reduction in the radioactivity level of zircon is more than the reduction in Th+U indicated by XRF analysis. A schematic flow sheet of the HL process is shown in Figure 1. Although the HL process successfully lowers the radionuclide levels in zircon sands, the final product contains significant amounts of sodium (up to 14 per cent Na2O) and small amounts of CaO. By comparison, the sodium content of the commercial zircon sands is in general 2O. Zircon is used mainly as an opacifier in tile glazing where the addition of ten to 15 per cent zircon to a translucent base glaze gives the sanitary white colour to the tile surface. Opacification is the result of the refractoriness of zircon particles at the glaze firing temperatures that is generally around 1050¦C.

Jan 1, 2001

By S Nkwanyana, I Govender

Batch experiments in a 0.6 m diameter mill have shown that improvements of about 13 per cent in the efficiency of energy utilisation can be realised in ball mills by replacing 25 per cent of the ball charge by an equivalent volume of cost-free critical size pebbles from AG/SAG mills. For a mill of a given size, speed and charge filling, the rate of size reduction of ore particles depends on (i) the frequency of grinding media collisions (ii) the probability of capture of ore particles between the colliding grinding media (iii) the probability of fracture of the captured particles. The probability of fracture depends on the magnitude of collision energy. The distribution of collision energy into shear and impact events determines the relative strengths of attrition breakage and impact breakage. The efficiency of energy utilisation depends on which of the two mechanisms of breakage is more desirable in a particular milling stage. In this paper collision data from a series of DEM simulations of a mill charged with steel media and a mixture of steel media and pebbles is presented in energy spectra and spatial distribution maps. The data provides the necessary detail to elucidate the improvements in the efficiency of energy utilisation in ball mills when using a mixture of pebbles and steel media.

Aug 24, 2022

By G M. Evans, C M. Phan

This paper presents an analysis on the dynamic adsorption of frothers and collectors onto air bubbles in flotation. The analysis was carried out using the theory on the surfactant transfer by diffusion and adsorption. The bubble size was considered when solving the diffusion equation for the dynamic surface excess. The adsorption kinetics was modelled employing the Langmuir adsorption isotherm and its extension with the inclusion of the lateral interaction of the adsorbed molecules (the Frumkin adsorption isotherm). The numerical computation was applied to solve the governing equations. The dynamic adsorption of the surfactants was measured in terms of the dynamic surface tension for sodium dodecylbenzene sulfonate (SDBS) and Dowfroth 250, using pendant bubble tensiometry. The results show that for air bubbles with diameter of the order of 1 mm, the bubble size effect on the dynamic surface tension is small and the solution of the diffusion equation for a planar gas-liquid surface can be used to describe the dynamic adsorption onto the air bubbles. The experimental data obtained with SDBS were well described by the Frumkin adsorption isotherm and the molecular diffusion. The model description for the experimental data obtained with Dowfroth 250 required the kinetic equations. The paper is relevant for further analysis of the role of the adsorbed surfactants in the particle collection.

Jan 1, 2005

By R F. Sandenbergh

Due to environmental considerations, mineral processing plants are increasingly recycling water to decrease the impacts of wastewater on environment and the depletion of fresh water resources. Industrial experience has shown that increasing recycling water in flotation typically negatively impacts the recovery and selectivity, especially in the selective flotation of minerals from complex sulfide ores. The major reason for the reduced selectivity is typically the inadvertent activation of sphalerite or pyrite by the heavy metal ions (HMI) in solution. These HMI are often produced during milling and flotation and absorbed by other minerals. In the normal flotation pH value range (8 - 10), these HMI are often in the form of precipitates or complex ions that may re-appear in solution or become active should conditions favour this. In this paper, microflotation, batch flotation and XPS surface measurement were used to investigate the use of HMI absorbents additions to the pulp to improve flotation selectivity of a complex sulfide ore. It has been demonstrated that HMI removal does improve flotation selectivity by facilitating more effective depression of the sphalerite. Microflotation and XPS surface measurements have shown that HMI absorbents compete with sphalerite to absorb HMI, and thus reduce the surface concentration of HMI on those sulfides. The practical use of HMI absorbents in complex sulfide ore flotation is also discussed.

Jan 1, 2005

By A Black, A de Jo, J Cavanagh, J Harding

Acidic and metal-rich waters have been discharging from Sullivan Mine, West Coast, New Zealand since the closure of the mine during the early- 1990s. This has resulted in a decrease in pH from a background of 4.5 to 2.8 and an increase in metallic elements in nearby Rapid Stream. In addition to the chemical effects on Rapid Stream, a study of freshwater macro-invertebrates revealed the absence of most biota downstream from the discharge. An attempt is being made to use the Sullivan Mine as a case study of problem and remediation analysis.

Jan 1, 2003

By Stephenson D. B, Burgess J, Burgess F. L, Marshall S. H

A new high intensity flotation process 'FASTFLOT' is explained and its theoretical advantages compared with other flotation systems are discussed. The results of initial FASTFLOT testing on the zinc roughing circuit at Pasminco Mining, Broken Hill South concentrator are presented and compared to recent plant data. The comparison suggests that on roughing duties, the FASTFLOT process yields superior concentrate grade while requiring less than one third the residence time of a conventional mechanical cell plant. Strategies for FASTFLOT deployment are also presented.

Jan 1, 1994

By Kelly D, Moore C

The Golden Mile, which has been mined continuously for the past 100 years by both underground and more recently open pit methods, occupies an area of 1.2 km by 4 km adjacent to the city of Kalgoorlie Boulder in Western Australia (Figure 1). Large-scale open pit mining at the Kalgoorlie Consolidated Gold Mines (KCGM) Fimiston operations is currently extracting 7.8 million tonnes of oxide and sulphide ore for a total production of 522 000 oz per annum. The effectiveness of grade estimation techniques at KCGM has been examined with reference to existing 10 m bench sample data from all operating areas within the Eastern Lode System of the Main and North pits. The aim of the study was to recommend practical parameters for grade control estimation. The review included comprehensive variography and comparison of nonparametric estimation methods (Joumel, 1983) such as indicator kriging and probability kriging with ordinary kriging, leading to the development of improved grade control parameters and procedures for both daily quality control and short term mine planning. This paper reviews the geological, statistical, geostatistical, mining and modelling features studied in order to present KCGM's Mining Department with recommendations for improving grade control.

Jan 1, 1994

By R-H Yoon

A turbulent flotation model has been developed by considering the subprocesses of collision, attachment, detachment, and froth recovery. AbrahamsonÆs model (1975) of infinite Stokes number is used to model collision, while the attachment and detachment subprocesses are modelled by considering the kinetic energies required to overcome the energy barriers and the work of adhesion, respectively. The energy barriers are determined by considering various surface forces, including electrostatic, dispersion and hydrophobic forces, while the kinetic energies are determined from the particle velocities at close separation distances from air bubbles. The latter has been determined by modifying the turbulent root-mean-square (RMS) velocities of Liepe and Moeckel (1976) and Schubert (1999) in view of a lubrication theory. In calculating the RMS velocities, it is assumed that a flotation cell is subdivided into low and high energy dissipation zones. The model predictions made by varying various hydrodynamic and surface chemistry parameters are consistent with flotation practice.

Jan 1, 2005

An automatic control system of a longwall roof support is dis-cussed. Hydraulic automatic control systems for longwall roof support have not met all requirements for such systems. Utilization of standard hydraulic elements to form a system that would-comply with all demands leads to a very complicated structure with a large number of hydraulic hoses within and between adjacent supports. So, only simplified systems have been made. This paper describes the multifunctional valve that per-mits realization of any desired logic functions, while maintaining a com-pact form, and analyses its application as a fully hydraulic automatic control system of a roof support.

Jan 1, 1985