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By J. D. Marchant

As part of its mission to assure the maximum recovery and use of the Nation's mineral resources, the Bureau of Mines, investigated an improved procedure for producing rare earth-silicon alloys. For example, a charge consisting of 681 grams of mixed rare-earth oxides, 309 grams of ferrosilicon (75 wt-pct Si), and 182 grams of aluminum metal along with a flux consisting of 681 grams of CaO and 45 grams of MgO was reacted at 1,500° C in an induction furnace. Good slag-metal separation was achieved. The alloy product contained, in weight-percent, 53 RE, 28 Si, 11 Fe, and 4 Al with a rare earch recovery of 80 pct. In current industrial practice rare earth recoveries are usually about 60 pct in alloy products that contain approximately 30 wt-pct each of rare earths and silicon. Metallurgical evaluations showed the alloys prepared in this investigation to be as effective in controlling the detrimental effect of sulfur in steel and cast iron as the commercial rare earth-silicon-iron alloys presently used in the steel industry.

Jan 1, 1980

By G. A. Burrell, G. W. Jones

As a part of the work which the Bureau of Mines carried out in 1916 and 1917 pertaining to the compressibility of natural gas , it became necessary to de termine the pressure -volume relations of several of the paraffin hydrocarbons of which natural gas is composed . Results of the work on natural gas were published in Technical papers 131 (Burrell , G.A. , and Robertson , I.W. , The compressibility of natural gas to high pressure , Bureau of Mines Tech . Paper 131 , 1916 , 12 pp. ) and 158 (Burrell , G.A. , and Robertson , I.W. , Compressibility of natural gas and its constituents with analyses of natural gas from 31 cities in the United States , Bureau of Mines Tech . Paper 158 , 1917 , 12 pp . ) , and curves were given of pressure volume deviations of the gases , methane , ethane , propane , and carbon dioxide at high pressures . original experimental data on these gases , however , were not published . The In view of many inquiries which the Bureau has received with reference to the original data on the se gases , and the importance of the pressure -volume relations from which it is possible to calculate the deviation of any natural gas who se composition is known , the original data as determined by Burrell and Robertson are pre sented below .

Aug 1, 1921

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

9. Remote Sealing System Sensitivity 9. 1 Introduction In the previous sections a description of the overall system has been presented along with detailed descriptions of the equipment and techniques employed with the preliminary probing system, the seal em¬placement system and the seal checking system. In addition, the use of these subsystems in a specific mine application has been described in considerable detail. A broad range of parameters of interest was specified in the contract, as summarized in Section 1. 3. Most of these are a function of the general location; i. e. , the location of the mine, and the specific location; i. e. , the location of the boreholes. These parameters of interest include passage size, shape, depth, slope and water con¬ditions. The length, diameter and location of the boreholes within the mine passage and on the surface are critical parameters as well. A few additional parameters may affect one or more of the remote sealing subsystems. These include temperature, topography, rock and soil conditions, and underground water. While variation in these parameters will not render the system inoperative, consideration of them in the planning stages will simplify and expedite the field operation. In the following sections the effect of the various parameters on the remote sealing operation will be discussed. For clarity, the several tasks, borehole drilling and casing, preliminary probing, fly ash delivery, foam topping and seal checking, will each be considered separately.

Jan 1, 1973

By David W. Wisecarver

This report describes a tool to engage and/or place a Bureau of Mines type gage to measure borehole deformation in a horizontal , 1½ - inch - diameter , stress relief borehole . The tool was successfully used at a borehole depth of 105 feet . Practical usage up to borehole depths of 200 feet might be realized . The tool was designed to work inside EX- size ( 1½ - inch ID ) diamond - drill drive casing used as drill rod and through which the deformation gage is guided into an EX- size stress relief borehole . Through laboratory experiments it was found that by exercising a reasonable amount of care the deformation gage could be placed at a point within a ± .01 foot distance of a predetermined depth in a horizontal EX- size hole and that the deformation measuring piston or plunger of the gage could be oriented in the borehole within 0.5 ° of a preselected angle of orientation in a vertical plane .

Jan 1, 1964

Improve the dust control effectiveness of dry collection systems on surface coal mine drills. Approach Use a dust pelletizer to convert the respirable dust particles discharged by the dry collector into dust pellets that present no health hazard. Background Blasthole drills are well-known sources of respirable dust that can contain significant amounts of quartz. The drills frequently use a dry cyclone-filter type collector that can obtain dust reductions theoretically greater than 95 pct. However, surface mine drills using dry collectors typically have three major dust sources that significantly reduce the overall effectiveness of the collection system: (1) the dust collector dump cycle, (2) drill shroud leakage, and (3) leakage around the drill stem seal in the drill table.

Jan 1, 1989

By C. J. Chindgren

The Bureau of Mines investigated the technical problems involved in recovering commercial-grade vanadium products from alkaline solutions of low vanadium content. Conditions were defined for precipitating calcium vanadates from sodium vanadate solutions with calcium chloride and calcium hydroxide and for dissolving the precipitates with acid, sodium carbonate, and sodium bicarbonate to obtain vanadium-enriched solutions from which either red cake or ammonium metavanadate was recovered. Calcium vanadates with CaO:V205 mole ratios of 2, 3, and 4 were produced with recoveries of 93 to 100 percent. Optimum recovery of the low-lime variety of calcium vanadate was obtained by employing excess calcium chloride and adjusting the pH to a range of 8.0 to 8.5. High vanadium extractions were obtained in concentrated solutions by dissolving the calcium vanadate precipitates with any of the reagents tested. The resulting extracts contained 25 to 125 grams V205 per liter. Conventional procedures used to precipitate either red cake or ammonium metavanadate from the enriched solutions gave excellent vanadium recoveries.

Jan 1, 1967

By D. E. Seizinger

The Bureau of Mines has developed analytical methods, primarily gas chromatographic, for measurement of exhaust oxygenates produced from selected simple fuels. The resulting data were used to estimate levels of carbonyls and noncarbonyl oxygenates in exhaust from gasoline fuels. Estimated noncarbonyl oxygenates in gasoline exhaust may comprise as much as 30 pct of total oxygenates which include unsaturated carbonyls and noncarbonyls believed to be significant potential pollutants.

Jan 1, 1972

By Gerald J. Joy, Paul J. Middendorf

This study examines the patterns and trends in noise exposure documented in data collected by Mine Safety and Health Administration inspectors at U.S. coal mines from 1987 through 2004. During this period, MSHA issued a new regulation on occupational noise exposure that changed the regulatory requirements and enforcement policies. The data were examined to identify potential impacts from these changes. The overall annual median noise dose declined 67% for surface coal mining and 24% for underground coal mining, and the reduction in each group accelerated after promulgation of the new noise rule. However, not all mining occupations experienced a decrease. The exposure reduction was accompanied by an increase of shift length as represented by dosimeter sample duration. For coal miners exposed above the permissible exposure level, use of hearing protection devices increased from 61% to 89% during this period. Participation of miners exposed at or above the action level in hearing conservation programs rapidly reached 86% following the effective date of the noise rule. Based on inspection data, the occupational noise regulation appears to be having a strong positive impact on hearing conservation by reducing exposures and increasing the use of hearing protection devices and medical surveillance. However the increase in shift duration and resulting reduction in recovery time may mitigate the gains somewhat.

By Jack C. White

The purpose of this Bureau of Mines work was to develop information useful in improving copper recovery during copper milling operations. Eleven copper mill tailings from the Western United States were subjected to froth flotation and cyanide leaching to provide an experimental basis for comparing their beneficiation response. Recoveries in flotation concentrates made from mill tailings ranged from 65 to 15 percent, at copper grades of 13 and 2.2 percent, respectively. Liberated copper sulfide minerals present in two samples were readily recovered by laboratory froth flotation. Nine of the samples were less amenable to froth flotation because of physical locking between copper sulfide minerals and gangue. Correlations among tailings indicated that recovery of sulfide copper by flotation was directly related to the sulfide copper content. Empirical equations derived from flotation data provided average values for unrecoverable copper and for recovery efficiency. Flotation response of copper mill tailings may be predicted from the equations. Data from cyanide leaching provides an equation describing the limiting high values for removal of copper by this method.

Jan 1, 1974

By M. L. Whisman

The Bureau of Mines developed a radiotracer method for detecting the contribution of selected components and additives to thermally induce deposits of turbine aircraft fuels. Fuels were examined before and after 52 weeks of storage at 130° F. Of particular concern was the influence of aromatic hydrocarbon fuel constituents on thermal-stability quality of jet fuels during storage. A microfuel coker test apparatus was used to thermally stress the test fuels and blends, and the resultant contribution to deposits of selected fuel components, labeled with carbon-14, was determined by radioactive-counting techniques. Ninety-one blends of five test fuels with carbon-14-labeled fuel additives or components were prepared, tested, stored for 52 weeks at 130° F, and reanalyzed for deposit-forming tendency. These additives included two anti-oxidants, a metal deactivator, and a corrosion inhibitor. Of the labeled hydrocarbon fuel systems studied, the greatest reaction was observed in blends containing methyl-and ethyl-substituted indenes. Other aromatic types also showed some contribution to the deposits. Three of the additives showed a marked tendency to degrade and react during storage and thermal stress. A cresol antioxidant, however, barely contributed to deposit formation. Oleic acid interacted with cadmium present in aircraft fuel systems and produced deleterious effects upon the thermal-stability quality of the fuel.

Jan 1, 1971

CESIUM metal production increased sharply in 1963. Domestic Production.--Cesium metal was produced by The Dow Chemical Co., Midland, Mich., MSA. Research Corp., Callery, Pa., and by Penn Rare Metals, Inc., Revere, Pa. American Potash & Chemical Corp., Trona, Calif., produced some combined cesium and rubidium. This company, Penn Rare Metals, Inc., and Rocky Mountain Research, Inc., Denver, Colo., produced various cesium compounds. Complete production data on cesium and rubidium and their compounds were not available for publication. Consumption and Uses.-Substantially more pollucite was consumed to produce cesium metal and compounds in 1963 than in 1962 but the overall consumption of pollucite continued to be small.

Jan 1, 1964

By Lisa Steiner, Robin Burgess-Limerick

In 2004, there were 646 underground coal mines in the USA employing 37,445 miners. These mines reported 3556 injuries to MSHA that year - 17% were associated with bolting machines (593 injuries), 8% with continuous miners (283 injuries), and 4% each with Scoop/LHD (1 51 injuries), shuttle cars (134 injuries), and personnel transport (145 injuries). The use of the frequency of reported injuries for the prioritization of risk control strategies has limitations because of the tendency to underestimate the importance of relatively rare but high-consequence events. Injury reports also underestimate the contribution of risk factors such as whole body vibration, which have a long-term cumulative contribution to an elevated risk of injury. However, taking these limitations into consideration, the results of the injury narrative analysis suggest the following hazards as the highest priority for elimination or control: • rock falling from supported roof • inadvertent or incorrect operation of bolting controls • handling continuous miner cable • collisions while driving LHD/Scoop, shuttle cars and personnel transport • rough road while driving or traveling in LHD/Scoop, SC & PT

Provide a low-cost, low-maintenance method for im¬proving mine water quality on abandoned mine land (AML) sites. Approach A model (figure 1) is presented for selecting, designing, and sizing one or several passive mine drainage treatment systems that can be used in remediation of AML. The three principal types of passive mine drainage technologies for the treatment of coal mine drainage are an aerobic system, a compost wetland, and an anoxic limestone drain. The multistep approach presented here provides a simplified method to characterize the type and magnitude of the water quality problem and then to select either a single treatment system or a combination of treatment systems to address the specific site situation. How It Works Step 1. Discharge Characterization. Characterization of the discharge consists of measuring the discharge flow rate and collecting water samples at the point of discharge for chemical analysis. Both the flow rate and chemistry of a discharge can vary seasonally and in response to storm events. It is important to account for this variability by determining flow rates and water chemistry under various conditions. Water should be analyzed for pH, dissolved iron (Fe), alkalinity, and hot acidity (using the H2O2 method).

Jan 1, 1994

By H. K. Sacks

The Bureau of Mines has improved a mine dust incombustibles analyzer originally developed at the Bartlesville Energy Research Center (BERC). This analyzer provides quick, accurate analysis of the percentage of incombustible material present in dust samples taken from mine ribs, roof, and floor so that costly overdusting may be eliminated while still maintaining a proper level of incombustibles. The changes being effected on the present design of the BERC model IV rock dust analyzer should simplify its operation and calibration procedures, resulting in increased accuracy.

Jan 1, 1976

By J. E. Murphy

Field freezing was used by the Bureau of Mines to effect the redistribution of the components in a cerium-12.5-atomic-percent-iron alloy. The application of the electric field caused the iron to migrate toward the anode. A field intensity of 0.04 v/cm and a current density of 240 amp/cm2 were used. The conditions that yielded the greatest redistribution of alloy components were a small thermal gradient along the specimen (from 5° C/cm to 10° C/cm) and a very slow freezing rate (0.15 cm/hr). Under these conditions it was possible to process specimens of ½ -inch diameter as compared with the capillary-size specimens used by most previous investigators.

Jan 1, 1968

By Theodore Christos

The Bureau of Mines sponsored an investigation of the thermal oxidative degradation characteristics of certain solvents and hydraulic fluids used in underground mining operations. The following halogenated solvents were studied in view of their usefulness and their flame retardant property: tetrachloroethylene, C12C = CC12; 1, 1, 2-trichloroethane, CIH2CCHC12: and trichloroethylene, C12C = CHC1. The hydraulic fluids studied were representative of five groups approved by the Mine Safety and Health Administration for underground operation, namely: glycol-water solutions, mineral oil-water emulsions, synthetics other than phosphate esters, synthetic phosphate esters, and mixtures of phosphate esters with mineral oils and other ingredients. It was observed that the partially halogenated solvents present a greater potential toxic hazard than the fully halogenated materials, due not only to the easy production of hydrogen chloride but also to their ease of oxidation leading to the formation of phosgene and carbon monoxide. The pure phosphate esters exhibited the best thermal oxidative stability of the five groups of hydraulic fluids tested. A fluid containing phosphate esters mixed with mineral oils and other unidentified ingredients appeared to be the most hazardous On the basis that it produced very toxic acrolein and phosphine.

Jan 1, 1980

By J. E. Dooley

An analytical procedure developed by the Bureau of Mines was applied to the separation and characterization of a 370° to 535° C distillate from Swan Hills (south field), Alberta, Canada, crude oil. Investigators determined the general characteristics of the crude oil by the Bureau's routine method for crude oil analysis. Suitable fractions were prepared for instrumental analyses by utilizing such techniques as isothermal and molecular distillations, chemical treatment, silica-alumina gel chromatography, and gel permeation chromatography (GK). A detailed characterization of the 370° to 535° C distillate was possible by the application of GPC-mass spectrometry correlations and nuclear magnetic resonance spectrometry. Semiquantitative data based on mass Z series distributions were determined and are shown. The data will be valuable in developing future processing techniques and in calculating yields for converting high-boiling distillates into more useful energy forms.

Jan 1, 1973

By M. L. Skow, Maurice Deul, M. G. Zabetakis

This Bureau of Mines report presents a brief summary of the explosion trends in United States coal mines for the past 160 years. These trends show that in spite of the overall improvements in mine safety, the number of fatalities from ignitions of methane has actually increased in recent years. Suggestions are made of procedures that can be utilized to reverse this trend.

Jan 1, 1972

By Jalna R. Zatko

The Bureau of Mines, U.S. Department of the Interior, has developed a novel method of flocculation dewatering of phosphatic clay wastes using polyethylene oxide as the flocculant. Research was conducted to determine whether ethylene oxide gas was present in the air in the vicinity of disposed waste materials which had been flocculated with polyethylene oxide. Samples of clay waste materials containing polyethylene oxide were prepared in stoppered glass bottles in simulated disposal environments. Gaseous samples, removed over a 75-day period using an airtight syringe, were injected into a gas chromatograph that was capable of separating ethylene oxide from air. The presence of ethylene oxide gas was not detected in any sample. To determine possible degradation products of polyethylene oxide, the properties and reactions of ethylene oxide and its polymers were reviewed. Based upon the literature survey and experimental study, it was concluded that adverse environmental effects were not likely to result from the use of polyethylene oxide for flocculating phosphatic clay waste products.

Jan 1, 1980

Provide reasonably priced, reliable fire protection for blasthole drills. Approach An automatic fire sensing and suppression system using both dry and gaseous chemicals was developed, and is more shock and vibration resistant than similar industrial fire protection systems. How It Works Temperature sensors mounted in the drill's machinery house, hydraulic room, operator cab, and transformer area detect the heat from a fire, and trigger a sequence of actions. The same fire fighting sequence can be initiated from manual alarm boxes in the cab, hydraulic room, or machinery house. Electrical power to the drill Is immediately cut off, and a horn sounds to warn the drilling crew. After a 40-second, built-in, delay to allow time for drill's ventilating fan to stop, gaseous and dry chemical fire extinguishing agents are piped to and released in various rooms of the drill. The gaseous extinguishing agent (Halon 1301) is released in the machinery house, hydraulic room, and operator cab where dry chemical clean-up from electrical panels and machinery would be difficult and costly. Dry chemical is piped to the transformer room at the rear of the machine. Location of the principal components of the system are shown in the drawing.

Jan 1, 1979