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By Gerard P. Hand

The use of graphite in industrial applications is one of the oldest in the world. Yet, it is one of the fastest-changing technologies today. Graphite was first used centuries ago in developing writing instruments and as a raw material in crucibles used in melting metal. Today, graphite is used in some of our most demanding industries. These include aerospace, electronics and automotive applications. Graphite usage has historically been split between the natural and synthetic forms. Figure 1 shows the breakdown of natural graphites and synthetic graphites used. The usage of natural graphites and synthetic graphites is split fairly evenly, although the applications are quite different. Figure 2 shows the breakdown of applications using natural graphite. The largest application is the refractory industry. This includes refractory brick and plastics, crucibles, shrouds and other refractory parts. This main application uses roughly 50% of all natural graphite. The refractory industry is an important application for natural graphite. However, the refractory markets have been struggling for several years. As demonstrated in Fig. 3 (Semler, 1996), the production of refractories in tons per year has declined by more than 32% during the last 25 years. Refractory prices have actually risen on a dollar per ton basis during that same period as the product mix has shifted to the value-added side. Raw material and production cost increases, inflation and other related costs have kept profitability at low levels for the industry. Furnace linings that once lasted 1,000-2,000 heats now last 8,000-12,000 heats. This means that tonnage requirements have gone down and quality requirements have gone up for graphite suppliers. Therefore, new opportunities and applications must be developed if the graphite industry is to grow. Synthetics are the other major forms of graphite. There are two forms of synthetic material currently used. One is the traditional type. It is made from the turnings of graphite electrode production. The second was developed in the mid-1970s in response to a shortage of conventional synthetic graphite. This occurred by a breakthrough in thermal technology. This new technology purifies, desulfurizes and graphitizes petroleum coke on a continuous basis at temperatures of more than 2,500° C (4,532° F). This product is called desulfurized petroleum coke (Desulco). It now accounts for about half of the synthetic type material used in the United States. Figure 4 shows the breakdown in the use of synthetic types of material by application. The largest requirement is for use as a carbon addition in iron and steel. This is followed by alkaline batteries and friction materials. Current technological opportunities New opportunities for graphite products are now being developed. These new areas are made possible due to the advances in graphite thermal technology. The ability to purify and modify graphite and carbon products is the key to future growth in the graphite industry. New, higher-purity, more consistent graphite products are leading to enhanced performance in current applications. They are also opening the door to new applications.

Jan 1, 1997

By Paula N. Wilson, W. T. Parry

Carbonaceous and metalliferous black shales occur in close proximity to Mercur-type gold deposits in the southern Oquirrh Mountains, Utah. These shale units, the Manning Canyon shale and the Long Trail shale, have undergone regional hydrothermal alteration. Hydrothermal solutions oxidized organic matter and pyrite, replaced shale by hydrothermal phyllosilicates and silica, and replaced fossils by phyllosilicates. The shales are depleted in organic carbon, calcium carbonate, alkali and alkaline earth metals, and enriched in aluminum and hydrogen. Hydrothermal veins containing illite, chlorite, pyrophyllite, kaolinite, Fe-oxides, and sulfides are present throughout the study area.The illite in veins is an ammonium illite that contains up to 2 % NH4 and is correspondingly depleted in K. Correlations among Au, As, Hg, TI, Sc, and rare earth elements indicate that hydrothermal fluids responsible for formation of ammonium illite were gold bearing. K/Ar ages of illite veins and illite-rich, clay-size separates of altered shales indicate hydrothermal activity occurred in the time range 193 to 122 Ma. Several ages from clay-size separates within the Mercur district cluster near 160 Ma. These ages are coeval with thrust faulting recognized to the north and west.

Jan 1, 1990

By L. W. Pommier

In the field of minerals processing the concentration of valuable minerals normally takes place in suspensions of ore particles in liquids. The fluid resistance offered by Newtonian liquids to the movement of free settling spheres for the limiting cases of creep flow and turbulent flow is well described by Stokes' and Newton's Laws. However, these equations are not applicable to non-Newtonian fluids, since the relationship between applied shearing stress and resulting rate of shear is a non-linear function, and more than one viscosity parameter is necessary to describe their rheological properties. For this reason, the term "apparent viscosity," which has been commonly used to explain the flow resistance of the non-Newtonian systems including suspensions, may be misleading. A rigorous analysis of the mechanisms of momentum transport of solid-liquid systems is complex indeed. There are many variables that affect the properties of such systems, and precise limitations and assumptions are necessary in order to produce quantitative relationships for predicting their behavior. Very dilute suspensions of spherical particles in Newtonian liquids of identical density as the solids have been examined in the past (12); however, the study of suspensions in which there is a considerable difference in density, between the liquid and the suspended solids has been neglected.

Jan 1, 1968

By R. Kneisley, D. Conover, K. Haramy, K. Hanna

INTRODUCTION Coal mine entry intersections are high-risk areas for roof falls due to inherently wide roof spans, excessive stress, and variable intersection shapes resulting from breakthrough misalignments. Statistics from underground coal mines reveal that a high percentage of injuries occurs from roof and rib falls in entry intersections (Peng, 1980). The U.S. Department of the Interior, Bureau of Mines, is conducting a field research project to investigate failure modes surrounding underground coal mine entry intersections. The research objectives are to (1) develop a method to determine failure modes and stress-displacement relations around coal mine intersections and (2) develop engineering guidelines and empirical relationships for use in designing safer coal mine entry intersections. The basic approach to achieve the objectives is to instrument and monitor intersections before, during, and after intersection development in order to determine contributing parameters, such as in situ stresses, stress changes, strata movement, geology, physical properties, and mining sequence, that may influence the short- and long-term stability of the intersection and adjacent entries. This paper describes a rock mechanics instrumentation program, data analyses, and a comparison of two case studies conducted at two underground mines, designated as "A" and "B", in the Illinois Coal Basin. The instrumentation plans and data collected during development and long-term monitoring of four-way intersections and adjoining entries are presented. Data analyses of pre- and post-mining roof stress, pillar loading, strata movement, roof bolt loading, and geologic features are included. INTERSECTION FAILURE MECHANISM The region surrounding an entry intersection is characterized by different failure criteria than the region surrounding a single entry. Stresses induced during intersection development may result in a high incidence of roof and rib failures. Various numerical modeling techniques have been used to evaluate the failure modes surrounding intersections (Gercek, 1982; Chugh et al., 1975). Numerical modeling techniques include problems associated with the analysis of post-failure behavior, provision for different horizontal stresses (i.e., 01 f 021, and determination of inputs required for any non-elastic behavior. It seems likely that more sophisticated failure criteria, based on actual field data, are needed. The Bureau of Mines has conducted an extensive instrumentation program to investigate actual intersection failure mechanisms and to provide an improved understanding of stresses and deflections using beam and plate theories. Beam theory is not applicable to analyzing intersections (Wright et al., 1964); however, it can be used to explain roof deflection and failure (shear and flexure) of adjacent entries and to provide an improved understanding of stress changes and displacements as the entries, crosscuts, and intersection are developed (Hanna et al., 1985). Beam theory may be used for entries when the roof length is twice the width. When the length is less than twice the width (as in intersections), the roof must be analyzed as a three-dimensional problem, and stress and deflection calculations are based on flat plate theory (Adler and Sun, 1976). The confined-core theory (Wilson, 1972) hypothesizes that within a typical pillar, two regions exist: a confined-core region where the horizontal confining pressure is uniform and approximately equal to the overburden pressure, and a yield zone where the vertical pressure increases from nearly zero at the rib to a pressure peak at the boundary of the yield zone. The strength of coal in the yield zone ranges from nearly zero at the rib to nearly full strength at the confined core. The vertical stress in the confined core decreases from maximum at the yield zone boundary to the overburden pressure some distance into the pillar. Excavation of the adjoining entries

Jan 1, 1986

By R. V. Ramani, S. Skankar

Available literature on the effect of re-entrainment on overall airborne dust concentration in mine airways or the fundamental mechanisms of coal dust re-entrainment in mine atmosphere is scant (Shankar and Ramani, 1991). Therefore, as part of the Respirable Dust Center's ongoing research, the following three-part study was undertaken: •a study of the re-entrainment phenomena of anthracite and bituminous coal dust particles in a wind tunnel under the influence of varying air velocities; •a study of the same in the Lake Lynn Laboratory Mine of the USBM with both air flow and walking by personnel causing re-entrainment; and •the mathematical modeling and computer simulation of the re-entrainment phenomenon. In this paper, results from the re-entrainment studies in the wind tunnel and the Lake Lynn Laboratory mine are presented. Comparing the results from the two studies, it was observed that increasing the air velocity increased the rate of re-entrainment (Shankar and Ramani, 1994a) and the rate of re-entrainment decreased with the time of exposure of the source dust to the flowing air. In addition, when the source dust was composed of particles of different sizes, the airborne dust concentrations due to re-entrainment were higher than when the source dust was composed of particles of the same size. The contribution of airborne dust concentration due to airflow was negligible compared to the contribution due to walking.

Jan 1, 1996

By S. Ostap

INTRODUCTION Paradoxically, it has been found that the people who are the most aware of the origin, mineralogy and composition of bauxite are also the people who are the least aware of how bauxite composition affects its treatment by the Bayer process. These people are the exploration and mining geologists normally associated with aluminum producing companies. The purpose of this paper is to give some idea of how the concentration and physical nature of the different minerals found in bauxites affect the operation of the Bayer process used to extract their alumina content. The bauxites we will consider here will be only the tropical bauxites such as occurring in Jamaica, various countries in South America i.e. Guyana, Surinam, Brazil, African bauxites, Malaysia and in Australia. When we speak of the Bayer process, it will be the North American version of the Bayer process using low caustic concentrations and bauxite digestion temperatures varying between 130° to 250°C. TABLE 1 shows the minerals and elements of interest occurring in tropical bauxites. The minerals and elements listed in the table do not by any means represent all of those identified in bauxites. Using mass spectrographic analysis on six bauxites from different geographic locations, we managed to identify between 50-60 different elements. Fortunately, only about 13-14 of these elements possess the necessary chemical properties to be able to accumulate in caustic Bayer solutions. The remainder are either not attacked, or form insoluble reaction products with some main liquor component, i.e., hydroxide, aluminate or carbonate, or reprecipitate with alumina trihydrate during the precipitation stage.

Jan 1, 1984

By Robert G. Moorhead

Fine-coal screening can be one of the most critical operations in a modern coal-cleaning plant. The yield and quality of clean coal produced in fine-coal circuits is controlled as much by how efficiently 0.15 mm (100 mesh) particles are sized as on the performance traits of the fine-coal cleaning device itself. In addition, the increased interest in effective fine-coal sizing operations indicates that many operators have also discovered its importance in affecting the quality and yield of clean coal produced in fine-coal circuits. This paper describes the three most prevalently used fine-coal screening technologies and discusses their sizing mechanism, performance, and application.

Jan 1, 1988

By B. K. Mishra, R. K. Rajamani

This paper focuses on the use of a numerical tool known as the discrete element method (DEM) to study the motion of ball charge in ball mills. DEM is employed to simulate the motion of individual balls. While doing so, the effect of liner design on the grinding performance of the mill is studied. Two important, factors, such as the configuration of the liner and the geometry of the lifting surfaces, are correlated with the overall mill performance. An attempt is made to show the effectiveness of the lifter bars in transmitting power from the mill shell to the interior of the mill, with particular emphasis on large diameter mills.

Jan 1, 1994

By D. Greene

Close integration of mine planning and operation is a long-sought goal. Success is achieved in varying degrees depending upon mine complexity, size, and sophistication, but too often is more limited than desired. Despite tremendous strides in the development of computer-aided mine planning, digital plans usually must still be converted to error-prone paper maps and physical ground surveys for actual excavation and reclamation. However, advances in GPS, operator displays, and mobile computers now enable equipment operators to work directly from on-board digital plans. CAES offers reduced survey costs, faster field transition time and improved excavation accuracy coupled with faster, more informed decision making regarding key mining operations.

Jan 1, 1997

By Francis S. Kendorski

INTRODUCTION Drift design problems in caving operations are a re¬sult of the geologic factors contributing to the overall success of the system, of the engineering factors dictated by economic and technical considerations, and of ore production practices. Combining these factors, a rational underground sup¬port system of rock reinforcement, light steel channel section or welded wire fabric, and shotcrete can be de¬signed based on rock fracturing, rock load, abutment loadings, ground movement, expected repair and desired flexibility. The design concept uses the effect achieved by restraining, reinforcing, and maintaining some of the intrinsic strength of the fractured rock mass composed of interlocked blocks of intact rock and rock fractures. Three different examples of drift support design in hypo¬thetical mines using the caving system are given. Caving is a system of underground mining where ore is extracted by means of gravity after the ore body is allowed to fail by removing support from underneath. The rock mass of the ore body fractures and flows ver¬tically downward to let gravity do as much work as pos¬sible. Caving differs from many other mining systems in that blasting is used only to initiate the rock mass failure by removing the rock supporting the ore but not to break the ore itself. The initial movement of the rock mass dur¬ing failure and the consequent crushing and grinding during the continued movement serve to reduce the ore to particles of a manageable size, with only limited sec¬ondary blasting necessary. The broken ore is extracted from the bottom of the failed rock mass through funnels of some sort pre-excavated in the rock. Ore extraction must continue or the swell of the broken rock will even¬tually fill the cavity and stop further rock mass failure and movement. The excellent general discussion on block caving in the SME Mining Engineering Handbook (Julin and Tobie, 1973) adequately covers the principles and application of this type of underground mining. Many rock mechanics aspects of block caving have been covered by others (McMahon and Kendrick, 1969; Swaisgood, et al., 1972; Mahtab and Dixon, 1975; King, 1946) and will not be reviewed further. Maintaining the stability of production drifts is one of the most troublesome problems plaguing the mine manager in a caving operation. Many factors contrib¬ute to drift support problems, and identifying the causes of instability and producing a reasonable support design are two steps toward achieving stability consistent with the mine plan. This chapter sets forth a technique for the design of support systems for production drifts in caving opera¬tions. The basic support system elements employed are rock reinforcement, welded wire fabric, and shotcrete. Recognized as contributing to the design are the factors of rock load, additional load from mining activity, rock fracture characteristics, repair expected, and flexibility. It must be emphasized that the drift must first be stabilized as for a tunnel, and the additional strengthen¬ing for mining-induced loads cannot contribute to the initial premining stabilization, or the reserve of strength is used up. MINE PLANNING The efficient mine planning engineer not only must satisfy the economic, human, and environmental aspects of his task but must also consider the mechanical con¬sequences of his plan. The problems created for the mine by placing parallel drifts too close, by crossing drifts on different levels with inadequate, if any, separa¬tion, and by installing connections and crossovers in the haulage plan without regard for the effective spans cre¬ated, are only a few of the problems a mine planning engineer can create for himself and the mine. The effect on immediately adjacent mine areas when an area is caved is important to drift design because the removal of vertical support from a rock mass causes the weight of that rock mass to be shifted elsewhere. The adjacent rock mass will carry this load and reach a new equilibrium with the applied stress. The advancing front of stress increase that results from caving (and many other mining systems) is generally called the abutment load and is the increase in stress over the gravity or tec¬tonic stress that already exists, as shown in Fig. 1. In general, the abutment load will be similar in nature to the stress change found around an opening in rock and will be taken as causing an increase in the vertical prin¬cipal stress, due to an approaching caving boundary, so that

Jan 1, 1982

By Brian Kenner, Peter Swanson, Todd Krahenbuhl

NIOSH has developed an automated PC-based seismic event (induced earthquake) monitoring, system for use in mine ground control studies. The distribution and coordination of data acquisition and processing functions across a local area network is a central feature of the system. Mine-wide installations utilize multiple, autonomous seismic networks located both underground and on the surface. Seismic event locations, magnitude estimates, and other processed data are distributed for display and analysis on network nodes both underground and in the offices of mine engineers and managers. This paper describes the system's design philosophy, hardware and software components, examples of installations, and a few observational results.

Jan 1, 2002

By J. F. T. Agapito, R. R. Goodrich

Yield pillars have been used for many years to help reduce stresses near mine openings and improve roof and floor stability. A yield pillar is often defined as a pillar that fails but retains residual strength. Stress transfer occurs through the roof and floor after the peak strength of the pillar is reached. High stresses are transferred from around the openings onto abutments that can be barrier pillars or unmined ground. This mechanism, often referred to as pressure arching, is possible as long as the width of yield pillar mining (panel width) is less than the critical width above which stresses cannot be carried by the overburden. Significant stress transfer also can occur due to small amounts of pillar and/or floor yielding before the peak strength is reached. This is accomplished in a quasi-elastic manner with little or no visible roof and pillar fracturing or floor heave. Long-term stability may be achieved when stresses and mechanical properties are favorable to prefailure yielding. This paper gives practical examples where improvements in stability and resource recovery were achieved with this mechanism. Yielding was assessed by comparing measured and calculated vertical pillar stresses. Results indicated that calculated stresses in the pillars were 25% to 40% higher than the measured stresses, demonstrating significant arching load transfer to the abutments. Prefailure yielding is probably often present but unintentional in both development and production areas. Better recognition and use of this mechanism should lead to design improvements, as mines become deeper.

Jan 1, 2003

By R. S. Conti

The US Bureau of Mines (USBM) has developed an inflatable feed-tube seal (IFTS) for high-expansion foam generators. The IFTS is a lightweight, portable, rectangular inflatable bag that can be used by firefighters to rapidly seal large openings, such as those in underground mines, and to simultaneously provide a feed-tube for a high-expansion foam generator. Thus allows fire fighting foam to freely flow to the fire site and control or extinguish the fire. Studies indicated that a high-expansion foam plug will travel 183 m (600 ft) down an entry with a 4.5% rise in elevation, before leakage of foam from around the inflatable partition.

Jan 1, 1996

By Joyce A. Ober

Strontium occurs commonly in nature, averaging 0.034% of all igneous rock; however, only two minerals, celestite and strontianite, contain strontium in sufficient quantities to make its recovery practical, and these minerals are found in sedimentary rocks. Of the two, only celestite has been found to occur in deposits of sufficient size to make development of mining facilities currently attractive. Celestite, the most common strontium mineral, consists primarily of strontium sulfate (SrSO,). Strontianite, the second most common mineral, consists primarily of strontium carbonate (Sr CO3). Strontianite would be the more useful of the two common minerals because strontium is used most commonly in the carbonate form, but few deposits have been discovered that are suitable for development. The physical properties of strontium ores are listed in [Table 1].

Jan 1, 1994

By R. S. Kramer

A bulk compositional chemical analysis often provides incomplete information to help the mineral processor when faced with the problem of removing troublesome contaminants in low concentrations. Michigan Tech has developed a unique approach for addressing this problem. A combination of Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), and image analysis was successfully used to characterize the species responsible for phosphorus contamination of less than . 05 weight percent in iron ore. An automated routine acquired the chemical signature of each particle on a back scattered electron image. The few particles containing phosphorus were identified from the hundreds of particles examined, and the phosphate phases present were easily characterized.

Jan 1, 1993

By Adrian Smith, Debra W. Struhsacker

There is now overwhelming evidence that, despite concerns to the contrary, natural degradation of cyanide and cyanide attenuation by hydrogeochemical processes are capable of minimizing or eliminating potential water qua1ity impacts from heap leach systems. A1 though there was some recognition of these data by the regulatory authorities, for example the initial USEPA modification of cyanide standards to an advisory level, many states have codified standards inappropriate to the clearly site specific nature of heap leach operations. As an overview to this problem, this paper will integrate the theoretical chemical data on cyanide with the observed geochemical behavior of cyanide in the decommissioned heap leach environment. The cyanide species that are likely to exist within an abandoned heap leach system will be identified, and the relative toxicity and potential environment effect of these cyanide species will be discussed. These data will then be used to evaluate cyanide detoxification regulations for decommissioned heap leach projects in 14 states.

Jan 1, 1987

By J. M. Kaufman

Recent mining regulations have increased the need for detailed engineering and environmental information pertaining to the hydrogeologic environment in mining areas. The cost of obtaining such hydrogeologic information has also increased. After mineralization of potentially economic grade ore and tonnage has been identified, and after completing preliminary mining feasibility studies (suggesting that development is merited), a second exploration phase can incorporate a simple, cost-effective baseline hydrogeologic data reconnaissance program that is linited but useful. Using exploration drill holes only, this program can provide a direct indication of where ground water is encountered. Also, reasonable estimates can be made on the relative production of water from various water-bearing strata, a composite potentiometric surface map can be prepared, and the general chemistry of the ground water can be characterized.

Jan 1, 1984

By Y. Zimmels, C. Feldman

Closed-circuit grinding processes are considered in the context of a reactor-separator circuit that involves multifraction streams and products. Because grinding circuits are low-efficiency, capital-intensive operations, modeling to maximize their economic return is appropriate. An attempt to develop and test such a model is presented in this work. The model relies on process simulation for both the mill and the separator, in conjunction with constraints imposed by product specifications. The grinding process was simulated using breakage functions, which provided complete data on the feed and product of the mill. A cyclone bank used as the separator was also simulated using known models. The overall process model provided a complete simulation of the multistream grinding and separation process. The process model was then incorporated into an economic model that predicts grinding cost, subject to process constraints, for a given set of operating variables. The model facilitates economic optimization of the grinding process as it relates to process variables and process hardware.

Jan 1, 1993

By A. W. Hamilton

If you don't know a gauss from a grasshopper, you may be better off than you, think, particularly if you're an ore dressing engineer charged with the responsibility of selecting magnetic equipment for minerals separation and beneficiation. Gauss is a unit of measure for a magnetic field. It indicates the number of imaginary lines of force per square centimeter or per square inch radiating from a magnet. In discussing the strength characteristics of a magnet, we have come to speak of a magnetic field of 800 gauss, for example, meaning 800 lines of force per square centimeter. Gauss became the standard for selecting drum type separators many years ago under an arbitrary set of circumstances. The standard has continued to this day even though magnetics applications engineers have long considered it inadequate. The configurations of the older gauss meter were such that the most accurate and convenient readings on a drum type separator could be made at distances greater than one inch. So, an arbitrary distance of two inches was established and that two inches became the standard. Since then, it has become commonplace to specify magnetic strengths for drum separators according to average gauss readings at two inches; for example 500 gauss average at two inches, 750 gauss average at two inches and so on, even though gauss readings at two inches have much less to do with the separating and beneficiating function of a given application than was formerly believed. The standard was adopted as a means of gauging the strengths of electromagnetic drum type separators, for they were the only ones around at the time. These machines were usually designed with no magnetic considerations other than that the material to be separated should be agitated vigorously and the magnetic fields should be deep and strong. Drums built this way performed well enough, so it seemed logical to measure their magnetic strengths. Hence, gauss at two inches. Now, new improvements in magnetic techniques have made average gauss measurements at 2 inches positively obsolete.

Jan 1, 1971

By Y. J. Wang

The use of controlled recirculation began in the early 1930s. Although this method has been applied in many mines since then, a generalized comprehensive network analysis is still lacking. This paper presents a unique approach in which the ventilation network with a controlled district recirculation is divided into two subsystems: a main subsystem and a recirculation subsystem. The subsystems are analyzed individually, and the results and their relationships are then integrated into discussions of the total ventilation system. The analysis of the recirculation subsystem is facilitated by introducing a nondimensional parameter (A), which represents the ratio of the air quantity for the working face to that for the subsystem. As a result, far and regulator pressures and air power for various recirculation arrangements can be effectively expressed as a function of and the subsystem air quantity. Numerical examples are included.

Jan 1, 1997