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By Gerald L. Finfinger, Michael A. Trevits

Since 1964, the US Bureau of Mines has been conducting a comprehensive program of research on the origin and control of coal bed gas. Several extensive databases have been developed during the work representing information from every major coal producing region in the United States. Gas content measurements have been made on 885 coal samples from 15 states representing 221 coal beds. Records indicate that the range of gas content varies from zero to over 640 ft3 per ton (20 cm3 per gm). During the conduct of the research program, several drilling and completion techniques have been developed or refined to divert and collect coal bed gas before it enters the mine environment. Such techniques include horizontal, cross-measure and vertical boreholes. Samples of gas collected from boreholes drilled under the program indicate that the primary gas constituent is methane which comprises 97 pct, the remaining hydrocarbons make up approximately 0.2 pct. Nitrogen and carbon dioxide account for the majority of the remaining gases at average concentrations of 1 pct each. Surveys have been made on the total daily gas emissions from underground coal mines. In fact, the most recent survey indicates that 180 mines had emissions in excess of 100 Mft3 per day (2.8 Mm3 per day). Furthermore, total mine emissions were in excess of 300 MMft3 per day (8493 Mm3 per day). An analysis of the data showed that there appears to be no relationship between in-place gas content and coal bed gas composition. Furthermore, no correlation was observed between in- place gas content and daily mine emissions. In a general sense, the higher the gas content the higher the relative gas emissions. Perhaps a more direct relationship would be observed if more complete emissions information (including gob gas borehole production) was available.

Jan 1, 1989

By W. M. Haffner, S. L. Borek, H. M. Edenborn, R. W. Hammack, D. H. Dvorak

The conceptual designs of three new applications for the biogenic &S treatment of metal- containing waters are presented. These include: 1. the treatment of a circumneutral-pH ground water containing Zn and Cd using limestone as an alkalinity source, 2. a two-step treatment process where toxic heavy metals in contaminated ground water are recovered separately from nontoxic metals to lessen disposal costs, and 3. a copper recovery process that may be a low-cost alternative to solvent extraction/electrowinning or cementation for dilute copper leach liquors. Preliminary results of initial field testing are discussed

Jan 1, 1995

By A. Pradakar, J. G. Groppo, J. W. Leonard

All coal transportation systems from the coal face to the final point of use would become more productive if additional tonnages, obtained through improvements to bulk density, could be placed in fixed volume containers such as scoops, shuttle cards, trucks, barges and ships, as well as conveyors. This paper reviews previously reported work where the treatment of coals with small amounts of mining chemicals (0.12 to 0.28 kg/t or 0.25 to 0.56 lbs/st) during lavoratory testing was show to increase loaded coal bulk density by about 15%. The latest bulk density enhancement findings to develop from ongoing research involving underlying chemical and physical theory together with the added use of simple mechanical excitation are discussed.

Jan 1, 1995

By Tan Xiang-Kun, Liu Ming-dong, Yao Dun-Pu

Since the 1980s, heap leaching of gold and silver ores has been developing rapidly and experienced widespread use in China because of its lower capital and operating costs, less time consumed in construction and specific applicability to small-to-medium scale mining operations and low grade ores. Ores treated include ordinary oxidized ores, refractory sulfide ores and even those containing deleterious elements (such as arsenic or antimony) and/or carbonaceous substances. In addition to chemical leaching agents, some micro-organisms (e.g. T-ferrooxidians and T-thiooxixians) and their biochemistry mechanism have been equally emphasized. To overcome the adverse effect caused by excessive content of fines and slimes, research and pilot experiments of agglomeration-heap leaching are currently underway at two gold mines in South China and their encouraging preliminary achievements will be briefly described as illustrations in this paper. It could be expected that heap leaching of gold and silver ores holds promise and will play an increasingly important role in China's gold industry.

Jan 1, 1998

By R. D. Hendry, R. A. Pearce, Allyn J. Steward, Dennis C. Martin

This paper outlines the geotechnical exploration and design approach utilized for the Km 80 and Km 86 Tunnels on the British Columbia Railway Tumbler Ridge Branchline. Information from surface mapping, trenching and diamond drilling was used to prepare a rational support design using accepted rock mass classification systems. Four possible support types were developed and used as a basis for preparing a cost estimate and contract documents for the tunnels. A unit price contract was selected to provide flexibility and to enable rational selection of support based on actual ground conditions encountered during excavation. Although ground conditions along the tunnels are variable, the general geology and quantities of support installed were consistent with those estimated from the geotechnical investigation and design.

Jan 1, 1985

By J. M. Melluish

The metallurgical response of the Point Leamington deposit has been studied. Two series of bench tests were conducted and various ore samples and flotation products were examined using image analysis techniques. The majority of sphalerite and chalcopyrite grains in this texturally complex ore were found to be smaller than 10 micrometers. Copper recoveries were low with losses mainly as fine inclusions in pyrite. Sphalerite recoveries were somewhat better due to a generally coarser habit. Gold and silver recoveries were also low and only solid solution silver was identified in the ore. The deposit shows poor economic prospects unless additional tonnage of high grade zinc ore can be delineated.

Jan 1, 1989

By Steven W. Hunt, J. Patrick Powers, Roger C. Ilsley

Artificial groundwater recharge has been used successfully to mitigate water level drawdown in upper alluvial deposits during construction of the Milwaukee deep rock tunnels. Recharge wells in rock as well as soil were used. The effort reduced settlements from consolidation of compressible estuarine deposits, and has minimized damage to existing structures. The paper describes the geology that presented the consolidation problem, and the hydrogeologic conditions that caused the drawdowns. Also presented are the details of recharge well design, construction, operation and performance in an urban environment. The project design calls for grouting and lining of the tunnels to control groundwater in the long term.

Jan 1, 1991

By P. J. L. Nel

The paper describes several successful concepts used in the sinking of shafts on the Elandsrand Gold Mine. The concepts enabled the shaft sinking time to be reduced as well as the period in which development would normally take place to establish initial ore reserves.

Jan 1, 1981

By Harry Holle, Ivan Hunter, Darrin Thomson, Gary Johnson

Over the past five years Dominion Mining Limited has directed an on-going effort towards optimising the performance of its milling circuits. The approach has been on a wide front, and has addressed a variety of issues associated with the design and operation of SAG milling circuits. Major projects have been conducted in the areas of flowsheet optimisation, mill liner efficiency, and dynamic circuit performance. As a result the initial designs of many of the Dominion circuits have been modified, mill liner specifications have been rationalised, and a robust automatic control system has been developed. A group-wide approach was taken on most of these projects, resulting in substantial benefits to both the individual operations and the company as a whole. By applying the projects group-wide a significant multiplier effect has been gained on the funds invested in each project. Extensive use of steady state modelling techniques has been made in order to understand the performance of the different circuits, and to highlight the potential areas in which improvements can be made. Liner optimisation has been primarily aimed at achieving predicability of performance, both metallurgical and mechanical. The development of a robust automatic control system has enabled the dynamics of the milling process to be controlled, and resulted in an additional increment in throughput being achieved. The combined effect of these efforts has been to raise plant availability to consistently over 95% (on a long term basis), to improve the power efficiency of comminution (in SAG mills) by 20% or more, and to enhance the dynamic performance such that a more than 10% increase circuit throughput has been demonstrated.

Jan 1, 1993

By Thomas M. Goodell, Timothy D. Arnold

Dilute-phase pneumatic conveying has been used in the mining industry since the 1920s. It has primarily been used for the hoisting of coal and salt ores, and as a transportation medium for backfill material. More recently there have been investigations into a wider variety of applications, which this paper addreses. The paper will point out some deficiencies in the system. It 1s not the "champion" of the mining industry, but rather an excellent srste?1 with a variety of applications that may not have been studied m enough detail. The most imaginative applications to the Redpath Pneumatic Conveying System have been initiated by persons needing an innovative application to a specific predicament.

Jan 1, 1992

By Harry M. Castrantas, James L. Manganaro, Craig W. Rautiola, James Carmichael

Caro's acid (peroxymonosulfuric acid) was successfully field tested as a cyanide detoxification agent at a North American gold mine. An on-site FMC generator injected Caro's acid into a mill tailings slurry sump. The WAD cN-(weakly acid dissociable plus free cN-) was reduced from 40-108 ppm to below the target level of 20 ppm using a 1/1 mole ratio of CA (Caro's acid) /CN-. At an inlet CA/CN-mole ratio of 1.8/1, WAD CN­concentrations as low as 4 ppm cN-were achieved. Raw material costs for the cyanide detoxification were cut by 60% compared to using hydrogen peroxide (H202) alone. Detoxification time with Caro's acid was much faster compared to H202. This resulted in completion of detoxification before the treated slurry reached the tailings pond thereby substantially reducing the probability of wildlife fatalities.

Jan 1, 1993

By G. S. Adisoma

To address the problem of grade estimation in a general three-dimensional shape and the uncertainty associated with the estimate, the technique of jackknifing/block kriging short-cut is proposed. A new estimator called jackknife kriging is introduced first. Through the jackknife variance, a confidence limit for the reserve grade estimate can be calculated. Unlike the kriging variance, which is more a measure of data configuration and is independent of data values, the jackknife variance reflects the true variability of the data. This approach provides a simple way to set a confidence level for global estimation of resources.

Jan 1, 1995

By Z. Jin, D. DePaoli, P. Zhang

"Phosphate beneficiation in Florida generates more than one tonne of phosphatic clay, or slime, per tonne of phosphate rock produced. Since the start of the practice of large-scale washing and desliming for phosphate beneficiation, more than 2 Gt of slime has accumulated, containing approximately 600 Mt of phosphate rock, 600 kt of rare earth elements (REEs) and 80 million kilograms of uranium. The recovery of these valuable elements from the phosphatic clay is one of the most challenging endeavors in mineral processing, because the clay is extremely dilute, with an average solids concentration of 3 percent, and fine in size, with more than 50 percent having particle size smaller than 2 µm, and it contains nearly 50 percent clay minerals as well as large amounts of magnesium, iron and aluminum. With industry support and under funding from the Critical Materials Institute, the Florida Industrial and Phosphate Research Institute in conjunction with the Oak Ridge National Laboratory undertook the task to recover phosphorus, rare earths and uranium from Florida phosphatic clay. This paper presents the results from the preliminary testing of two approaches. The first approach involves three-stage cycloning using cyclones with diameters of 12.4 cm (5 in.), 5.08 cm (2 in.) and 2.54 cm (1 in.), respectively, to remove clay minerals followed by flotation and leaching. The second approach is a two-step leaching process. In the first step, selective leaching was conducted to remove magnesium, thus allowing the production of phosphoric acid suitable for the manufacture of diammonium phosphate (DAP) in the second leaching step. The results showed that multistage cycloning with small cyclones is necessary to remove clay minerals. Selective leaching at about pH 3.2 using sulfuric acid was found to be effective for removing more than 80 percent of magnesium from the feed with minimal loss of phosphorus.IntroductionFlorida phosphate ore, or “matrix,” as it is called locally, contains three different mineral groups that have to be separated from each other: (1) phosphate minerals, (2) clay minerals and (3) quartz, or sand. As mined, the phosphate and sand particles are embedded in compacted mud, or clay-balls. Before separation can begin, all of the particles must be liberated from the matrix of mud. The very first unit operation in the beneficiation process is to disaggregate the various particles. This actually starts while the matrix is flowing through the multimile pipeline from the mine to the beneficiation plant. While in the pipeline, the matrix is exposed to shear forces as it passes through the various centrifugal pumps along the pipeline. These intense shear forces cause a significant percentage of the sand and phosphate particles to be liberated from the clay-balls by the time they arrive at the plant. Once they reach the plant, the first goal is to finish disaggregating the clay, and follow that by making a size separation at 1 mm. This processing is conducted in the washer, consisting of a large rotating trammel screen and a few stages of log washer, screens and hydrocyclones. In all of the currently operating beneficiation plants, the washer is a large structure that receives the matrix, screens it and then discharges a pebble phosphate product sized larger than 1.0 mm and a slurry of liberated clay, sand and phosphate particles that are smaller than 1.0 mm."

Jan 1, 2017

By R. A. Lowe

Smectite is a common impurity in the kaolins of Georgia. This impurity is harmful to the low-shear rheology of kaolin slurries in concentrations as low as a few weight percent. The deleterious effect of smectite on the low-shear rheology is due to the swelling of the mineral. Montmorillonite containing clays were treated to precipitate a compact brucite layer {Mg(OH)2} in the interlayer region of the expandable layer silicate mineral. This treatment forms a hydroxy-Mg-montmorillonite with characteristics similar to chlorite. This treatment effectively reduces the swelling capacity of the mineral and improves the rheological properties of kaolin slurries contaminated with smectite impurities.

Jan 1, 1999

By R. Woods

"Comments on the paper ""Formation of hydrogen peroxide by chalcopyrite and its influence on flotation,""by A. Javadi Nooshabadi and K. Hanumantha Rao (Minerals & Metallurgical Processing, 2013, Vol. 30,No. 4, pp. 212-219)The formation of hydrogen peroxide from water during the grinding of chalcopyrite in a nitrogen-sparged environment, as reported by Javadi Nooshabadi and Rao (Minerals & Metallurgical Processing, 2013, Vol. 30, No. 4, pp. 212-219), is questioned on the grounds that oxidation of water by the mineral is unlikely to be thermodynamically feasible. It is argued that it is more likely that any peroxide that had been formed would have been generated from residual oxygen in the nitrogen-flushed system than from the oxidation of water.The formation of hydrogen peroxide by finely divided pyrite had been reported by a number of authors (Borda et al., 2001; Borda et al., 2003; Cohn et al., 2006; Schoonen et al., 2006; Schoonen et al., 2010; Jones et al., 2011; Javadi Nooshabadi et al., 2013). That hydrogen peroxide is formed in the presence of oxygen in solution can be comprehended from wellestablished mechanisms. Pyrite in aerated solution is known to oxidize by an anodic process that is coupled with the cathodic reduction of oxygen (Holmes and Crundwell, 2000). The latter process has been shown to occur through the formation of hydrogen peroxide (Biegler et al., 1975; Ahlberg and Broo, 1996). The pH dependence of cathodic oxygen reduction at other sulfide minerals, including chalcopyrite (Biegler et al., 1977; Rand, 1977), implies a similar mechanism at these surfaces."

Jan 1, 2015

By Gunter Fauth

The setting of tasks for the process control of coal cleaning, and in this connection the requirements for instrumentation can be classified into the following three fields: - Monitoring the operation of individual units, or process steps, - Control of units or process steps, - Control of the entire coal cleaning process with the intention of optimizing the operation and the profitability of the process. Instrumentation is affected by the type of cleaning processes. For introduction Figure 1 shows the simplified flow sheet of coal preparation which is usual in the German Ruhr District and in which desirable places for the measurement of ash, moisture and sulfur content are marked. The preparation plant is supplied with run-of-mine coal from the shaft via a homogenization facility. In a first step of primary classifying the raw feed coal is screened at about 10 mm. The raw coarse coal ( = 10 mm) is sorted by jig washers or heavy-medium separators. the raw fine coal (< 10 mm) at first is pneumatically sized at about 0.5 to 0.75 mm. The fines, the aspirated dust, are a finished partial product which will be added to the final metallurgical or steam coal. The material 10 to 0.75 mm subsequently is sorted in fine coal jigs and dewatered in centrifuges. The sludge obtained with the wet cleaning processes is dewatered in thickeners and fed to the flotation. Concentrate and tailings are dewatered by filters or bowl centrifuges and by chamber filter presses or belt filter presses, respectively. The partial products coarse coal, fine coal, flotation concentrate, aspirated dust, and middlings are blended to result in the sellable products metallurgical and steam coal.

Jan 1, 1984

This paper reports on the behavior of mercury and its compounds during the thiosulfate leaching and recovery of gold. Thiosulfate solutions are shown to dissolve Hg0 and Hg2Cl2 to a similar extent as cyanide, but the leaching of HgS is significantly slower in thiosulfate solutions compared to cyanide. Hence, the use of thiosulfate may be an option for treating ores containing high levels of cinnabar, especially since the legislation concerning the discharge or sale of mercury is becoming more restrictive. The deportment of mercury during gold thiosulfate loading and recovery using a strongly basic anion-exchange resin was also studied. Although the mercury thiosulfate complex loads on the resin, the adsorption is weaker than for gold, with an equilibrium constant between gold and mercury of 51. Resin loaded with gold, mercury and copper was pre-eluted with thiosulfate (to remove copper) and eluted with a chloride and sulfite eluant. The majority of the mercury is eluted by the eluant and, hence, its deportment closely follows gold and the eluate would need to be treated to remove either mercury dur-ing or prior to gold electrowinning.

Jan 1, 2010

By R. W. Barbaro, J. M. Mutrnansky

This paper presents a nonlinear integer goal programming model that optimizes a mineral production schedule while considering the penalties and bonuses based on quality variations in the final product. It involves five coal quality goals plus a profit objective in its formulation and uses the weighting method of goal programming for a solution. The goals to be sought involve the sulfur, ash, heat content, moisture content, and ash softening temperature of the blended coal product. The model is linear in its handling of most of these goals but uses a piecewise linear integer formulation for the sulfur and heat content bonus and penalty schedule. The model is applicable to any mineral product blended from several different sources and subject to a varying price dependent on blended product quality or qualities. However, it seems to be most pertinent to optimizing production schedules for coal deliveries to power plants. Accordingly, the model is applied to a hypothetical coal production problem where multiple coal mines are operated to supply a final blended product to a power plant. In this example, the price paid for the coal is assumed to be a function of five of the most important coal qualities. The problem is solved as a direct function of the coal supply contract, thus removing the necessity of determining the weighting coefficients on a subjective basis.

Jan 1, 1987

By G. Van Weert

Oxygen transfer from dispersed air in agitated slurries represents an important unit operation in the minerals processing industry. Gold leaching, iron precipitation and especially bio-oxidation come readily to mind. However, little engineering information is available on the variations between impeller types on such O2 transfer. Engineering literature on the subject, i.e. information which relates slurry density and energy input to O2 transfer, is reviewed and compared to current experimental work. The latter was carried out with minus 50 micron sand/water slurries in a 64 I laboratory tank of standard proportions, equipped with a variable speed drive with torque meter. A standard Rushton turbine and a specifically sized A315 were compared. Results confirm an increasing impairment of O2 transfer with increasing slurry density for both impellers. The volumetric mass transfer coefficient, k,a, in a 10 vol. % slurry shows a decrease of 30% compared to the k,a in water. At 20 vol. % sand this decrease is near 50 %, depending somewhat on superficial gas velocities. Power efficiency, i.e. the kg O2/kWh, decreases about 25 % more rapidly for the Rushton turbine than for the A315 with the addition of sand. However, for equivalent O2 transfer the Rushton turbine was more efficient in this work. Experimental results are presented and their significance for slurry bio-oxidation discussed.

Jan 1, 1996

By E. D. Gálvez, L. A. Cisternas, A. López-Valdivieso, F. Lucay

"The floatability of molybdenite fines in saline solutions was investigated through microflotation studies using a modified Hallimond tube. In addition, the effect of pH and gypsum precipitation from calcium ions (Ca2+) and sulfate ions (SO4 2-) ions in saline water on the recovery of the molybdenite was analyzed. It was found that the floatability of molybdenite fines significantly increased with the ionic strength of the saline solutions and is independent of pH above 0.5 mol/L ionic strength. The high floatability of molybdenite in saline solutions is explained as being due to the low electrostatic repulsion between bubbles and the edges of molybdenite particles, which is exceeded by interactions due to van der Waals and hydrophobic forces. The precipitation of Ca2+ and SO4 2- ions as gypsum had a detrimental effect on the natural floatability of molybdenite because of gypsum crystal attachment on the faces of the molybdenite particles. This precipitation phenomenon may be initiated in copper–molybdenite flotation circuits that use recycled saline water, like seawater containing Ca2+ and SO4 2- ions.IntroductionWater availability is a significant factor in mining projects. Water, particularly fresh water from rivers and underground water, is becoming a scarce resource for mining operations and new projects. Under these circumstances, the use of water with high concentration of salts in flotation plants is becoming increasingly important (Cisternas and Moreno, 2014). The use of seawater has been studied as a sustainable solution for many mining companies in dry areas located near the sea. Notably, using seawater in mining operations is how mining companies in Chile have coped with the problem of water resources (Cisternas and Gálvez, 2014). In 1930, small plants in Chile used seawater to float chalcopyrite from high-copper-grade ores. In 1975, the results of tests in pilot plants for the flotation of copper minerals with seawater were reported. It was found that froth formation in seawater at pH 9.5 was suitable to make the rougher circuit work properly, even without frothers. The Cenizas mining group successfully floated chalcocite, bornite and chalcopyrite in the Las Luces plant in Taltal in Chile using seawater (Moreno et al., 2011). Minera Centinela (Antofagasta Minerals S.A. Chile) is currently processing porphyry copper ores using a seawater mixture consisting of 20 percent fresh seawater and 80 percent recycled water. Lower consumption of flotation reagents was reported in both seawater and salt water. In addition, studies performed with synthetic seawater showed that certain frothers increase the froth volume, whereas others decrease it. Additionally, the froth produced with seawater carries a high amount of gangue, and low-quality concentrates are obtained, requiring more cleaning stages."

Jan 1, 2015