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By Jon C. Volkwein

The Bureau of Mines conducted a series of tests to evaluate the effectiveness of mixing a compressed-air-generated foam with dried whole-grain silica sand to suppress dust in minerals processing plants. Dust at downstream transfer points was monitored with personal gravimetric samplers and with Real-Time Aerosol Monitors (RAM's) that were connected to strip' chart recorders. Results showed dust reductions of 80 to 90 pct on three separate occasions at two different plants. The mechanism by which foam suppresses dust is discussed, as are the constraints on the use of foam, which may include incompatibility of the foam with the mineral product, difficulty in controlling the foam generator, and cost.

Jan 1, 1983

By A. L. Engel

This report is a compilation of the results of preliminary tests on ores containing scheelite (calcium tungstate). In most of the ores, scheelite was the only value; but several samples contained other values, such as gold, base metals, or, in one instance beryl. These investigations were made to assist the development of domestic tungsten resources by establishing satisfactory treatment methods suitable for small-scale operations. The samples were obtained through the Mining Division of the Bureau of Mines and represent, for the most part, newly discovered deposits. A previous report2/ discussed laboratory test procedures. A less detailed description of test procedures is included in the present report. As is usual in an investigation of this type, only a limited amount of work was done on most of the samples to indicate the results that could be expected from simple treatment of the particular ore. The occurrence of scheelite and the texture of the minerals present differ greatly in individual ores and must be determined and considered in establishing such details of treatment as grinding to obtain optimum liberation of the minerals, the preferred type of gravity concentration, or possible further treatment by flotation.

Jan 1, 1954

By John J. Mulligan

The Bureau of Mines investigated reports of mineral deposits within 10 miles of the route of the proposed pipeline from Prudhoe Bay to Valdez. No producing lode deposits or lode prospects of possible national economic significance were found. Measured placer deposits in the route are or slight value except possibly some deeply buried gold placer deposits in the Fairbanks and Livengood Quadrangles. The pipeline corridor crosses five belts of minerals having potential economic value: (1) The north slope of the Brooks Range (oil, gas, oil shale, coal, phosphate); (2) the south slope 01 the Brooks Range (copper, gold); (3) the Livengood area (gold); (4) the Fairbanks area lead-silver, antimony); and (5) the Wrangell Mountains-Denali copper belt (copper-gold). The Jarvis Creek coalfield, an eastern extension of the Nenana coalfield, is on the north side of this belt. Scattered along the corridor across the Chugach Mountain and in the vicinity of Valdez are a wide variety of metallic deposits that make up the eastern margin of the Chugach gold belt but do not seem to constitute a well-defined zone.

Jan 1, 1974

By J. L. Stauffer, L. J. Gaydos, L. M. Demers, D. C. Kuhn

"Eicosanoids and cytokines produced by alveolar macrophages (AM) are key mediators of pulmonary inflammation and fibrosis. In order to determine if eicosanoid production and cytokine production are altered in AM obtained from coal miners, we compared production of prostaglandin E2 (PCE2), thromboxane A2 (TXA2), leukotriene B4 (LTB4), interleukin-1 beta (IL-1B ), and tumor necrosis factor alpha (TNfa.) by cultured AM from normal human subjects and coal miners. The recovery of AM from miners' lungs by bronchoalveolar lavage was significantly greater than that from control subjects. Mean eicosanoid and cytokine production by AM from active miners was also increased compared to AM from control subjects, but this increase was not statistically significant. AM from control subjects produced significantly more TXA2 and TNFa. when exposed to lipopolysaccharide than did AM from miners. The cyclooxygenase inhibitor suprofen reduced PGE1 and TXA1 production and TNF0t. release but had no effect on LTB4 production or IL-1B release by miners' AM. The lipoxygenase inhibitor nordihydroguaiaretic acid attenuated TNFa release, as well as that of LTB4, but had no effect on IL-1B release. Inhibition of thromboxane synthase by UK 38,485 also reduced TNFa release by active miners ' AM but had no effect on PGE1, LTB, production, or IL-1 f3 release. The results of these studies suggest that occupational inhalation of coal dust may increase total lung eicosanoid and cytokine levels and reduce the reactivity of AM to bacterial endotoxin. Furthermore, coal dust-induced changes in both eicosanoid and cytokine release may be subject to pharmacological modulation.The alveolar macrophage (AM) is a primary defensive cell in the lung and is one of the first cell types to encounter inhaled mineral dust. The response of the AM to invading foreign material is designed to enhance the defensive capacity of the lung. However, in the case of occupational inhalation of mineral dust particles, this response may be inappropriate, resulting not in the defense of the lung but in chronic inflammation and fibrosis (Rom et al., 1987; Takemura et al., 1989). The reaction of the AM to chronic mineral dust exposure may involve the exaggerated release of paracrine mediators of lung function, including eicosanoids (oxygenated derivatives of arachidonic acid) and peptides, including cytokines and growth factors (Sibille & Reynolds, 1990). Eicosanoids are involved in bronchial and vascular smooth muscle reactivity, vascular permeability, fibroblast growth, and the recruitment of additional immune cells to the alveolar space (Barnard et al., 1992; Elias et al., 1985; Scott et al., 1982). AM-derived cytokines such as interleukin-1 beta (IL-1 B) and tumor necrosis factor alpha (TN Fa) have a variety of biological activities including the regulation of fibroblast growth and proliferation (Becker et al., 1989; Libby et al., 1989; Schmidt et al., 1984). Interestingly, in vitro studies with macrophages suggest that the production of cytokines may be linked to eicosanoid production, in particular that prostaglandin E2 (PGE2) may down-regulate IL-1 f3 and TN Foe production by the AM (Bonta et al., 1989; Kunkel et al., 1986; Monick et al., 1987)."

Dec 1, 1996

By L. Kaufman

Fifteen boride composites were synthesized by hot pressing and evaluated by physical and incendivity testing as non-sparking tool materials. The incendivity tests, conducted at the U. S. Bureau of Mines, Albany Research Center, compared the boride compo-sites with standard cobalt-bonded tungsten carbide material used for coal cutter bits. Two titanium diboride composites and two zirconium diboride composites out-performed cobalt-bonded tungsten carbide in wear resistance and reduced tendency to cause ignitions. However, three of these candidates exhibited undesirable chipping. The remaining candidate, a TiB2-(Ni, Cu) composite, did not chip, nor did it cause ignitions at levels where cobalt-bonded tungsten carbide tools caused ignitions in the incendivity tests. Thus, this material appears to be a logical candidate for further development.

Jan 1, 1973

By E. A. Johnson

The Bureau of Mines determined the effect of slag additives on copper solubility and the distribution of typical impurity elements between copper-iron matte and silica-saturated fayalite (iron silicate) slag at 1,250° C, in CO-C02 atmospheres with 10 pct S02. Small additions (<10 pct) of CaO, A1203, and MgO were shown to decrease copper solubility in the slag. Additions of CaO increased the solubility of bismuth and tellurium in the slag at lower matte grades. Al 20 3 additions decreased the solubility of tellurium in the slag, but increased that of bismuth at lower matte grades. A1203 additions increased the solubility of both at lower matte grades. With no additives, matte grade did not affect the solubility of bismuth in slags, whereas increasing matte grade resulted in a slight decrease in the tellurium solubility in slag. Additions of CaO or As203 alone to the slag increased selenium and arsenic distribution to the matte, but had little or no effect on antimony distribution; whereas small MgO additions decreased antimony distribution to the matte but had no effect on arsenic and selenium distribution. In slags with no additives, selenium distribution to the matte increased with increasing matte grade, while that of antimony decreased and that of arsenic was unchanged.

Jan 1, 1982

By I. AITKENS

Quartz maintains a rather conspicuous position among gem stones , despite its being the commonest and, in its natural form, the most easily recognized of mineral substances . This prominence is due primarily to the extensive use of amethyst , which provides stones of the finest violet color , and also to the wide employment of yellow quartz ( citrine ) which is called topaz by jewellers and vies with the true topaz in color and brilliance . Unlike many less costly gem materials quartz is hard and durable .

Mar 1, 1932

By H. R. Batchelder

Much information on oxygen production and the manufacture of synthetic liquid fuels has been published during the past several years. From time to tine the investment and operating cost of oxygen plants of various sizes has been estimated. Surveys have been made so that the various processes by which oxygen is produced commercially might be compared. The gas-making processes in which oxygen is employed, which wore used in Germany during the war, have been described in T.O.M. reels, and this information has been published. Descriptions of pilot-scale or proposed commercial plants for the production of synthesis gas or hydrogen and their conversion to synthetic liquid fuels also have been published. In general, each of these publications has dealt with a particular phase of the over-all problem. The present paper will discuss the relationship between these phases: The factors that affect oxygen manufacture and costs, the methods for the use of oxygen and for the production of synthetic liquid fuels, and, to some extent, the economic factors that must be considered.

Jan 1, 1951

By T. J. Ballard

Corundum is a natural alumina (A120 ) and is next to the diamond in hardness . Except for the gem varieties , it is used principally as an abrasive , chiefly in grinding , dressing , and polishing metals and optical glass . Natural corundum is preferred to artificial abrasives for certain specialized jobs . Most of the corundum ( excluding emery ) mined in the United States came from the Corundum Hill mine in North Carolina and the Laurel Creek mine in Georgia . The Corundum Hill mine provided over half of the domestic production of corundum prior to 1900. Since 1900 , the importation of foreign corundum and the manufacture of artificial abrasives caused the decline of corundum mining in the United States .

Mar 1, 1947

By L. O. Bacon

This Bureau of Mines report summarizes the results of laboratory work in the design of instrumentation for obtaining the dynamic tensile strength of rock at minimum loading. Minimum loading is defined as the lowest tensile loading by pulse reflection to cause fracturing. The instrumentation for obtaining dynamic tensile strengths of rock cores evolved into the use of a compressed-air pellet gun to impact one end of a rock core, suspended by wires, at increasing increments of air pressure. Maximum strain was measured on most or all of the impacts, and the strain at fracture of the core was obtained by extrapolating the pellet velocity-strain curve to the pellet velocity at fracture. Stress at tensile fracture was obtained from the maximum s train, and the dynamic Young&apos;s modulus was calculated from the rod velocity by using simple rod theory.

Jan 1, 1962

By B. J. Scheiner

A ferrous chloride-oxygen leaching system was investigated by the Federal Bureau of Mines to determine its effectiveness for recovering copper and silver from a tetrahedrite concentrate that had been pretreated to remove a majority of the antimony. The pretreated concentrate contained coppers, silver, lead, zinc, antimony, and arsenic. Parameters affecting metal extraction (such as temperature, pressure, amount of ferrous chloride, and initial hydro-gen ion concentration) were studied. Copper extraction of 98 pct was achieved by leaching 4 hours at 40 pounds per square inch gage (psig) and 100° C. Copper was recovered from leach solutions by cementation with iron, and the resulting ferrous chloride was recycled. Leaching the residue with cyanide followed by electrowinning recovered 99.7 pct of the silver. Iron, antimony, arsenic, and sulfur reported to the tailings.

Jan 1, 1978

By Richard A. Andre, R. Larry Grayson, Thomas Simonyi

"INTRODCICTIONThe search for the cause(s) of coal workers' Pneunoconiosis continues despite the vast amount of research that has been undertaken over the past forty to fifty years. Good correlation between the mass of dust inhaled over workers' lifetimes and the incidence of the disease has led to the development of effective environmental standards and implementation of good procedures for the control of dust generation and dispersion in the working place. Research has only begun, however, to uncover the biochemical mechanisms involved in initiating the disease.Correlation between the rank of the coal seam in which miners worked and disease incidence and severity is acknowledged worldwide, but the agents in the higher rank coal seams which cause CWP arc still not defined. The basic components of the coal seams, i.e., the elements and minerals, are generally known, but the way in which they interact with human pulmonary cells is largely still a mystery.The process of disease development is a biochemical one which depends on the characteristics of the pulmonary cells within their immediate biochemical environment and the characteristics of invading respirable coal mine dust particles, probably both chemical and physical ones. The cell-particle relationship, therefore, must be defined, and both cells and particles must be characterized according to properties which potentially are involved in the disease process.Following such characterization, specific respirable dusts from different coal seams, which appear to have different effects on coal workers, must be obtained or constructed and then used in experiments designed to determine dust toxicity or the response of animals exposed to the dusts.The results presented here focus on characterizing properties of respirable coal mine dust particles collected from operating longwalls in West Virginia and Virginia Longwall panels were selected for analysis because the respirable dust in the coal face areas is largely uncontaminated by rock dust and analysis of the dust yields results unconfounded by rock dust."

Jan 1, 1990

By G. W. Reimers

Exothermic oxidation reactions of sulfide minerals can produce self-heating situations in underground mines. If the self-heating is unchecked and the resulting heat is not sufficiently dissipated, the result can be spontaneous combustion fires. This U.S. Bureau of Mines report describes laboratory tests conducted to measure the reactivity of pyrite following treatment with additives to counter its self-heating tendencies. Thermal gravimetric analysis (TGA) and isothermal oxidation procedures were used to obtain information on pyrite ignition and the behavior of pyrite during low-temperature oxidation to ferrous sulfate. The determination of treatment effectiveness was evaluated by adding 5 wt pct of the compound to the pyrite before milling. The resulting samples were then heated in moistened air and after 24 h, the amount of pyrite oxidation determined. Results of these tests indicated that several phosphate compounds reduced the oxidation of pyrite to sulfate to about 50 pct or less compared with the oxidation of untreated sample at 200° C. Cupric sulfate reduced oxidation to about 20 pet untreated sample at 200° C. Sodium, calcium, and potassium chloride reduced pyrite oxidation to levels of approximately 15 pct or less of the untreated sample. Using only 1 pct of sodium or calcium chloride was effective in slowing pyrite oxidation to less than 20 pct of the untreated sample.

Jan 1, 2010

By S. L. May

Investigations by the Federal Bureau of Mines indicate that hafnium and zirconium compounds of acceptable purity can be extracted from Nigerian zircon concentrates. Chlorination and caustic soda fusion techniques were used to extract 85 to 95 percent of the valuable metals from the concentrate. The extracted hafnium and zirconium compounds were purified by recrystallization of the oxychlorides or by formation of complex salts during chlorination. The zirconium-hafnium product of the recrystallization method contained 15 parts per million of uranium, and the product of the salt-complex method contained less than 10 parts per million of uranium. The hafnium was separated from zirconium by solvent extraction methods. A zirconium product containing 0.3 percent hafnium and a hafnium product containing 4 percent zirconium were obtained. At the request of the Atomic Energy Commission (AEC), work was started to develop techniques for processing Nigerian zircon concentrates in commercial installations presently engaged in producing zirconium and hafnium metals from ores. The Nigerian zircon has a high hafnium content, but the presence of uranium and thorium is a problem not normally encountered in processing zircon concentrates.

Jan 1, 1961

By C. H. Elder

An analysis of the geologic structure of an area of Buchanan County, Va., was made by the Bureau of Mines using imagery from an airborne AN/APQ-97 side-looking radar system to evaluate that mapping technique for delineating structural features that may cause mining problems. Side-looking airborne radar (SLAR) was found to be a useful remote sensing tool for geologic structural analysis, Fault and joint systems identified by lineaments and linear patterns in the imagery were verified by surface and in-mine observations. Little Paw Paw fault was extended 10 miles by SLAR lineament analysis. A 22-mile fault, here named the Bishop-Bradshaw Creek fault, was mapped by lineament analysis and verified by observation of the fault on the Bishop Coal Co. mine map and on offset patterns of commercial gas production along the fault and surface observation of lineament along the fault. Three major super-imposed joint sets and several fault or fractured zones were identified by SLAR lineament analysis, showing more complex structure than earlier mapping indicated. SLAR imagery accurately delineated structural features that are known to affect gas migration and accumulation and that weaken the rock forming the immediate roof to mine workings, causing mining problems and potentially hazardous environment in the mines.

Jan 1, 1974

By Constantine C. Popoff

During 1946 several limestone deposits near Fortson, Snohomish County, Wash., were examined by the Bureau of Mines. These examinations were part of a long-range investigative program of regional mineral supplies required by the anticipated industrial development of the Pacific Northwest. The .study outlined in the following paper was specifically undertaken to disclose new sources of high-purity limestone and to appraise, their economic aspects. The deposits examined -namely the Galbraith, Climax, and Hi, Hi -are somewhat similar in physical features and geologic environment. They are lenticular and belong to the same formation of metamorphosed sediments that underlies the prominent Whitehorse Ridge.

Jan 1, 1949

By Gwendolyn D. Hood

The Bureau of Mines investigated techniques for dewatering slurries from talc-processing operations to improve water reclamation and pro-duce dewatered solids suitable for disposal. Various flocculating reagents were evaluated, and a nonionic polyacrylamide was found to be most effective in a specialized flocculation dewatering technique. The flocculation dewatering method was applied in laboratory batch tests and in continuous tests using a static screen, a belt-roller device, and a clarifier-thickener laboratory unit. In continuous tests using the unit, wastes of 3.5 pct solids were dewatered to 56.9 pct solids using 0.03 Ib of flocculant per ton of dry solids treated.

Jan 1, 1983

By Ted A. Lewtas

The effectiveness of induction fans in ventilating dead headings was studied in the laboratory and underground. The following fan attachments were evaluated: a. Aerodynamic nozzle b. Various lengths of vent tube c. Honeycomb airflow straightener. Various fan locations were also tested. The following conclusions were reached: a. A nozzle on a fan located against the drift wall gives the greatest jet penetration distance. b. Air straighteners are ineffective in increasing jet penetration. c. Induction fans are ineffective in removing contaminants from dead headings without sufficient main ventilation flow.

Jan 1, 1980

By Kenneth L. Cashdollar

The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) and the Mine Safety and Health Administration (MSHA) conducted joint research on dust explosions by studying post-explosion dust samples. The samples were collected after full-scale explosions at the PRL Lake Lynn Experimental Mine and after laboratory explosions in the PRL 20-L chamber and the Fike 1-m3 chamber. The dusts studied included both high and low volatile bituminous coals. Low temperature ashing for 24 hr at 515°C was used to measure the incombustible content of the dust before and after the explosions. The data showed that the post-explosion incombustible content was always as high as or higher than the initial incombustible content. The MSHA alcohol coking test-was used to determine the amount of coked dust in the post-explosion samples. The results showed that almost all coal dust that was suspended within the explosion flame produced significant amounts of coke. Measurements of floor dust concentrations after LLEM explosions were compared to the initial dust loadings to determine the transport distance of dust during an explosion. All of these data will be useful in future forensic investigations of accidental dust explosions in coal mines or elsewhere. Disclaimer: The findings and conclusions in this report are those of the authors and do not necessarily represent the views of the National Institute for Occupational Safety and Health or the Mine Safety and Health Administration.

Jan 1, 2006

By K. K. Kelley

This report contains heat-content values for hexagonal crystalline germanium dioxide between 298.15° and 1,350° K., and for germanium dioxide glass between 298.15° and 1,800° K. experimentally determined by the Federal Bureau of Mines. No similar data for these substances are to be found in the literature. The heat-content and corresponding entropy-increment data are presented both in tabular form and by equations. Free energy of formation values are estimated for germanium dioxide glass at 298.15° and 1,800° K.

Jan 1, 1961