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By S. Subramanian, K. A. Natarajan, D. N. Sathyanarayana

FTIR spectroscopy is used to study the ad¬sorption of an oxidized starch on hematite, corundum, and quart: substrates. The difference spectrum of the adsorbed starch on hematite indicates surface reactions involving -CH2OH and -COH groups and shows striking similarities with that of the ferric-starch system, suggesting chemical interaction between the iron of hematite and the starch adsorbate. The IR spectra of starch adsorbed on corundum and quart: show no evidence of chemical interaction, although hydrogen bonding is apparent. The extent of adsorption of starch on hematite. corundum, and quartz decreases along the series. The evidence for chemical interaction of starch with hematite is further obtained by the X-ray photoelectron spectra of starch adsorbed on hematite, showing noticeable decrease in peak positions of O(Is) and C(Is) of free starch. The Mössbauer spectrum of hematite with stanch adsorbed on it complements these findings.

Jan 1, 1990

By R. P. King

Direct observations of intergranular fracture during comminution are very difficult to make. The best indirect method is based on the measurement of interphase area before and after comminution. If intergranular fracture does not occur, the interphase area should be conserved during comminution, but it should decrease if significant amounts of intergranular fracture occur. The interphase area per unit volume can be determined by image analysis from measurements on sections of the unbroken ore and on sections through the particles after comminution. However, the measurements must be corrected for the effects of image resolution on the measured phase and particle perimeters. A correction procedure was developed, and the true interphase perimeter per unit volume was measured before and after comminution in a sample of chromite-serpentinite ore and two samples of Witwatersrand pyritic quartzite. The pyritic quartzite showed no significant evidence of grain- boundary fracture while the chromite-serpentinite showed a significant decrease in interphase area per unit volume of chromite, indicating that intergranular fracture occurred.

Jan 1, 1992

By R. Gerling

A computer program has been developed for finding a near-optimum schedule of the mining sequence for flat lying, tabular orebodies. The deposit is divided in blocks with equal areas and definite grades, thicknesses and ore contents. Mining is done by room and pillar method and trackless haulage to surface. Access from surface is by adits or ramps with additional vent raises. In total eight different general concepts for access and development can be realized. The optimum mining sequence is found by a heuristic method. Criterion is the maximization of the net present value over the lifetime of the mine. Specific stoping costs per t of ore are taken for con¬stant, whereas development and haulage costs for individual blocks and also sequences will be different. Correct ventilation and a technically sensible sequence are guaranteed. Beginning with a single block, neighbouring blocks are tested and an optimum stoping sequence is generated. The net present value of the total mining operation for the planning period is calculated, taking into account ore, which is mined during development. The program can also be used to investigate given mining sequences.

Jan 1, 1986

By Alan R. Grant

Interpretation of presently available geological information indicates that most of the periods of significant metal deposition in the Washington Cascades Range are, at least in part, genetically related to late Cretaceous -Tertiary intrusive episodes. Chemically, the most favorable environment for base metal deposition is high in potassium. Characterizing the advanced stages of these chemical alteration conditions are the silicate mineral assemblages orthoclase and/or secondary biotite. Wall rock alteration includes both deuteric and hydrothermal processes, the intensity of which primarily depends upon the degree of fracturing in the country rock prior to the introduction of secondary material. Broadly speaking, the primary physical controls for the distribution and concentration of sulfides appear to be a series of structural couples involving both northwest (paralleling regional trends) and northeast--striking systems. Meaningful base metal exploration in the Washington Cascades demands a basic understanding of the various geologic factors related to the distribution of the sulfide deposits. Any geologist contemplating Cascade work should be well grounded in the fundamental concepts of petrology and structure.as these constitute two of his most beneficial aids. The acquisition of the detailed data necessary for this understanding may seem a bit academic, yet it has been demonstrated in numerous instances that a fair economic appraisal of a particular property or mining district depends primarily upon the ability of the geologist to recognize the subtle environmental differences which could lead to the discovery of a major ore deposit.

Jan 1, 1971

By Tracy E. Barnes

The process of computerized reserve estimation consists of assuming a model of the spatial continuity of a deposit and then, working within the assumed model, estimating the grade and tonnage of the deposit. The basis for geostatistical analysis is a statistical definition of this continuity or the variogram. The true variogram is essentially impossible to define. So an experimental variogram is defined from the sample data and kriging proceeds assuming that this experimental variogram is a good approximation of the true variogram. Therefore the closer the experimental variogram is to the true variogram the better the estimate will be. Realizing that the variogram is nothing more than the definition of the spatial continuity of the deposit, taking the known geologic continuity of the deposit into account will give a superior variogram. The use of known geology is a widely recognized necessity for good structural analysis of a deposit, but is rarely fully incorporated into the structural analysis.

Jan 1, 1982

By J. D. Miller

On the basis of nonequilibrium zeta potential measurements by laser-Doppler electrophoresis, the sign of the surface charge of alkali halides in their saturated brines has been established. The results are generally as expected from simplified lattice ion hydration theory. This recent electrokinetic information coupled with the stability and prevalence of collector colloids in such soluble-salt flotation systems suggests that the selective flotation of alkali halides is due to the adsorption of oppositely charged collector colloids by heterocoagulation. Experimental flotation results confirm this surface-charge/collector-colloid adsorption model and are presented herein.

Jan 1, 1992

By A. S. Astakhov

Working out of the production calendar plans (schedules) at deep mines which provide for the interaction of all kinds of mining operations determining coal output growth and mining and technical indices is a striking example of mining art. However, multi-variant decision making, a sophisticated system of integration, as well as high labour consumption for calculation and graphic operations in calendar planning require the improvement of traditional techniques and the development of new methods for calendar planning of mining operations at deep mines. The following specific aims were pursued in developing a computerized system of calendar planning (scheduling) of mining operations.

Jan 1, 1979

By Winfield G. Wright, Philip L. Verplanck, Douglas B. Yager, Dana J. Bove, M. Alisa Mast

The upper Animas River watershed is affected by metal-rich drainage from abandoned mines and by natural weathering of mineralized bedrock. To investigate the importance of natural metal sources, surface waters were sampled in a minimally mined but intensely altered area of the watershed. Water chemistry was strongly controlled by the degree of bedrock alteration. Propylitically altered rocks, which contain calcite, produced neutral waters with low metal concentrations, whereas quartz-sericite-pyrite alteration was characterized by acid-sulfate type waters with high metal concentrations. A mass-balance approach was used to estimate natural metal sources, which accounted for 56-905 of the dissolved metal load discharging from the study area

Jan 1, 2000

By Michael C. Stanley

The set of discoveries for a mining district or camp is a reflection of the exploration history. In the western Abitibi greenstone belt of Ontario, future exploration can be guided by a study of statistical trends of known gold deposits. In this area simple trends indicate a strong decrease in the contained quantity of gold discovered through time. Much of this decrease is attributed not to falling mining grades but to smaller tonnages of ore. A plot of the largest discovery in each ten year time period suggests that deposit discoverability is following a size-biased sampling model. Cumulative ounces of discovered gold indicate that an asymptotic value has been reached where exploration is not expected to add significantly to known reserves. This is substantiated by a downward trend in the exploration success ratio of the number of new deposits discovered versus the number of new mineral prospects. The set of discovered deposits reflects a non-random sampling process where size- biased modeling suggests that the largest deposits will be discovered early in the exploration effort. It is the exceptionally large deposit contributing to the observed size-biased distribution. Although this pattern is observed for the western Abitibi the model is complicated by recent, large reserve additions that are attributed to the original discovery. There is present in this area a subtle learning process in exploration leading up to the largest discovery. For comparison a learning model was estimated using cumulative size of discovery per unit of time. This model yielded results consistent with the statistical trends and is thought to be a superior forecast of future discoveries in this region.

Jan 1, 1992

By M. K. Gangal, E. D. Dainty

The paper describes the use of portable aerosol monitors in determining real-time concentrations of diesel soot and respirable total dust in dieselized mines. The field studies were conducted in a simulated diesel environment in the laboratory where no other type of dust was present, and in four underground mines with multi-diesel machine operations. Two packages for the real-time monitoring of diesel soot were prepared which included two types of aerosol monitors: a Miniram, model PDM-3, and a Sibata, model PDS-1. These monitors utilize the principle of light-scattering to measure the airborne mass concentration in the environment. The monitoring device results were compared against the Time-Weighted-Average (TWA) values produced by the gravimetric filter sampling method, permitting calibration factors to be determined for each field test. Both instrument packages provided comparable results. The instrument calibration factors varied for different tests, which may be due to different material composition, particle size distribution, density and shape of the aerosols. This approach for real-time determination of diesel soot is found to be simple, inexpensive and easy to use. More field tests for diesel soot determination and further research on size distribution of particulates in dieselized mines are required.

Jan 1, 1989

By J. R. Mattern

The engineering geology of the Rio Tinto Borax Boron Mine creates challenges in providing practical slope design recommendations to mine planning engineers. Low strength sedimentary units interbedded with very low strength lakebed clays surround the orebody. Faulting has offset and juxtaposed these units into variably adverse orientations, while groundwater is compartmentalized both vertically and horizontally within fault blocks. A collective program of geologic data collection, geomechanical strength testing, geologic modeling, slope depressurization, confirmation of underground stope locations, and documentation of slope behavior provides vital information for design investigations and sensitivities. Analysis results lead to risk assessments and operational procedures that add value to the business by optimizing slope configurations and minimizing risk.

Jan 1, 2004

By Karen M. Kessen

The isotopic variations of lead from Mississippi Valley galenas have long been used to place constraints on the sources of the lead, and on the residence the of the lead in crustal reservoirs prior to its emplacement in the Mississippi Valley province. Similar studies based on strontium isotope variations in gangue minerals associated with the lead-zinc sulphides have been neglected until Haden's (1) study of such minerals from several localities in northwestern Ohio. His work revealed two things about the mineralization. Firstly, it shoved that the average isotope composition of lead from galenas from northwestern Ohio lies on the anamalous lead line characterizing Mississippi Valley-type leads, albeit at the least radiogenic end of the entire data array. This confirm earlier assignments of the Ohio mineralization as Mississippi Valley-type (Hey1 and others (2)). Secondly, Haden (I) showed that the strontium in the calcite, strontianite and fluorite is broadly similar in isotopic composition to the strontium in the host Silurian to Devonian marine carbonates within which these minerals arc emplaced. He concluded that the mineral strontium my have been very locally derived, from the carbonate hosts.

Jan 1, 1979

By Daryl R. Tweeton

The Bureau of Mines has developed PC-based tomographic computer programs for geophysical applications, and is making them available to potential users as part of a Bureau plan to facilitate the transfer of technology to industry. These programs were initially developed for predicting and monitoring the flow pattern of leach solution during in situ mining. Seismic crosshole tomography has located fractured zones of low seismic velocity and saturated zones of high seismic velocit above the natural water table. The Bureau has applied tomography also to assessing high-wall blast damage, and examining the integrity of mine-related geological structures. The tomographic programs include the straight ray pro ram BOMTOM (Bureau of Mines Tomography? and the program BOMCRATR (Bureau of Mines Curved Ray Tomographic Reconstruction) that can be run with either curved or straight rays. Both programs provide optional mathematical constraints to help counteract the nonuniqueness of reconstructions that occurs with crosshole data. They are available from the Bureau free of charge. With typical data sets, they can be run on a 386 microcomputer with 640 Kb RAM. BOMTOM was described in the Bureau Report of Investigations 9159, so this report emphasizes BOMCRATR. Curved and straight ray reconstructions using seismic field data collected while simulating injection of leach solution were compared. The curved and straight ray tomograms were quite similar even with velocity variations of more than 50 percent.

Jan 1, 1992

By M. K. Patel, K. C. Wade, M. Cross

In the past decade a good deal of effort has gone into the computer simulation of the heat distribution of pellet induration systems. The major uncertainty in the analysis of such systems is the gas flow distribution and, in particular, the role of leakage. Evaluation of the leakage into or out of a zone has proved to be very difficult, as has the cross-flow from one zone to another when adjoining zones have gas flows which change direction from up draft to down draft for example. This paper describes an initial model to calculate the gas flow distribution in a variety of practical situations of interest to those involved in pellet induration. The model is based upon a multiphase CFD code called CASCADE which is used in conjunction with the pellet induration simulation INDSYS.

Jan 1, 1990

By Yongping Hu, Dianchen Cai, Congya Zhang

China is a rich in stromite mineral resource. Unfortunately, the resource is very difficult to separate by using conventional flotation method because stromite and gangue minerals are very fine disseminated, the average size of them is about 10 µm or below, and the content of clay minerals such as illite is 19% or even more. In this paper, the aggregation floatation behavior of ultrafine (-10 µm) stromite, illite, ablbite and quartz using anion collector were studied. The result show that, Oxidized paraffin (O.P) is a good collector and has better selectivity for stromite particles flotation. The salted sodium silicate depressed illite gangues minerals effectively. The separation of mineral mixtures was carried on successfully at one stage flotation by the technique. The mechanism of O.P. and salted sodium silicate were studied and discussed by using IR and Zeta- potential measurements.

Jan 1, 1995

By K. Hanumantha Rao, P. K. Sharma

A pure strain of Paenibacillus polymyxa and mineral- adapted strains are used to bring about surface chemical changes on pyrite and chalcopyrite and, thus, theirflotation. Paenibacillus polymyxa was adapted by repeated subculturing in the presence of pyrite and chalcopyrite. The surface chemical changes of bacteria due to adaptation and of minerals after their interaction with bacterial cultures are evaluated by electrokinetic and infrared spectroscopy and are discussed with reference to their flotation responses. Interaction of bacterial cells, bacterial metabolites and whole bacterial cultures affected the Hallirnondflotation behavior of the sulfide minerals. The Xanthate flotation results show that pyrite, but not chalcopyrite, is depressed when the tests are carried out after interaction with chalcopyrite-adapted Paenibacillus polymyxa. This investigation demonstrated that the surface chemical properties of bacteria can be manipulated successfully to achieve the desired effects in the flotation process.

Jan 1, 2000

By G. S. Grainger, R. A. Cummings, F. S. Kendorski, R. L. Butts

Georgia Power Company's Rocky Mountain Project, located approximately ten miles northwest of Rome, Georgia, in the Valley and Ridge Physiographic Province, is a pumped-storage facility rated at approximately 800 megawatts of peaking energy. Geological field explorations and borings enabled the division of the rocks along the tunnel and shaft alignment into distinct lithologic units and defined the ground--water regime. Field explorations included a detailed analysis of the rock mass discontinuities at available rock unit exposures. Testing of rock strengths was performed in several phases in both the field and the laboratory. The field testing consisted of point-load testing, geophysical testing, in situ load testing, and hydro-fracture testing. Laboratory testing determined the Brazilian split-tensile strength, the unconfined compressive strength, the triaxial compressive strength, the joint-direct shear strength, and the pulse velocity. The rock mass along the tunnel and shaft was also characterized by empirical classification systems. The classification systems included the Rock Mass Rating (B1IR) and the Rock Mass Strength Determination (RHSD). The results of the field explorations, field testing, laboratory testing, and rock classifications were used to divide the rocks into two structural groups. These rock groups were defined as volumes of rock wherein the rock mass behaves similarly in response to the excavation. Each group, therefore, required separate rock engineering consideration.

Jan 1, 1986

By J. Y. Kim, S. L. Chryssoulis

Lead ions that originate from galena during the processing of complex sulfide ores migrate onto the surfaces of sphalerite and iron sulfide minerals. This results in poor selectivity during differential flotation. Generally, in sulfide ore processing, the lead-activated minerals float in the Cu/Pb rougher circuit. The surface lead complicates the zinc flotation circuit by lowering the concentrate grade. The effect of lead in the differential flotation of sphalerite from Cu-Pb-Zu and Pb-Zu ores is discussed. Plant and laboratory-test data are interpreted by determining the surface compositions of individual grains of sphalerite and iron sulfide particles. For the first time, surface compositions were determined by using laser-ionization mass spectrometry (LIMS) and time-of-flight secondary ion mass spectrometry (TOF-SIMS). Cationic and cationic species on the surface were analyzed to elucidate the phenomena. It was proven that these new techniques are very useful in understanding the basic mechanisms of a sulfide mineral-flotation system.

Jan 1, 1997

By E. C. Grunsky

Spatial auto- and crosscorrelation assessment of variables can be carried out using quadratic function estimates. From the function estimates, multivariate relationships of the variables can be determined in the form of spatial factors. The calculation of the spatial factors requires computation of the corresponding amplitude vectors from the eigenvalue solution. This vector reflects the relative amplitudes by which the variables follow the spatial factors. Instability of some of the eigenvalue solutions requires that caution be used in interpreting the resulting factor pat- terns. A measure of the predictive power of the spatial factors can be determined from the auto- correlation coefficients and squared multiple correlation co-efficients which indicate which of the variables are significant in any given factor. The use of unconditional simulations provides a basis by which geological variables of varying spatial ranges can be modelled using the spatial factor technique. Simulations were generated for a variety of ranges and variables were created that form single or multiple combinations of the spatial patterns. The success of the spatial factor technique depends on the amount of associated noise, and the size of the neighbourhood relative to the spatial range of the variable. The predictive power of the components is dependent on these two factors. Problems with collinearity of variables can result in unrealistic eigenvalues and result in the failure of the method. Application of this method to spatial data in mineral exploration can assist in outlining spatially continuous zones of alteration associated with mineralization.

Jan 1, 1989

By Stanislaw Nawrat, Waclaw Trutwin, Waclaw Dziurznski, Janusz Roszkowski

In recent years attempts have been made to fight open and intensive mine fires by the use of special extinguishers, which are able to produce great volumes of inert gases directed into the fire zone. These extinguishers are derived from turbo-jet engines used in aircrafts and adopted for operations in mine conditions. The purpose of this paper is to draw the attention to a computer simulation method, enabling studies of dynamical behaviour of mine ventilation processes disturbed by open fires, which are also influenced by measures taken during fire fighting actions i.a. the mentioned operating extinguishers. The first part of this paper gives an account of the principles on which the computer simulation program, concerning the non- steady mine ventilation process, the fire as a heat source and the extinguisher as a source of inert gas and moisture has been based. The next part of this paper deals with simplifying assumptions and the subsequent limitations of the derived simulation pro- gram. Finally, from an example of a computer simulation, the results will be presented and relations shown between parameters characterising the ventilation process during the fire fighting action.

Jan 1, 1997