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By Jon J. Kellar

The adsorption of oleate at the surface of a fluorite single-crystal internal reflection element has been investigated using Fourier transform infra-red/internal reflection spectroscopy (FTIR/IRS). The application of this innovative experimental technique has added a new dimension to the investigation and understanding of collector adsorption phenomena. It is now possible, for the first time, to measure in-situ and in real time the adsorption density and bonding nature of collector species adsorbed at mineral surfaces. In this regard, oleate adsorption densities were calculated from spectral data, and the equilibrium adsorption isotherms were found to agree quite well with other adsorption isotherms reported in the literature. At low equilibrium oleate concentrations(<10-5 M), monolayer-type cover-age was observed in the chemisorbed region. It was found that in this region the adsorption density increases with an increase in temperature, which sup-ports experimental results from previous ex-situ FTIR studies and thermochemical studies in which it was shown that the chemisorption reaction was endothermic. At higher equilibrium oleate concentrations (>10-5 M), the adsorption density increases dramatically at the point of surface precipitation. The oleate adsorbed in the chemisorbed region has a distinctly different spectrum than the oleate adsorbed in the surface precipitation region of the adsorption isotherm. In the chemisorbed region, the oleate appears to be mono-coordinated at the fluorite surface.

Jan 1, 1989

By S. Formby, J. Avraamides

Transportation of sodium cyanide from factory to minesite often attracts adverse comment from both the community and government agencies. In Western Australia the transportation of 30% w/w aqueous sodium cyanide solution raised fears in the community concerning the safety of such material in the event of spillage. The Chemistry Centre of Western Australia initiated a study of the effects of such a spill, to determine appropriate short and long term response strategies. Factors which were considered included the rate of hydrogen cyanide gas release under various climatic and soil conditions and the effect of alternative treatments in reducing such emissions. The data collected have been used to plan emergency response procedures.

Jan 1, 1989

By V. R. Voller

The WTBAL computer program for evaluating material balances for minerals processing flowsheets was developed at the MRC and has been in general use for a number of years. This paper reports on two enhancements to the basic MTBAL routine. The original program accounted for errors in the process measurements and used estimates of measurement variability to calculate stream weights. Unfortunately, the estimate of measurement variability was fixed over all streams. In the enhanced version of MATBAL, named IMTBL, the program equations and their solution procedure have been modified to allow the estimated variability in a process measurement to vary from stream to stream. The .second enhancement involves making MTBAL interactive. As such, the user now prescribes his information in an easy-to-use fashion in a conversational mode via a terminal. Finally, an assessment of the feasibility of implementing IMTBL on microcomputer systems will also be reported.

Jan 1, 1982

By S. N. Groudev

Intensive uranium mining activities at the Curilo deposit in Bulgaria has caused widespread contamination over a wide area. A number of receptors including soils and watercourses as well as the ecosystems in the area have been severely affected. Even today, 10 years after the cease of activities, acidic waters generated from the abandoned mining works, the low-grade ore and waste dumps contaminate soil, surface- and groundwater. The present paper describes in general the environmental status of the wider Curilo area and examines the potential of preventive and remedial measures that can be applied in situ to rehabilitate the site and restore the ecosystem. The main rehabilitation technologies examined include modification of the acid generation potential of the pollution sources, treatment of the acidic drainage by means of a natural wetland and in situ bioremediation the of contaminated soils. Finally, a number of efficient indicators are proposed so that the rehabilitation potential at Curilo and similar heavily contaminated sites is assessed.

Jan 1, 2003

By David Humphreys

Assumptions about future commodity prices need to be made with close regard to the purposes for which they are being used. Prices generated for financial planning or trading purposes are unlikely to be suitable for the longer run purposes of project evaluation and reserve estimation. In this latter context, price assumptions need to be realistic, stable and rooted in a rigorous fundamental analysis of long run industry drivers. Amongst the factors to be considered in such analysis are price history, production costs and structural dynamics. It is also important that prices adopted are consistent with other information being used by a company in its decision-making.

Jan 1, 2003

By C. Villa Diniz, A. H. Martins, Fiona M. Doyle

It is proposed that battery grade MnO2 can be produced directly from a manganese ore from Azul Mine in Brazil, by leaching with HCI to remove heavy metals selectively. We are working to find a way of selectively separating Cu, Ni, Co, Pb and Fe from the resulting acidic manganese chloride solution, to detoxify it and produce marketable chloride solution. Chelating ion exchange resins are proving more promising for this separation than solvent extraction with commercially available reagents. Results from batch and column ion exchange tests that characterize the behavior of copper, nickel, cobalt, lead and iron are reported.

Jan 1, 1999

By R. Codell, D. L. Hughson

The authors benchmarked the integrated finite-volume code MULTIFLO against the analytical solution of Philip et al. (1989) for cylindrical underground openings. They found that the numerical simulation of dripping threshold flux was consistently higher than the analytical solution for rectangular and unstructured grids. The magnitude of this error was proportional to the alpha parameter characterizing capillarity. This error may bias estimates of seepage into drifts for repository performance towards nonconservatism.

Jan 1, 2002

By Li Honggui, Liu Maosheng, Zhao Zhongwei, Sun Peimci, Li Yunjiao

Leaching of Shizhuyuan low-grade refractory tungsten ore was carried out in a mechanically activating reactor. The effect of experimental parameters-temperature, amount of Na2C03, addition of NaOH, ratio of liquid to solid and leaching time - on the recovery of WO3 was studied. The WO3 recovery up to 96.99% have been achieved when the tungsten ore was digested by soda not more than three times the stoichiometric amount at 185-195°C for 1 .O-2.0 hours. Iso-extraction countour diagrams were drawn to illustrate the effect of various parameters on leaching. The WO3 recovery could be expected to increase 10-15% compared to that of conventional soda autoclave process.

Jan 1, 1995

By P. Worley

With Utah Power & Light Mining Division&apos;s commitment to operate the safest and most productive mines possible, a decision was made to purchase and install mine-wide monitoring systems for use in the mines. After review of several different systems the Conspec Senturion 200 system was chosen. Three separate systems were ordered to fulfill the monitoring requirements of the six mines in operation: one system for the Deer Creek Mine one for the Wilberg/Cottonwood complex, and one for the Deseret, Beehive and Little Dove complex.

Jan 1, 1989

By R. Reifsnyder, J. LaRosa Thompson

Slurry or slimes dispersion is a critical factor controlling the efficiency of sulfide mineral comminution and concentration operations. The PQ Corporation has conducted innovative sodium silicate-based studies to determine the effects of enhanced dispersion on whole ore grinding and flotation behaviors and on downstream separation and cleaning steps. The work has advanced the understanding of the role of pulp rheology on the optimization of commercial grinding, agitation leaching, and flotation operations. This paper reviews the role of sodium silicate as a selective wetting agent and surface charge modifier in sulfide mineral systems, and discusses the results of silicate experiments conducted on various ores of copper and molybdenum, gold, platinum-palladium, and copper zinc, all of which contain clay minerals or highly floatable gangue constituents.

Jan 1, 2002

By Mary Korpi

So now you ask, Where are the transcripts? The well-organized co-chairs, Harry and Mary, did their job. Doug Halbe was active in the audience encouraging people to speak up and keeping everything moving along. So where are they? Were the comments so provocative that they could not be written? Was the profanity so bad (even for miners!) that it couldn&apos;t be repeated? It appears that at the first session of the Plant Operators&apos; Symposium a glitch occurred with the recording equipment. Thanks go to everyone who did comment during the dis- cussion period. The People I session had a lot of lively conversation and we are sorry that it will not be printed. However, there is now another reason to hold the plant operators&apos; sessions on a regular basis! Another People session can and will be held in the future.

Jan 1, 1998

By T. Stuczynski

In the past ten years about 3000 wastewater treatment plants have been built in Poland. The result of this development has been a massive increase in overall sludge production. According to data supplied by the Ministry of Environmental Protection, 400,000 dry tons of sludge are generated every year in Poland (Koblak-Kalinska 1996). Still it is difficult to estimate the amount of sludge, which is used in agriculture or for reclamation purposes. However, it can be assumed that this comes to no more than 10 percent of all sludge produced in Poland on a yearly basis. Thus it became obvious that an urgent solution to this problem was needed. Local authorities in Silesia realized in the early 90?s that a demonstration was necessary to encourage the proper utilization of sludge. This was the basis for establishing the Biosolids Subpart of the Silesia Project, which addressed the use of biosolids in the reclamation of mining and smelting dumps (Stuczynski et al. 1996). Metal waste sites themselves are known to contain more than 87 million tons of waste (Pistelok et al. 1995). Each year this amount increases by approximately 400,000 tons. We realized that a simple solution for stabilizing these sites would be to cover them with vegetation in order to reduce leaching of toxic elements, as well as to keep metallic fugitive dust from entering the environment. The reclamation of smelter waste sites, which was carried out within the framework of the Silesia Project was a joint effort of local government, industry and international research institutions/agencies, including the US Environmental Protection Agency (EPA), the Center for Research and Control of the Environment (OBIKS), Virginia Polytechnic Institute and IUNG. One of the goals was to evaluate the possibility of adapting the rules of sludge management currently used in the United States to conditions commonly found here in industrial regions of Poland. However, the main objective of the Silesia Project was the development of guidelines concerning all aspects of sludge use for the reclamation of degraded lands and waste sites. Biological aspects related to reclamation of metal waste with the use of biosolids will be discussed in this paper.

Jan 1, 2002

By Raymond E. Blair

Introduction Mining and minerals transportation spans the distance from the pit face and mine wall to the consumer. This transportation can be as simple as coal transfer from the mine and preparation plant by conveyor to a mine mouth electric generating plant. Or it can be as complex as copper ore transportation: concentrated, smelted, refined; drawn into wire and insulated; and cut into reels and transported to local industrial supply houses. The route of aluminum from the bauxite pits to the supermarket shelf in the form of household food wrap is another example of the potential complexity of minerals transportation. For perspective, however, mine to market minerals transportation can be split into three components: materials handling, transportation, and distribution. It should also be recognized that each mineral, market, producer, and consumer has unique transportation characteristics regarding costs, transportation mode, and alternatives in the transportation scheme. Some obvious considerations are the number of producers and consumers, the number of markets and customers the mineral serves. Concerning the latter, are you selling a million tons to one customer or a ton each to a million customers? Transportation volume About the only generalization that can be made about minerals transportation concerns the large volume of materials involved. No other industry compares to the mining and minerals industry in its huge movement of product in the crude, semi-processed, processed, fabricated, and converted states, as shown by the accompanying table of US mineral production. Whether it is crushed stone or sand and gravel moving by truck to a local market from local producers, or coal moving by 9.07 kt (10,000 st) unit trains from a mine to a power plant, or iron ore moving by lake vessel from the upper lake ports to the lower lake steel mills, mineral transportation volumes are huge. The nature of production and consumption affects the transportation mode. More than 60% of the coal moves by rail. The majority of iron ore moves by lake vessel. Ninety per cent of the sand and gravel and more than 80% of crushed stone moves by truck. Factors Affecting Minerals Transportation Some would define minerals transportation as the cost and route to move a mineral product from the first point of sale to the first point of consumption. This definition does not recognize that there can be many

Jan 10, 1982

By K. F. Hollberg, D. Graehl, L. Despain

OCI Wyoming&apos;s recent expansion of its surface Soda Ash production facilities outstripped the mine&apos;s ability to supply Trona ore necessitating infrastructure changes to the mine. A computer simulation of the mine&apos;s production systems along with the surface facilities was created to determine the most economic investment alternatives to increase mine production. This paper describes the development of the simulation model; the results obtained, and discusses the issues involved in using simulation modeling for mine production system design.

Jan 1, 2002

By R. S. Dennen

A ground penetrating synthetic pulse radar system has been used by the Bureau of Mines to probe into a coal pillar to locate hidden structures or anomalies. Two types of velocity tomographic reconstruction methods, direct matrix inversion and iterative, were used to obtain a velocity image of the interior of the pillar. The reconstructed image showed the existence and location of a relatively low velocity material within the pillar. Core samples were taken from the pillar in a region surrounding the low velocity material. Analysis of the cores showed the presence of a clay vein coinciding with the low velocity material imaged in the tomogram.

Jan 1, 1989

By M. Sagisaka

The purpose of this study is to obtain carbon dioxide emissions by copper production systems and quantitative merit to use copper scraps in Japan. Electrolytic copper and sulphuric acid originating from the refining gas are produced in the system. In this study, the inventories such as the fuel consumption of the unit processes and the in-house electricity generation were obtained from published papers and public statistical data. The following observations were made based on the Life Cycle Assessment (LCA) method: (1) Carbon dioxide emissions from the production of electrolytic copper and sulphuric acid in the system are about 1.0 kg and 0.4 kg/kg-product respectively. The carbon dioxide emissions attributable to the transportation of copper concentrate correspond to 20% of the total emission. This emission is higher than that of zinc because the metal content in the concentrate is lower than zinc. (2) The carbon dioxide emissions from the system decrease with the recycling of copper scrap to the converting process because the consumption of copper concentrate is reduced. The reduction is estimated to be 0.18 kg-CO2/kg-Cu at the point of 0.1 kg-scrap/kg-blister Cu. This corresponds to 9% reduction for the present system. However, this recycling leads to the decrease of sulphuric acid by 450x103 tonne at the point. The recycling of scrap should be evaluated not only from the reduction of carbon dioxide emissions, but also in terms of sulphuric acid demands as well as advantage of waste management.

Jan 1, 2003

By J de Cuyper, G. Rinelli, A. M. Marabini, V. Alesse, W. Freyberger

Salicylaldehyde, a chelating agent for tin, has been found to function as a collector for the flotation of cassiterite. Infrared and nuclear magnetic resonance studies clearly show that salicylaldehyde can form a chelate compound in bulk and at the surface. Results are also given for the flotation of a tin ore with this reagent.

Jan 1, 1976

By Peter Keppler, Stephen D. Bundy

"Due diligence" is a review or audit of a facility or business to assess and quantify risks and operating status before an acquisition. Due diligence findings can be used to negotiate the price, general terms, and indemnification provisions in the purchase and sales agreement. In addition to assessing out- standing liabilities, necessary capital improvements, and the adequacy of operating budgets, due diligence should include "nontechnical" considerations, such as local community acceptance and relations, and the effect on the company&apos;s public image and operations. This paper will discuss how these considerations can be addressed in the due diligence process and factored into the transaction. Also, innovative means for risk reduction and risk transfer, during and after the transaction, will be discussed.

Jan 1, 2001

By Vanessa M. Torres, Renato S. Costa

This work presents the experience of Cia. Vale do Rio Doce in using Diagnostic Leaching tests to characterize refractory ores and CIP tailings. With the diagnostic leaching results of the highly refractory gold ore from Maria Preta Mine (Brazil), a process flowsheet was defined for a feasibility study of possible process modification on the existing plant. With CIP tailings from its Fazenda Brasileiro and Caué operations the amount of cyanidable gold was determined to aid plant optimization.

Jan 1, 1995

By Eric Forssberg, Benny Andreasson

The paper describes experiments to stabilize mineral processing waste materials for use in construction. Fine mineral processing wastes from various mines have been mixed with binders and compacted. As binders blast furnace slag and other materials have been used. Experiments have been made in laboratory scale and in large scale. The results have been evaluated by means of determinations of compression strength and the modulus of elasticity. The paper also describes some experiments in laboratory and large scale to use stabilized mineral processing wastes for back filling in cut and fill mining.

Jan 1, 1992