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By Y. G. Zhu, G. B. Zheng, X. X. Hu

Reverse flotation by cationic collectors is the classical method to reduce the silicon content in magnesite. But because of the low selectivity, there is a large loss of magnesite in the reverse flotation froth. To improve the efficiency of the collector, a novel collector named BK433 was developed in this paper. In order to determine the performance of the BK433 collector, a systematic experimental study was carried out with a high silicon magnesite in China. The suitable pH environment of slurry was confirmed, the depression effect of different depressants was investigated, and the flotation effect was compared with commonly used traditional collectors. The results show that the BK433 shows remarkable good selectivity and collection ability. After the 4 stages reverse flotation, the SiO2 content decreased from 3.76% to 0.25%, SiO2 impurity removal rate reached 94.69%. Meanwhile, the MgO content increased from 45.06% to 46.73%，the recovery of obtained concentrate (calculated by MgO) was 82.79%. Keywords: Magnesite, Desilicication, Reverse flotation, Collector

Jan 1, 2020

By N. Hadebe, A. Mampuru, F. Jantjies

Mintek conducted test work to study the effect of media wear when using Mintek’s Milling-in-raffinate technology. The grinding media consisted of high-chrome and ceramic balls. The tests were conducted using a laboratory 5L 316 stainless-steel rubber-lined mill. Magotteaux supplied the high-chrome and ceramic balls. The raffinate was synthetically prepared using a typical Cu/Co (2.2 g/L Cu, 3 g/L Co) composition. The milling rate, media wear, mill, leach extraction efficiencies, gangue acid consumption, and residence time were studied. The tests indicated that the high-chrome balls had a higher corrosion rate than the ceramic balls. The ceramic corrosion rate was lower than 0.1 mm/y. The highchrome balls performed better during the leach stages with faster milling time, higher leaching efficiencies for both Cu and Co, lower gangue-acid consumption, and lower residence time

Jan 1, 2023

By F. M. Ramadhan, M. R. Pratama

Monitoring open-pit mine road conditions has become very critical nowadays. There are several benefits to in conducting research on this field such as opportunity to improve truck’s speed which directly influences truck’s productivity. This research aims to provide a semi real-time, and sensors-based automatic road damage detector that predicts the road quality through road damage exact location tracing, road damages auto-classification, and real-time instruction in the form of work order format to mining road maintenance, and repair authorities through mobile apps and maintenance unit’s in-cabin display. It will also provide the maintenance/repair activity performance evaluation via integrated dashboards. The artificial neural network algorithm is applied during the process of data training regarding classifying road damages and severities which resulted in a valid model. The road damage classification model has a precision level of 80.5% in predicting whether the road is damaged or not. Using this approach, we are expecting to visualise a road quality map of all active roads on mine site.

Sep 1, 2021

By D. A. Cowen

Toll and custom treatment of base metal concentrates have been performed for decades as mines and concentrators are developed distant from capital and, energy-intensive smelting and refining facilities. Commercial treatment terms have been developed and refined for over a century, and are negotiated taking into account a complex array of quality and economic factors. Treatment of third-party concentrates in the South African platinum industry is a comparatively recent development, brought about by the opening up of mineral rights and operations being developed that are smaller than the critical size required to sustain capitalization of smelting or refining plant. Published commercial terms have not been demonstrated to reflect the complexities and subtleties of base metal concentrate markets. This paper outlines some key elements and parameter ranges of base metal concentrate treatment contracts, and applies similar principles to typical Merensky and UG2 platinum group element (PGE) concentrates to determine potential value distribution between the mining and treatment parties in tolling arrangements.

Jan 1, 2012

Council and Standing Committees-1984/85 President: J.D. Austin Vice Presidents: H.E. James and Dr H. Wagner Immediate Past President: Prof. R.P. King Honorary Treasurer: Prof. D.G. Krige Members of Council: B.C. Alberts, Prof. S. Budavari, E.B. Crocker, N.J. Devine, C.E. Fivaz, J.S. Freer, Prof. G.G. Garrett, J.J. Geldenhuys, Dr A.K. Haines, R.W.O. Kersten, Dr B.K. Loveday, I.D. Matthews, G. Maude, H.G. Mosenthal, B.E. Protheroe, Dr O.K.H. Steffen, Dr P.T. Wedepohl Chairman, Witbank/Middelburg Branch: W.C. Mather Chairman, Orange Free State/Klerksdorp Branch: Dr M.A. Orridge Past Presidents Serving on Council: Dr M.G. Atmore, Prof. A.N. Brown, Dr P.R. Jochens, G.Y. Nisbet, Prof. R.P. Plewman, Dr R.E. Robinson, Prof. M.D.G. Salamon, P.W.J. van Rensburg, D.A. Viljoen, P.A. von Wielligh Standing Committee Chairmen: Adjudication, Prof. R.P. King; Awards, Prof. R.P. King; Constitution, Rules and Policy, Prof. R.P. King; Excursions and Banquet, B.E. Protheroe; Journal, H.E. James; Membership, Dr H. Wagner; Phoenix National Committee, Dr M.G. Atmore; SAIMM School-Extractive Metallurgy, J.S. Freer; SAIMM School-Mining, Prof. S. Budavari; Special Publications, J.D. Austin; Technical Programme¬Extractive Metallurgy, Dr B.K. Loveday; Technical Programme-Mining, J.J. Geldenhuys; Technical Programme-Physical Metallurgy, Dr P.T. Wedepohl; Training, Career Guidance and Education, Prof. R.P. King; World Mining Congress-National Committee, Prof. R.P. Plewman; Working Group Physical Metallurgy, Prof. G. G. Garrett

Jan 1, 1985

By C. N. Eze, C. K. Ezeh, O. Nnabuife, N. M. Ugwoju, S. C. Enemuor, V. Okechukwu

In this study, the efficacy of Providencia vermicola KUBT-1 in the leaching and beneficiation of Agbaja iron ore was evaluated under varying conditions of temperature, ore particle size, and pH. Agbaja iron ore is a Nigerian low-grade ore containing about 43%–52% iron and a high amount of gangue materials, including phosphorus (1.4%–2.0%) and sulphur (0.12%). The study was organised in triplicate in shake flasks with 48 samples. One millilitre of washed cells of Providencia vermicola KUBT-1 suspended in normal saline at 0.5 McFarland standard (108 cells ml-1) was introduced into each flask containing 50 g of sterilised ore in 100 ml of bioleaching medium, and the samples incubated at room temperature for eight weeks. The levels of upgraded iron, mobilised sulphur, and phosphorus were determined by atomic absorption and ultraviolet spectrophotometric analyses, respectively. Results showed that a particle size of 0.8 mm was optimal for iron upgrading and sulphur mobilisation while 1.0 mm ore size was optimal for phosphorus mobilisation. Up to 89.60% of the iron was upgraded while phosphorus and sulphur were mobilised, leaving residual values of 0.223% and 0.02%, in the ore, respectively. The organism produced best beneficiation results at a pH of 2.5 and a temperature of 3ºC. Correlation analysis with the Pearson’s correlation model showed a positive correlation between iron upgrading and sulphur-phosphorus removal (r =1.000, and r =0.967), respectively. These results present Providencia vermicola KUBT-1 as a promising candidate for large scale leaching and beneficiation of Agbaja iron ore.

Dec 15, 2025

By S. Botes, H. van der Merwe

While the refractory lining contains the process on a steady-state basis, the tap-hole must provide a channel for transport of molten materials at discreet intervals, with thermal cycling as routine. The tap-hole introduces a discontinuity in any lining, and this fact can lead to failure in the region around the tap-hole before general lining failure occurs. Hence there is a need for a rapid and reliable tap-hole repair technique that can be readily implemented in conjunction with all types of linings. The UCAR®V Repair supplied by GrafTech is a durable solution capable of repairing all types of lining designs and has been extensively utilized in the ferroalloy industry. More than 20 UCAR®V Repairs have been successfully performed in South Africa alone. This paper describes the system in general and reviews recent repairs and their unique challenges.

Jan 1, 2014

By Y. Yang, M. Zhang, X. Xia, S Shi, Z. Shen

A stepwise arrangement of flotation cells is the most common layout of a flotation circuit in the mineral processing industry. In such a design, slurry flows from upstream to downstream by means of gravity, and the middling products are returned to previous stages by pumps. This paper will introduce an alternative solution in which the forced-air and slurry-induced flotation cells are adopted so that all the flotation cells can be placed on the same horizontal platform and no pumps will be needed for middling product transferring. The technology of the forced-air and slurry-induced flotation cell will be described in detail, including unique features, the working principle and the related fundamental problems. The comparison of capital investment, operating cost and metallurgical performance will be made between the conventional stepwise arrangement and the samelevel arrangement technology based on industrial practice. Keywords: Forced-air and slurry-induced flotation cell, same-level arrangement, stepwise

Jan 1, 2020

By H. P. Kritzinger, T. C. Kingsley

Rotary kilns are used for a variety of mineral processing operations. Hatch makes use of a kiln model developed from first principles to evaluate designs for its clients. This tool has been applied to a variety of pyrometallurgical applications. This paper illustrates the application of numerical optimization techniques in combination with the kiln model in the interrogation of a generic iron-ore reduction process. The fundamental modelling concepts are explained, followed by a description of the optimization approach. The results show how the combination of the two methods, with modern computing power, can generate a large number of viable design and operating candidates.

Jan 1, 2014

By E. Maritz

"The localized uniform conditioning (LUC) technique was proposed by Marat Abzalov in 2006. The technique converts conventional uniform conditioning (UC) grade-tonnage curves into single grade values attached to each smallest mining unit (SMU). This is achieved by ranking the SMUs within a panel in increasing order of their grade (based on the direct kriging of SMUs). This ranking is then used to localize the conventional UC grade-tonnage curves for each panel by dividing them into classes and computing their mean grades, which are assigned to the SMUs. The quality of this localization process will depend heavily on the validity of the grade patterns predicted by the direct kriging of the SMUs. Abzalov noted that where the distribution of data available for the direct kriging of the SMU is characterized by strong short-range variability, the advantages of using the LUC approach may be more limited. Consequently, a study was undertaken to determine how valid the predicted grade patterns of a typical Birimian-style gold deposit (with high nugget effect and strong short-range variability) might be expected to be. This was determined by comparing the direct SMU kriging ranking (based on sparse data) with the grade control model ranking (based on close-spaced data and the best available estimate of the deposit). The results showed a satisfactory correlation between these rankings and it was concluded that, although the grade patterns predicted by the direct kriging of the SMUs may be less meaningful for deposits exhibiting strong short-range continuity, there is nevertheless a convincing relationship with the actual (or best available) rankings. Therefore, the LUC technique is still considered to be useful for this style of deposit. IntroductionFor adequate technical and financial evaluation of a project, attempts should be made to estimate the recoverable resources – the portion of the in situ resource that can be economically extracted by mining. To achieve this, the estimates of the tonnage and grade of the mineralization should be produced above a given economic cut-off and should take into consideration the proposed mining selectivity."

Jan 1, 2016

On 8th August, 1973, 57 members of the Institute visited Prieska Copper Mine at Copperton in the North Western Cape. After tea, the group was welcomed by the Management of the Mine, and Mr Grobler, the General Manager, gave an introductory talk. After they had been taken on a bus tour of the property, the members split up into groups and proceeded underground or to the concentrator. Of special interest to the mining members were the rock-handling methods in use at the mine. The stoping method that has been adopted is the continuous, long-hole sub-level open stoping system. The broken ore is moved with rubbertyred front-end loaders from the stope drawpoints to the ore passes. On the main tramming levels, the ore is collected by electric locomotives and discharged into the main shaft system at the bottom. At the shaft ore-pass system, a gyratory crusher that can accept rocks up to 1 m in diameter has been installed. The crushed product (minus 150 mm in diameter) will then be hoisted by a Koepe winder, which has a rated capacity of 900 tons per hour. The mine is also served by a declined roadway from surface, which facilitates the movement of heavy equipment. The most striking aspect is the productivity that can be achieved by the use of a trackless-mining system. For the production of 230 000 tons per month, it is estimated that 6 stopers and 7 developers will be required. The total labour force will be approximately 2500-2000 Bantu, 200 Coloured, and 300 Europeans. Training of maintenance and operating personnel is of the utmost importance, and it was interesting to note the extent to which non-White labour is being used in these occupations. Lunch was served at the single quarters, after which the group proceeded to the airfield for the return trip to Johannesburg. On behalf of the visitors, Professor de V. Lambrechts thanked Mr Grobler and his staff for the most interesting morning and for their hospitality,

Jan 10, 1973

By Huanhuan SU, Jianqiang Zhang, Zhongyuan Liu, Junwei Ma

The high-sulfur bauxite in Henan Province was used as raw material. The grinding fineness, pH value and collector dosage on its desulfurization performance, and industrial flotation desulfurization process were studied. The best flotation desulfurization conditions were grinding fineness of 75%, pH of 8.5, and collector of 600 g/t. “One coarse, one cleaning and one sweep” closed-circuit flotation was established as the industrial flotation desulfurization process. After the closed circuit test, the sulfur content of aluminum concentrate with the yield of 93% was 0.23%, and the sulfur removal rate was 83.16%, and the sulfur content of tailings (sulfur concentrate) was 15.09%. Keywords：High-sulfur bauxite under coal mines, flotation, desulfurization

Jan 1, 2020

By M. Ndabeni, J. H. van Vreden, M. Le Roux, Q. P. Campbell

It is not uncommon for gold slurry ponds or screen oversize dumps to contain several different types of carbon-rich contaminants. These contaminants act as robbers of dissolved gold which has a detrimental effect during the downstream carbon-in-leach (CIL) or carbon-in-pulp (CIP) processes. With a renewed interest in the reprocessing of contaminated gold waste ponds and dumps, preconcentration of the feed to either the CIL or CIP process becomes important to maximise profits from these resources. An added advantage in removing these resources, which were once thought of as being uneconomical, is the availability of land that can further be rehabilitated for community development projects. For gravity separation, an example of suitable technology is the Reflux Classifier (RC), which can be used for the separation of materials of different densities and can be used as a pre-concentration step. In this project, a laboratory-scale Reflux Classifier was used to pre-concentrate a gold-bearing sample obtained from a waste dump situated to the east of Johannesburg, South Africa. The material had an average gold grade of 1.9 g/ton and a carbon content of 10%. This material was first fed to a semi-batch Reflux Classifier that was used to fractionate it into several different density intervals by varying the fluidisation water feed rate, followed by continuous runs at fixed water flow rates. The results showed that a cumulative gold recovery of 60%, carbon recovery of 85%, and mass pull of 41% was possible for a fluidisation water feed rate of 15 L/min, while a rate of 20 L/min resulted in a gold recovery, carbon recovery and mass pull of 83%, 92% and 79% respectively, which translated into a concentrate gold grade above the set target of 3 g/ton. Continuous operation at 20 L/min yielded an underflow stream with 84% gold recovery at a grade of 5.4 g/ton. Keywords: Reflux Classification, gold recovery

Jan 1, 2020

The April General Meeting of the Institute was held in Kelvin House, Johannesburg, on 16th April, 1969, at 4.30 p.m. Mr R. C. J. Goode (president) was in the Chair. There were also present nineteen Members, including Messrs R. J. Adamson, F. P. Bath, J. K. E. Douglas, A. R. C. Fowler, P. Lambooy, D. G. Maxwell and J. A. Nixon, (Council Members), Messrs E. L. Atkinson, I. R. Chaston, J. L. Edwards, J. S. Hall, S. A. Hancox, A. F. Lee, W. K. B. Loftus, H. S. Simpson, A. N. Shand, R. A. Wilson, H. J. Wright and J. E. Van Leeuwen. Nine Associate Members, including Messrs O. Davel, G. Douglas, P. R. Garcia, D. J. Murphy, D. Rankin, G. Schwartz, H. N. Singer, S. Thompson and D. A. Viljoen. One Graduate Mr D. Bosley. Ten Visitors, including Messrs S. Adler, C. E. Alvey, B. J. Botha, K. Chant, L. W. Davis, R. N. Guest, R. V. Keet, E. G. Keown, M. D. Lourie and S. McMurray. Secretary Mr D. C. Visser. Total present: Fourty-one. MINUTES The President requested that confirmation of the minutes of the previous meeting be held over as they would only be appearing in the Journal of the following month. Agreed. MEMBERSHIP The President: "I have much pleasure in announcing that the names of the under-mentioned candidates, having been published in accordance with By-law 5.2.2, Council has elected them to membership of the Institute in the following grades: Members: Kenneth Sinc1air Rae, Ian Robert Malcolm Chaston. Associate Members: Norman Isaac Thomas, Ian Connell Robinson. Graduates: Simon Richard Jeremy Perkins, Bleddyn Reginald Lear, David Williams. Affiliate: Richard Robert Will. Students: Angus David McElwee, Clive Renard Archer, Peter Andrew Locke. MEMBER TRANSFERRED TO A HIGHER GRADE From Graduate to Associate Member: Patrick James Burns. I welcome the newly elected members to the Institute and congratulate the member who has been transferred to a higher grade." (Applause). GENERAL BUSINESS The President reminded members that a buffet supper at a cost of 55c would be available after the meeting. PAPER FOR PRESENTATION The President noted with pleasure that a strong contingent from De Beers and the Finsch Mine were present. He expressed gratitude to Mr Loftus for coming

By I. A. Mwamba

Titanium aluminide of composition Ti-47.5 at.% Al was prepared by melting titanium and aluminium of commercial purity with additions of precious metals of 0, 0.2, 1, 1.5 and 2 at.% content. The microstructure, hardness and oxidation properties were assessed. It was found that at 47.5 at.% Al, the microstructure of plain TiAl alloys was duplex, consisting of duplex lamellar grains and ? grains. The lamellar grains consisted of alternating lamellae of ? (TiAl) and a2 (Ti3Al), with overall aluminium content in the range of 43?47 at.%. The ? grains had a aluminium content above 50 at.%. The addition of precious metals to the TiAl alloy resulted in the formation of a new phase, with a high precious metal content, occurring mostly in the ? phase, without any major change to the microstructure. Increasing the amount of precious metals resulted in an increase of the new phase amount, at the expense of the ? phase. The hardness of the different alloys was around 300HV10. Overall, the research has shown that addition of precious metals to TiAl resulted in a slight increase in hardness and a significant improvement of the oxidation resistance. This shows that alloying TiAl with precious metals, at the addition levels investigated, does not alter the mechanical properties very much, but improves oxidation resistance.

Jan 1, 2012

By A. E. Lewis, J. Du Plessis, J. Chivavava

Current metallurgical processes lack selective and efficient REE recovery from aqueous leach liquors. Antisolvent crystallisation is used to selectively recover pure inorganic salts from aqueous solutions without excessive chemical use in ambient conditions. Yttrium sulfate octahydrate (Y2(SO4)3.8H2O) was used as a representative rare earth salt to investigate the effect of antisolvent selection on the crystal morphology and size distribution of the final crystalline product produced through antisolvent crystallisation. The antisolvents of choice were short length alcohols that are water miscible i.e. methanol, ethanol, 2-propanol and t-butanol. All experimental parameters except the type of antisolvent were kept constant under isothermal conditions. The large reduction in solubility of the salt by the antisolvent creates high supersaturations. This leads to high product yields as observed in this study at > 91%. In general, a variety of morphologies were successfully formed in each individual alcohol including; rods, plates, prismatic cubes and starburst clusters. The powder X-ray diffraction (XRD) analysis indicated that Y2(SO4)3.8H2O was the only species present for all final products. There was a change observed from the starburst and rod structures for the shorter alcohols towards prismatic cubes for the longer alcohols due to different strengths in the solute-antisolvent interaction at the crystal growth faces. The crystal sizes increased with an increase in the alcohol chain length because of the lower supersaturation conditions due to a limit in the mass transfer induced by the bulkier alcohol structure. In conclusion, it has been shown that the particle morphology and size can be greatly affected by the selection of antisolvent even under high supersaturation conditions, contributing to understanding the effect of different antisolvents on the final particle characteristics. The engineering of favoured product characteristics can therefore be achieved by antisolvent crystallisation, presenting a viable alternative process for the recovery of REE. Keywords: Antisolvent crystallisation, rare earth elements, morphology, particle size

Jan 1, 2020

1. Mintek publications The folowing are available from Mintek (Private Bag X3015, Randburg, 2125 South Africa) at R35 (including GST) per copy to purchasers in South Africa and US$30 (including airmail postage) to purchasers elsewhere. Report M402 The preparation of synthetic fusion standards for use in the X-ray-fluorescence analysis of rocks and minerals, by RT. Eddy and J.J. Jacobs. Apr. 1990. 19 pp. Report M405 Slag-metal equilibria in the system Fe-Cr-Si-C-Ca-Mg-AI-O, by R.H. Eric and M. Akyizli. Aug. 1990. 29pp. Application Report no. 8 The development of a process for the recovery of gold from gold-bearing solutions by means of activated carbon or resin in a NIMCIX column. 1990. 19 pp. 2. New publications from Trans Tech The folowing are available from Trans Tech Publications Ltd, Old Post Road, Brookfield VT05036, USA. Efect of iron and silicon in aluminium and its aloys, edited by I. Kovacs. 1990. 450 pp. $124. Martensitic transformations, edited by B'.C. Muddle. 1990. 714 pp. $190. Ferites, edited by C.M. Srivastava. 1989. 2 vols. 1280 pp. $254. Properties and characterization of amorphous carbon films, edited by J.J. Pouch and S.A. Alterovitz. 1990. 714 pp. $152. Synthesis and properties of boron nitride, edited by J.J. Pouch and S.A. Alterovitz. 1990.426 pp. $192. Electronic structure and latice defects in aloys, edited by R. W. Siegel and F .E. Fujita. 1989. 320 pp. $78. 3. A new edition Tomorow's materials, by K.E. Easterling. London, The Institute of Metals (1 Carlton House Terace, London SWIY 5DB, England), 1990. 2nd ed. 170pp. US$29. 4. Books for exploration geologists The folowing books are obtainable from Elsevier Science Publishers, P .0. Box 211, 1000 AE Amsterdam, The Netherlands. Lateritic bauxites, by G. Bardossy and G.J.J. Aleva. 1990. 624 pp. DFL. 295. Platinum-group element exploration, by D.L. Buchanan. 1988. 186pp. DFL 150. Lead isotopes in mineral exploration, by B.L. Gulson. 1986. 246 pp. Dfl. 160. Prospecting and exploration of mineral deposits, by M. Kuzvart and M. B6hmer. DFL. 285. 5. Journal for earth scientists . Ore Geology Reviews, published by Elsevier Science Publishers, P.O. Box 211, 1000 AE Amsterdam, Netherlands. 6 issues per year. Annual subscription DFL 453 including postage.

Jan 1, 1990

By C. Birch

"Mineral reserve statements as well as optimizing mine planning require a block model with grades for each mining block. A cut-off grade is determined by considering the mining costs as well as the expected revenue for each block. These grades are estimated using various techniques, but in reality there is uncertainty in the grade values. These uncertainties result in two types of error. A type I error is where material is classified as ore and mined, but the true value is below the cut-off grade and the material is therefore waste. This material constitutes dilution. The type II error is where material is estimated to be below the cut-off grade and is classified as waste, whereas the true grade is actually above the cut-off grade. This material is not mined and the value is lost.This research considers the value of the lost ore and the costs of dilution under various degrees of uncertainty. Simulation using @Risk and mixed integer linear programing (Excel Solver) is used in a financial optimizer model to maximize either profit or net present value. This is applied to four Witwatersrand tabular gold deposits to investigate the impact of block grade uncertainty on cut-off grades.When optimizing for profit, value may be added by adjusting the cutoff grade slightly downwards. When optimizing for NPV, value may be added by lowering the cut-off grade significantly for the lower discounting rates. At higher discount rates, the lowering of the cut-off grades should be reduced, and in some cases an increase in cut-off grade may be required. Each mine reacted differently to the optimization and thus there is no single rule that can be applied across all tabular Witwatersrand gold deposits."

Jan 1, 2017

By J. L. Havenga, L. J. van der Walt, J. T. Nel, H. Bissett

"SynopsisNew technologies used to manufacture high-quality components, such as direct laser sintering, require spherical powders of a narrow particle size distribution as this affects the packing density and sintering mechanism. The powder also has to be chemically pure as impurities such as H, O, C, N, and S causes brittleness, influence metal properties such as tensile strength, hardness, and ductility, and also increase surface tension during processing.Two new metal powder processes have been developed over the past few years. Necsa produces zirconium powders via a plasma process for use in the nuclear industry, and the CSIR produces titanium particles for use in the aerospace industry.Spheroidization and densification of these metal powders require remelting of irregular shaped particles at high temperature and solidifying the resulting droplets by rapid quenching. Spherical metal powders can be obtained by various energy-intensive methods such as atomization of molten metal at high temperatures or rotating electrode methods. Rapid heating and cooling, which prevents contamination of the powder by impurities, is, however, difficult when using these methods for highmelting- point metals. For this reason plasma methods should be considered.Thermal plasmas, characterized by their extremely high temperatures (3000–10 000 K) and rapid heating and cooling rates (approx. 106 K/s) under oxidizing, reducing, or inert conditions, are suitable for spheroidization of metal powders with relatively high melting points. Thermal plasmas for this purpose can be produced by direct current (DC) plasma arc torches or radio frequency (RF) inductively coupled discharges. In order to obtain chemically pure spheroidized powder, plasma gases such as N2, H2, O2, and CH4 cannot be considered, while Ar, Ne, and He are suitable. Neon is, however, expensive, while helium ionizes easily and it is therefore difficult to obtain a thermal helium plasma at temperatures higher than 3000 K. Therefore argon should be used as plasma gas. Residence times of particles in the plasma region range from 5–20 ms, but this is usually sufficient as 7–8 ms is required for heating and melting of titanium or zirconium metal particles in the 30 µm size range at 3500 K. In this study the melting and spheriodization of titanium powders was investigated by DC non-transferred arc and RF induction plasma methods. The powders were characterized before and after plasma treatment by optical microscopy and scanning electron microscopy (SEM) to observe if any melting or spheroidization had occurred."

Jan 1, 2015

By C. Dorfling, M. Tadie, S. Grobbelaar

The physicochemical properties of the complex electrolytes used in direct copper electrowinning are an important consideration for the development of a high-fidelity model of the process. Direct electrowinning electrolytes typically contain a high background of metallic impurities. The effect of metallic ions on the properties and accompanying change in the limiting-current density for copper reduction have been the subject of several studies. Although various empirical correlations have been published for describing the physicochemical properties of electrowinning electrolytes, the correlations are only applicable to a limited range of conditions and cannot be extrapolated without further validation. Consequently, in this paper we validated existing physicochemical property correlations for the full range of operating conditions applicable to direct copper electrowinning and developed a new correlation for predicting the associated limitingcurrent density for copper deposition. Following, we evaluated the benefit of using the validated correlations as a component of a dynamic electrowinning model.

Jan 1, 2023