Search Documents

By Richard A. Brown, Robert D. Norris

By-product metals can be a significant source of revenue for a mining operation if their recovery can be accomplished without negatively impacting primary metal recovery. The main problem encountered in separating primary and secondary metals is to selectively control the solubility of the individually important metals with¬out affecting their ultimate recoverability As a class of hydrometallurgical chemicals, peroxygens have a versatility which permits the selective recovery of individual metal species. Peroxygens function as more than simple oxidants. They are effective solubility control agents and have proven utility in complexation, precipitation, dissolution, extraction, oxidation and reductive processes Peroxygens have been used commercially to recover by-products vanadium, uranium, molybdenum, and cobalt and have proven experimentally to recover rhenium, gold, silver, manganese and zinc

Jan 1, 1983

By D. Raicevic

The presence of residual uranium and other radionuclides in the uranium mill tailings are posing a continuous health concern to the surrounding environment. The slow generation of sulphuric acid from residual sulphide minerals is the cause of persistant dissolution and discharge of many metallic components of the tailings. The most effective long term solution to these problems would seem to be to produce chemically stable tailings. This paper describes two possible answers to the objective: (1) Removal of radionuclides and pyrite from tailings by mineral dressing techniques; some 60 - 68% of the residual uranium, 70 - 75% of the radium, 60 - 65% of the thorium and 95 - 98% of the pyrite have been rejected from the Elliot Lake tailings. The decontaminated tailings contained 0.003% uranium, 50 - 60 pCi/g radium226, 0.01% thorium and less than 0.1% sulphur as pyrite. (2) Preconcentration of radionuclides and pyrite by beneficiation from Elliot Lake ores prior to leaching; applying this approach about 97% of the uranium, 95% of the radium, 92% of the thorium and 98.5% of the sulphides were concentrated in a radionuclide and pyrite concentrates comprising 25% and 8% of the ore, respectively. The preconcentration tailings (waste) produced contained 0.004% uranium, 20 - 25 pCi/g radium226, 0.005% thorium and less than 0.1% sulphur as pyrite. Economic and environmental advantages of both approaches and the leaching of the concentrates are also discussed.

Jan 1, 1980

By Claude Hébert

The Grenville structural province, a 400 km-wide belt of Precambrian metamorphic rocks which crosses the province of Québec in a northeasterly direction, is the host of several wollastonite occurrences. Most of these are found in marble and calc-silicate rocks enclosed within or located near intrusive bodies. Reconnaissance and detailed mapping of such zones have helped to identify areas of interest for wollastonite exploration. The most important zone is located in the huge Lake Saint-Jean anorthosite massif in the central part of the Grenville. A recent geological mapping project has revealed the presence of wollastonite in metasedimentary faulted remnant of the roof. The main occurrence consists of diopside and wollastonite in a zone at least 3 km long and 150 m wide. Preliminary sampling suggests and average grade of 50 percent wollastonite with an aspect ratio of 151. Other wollastonite deposits occur in the western part of the Grenville, mainly north and west of Montreal, where the Morin anorthositic complex and a large syenite mass intrude the metasedimentary rocks of the Grenville Supergroup. Marble bands with up to 70 percent wollastonite occur locally at the southern margin of the complex or as an inclusion in the syenite. Significant wollastonite occurrences have recently been found in the eastern part of the Grenville. One of them is located in metamorphosed calcareous rocks which are part of the granulite facies Manicouagan metamorphic complex. A representative sample analyzed 54 percent wollastonite. Farther south, an inclusion diopside-wollastonite gneiss containing an estimated 40 percent wollastonite occurs at the margin of the Pentecôte River anorthositic complex.

Jan 1, 1995

"Foreword by Lisa SchlinkSuperintendent, operations, Freeport-McMoRan Inc.,Green Valley, AZ, USAThe sixth annual Student Poster Contest hosted by the Mineral & Metallurgical Processing Division of the Society for Mining, Metallurgy & Exploration was held during the 2015 SME Annual Conference and Expo in Denver, CO. The contest had another record-breaking attendance of 31 entries: 27 graduate and four undergraduate. The universities represented were: Colorado School of Mines, South Dakota School of Mines and Technology, University of Kentucky, University of Utah, Southern Illinois University Carbondale, University of Wyoming and West Virginia University.The competition began with an extended abstract review by a panel of judges selected from MPD members. At the SME Annual Conference, all students displayed their posters, highlighting their research. The students with the top abstracts from the graduate and undergraduate divisions presented their research at the MPD Student Poster Session Wednesday morning. The panel of judges then provided tallied scores for the abstract, poster and presentation to determine the winners of the 2015 Student Poster Contest. The first- and second-place winners of both the graduate and undergraduate divisions received $1,000 and $500 scholarships, respectively. The third through seventh places received $200 each, and all other entrants received $100 each and were invited to join the MPD Luncheon.In the undergraduate division, Annette Hein of the University of Wyoming received first place for her research on “Solvent Extraction of Europium from a Nitric Acid Solution.” Second place went to Jennifer Galvin of South Dakota School of Mines and Technology for her research titled “Solvent Extraction of Neodymium Using PC88A.”In the graduate division, Caelen Anderson of the Colorado School of Mines received first place for his research titled “Fundamentals of Rare-earth Flotation Surface Chemistry: Hydroxamate Adsorption on Bastnasite”. This is Caelen’s fourth year placing in the top finisher. Second place in the graduate division went to Seyed Hassan Amini of West Virginia University for his research on “Ultra Clean Coal Production for the Solar-cell Industry.”The 2015 Student Poster Contest was chaired by Lisa Schlink (Freeport- McMoRan Inc.) and Emily Sarver (Virginia Polytechnic Institute and State University). The panel of judges included Aaron Noble (West Virginia University), Nick Gow (FLSmidth), Ren Bryce (Freeport-McMoRan Inc.), David Perkins (Derrick Corp.), Jim Metsa (Weir Minerals) and Scott Shuey (Newmont).A special thank you is extended to the sponsors of the MPD Student Poster Contest, to all the students who participated and to the panel of judges. Watch for more information on the 2016 MPD Student Poster Contest to be published later this year on http://www.smenet.org/mpd/ and in the November issue of Minerals & Metallurgical Processing."

Jan 1, 2015

By John Ralston, Rossen Sedev, Nicola Richards, Quinn Anthony, Geoffrey Reynolds

Derivatised 2,4-diketopyrimidine groups have been anchored to planar gold surfaces as self¬-assembled monolayers (SAMs) for chemical and photochemical studies. Three derivatives, 5-methyluracil (thymine), 5-trifluoromethyluracil and 5-nitrouracil, were chosen for the specific moiety present at position C-5, which can exert strong or weak inductive effects on the adjacent aromatic ring. The measured acidity constants decrease from 5-methyluracil to 5-nitrouracil as the inductive properties of the group at C-5 position increase. When grafted to the surface the acidity constants increase, albeit still adhering to the expected inductive trend. The functionality also exerts an influence on the surface wetting properties. Surface wettabilities indicate that the orientation of the pyrimidine groups at the surface occurs so that the C-5 position has a direct effect upon the surface chemistry. Upon dimerisation the surface contact angles increase signifi¬cantly. At pH 11 the contact angle changes reflect that the dimer has a higher pKa than the monomer. The monomer surface is deprotonated at this pH while the dimer surface is partially deprotonated, leading to changes in contact angle of up to 22 degrees. Large changes in contact angle were observed for 5-nitrouracil which were independent of surface charge and were appar¬ently due to conformational changes alone. Electrowetting of three fluoropolymer surfaces by electrolyte solutions was studied with the sessile drop method. The electrowetting curve (contact angle/potential) is analogous to the elec¬trocapillary curve (surface tension/potential) and may be described by a combination of the Young and Lippmann equations. We demonstrate that for some specific surfaces a systematic deviation occurs at positive potentials. This departure is attributed to double layer effects, namely the adsorption of hydroxide and halide anions. pH, ionic strength and polymer composi¬tion can all influence electrowetting behaviour.

Jan 1, 2003

By M. Karmis

The algorithms for the mathematical modeling to predict productivity of underground room-and-pillar mining systems are well known and documented. These algorithms consider the time-varying relationships between mining equipment for a given geometty of operations as well as other constraints. This paper presents WebConSim, a newly developed, Web-based, user-friendly computer simulation tool for the Windows environment. The simulator is easily customized for use by field engineers, planning engineers and management and will help mine operators plan the optimum mining sequence for different mine geometrie and equipment layouts. Program output includes production data and equipment utilization indices, as well as time driven event chains that can be used for virtual reality presentations.

Jan 1, 2002

By K. R. Weller, U. J. Sterns, P. S. B. Stewart

Complex sulphide ores usually require very fine grinding of the whole ore stream to achieve adequate liberation. Recent improvements to DSM screens have made this device appear competitive with cyclones in circuits treating these ores. A DSM screen and cyclones were tested in pilot-scale grinding of a copper, lead, zinc ore and the resultant data were used to establish a multi-component simulation model. The model was used to assess the influences of mill environment, circuit flows and pulp densities, final product properties (size, relative size and SG of the values, and liberation characteristics) and a second grinding circuit on capacity and product size distributions, and hence define conditions for which one device is better than the other.

Jan 1, 1992

By Brian K. Failon

Scale formation is a problem that affects many mineral processing systems because the processes require the use of large volumes of water. Scale composition may vary from circuit to circuit, but the scale deposition mechanisms and needs for prevention are often somewhat similar. Likewise, there is a degree of commonality in the prediction, detection, and elimination of scaling conditions in various water systems. This paper briefly reviews some of the conditions which lead to scale formation, as well as some of the common problems associated with unchecked scale growth. The primary focus of the paper is on the variety of chemical scale inhibitors available for use in mineral processing circuits, and the actions of each type. The means of predicting and detecting scaling tendencies are also addressed, and include both direct and indirect methods, i-e., stability index determination and chemical analysis of deposits.

Jan 1, 1986

By Horace M. Varner

Under sponsorship of the USBM and later of the DOE, a new type of rotary rock drill has been developed by The Bendix Corporation. Originally developed for the production of holes for the installation of longer than seam height roof bolts, the flexible drill is a useful tool for many drilling applications. This drill allows hands-off or remote production of holes for increased drilling speed and greater operator safety in any strata suitable for rotary drilling. The paper discusses various applications and experience for the flexible drill system in coal mining, metal/nonmetal mining, and for general civil engineering uses. Manual, remote control, and automatic roof bolter modules are also discussed.

Jan 1, 1982

By M. W. Chanda

This paper presents the development of a rock-creep measuring apparatus using air as the initial pressure source. Servo-controlled machines can and have been used for time-dependent property tests. However, the long-term nature of some tests makes essential the complete independence of stress-maintaining equipment from main power sources or continuously running hydraulic pumps. The main objective of this paper is the development of a creep testing machine that is free from interference arising through power supply interruptions or mechanical maintenance normally associated with many compression testing machines. To achieve this, a compressed-air power source was used to drive a compression ram. A few trial results obtained and analyzed using the transient creep law are in reasonable agreement with the general creep law.

Jan 1, 1993

By J. D. Miller, Z. S. Nickolov

Sum Frequency Spectroscopy (SFS) is a powerful nonlinear optical technique to study interfaces at the molecular level. SFS has one major advantage over conventional vibrational spectroscopic methods, such as infrared (IR) absorption and Raman scattering, in that the method is inherently interface specific. As a result, the spectroscopy of molecules residing in the interfacial region can be probed selectively without any contributions from the molecules present in the more pervasive bulk phases. Analysis of SF spectra can yield information on population, structure, and orientation of interfacial species with several nanometers in-depth resolution. The recently acquired SF spectrometer at the University of Utah opens new possibilities for investigation of interfacial phenomena of great importance for separation technology, materials research, nanotechnology, bioengineering. Its application to studies of liquid/gas, solid/liquid, and solid/gas interfaces will be discussed.

Jan 1, 2004

By S. D. Thompson, L. Adler

Several researchers in the last 20 years have developed computer simulation models for designing coal mine belt systems. A careful review of these reveals that each omitted or oversimplified important factors, especially in belt loading. To remedy this, the coal mine belt capacity simulator (CMBCS) was developed to include various types of probability distributions, delays, and longwall and continuous haulage. CMBCS is computer coded in FORTRAN and employs the Monte Carlo simulation technique. Basically, the model simulates the loading and corresponding flow of coal through a belt system. By recording spillage and belt stoppage statistics for the simulated flow, belt and surge bin capacities can be evaluated. A complete user's guide is available. The modeling and verification of CMBCS are briefly described, and its major advantages and disadvantages are explored.

Jan 1, 1987

By Staff

Assembling consistent data for a 40-year time series is a challenge because of the many changes that have occurred in this period. In many cases, because of process improvements and consumer requirements, grades of materials change in a 40-year span. This can lead to a wide fluctuation in price data simply because of increased costs for premium grades. Sources for obtaining price data can also change during a 40-year period. Changing the data source also introduces anomalies in a time series. In some cases, published price data are not representative of the real value of the material and provide little basis for further analysis. For some industrial mineral commodities, there are only a few producers, and value and production data are considered proprietary. In the data presented in this chapter, every attempt was made to ensure that the data were as consistent and representative of the industry as possible. However, the factors mentioned above may have introduced inconsistencies in some of the data series. Many different factors influence trends for industrial minerals because of the diversity of end uses for these commodities. Trends in production and prices for most of the industrial minerals can be related to one or more of the following: changing demand or technologies in end-use industries, development of new end uses, the effect of environmental regulations, production and processing technology changes, energy costs, foreign competition and substitution by other materials, and production as a byproduct of other minerals. World economic conditions, such as recessions and inflation rates, also play a part in some production and price trends. Data for 40 years of production for industrial minerals in the United States are presented in [Table 1] in 10-year increments. Unit values for the industrial minerals, in actual and constant 1990 dollars, are shown in [Tables 2 and 3].

Jan 1, 1994

A chartered bus with about 30 attendees of the just completed 1998 SME Annual Meeting headed toward Green Cove Springs, FL, which the author had been told was located somewhere south of Jacksonville, FL. In conjunction with the meeting in Orlando, RGC (USA) Mineral Sands provided a tour of its facility. The author had worked with heavy minerals on a laboratory scale, performing the usual gravity and magnetic separations, but had never been to a heavy mineral mine and processing facility. Years ago as a metallurgist, the author once applied for a job in a heavy mineral operation in Florida -it may have been the same operation. After turning north on to Highway 95, the endless billboards promoting beach-front retirement communities proved the Atlantic ocean was just a few miles away (although the author never caught a glimpse of it). After another hour, the bus suddenly turned west and continued inland for about 65 km (40 miles). The thought occurred, "We are talking about beach sands, what are we doing heading away from the ocean?" As the bus continued inland, the author was struck by the flatness of the land and by the lakes, rivers and wetlands. He was also impressed by the many fine stands of pine and hardwoods. The office of RGC (USA) Mineral Sands is located about 16 km (10 miles) south of Green Cove Springs. Upon leaving the bus, members of the tour were greeted by Graeme Sloan, general manager, and Elliot Mallard, manager of mining. They provided some general information about the operation, including a slide show. RGC's Florida operation produces four concentrates: zircon (ZrSiO,), rutile (TiO,), ilmenite (FeTiO,) and leucoxene (an alteration product of ilmenite containing 67% to 70% TiO,). With a work force of about 170, the annual production of the above products is about 23,27, 45 and 14 kt (25,000 30,000 50,000 and 15,000 st), respectively. RGC also has other mineral sand operations, in addition to gold and base metal mines, mostly in Australia.

Jan 1, 1998

By David M. Mchaina, Allan E. Hall, W. C. H. Kruining, Alan Coode, Stephen Hardcastle

This paper details an investigation into the feasibility of recirculating mine exhaust air in Saskatchewan potash mines. This project was initiated following a previous study at Ruttan Mine, Manitoba, which indicated that recirculation of exhaust air to reduce winter heating costs was feasible. The potash industry was selected for study because the mines use a minimum of blasting in their production methods and the exhaust temperature is significantly higher than that of most metal mines. These factors simplify the monitoring system required and have the potential for greater waste heat recovery. A series of measurements of underground mine pollutants was made at the main exhaust and intake shafts in order to determine the feasibility of introducing controlled recirculation of exhaust air. An experimental recirculation circuit was created by opening two existing doors situated between the return and intake shafts. During this recirculation trial, the air quality parameters at the intake, mixed intake and exhaust measuring stations were monitored. The results obtained from a questionnaire circulated to the regulatory agency and the major potash producers together with results obtained from underground field studies at Central Canada Potash (CCP) Division of Noranda Minerals indicated that controlled recirculation of mine exhaust air has potential application in these mines either to reduce heating costs and/ or to increase the face air quantities. A recirculation system is to be designed in conjunction with CCP and the Saskatchewan Ministry of Labour, Mine Safety Unit to attempt to implement a working recirculation system for CCP.

Jan 1, 1989

By Jerry C. Tien

An overcast is a form of air bridge which permits one air current to pass another without mixing. It is an essential and indispensable ventilation device for underground air distribution in horizontal mineral deposits. Overcasts are also a major source of shock pressure loss under- ground. However, a well thought out overcast plan, and a well constructed overcast, will give minimum shock loss, which in turn can save money (Tien, 1986). So far, most research on shock losses has been concentrated on splits and junctions, and bends and turns, or on underground regulators. Practically nothing could be found in the literature regarding losses caused by overcasts (see reference on shock losses). In this investigation, shock losses are quantified for an overcast with different configurations, which will give useful clues toward an aerodynamically designed overcast.

Jan 1, 1987

By S. S. Cook, S. E. Paulson

The US Bureau of Mines is conducting core leaching experiments with sulfuric acid on oxide copper ores from the Cyprus Casa Grande and Asarco/Freeport Santa Cruz deposit in Arizona to further the understanding of the leaching process in supergene copper ores as it relates to in situ mining. Leach solutions from atacamite mineralization contained 5 to 30 g/L (0.05 to 0.28 oz/gal) copper and few extraneous ions. Leachant from chrysocolla ores, with grades similar to the atacamite, contained 2 to 9 g/L (0.02 to 0.08 oz/ gal) copper and abundant extraneous ions. Quartz and K-feldspar had no impact on leach solution composition at any acid concentration up to 40 g/L - (0.39 oz/gal) while illite and sericite had minimal impact. Biotite, calcium-rich clay, and limonite have a significant impact on solution chemistry when there is abundant free acid in solution. High acid concentra¬tions increase acid consumption in ores with abundant biotite and limonite gangue. High acid concentrations can be used in ores with quartz, K feldspar, and sericite gangues without increasing acid consumption per unit of copper removed.

Jan 1, 1990

By S. J. Czehura

The Butte quartz monzonite is the host rock for early porphyry copper style mineralization and subsequent mesothermal-epithermal, enargite-gold style veining that transects the district. The east-west Anaconda system veins: including the Emma, Anaconda-Original, Syndicate, Badger-State, and Alice-Rainbow veins, each with strike lengths of over 12,000 feet and vertical continuity in excess of 4,500 feet, along with mining widths from 5 to 50 feet, are unique to Butte. The incredible dimensions and tenor of these veins have yet to be surpassed and Butte is still touted as being the “Richest Hill on Earth.” The Anaconda Company was formed in 1895 to develop underground copper reserves in the district and eventually consolidated all operations under one company. Production from underground mining continued through the mid-1970’s. Open pit mining in the Berkeley pit began in 1955 with the extraction of supergene ores, along with the remnants of deeper horsetail zones inaccessible to the underground mines. Operations in the Berkeley pit were suspended in mid-1982 because of the rejection of high arsenic, copper concentrates at major smelting facilities throughout the world. Bulk mining of porphyry style mineralization in the Continental pit began in January 1980 to supplement copper production while stripping “C” pushback in the Berkeley pit. The Anaconda Smelter closed in September 1980. A molybdenum circuit was added to the Butte Concentrator in 1981 and mining continued in the Continental pit to produce copper and molybdenum concentrates. A blend of Berkeley and Continental ores were processed to dilute penalty metals in the final concentrates marketed to toll smelters. All mining operations ceased mid-1983 when Anaconda closed the Continental pit and offered the property for sale. Montana Resources reopened the Continental pit in June 1986 to produce copper and molybdenum concentrates. Operations were suspended mid-2000, because of exorbitantly high power prices, but resumed in November 2003 with rising metal prices. Bulk open pit mining of the early porphyry style mineralization has sustained production over the past twenty years and mining is expected to continue in the Continental pit with favorable prices. Future mining will eventually develop a 500 million-ton geologic resource incorporated in a supergene enrichment blanket situated between the Berkeley pit and the Continental pit. Grades in this enrichment blanket range in the neighborhood of 0.5% copper.

Jan 1, 2006

By P. D. Rao, D. E. Walsh, W. W. McClintock

A column flotation system was designed to conduct release analyses on a very finely disseminated, stratiform copper ore from the Denali Copper Prospect in Alaska. Chalcopyrite is finely disseminated in a carbonate matrix, and pyrite is disseminated in both the chalcopyrite and the gangue. Grinding to -20 µm is required for adequate liberation. A 25-mm x 2.4-m glass flotation column was designed. The ore and its flotation tailings were repeatedly floated to obtain a rougher concentrate. The rougher concentrate was then repeatedly floated to produce release fractions. These fractions were analyzed for copper, iron, calcium and magnesium, and release curves were plotted. The procedure was replicated at each of two grinds, i.e., 99% and 88% passing 37 µm (400 mesh). The procedure should find application for flotation characterization and process selection. Bond grindability testing was also conducted.

Jan 1, 1996

By Z. Zhang, R. G. Reddy

The viscosities of industrial lead slags of varying compositions were measured as a junction of temperature using a Brookfield viscometer. Based on the experimental data obtained from this study and based on other investigations reported in the literature, an expression was developed to correlate the viscosities of industrial lead silicate slags as a function of composition and temperature. The effect of each individual slag component on the variation of the slag viscosity is identified. The composition dependency of lead silicate slag viscosity is discussed. The calculated results using this viscosity expression are in good agreement with the measured data. Key words: Viscosity, Lead silicate slags

Jan 1, 2003