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By Mark I. Copeland

The Bureau of Mines discovered that silicon and nickel additions can prevent the formation of copper alloys of Sn, Sb, and As on the surface of steel during reheating to hot-working temperatures. When molten, these copper alloys cause surface hot shortness during hot working. Wrought steels were reheated isothermally and by simulated industrial practice; the resulting surfaces were metallographically evaluated. The steels contained, In weight-percent, 0.20 C, 0.45 Mn, and up to 1.00 Si, 1.00 Cu, and 0.15 Ni, and up to 0.30 Sn, Sb, or As. The larger the Cu, Sn, Sb and As content of the steels, the greater the amount of silicon necessary to prevent copper alloy formation. A content of 0.10 Ni considerably decreased the amount of silicon necessary for copper steels containing tin and antimony, but not for those containing arsenic. Theories for the beneficial effect of silicon and nickel additions are presented.

Jan 1, 1975

By W. E. Miller, Kennedy. R. E., G. W. Jones

"INTRODUCTION Ethyl mercaptan (CH3,CH2SH), a combustible organic liquid of the thioalcohol type, is employed at an odorant in many types of fuel gases and dangerous atmospheres, which in themselves are devoid of characteristic odors, to give warring against leakage of such gases or atmospheres into places where they might constitute health or explosion hazards.Ethyl mercaptan has a penetrating disagreeable odor resembling that of onions, garlic, hydrogen sulfide, or rotting cabbage, that exceedingly low concentrations of it can be detected. The of odorants as a beans of detecting leakage of gases and atmospheres has been investigated extensively by chemists and engineers of the Bureau of Mines, and numerous reports as to its value have been published."

Jun 1, 1942

By S. E. Khalafalla

The ability of potentiometric, gas-sensing electrodes to reliably monitor free gaseous molecules in solution has been recently demonstrated. A gas such as sulfur dioxide from a dilute sample solution diffuses through a hydrophobic, gas-permeable membrane to an internal filling solution. The latter solution contains a sufficiently large excess of sodium bisulfite, the concentration of which can be considered constant regardless of the quantity of sulfur dioxide entering by diffusion. The electrode response is essentially due to the liberated hydrogen ions from the bisulfite-sulfur dioxide equilibrium. This Bureau of Mines report describes a new technique used to detect the formation, and to estimate the stability constant, of gas-molecule and gas-ion complexes in solution, as part of an effort to minimize the undesirable environmental impacts associated with mining and mineral processing. Although the unknown activity coefficients of the neutral and ionic species in the external solution complicate the quantitation of results, methods to circumvent these difficulties are presented. The technique is based on the isometric shift of the Nernst diagram of ion-selective electrodes to higher concentrations relative to the standard aqueous calibration curve. The method is applied to detect and estimate the formation constant of a sulfitocitrate complex, and agrees well with an independently determined stability constant of the disulfitomercu-rate complex.

Jan 1, 1978

By M. V. Potter

"In nearly all fields of investigation, research laboratories and routine testing laboratories encounter problems in which the primary determinations involved in the study require the measurement of mechanical vibrations or motions. These vibrations,may be of an oscillatory nature covering frequencies from a few cycles per second up to hundreds of Kilocycles per second, or they may be more or less uniform study nations occurring at rather slow rates. In electrical, or mechanical methods. In the optical case the to cause the deflection of a light beam such that the motion of the mechanican system of the beam can be determined, then by direct the by direct observation on a suitable scale or by recording it’s the electrical methods the motions can be made to changes in resistance, capacity or inductance proportion to the mechanical displacement or electromagnetic means can used to generate directly a voltage that will be porpertuial to the instantaneous vicinity of the vibrations. Other devices are used in a special instance, also but in any cause the electrical methods produce a current that is an electrical counterpart of the mechanical motion, and the motion can then be studied by direct measurements of the current or by recording the current on suitable recording meters or oscillography. Mechanical methods are used in some instance but are generally not as convenient nor as flexible as the optical and electrical methods."

Feb 1, 1943

By Samuel A. Goldberg

The Federal Coal Mine Health and Safety Act of 1969 delegated to the Bureau of Mines a yearly program of health inspections. Respirable coal mine dust concentrations are measured by Bureau inspectors. Samples of respirable coal mine dust are weighed to determine dust concentration and then analyzed for ash and quartz content. This paper describes the laboratory procedure for determining the percent quartz in the respirable coal mine dust samples.

Jan 1, 1972

By Connie S. Musulin

Radon concentrations in shallow uranium mines such as the Bureau of Mines experimental research mine are affected by barometric pressure changes. The radon concentrations show a significant correlation with absolute pressure; but over a period of days, a steady rise or fall in barometric pressure will result in noncorrelation of data. Fan shutdowns also affect radon concentrations, and an equation was derived to determine the time required for the radon concentration to return to normal after a fan shutdown, whether the ventilation is blowing or exhausting.

Jan 1, 1982

By B. J. Dalton

This report gives general expressions for evaluating various thermo-dynamic properties applicable to a two-component system, including liquid-vapor equilibria. In addition, expressions are developed for some of the quantities useful in making thermodynamic consistency checks on phase equilibria data. These formulas were developed from the general principles of thermodynamics and are expressed in terms of the compressibility factor, which is assumed to be an explicit function of the molal density, the absolute thermodynamic temperature, and the composition.

Jan 1, 1968

By G. W. Murrie, W. P. Diamond, C. M. McCulloch

It is estimated that more than 1 trillion cubic feet of methane is contained within the coals of the Mary Lee group in Jefferson, eastern Tuscaloosa, and southern Walker Counties, Ala. Most of this methane will be encountered by mining. Coals of the Mary Lee group are presently being mined at depths exceeding 1,000 feet and will in the near future be mined at even greater depths, where the problem of methane gas affecting the mining operations will be acute. It is calculated that approximately 90 pct of the methane is at depths greater than 1,000 feet, and over half of the gas is contained within only 12 pct of the study area which is under more than 1,500 feet of over- burden. Degasification in advance of mining will increase mine safety, reduce ventilation expenditures, increase productivity, provide an additional energy source, and make it possible to mine parts of deep coalbeds that probably could not otherwise be mined.

Jan 1, 1976

By P. Comba

The U.S. Bureau of Mines investigated a hydrochloric (HC1)-calcium fluoride (CaF2) leaching procedure to treat domestic manganese (Mn)-bearing silicate resources. The proposed process is an alternative to high-temperature and energy-intensive extractive techniques. Single-stage leaching with a stoichiometric amount of HCl and a F-Mn mole ratio of 0.2 extracted 96 pct of the Mn when the leach conditions were 50° C, 3 h, and 35 pct solids. Ninety-eight percent of the Mn was extracted during countercurrent leaching at similar conditions. A process flowsheet was developed that incorporated HC1-Cab leaching, excess leach acid utilization, fluoride (F) recycle, and Mn recovery. When the domestic manganese silicate ore was processed, 98 pct of the Mn was extracted, 99 pct of the Cab was reclaimed, and a leach residue was produced that passed the Environmental Protection Agency (EPA) Extraction Procedure (EP) Test for nonhazardous waste.

Jan 1, 2010

By J. H. Perkins

The Bureau of Mines has conducted desorption work on fine coal particles at near atmospheric pressure. An apparatus Iris been developed that uses a capacitance manometer to measure desorption of methane from coal particles up to, 2 inches in diameter and pressures up to 1,000 psi. This will make it possible to duplicate the desorption process as it occurs in its natural underground environment.

Jan 1, 1969

By Martin S. Oudenhoven

This report describes the results of a Bureau of Mines investigation in which the stress concentrations and distributions caused by inclusions in a strained elastic plate were determined, Finite element analyses were made for 168 models containing single inclusions of elliptical, ovaloidal, and rectangular shape. The variables studied included: horizontal-to-vertical loading ratios, (Sh/Sv) of 0,0.33,0.5, and 1.0; width-to-height ratios (w/h), of 0.25, 0.5, 2, and 4; and Young's modulus of inclusion to Young?s modulus of plate ratios (K ratios) of 0.33, 0.5, 2.0, and 5.0. The results show that the theory for elliptical inclusions can accurately predict the average stress along the x and y axes of symmetry for circular, ovaloidal, and rectangular inclusions from the width-to-height and K ratios. The actual inclusion shape was insignificant, suggesting that the average stresses in other inclusions of irregular shape (orebodies) can be estimated with the theory for an elliptical inclusion. An application of this technique to mining problems is presented. The stresses in the elliptical inclusions were uniform throughout the inclusion for all the models studied.

Jan 1, 1972

By Edward L. McHugh, Jami M. Girard

While less than 1% of reported accidents are associated with slope stability problems, slope failures were responsible for about 15% of all U.S. surface mine fatalities between 1995 and 2001. Small rockfalls, which may involve hand-sized rocks weighing only a few kilograms, can cause fatal injuries to workers away from the protection of large machinery. Massive highwall failures containing a million cubic meters of material or more can be fatal even for heavy equipment operators. As part of an ongoing study at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health, several remote-sensing technologies are being evaluated as tools to monitor slopes for hazards and to assess slope stability. Field tests of a hyper spectral imager were conducted to assess its value for improving geologic maps of potentially unstable alteration zones on mine slopes. An interferometric radar device capable of detecting very small displacements on slopes awaits final assembly and field testing. Computerized monitoring methods using images from digital and video cameras are being assessed for application to mine slope surveillance. These and other techniques will eventually provide new tools to augment current methods for monitoring ground control hazards in mines.

By D. Harrington

"The fire boss in coal mining and the shift boss in metal mining, though held responsible to a large extent for safety of underground employees and of the mine, are, it seems to me, not always vested with sufficient authority nor given compensation commensurate with their duties. The metal-mine shift boss, although his position as regards his relations between employer and employee, is frequently an unenviable one, has as a rule much more authority than the fire boss and is not expected to perform the menial tasks required of the latter by many coal-mining companies.In most coal-mining States the coal-mine foreman and the fire boss are re¬quired to possess a certificate of competency obtained by passing an examination. The foreman is legally responsible for the safety of the miners, as in most instances the superintendent is not required to pass an examination. Although the foreman is held legally responsible for the safety of the miners, the law does not, in general, compel the superintendent or other higher officials to delegate sufficient authority to the foreman to enable him to put his wishes or judgment into effect; and this condition has tended in many instances towards perpetuation of unsafe conditions.The fire boss is held legally responsible for conditions in his ""beat"", but he is generally given only such authority as the mine foreman sees fit to delegate, frequently very little, Moreover, the fire boss is generally required to cover his ""beat"" within two hours before the entrance of the underground workers. Only too often his territory is so great that in order to reach all the working faces and chalk the required date at the face, he must travel at a rapid walk or even run. When such haste is necessary to cover the required ground, it is manifestly im¬possible for the fire boss to make a careful inspection or examination of the roof, timbering, wiring, gas, etc., at each place, and doubtless in his hurry many unsafe conditions escape his notice."

Sep 1, 1920

By C. W. Owings

Two problems perplex many coal-mine operators and employees. Is coal-mine dust harmful to breathe; and, if so, is it possible to keep the concentration below the danger point? The medical profession is not unanimous in its opinion of the danger of breathing bituminous-coal dust, but there appears to be ample and increasing evidence that coal-mine dust can be harmful if breathed in large enough doses for long periods. The question of controlling the dust at the point of formation is still unanswered in the minds of many in the mining industry. However, results of limited studies conducted by the Bureau of Mines in 9 bituminous-coal mines indicate that a full-shift average exposure of workers should not exceed about 20 million dust particles per cubic foot of air (m.p.p.c.f.) and that concentrations can be held within this limit without too much difficulty. Furthermore, these studies indicated that an exposure in the neighborhood of 40 m.p.p.c.f. should not be exceeded for an individual operation and that it is possible to hold within this ceiling.

Jan 1, 1957

By Leonard Obert

This report describes an inexpensive triaxial equipment for testing 2-1 / 8- , 4- , and 5-5 / 8 - inch - diameter rock cylinders subjected to loading conditions comparable to those encountered in underground mining . Only minimal specimen preparation is required . The maximum axial load that can be applied is 250,000 lb , which corresponds to an axial stress of 70,000 psi for the 2-1 /8- inch- diameter specimen . The maximum radial pressure that can be applied is the same for each specimen diameter ; namely , 10,000 psi . The mechanical parts in this equipment are relatively easy to machine and fabricate . The cost of all parts , including the 250,000- lb hydraulic press but not including labor costs , was approximately $ 1,000 .

Jan 1, 1963

By Ryron O. Pickard

"The Berkeley safety station of the U. S. Bureau of Mines was recently informed that a geologist was killed through entering an abandoned 90-foot exploratory shaft without making a preliminary test of the shaft atmosphere. He was one of a geological party which was investigating coal lands in California. The only light that he carried into the shaft was an electric flash light. After he had descended a short distance, one of his associates on the surface heard him exclaim, ""This place is full of gas, I am coming up"", He had no more than finished the remark when he was seen to lose his grip on the ladder and fall down the shaft. He was apparently weakened from impure air in the shaft, and could no longer suppers himself on the ladder. When his body was recovered, it was found that his neck had been broken by the fall.This is the ;second recent accident that has been called to the writer's attention where a life has been lost in abandoned exploratory workings; the other fatality being in Minnesota where a mining engineer was overcome while sampling a shallow pit in iron-ore formations. This engineer was on the bottom of the shallow pit and died before help could reach him. It was generally supposed that each of these deaths were due to poisonous gases, but the writer believes, after reviewing the information available, that death in both instances may have been directly caused by deficiency in oxygen.Frequently in the daily press there are items relative to lives being lost through cleaning out old wells, and as a general rule such accidents are also caused by impure atmospheres.In every abandoned shaft or pit, or in fact, any old working where the air has been stagnant for a considerable time, there is always danger of oxygen deficiency, as the oxygen which originally comprised one-fifth of the atmosphere may be appreciably replaced by gases that do not support life, usually by carbon dioxide (black damp) or methane (fire damp). Much valuable information on the subject of mine atmospheres, mine gases, and the effect of oxygen deficiency onthe human system is contained in Miners' Circular 14, ""Gases Found in Coal Mines"" by G.F. Burrell and F. M. Seibert; Technical Paper 122, ""Effects of Oxygen Deficincy on Small Animals and Men"", by G. A. Burrell and G. G. Oberfell; and ''Chit of Properties of Mine Gees"" by G. A. Burrell. These publications of the Bureau of Mines should be rent by all who are interested in the subject of this paper."

Nov 1, 1921

Measure the leakage through individual crosscut stoppings quickly and economically so that the worst ones can be identified and repaired. (Typically 60 to 80% of the air supplied to a mine short circuits before reaching a working face.) Approach Most of the leakage through a permanent stop-ping is channeled through two windows in a temporary stopping, and air velocities through the windows are measured; leakage is determined from a formula. How It Works A temporary stopping made of plastic brattice is erected in the same cross cut as the permanent stopping, either upstream or downstream. The brattice is fastened to the roof, bottom, and ribs of the entry with spads. Normal leakage of brattice was allowed for in deriving formula, and does not effect results. For best accuracy the brattice and the stopping should be separated by a distance of one hydraulic diameter.

Jan 1, 1979

By John Nagy

The Bureau of Mines examined explosion development in a closed spherical vessel, mathematically correlating flame travel, pressure, and time with parameters defining the reaction. The model assumes that burnt and unburnt zones are separated by a thin, radially moving flame front. Isothermal and adiabatic systems are considered. Correlation with gas and dust explosion data is better for the adiabatic system, but the isothermal development is simpler and in reasonably good agreement. Interpretation of the explosion phenomena is facilitated by expressing the rate of mole change in the flame front in terms of elementary parameters. This expression is developed by examining the components of spatial-flame velocity.

Jan 1, 1969

By R. B. Prater

Research by the Bureau of Mines includes efforts to devise means for maximum recovery of critical and strategic metals from primary and secondary domestic resources. As part of that effort, the Bureau developed a hydrometallurgical process to recover Co, Ni, and Cu from Missouri lead-smelter matte. The process includes leaching with H2S04 plus Mn02 as an oxidizing agent, liquor purification, selective precipitation of CuS, (Co,Ni)S, and MnC03, and crystallization of Na2S04&apos; This report is concerned primarily with liquor purification, in which As and Fe are removed from the leach liquor by pH adjustment and filtration. Two variations of the purification step are described. One variation provides liquor containing <1 mg/L As and Fe but requires two solid-liquid separations, The other is achieved with only one solid-liquid separation but leads to a lower degree of purification.

Jan 1, 1987

At the present time many coal preparation plants handle coal-clay wastes in one of two methods. In one method, the waste is processed in a thickener, followed by further dewatering through filtration, and subsequent blending with coarse waste refuse from the preparation plant. The resulting mixture is then disposed by stacking it in available storage locations. The coal-clay waste is often reslurried by rain or water from other sources, causing a potentially unsafe situation such as mud flows. The other method often used requires thickening and impoundment of the thickened slurry behind earthen dams which poses safety risks if structural failure of the dams occurs. To overcome these two problems, a flocculation method was developed which produces a stable agglomerated material resistant to reslurrying. How It Works The new method involves treating coal-clay waste with lime to raise the pH and flocculating the slurry with a nontoxic polymer of polyethylene oxide. The resulting floes are dewatered on a static screen and agglomerated. For extremely fine waste, further dewatering of the material is accomplished on a rotary trammel screen. The dewatered material may be ponded or mixed with coarse waste from the preparation plant to produce a stable mixture that can be stacked.

Jan 1, 1985