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By Przybycien Krzysztof, Tumidajski Tadeusz

"Materials being the feed to mineral dressing plants are the mixture of ore minerals having different physicochemical properties among others, especially susceptibility on crumbling. During exploitation of material and their preparation to communition the big number of narrow classes comes into being and they have different properties. The determination of common communition laws of multicomponent (on account of size and mineralogy) materials leads to the estimation of mutual influence of narrow classes and their rates, taking into account their endurance and mineral density, on general ratios and their simultaneous crumbling.If we try to accept the grain membership to the certain component as the differing feature, we can write the balance equation as: ( ) ( ) S= = k i i i g x p f x1where: fi – density functions of one type distribution and of different statistical moments (characterising the homogeneous materials grinding), pi – “stirring” proportions of each components, S== k i i p 1 1 . From the point of verification view of detailed versions of this equation the inverse operation should be done: in the base of the components’ mixture grinding results and the results of components grinding the legitimacy of equation should be checked.The using of finished distribution mixtures’ theories to the grinding process analysis allows, first of all, to verify the assumption of grinding independence of individual feed components. Talking more generally it would lead to the comparison of grain size distributions, obtained by individual components grinding from the defined in the mixture distributions theory calculations. One of experimental and calculation results for artificial mixtures of galena and dolomite is presented on figure below (df means distribution function)"

Jan 1, 2003

By K. C. Corin

It is well known that the grinding circuit plays a crucial role in flotation. The effect of pulp chemistry during grinding is often overlooked. It is believed that the surface properties of the minerals can be adjusted during flotation rather than during grinding. However, recent development in surface analysis techniques (TOF-SIMS, XPS, and AES etc.) have proven that the hydrophilic iron hydroxides formed at the mineral surface during grinding make it difficult for collector adsorption, which may result in poor grades and recoveries of the valuable minerals. This study investigated the effect of the pulp chemistry conditions during milling and the subsequent effects on flotation performance of an Nkomati ore. The results have shown that there was approximately 10 % increase in Ni recovery, when the ore was ground at a dissolved oxygen (DO) concentration of 0 ppm (DO-0) in comparison to no gas control during the grinding stage. However, when the pH was changed from 9 to 11, no gas control resulted in a 20 % decrease in the Ni recovery compared to only 5 % decrease in the Ni recovery at DO-0. A noteworthy observation is that controlling a combination of DO and pH during grinding is of critical importance for better floatability and selectivity for such a system. It also became clear from this study that the presence of oxygen is critical to the consumption of xanthate, which is consistent with the general literature. It has been established that grinding at lower DO levels/redox potentials (Eh) in the presence of xanthate significantly improves the flotation performance of the valuable minerals.

Sep 1, 2012

By H. Gallardo, J. Yianatos

Flotation is a separation process in which mineral recovery depends on the particle surface properties. The selective collection of particles by air bubbles requires hydrophobic mineral surfaces. Hydrophobicity can be selectively induced on a valuable mineral surface by means of reagents. For this purpose, it is required that mineral grains in the ore become physically liberated or exposed in the particle surface after grinding. The grinding process generates three types of particles according their exposed surface in the floatable mineral: locked particles (0-10%), associated particles (10-90%) and liberated particles (90-100%). Locked particles have low floatability, and they typically show low recovery (<20%), while liberated particles have a high floatability and can be easily recovered (98-100%) at different particle sizes (10-150 µm). The main challenge in the flotation process is the recovery of associated particles. These particles typically have recoveries of 20-80%, but strongly depend on the particle size, particle surface liberation and collector dosage. Recent studies on particle floatability by size-liberation have significantly contributed to improving the characterization of flotation processes. In this work, a study of flotation recovery of associated particles of 10-90% liberation is presented for particle sizes (10-150 µm) and collector dosages (5-40 g/ton). In this work historical data on galena recovery based on particle cross-section composition of galena was used, assuming they represent an acceptable estimate of particle surface composition, as shown by some previous researchers. The results showed that galena recovery can be well represented by a model consisting of the interaction of a linear function and a Gamma distribution function to account for the liberation and the particle size effects. Consequently, an alternative approach for modelling the recovery of associated mineral (10-90% liberation), with a reduced number of parameters, was developed and validated.

Jan 1, 2018

By Julian Dimitrov, Kremena Dedelyanova

"The paper presents research on hydrodynamic processes occurring at the elementary act of flotation. Discussed existing models to determine the effectiveness of conflict of bubbles with particles in vibration column flotation machine. The paper presents a disperser for a column flotation machine, in which the dispersion of the gas phase is carried out using vertical vibration with defined frequency and amplitude. The paper presents research of mechanism for the creation of air bubbles in vibratory column flotation machine. The factors influencing the increase in the duration of the bubble in the area of contact with the mineral particles are discussed. Research was carried out on the effect of frequency and amplitude of vibrations on speed of precipitation of mineral grains of different density. Formulas are derived for the parameter effect of vibrations, applicable to the design of flotation machine. The collision efficiency of the bubbles in vibratory column flotation machine is determined. The vibrations of the hydrated layer allow for cost-effective implementation of the elementary act of flotation by providing larger relative velocities at the contact point between the bubble and the solid phase. It is proposed to complement the model more accurate representation the mechanism of attachment of the particles to the bubble."

Jan 1, 2014

By Bulelwa Ndlovu, Saeed Farrokhpay, Dee Bradshaw

The effects of phyllosilicate minerals on the flotation performance and froth stability of a copper ore was investigated. It was found that various phyllosilicate minerals affect the copper recovery differently however they all caused the flotation grade to be reduced. The effect of different phyllosilicate minerals on the froth stability followed the order of talc >> montmorillonite > muscovite > kaolinite > illite. The results demonstrated that there could be a relationship between the deleterious effect of phyllosilicate minerals on the flotation and froth stability. Talc and montmorillonite have both shown the highest effect on the flotation recovery and grade as well as froth stability. On the other hand, illite has the least effect on the both flotation performance and froth stability. Kaolinite and muscovite also affected the copper flotation grade (but not the recovery) while they also affected the froth stability. Therefore it is possible to control the flotation performance when phyllosilicate minerals are present via monitoring and controlling froth stability which needs to be investigated further.

Jan 1, 2014

By Gábor Mucsi, Barnabás Csoke, Viktor Mádai, Zoltán Molnár, Viktor Török, Ádám Rácz

The application of the stirred media mill in dry mode came to the front only in recent years, but at the same time several questions arise, such as aggregation, agglomeration, sticking on the liners and the grinding media. During high energy milling, not only the particle size reduces, but among others, in numerous cases the crystal structure and the amorphous state of the material also change due to the mechanical activation taking place. The present paper deals with experiments carried out on the ultrafine fly ash grinding in dry mode at various grinding conditions in a stirred media mill to investigate the mechanochemical effect and the energy efficiency of the mill. During the experiments the particle size distribution, particle shape, specific surface area, amorphity and crystal structure of the products were examined. The product related stress model was used for the evaluation of the effect of milling parameters on the mechanical activation. It was found, based on the experimental results, that there is mechanochemical effect on crystal structure of fly ash in the stirred media mill, as it was revealed by X-ray diffraction and FTIR measurements. The experimental results made it possible to determine the effect of the rotor circumferential speed and so the stress intensity on the mechanical activation of fly ash could be revealed.

Jan 1, 2014

By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

In the leaching of gold in aqueous cyanide solutions the rate of gold leaching may be decreased by the passivation of the gold, that may however be prevented or reversed in the presence of lead species in solution. In the present study potentiostatic, potentiodyanamic and XPS (X-ray photoelectron spectroscopy) analysis were used to further clarify the action of lead ions on the anodic activity of gold in alkaline cyanide solutions. It was found that lead increased the gold dissolution rate as it deposited on the gold surface at potentials more positive than its reversible Nernst potential for bulk metal deposition, i.e. by underpotential deposition mechanism, but that it decreased gold activity if present as bulk plated lead on the gold.

Jan 1, 2003

By Paula Olea, Gonzalo Montes-Atenas

Froth flotation operation is a large tonnage process aiming at selectively separate economically valuable minerals from gangue material. The wellbeing of an industrial froth flotation operation has been historically assessed and understood in terms of many variables known to somehow affect the process performance. Among these variables, air dispersion have been pointed out as key to secure the correct transport of hydrophobic particles to the froth phase and, then, to the concentrate. One of the classic parameters assessed when evaluating the air dispersion in flotation tanks is the superficial gas velocity. Many reports have focused on studying the superficial air velocity profiles across the pulp phase and theories have been based on the fact that the measurements should be performed in the so called "quiescent zone", which is a volumetric region inside a flotation cell of difficult determination. The hypothesis behind this research work is that the reporting of particles to the concentrate would provide a better correlation with the effective air flowrate pattern created in the froth phase. The aim of this study, as a first step towards developing a flotation model fully froth phase-based, is to estimate the effective surface area used in a flotation cell derived from results obtained with a specific setup at laboratory scale. The methodology considers running a thin lateral flotation cell cut at different superficial air velocities, with and without particles. It was found a non-linear correlation between the superficial air flow rate and the characteristic distance between the vertical wall next to the cell lip and the cut point where the foam or froth flowrate almost stops contributing marginally to the overall amount of solid particles transferred to the concentrate. The presence of hydrophobic particles reduced the mobility of the froth phase reducing the characteristic distance.

Jan 1, 2014

By Y. Q. He

The methodology of active pulsing air separation is a new method for dry material classification. Especially, it is suitable to electronic scraps disposal and re-utilization. By studying the difference of drag coefficients of the particles moving through areas of varying Reynolds numbers, and considering the extra-mass forces acting on the particles in the active pulsing air field, models of the dynamic motion which particles follow were developed. A computer simulation was prepared that showed the traces of particles with different densities and/or diameters, but similar aerodynamic characteristics, as they moved through the turbulent flow, to modify and define the parameters of the models. The simulation was found to predict the observed results with artificial tracing spheres being separated by the laboratory equipment. The separation performance, as being affected by the particles, nature, the air velocity, the pulsing frequency and the air pattern, is discussed. In general, lower density particles are more responsive to variations in airflow velocity. In addition, an industrial scale active pulsing air separator was designed, and it provides a new and efficient method for resource re-utilization in China.

Jan 1, 2014

By Heinrich Hutchison, Thomas von Moltke, Roelof F. Sandenbergh, Katarina P. Cerovic

Although the cyanidation process for gold leaching has been applied for more than a hundred years, some aspects of it, such as the passivation of the gold and the depassivating action of heavy metals, are still not well understood. In this work the anodic behaviour and surface composition of gold in alkaline aqueous cyanide with lead additions were investigated using polarization experiments and XPS. It was found that lead in the solution activated the gold at low concentrations, somewhat more positive than the reversible potential for gold, but that the activity again decreased at higher concentrations of lead. The potential range for the activation of the gold coincides with that where underpotential deposition of lead occurs, i.e. –200 to –600 mV(SCE), as indicated by the surface composition of the gold, shown in figure 1. Note that the concentration of lead on the surface of the gold only increased with time in the bulk plating potential range for lead, where gold is not activated by the presence of lead. It is also shown that up to 20 mg/L of lead added to the solution will activate the gold, provided that bulk plating of the lead is avoided. It is also important to avoid reducing conditions during leaching, where bulk plating of lead may occur, if the gold is to be activated by lead to achieve a high leaching rate, as the bulk plated lead screens the surface rather than activating it.

Jan 1, 2003

By Vladimir E. Vigdergauz

"Bubble-mineral complexes could be formatted by an attaching of hydrophobic particles to the surface of air bubbles or by an evolution of bubbles from solution onto hydrophobic surfaces. Measurements of contact angles, detachment forces (DF), induction times (IT), evolution pressures (EP) and flotation recoveries (FR) for the studying of minerals wettability at various pH and electrochemical potentials were used. An analysis of the obtained IT results show that a process of bubble attachment to a mineral surface is a rather slow one and it will scarcely be enough for bubble-mineral complex formation under the conditions of real flotation.The ranges of adhesion potentials obtained by DF measurements, Figure 1, correlate with the data of floatability-potential for pyrite. The ranges of adhesion potentials obtained by DF measurements for galena (-1 ÷0.2V) and chalcocite (-0.5÷1.2V) correlate with the potential ranges of floatability for galena (<0.2V) and chalcocite (>-0.4V). An increase of the DF and the cathodic limit of the adhesion potential with increasing length of the hydrocarbon chain were observed. EP-pH curves for sulfides are a mirror-like to the DF-pH curves, Figure 2. Structure of solid-liquid and liquid-gas borders has a determinative importance for formation of bubble-mineral complexes and subsequently flotation results. Under vacuum on the mineral surface there are produced micro bubbles and preferably they will be appeared on the hydrophobic sites. Water structure breaks near a hydrophobic surface facilitate water mass destruction and formation of gaseous phase embryos under decompression in the impeller zone. It simultaneously reduces a probability of produced micro bubbles dissolution as a result of pressure increasing owing to constant fluctuation of liquid densities into impeller zone. Comparison of Taggart’s evaluation of the suction behind blades of the impeller of an agitation-froth machine and ABEP data on galena, Figure, shows that gas evolution will be observed in the range of 1300-2700 revolutions of impeller per minute for hydrophobic and hydrophilic surfaces successively."

Jan 1, 2003

By Nani Pajunen, Kari Heiskanen

"Products filling our societal needs, like communication and transportation needs, are becoming more sophisticated and efficient. The cost has been an increased complexity of material combinations. The same trend is also seen in investment goods. As an example, different crusher types have almost doubled the power to weight ratio in a relatively short time while producing even higher crushing rations. This has been possible by high performance materials and advanced designs. Another example is new hybrid materials in prefabricated high-strength steel structures in construction with the aim to lighten the products and obtain energy savings in the use phase e.g. in transportation. This development in general has made the end of life phase obscure. Recycling is often understood as the first phase of the material cycle. This has been supported by the material centric point of view. When, say indium, has been collected and mechanically treated to a concentrated fraction, it is assumed as recycled. This is not the case. The same applies to special steel alloys where one tends to lose some of the alloying elements to slag or even into the gas phase in the melting and refining stage, not in the earlier steps of recycling. At present there is no clear understanding of recycling of hybrid materials and no clear willingness to create new functional recycling systems. As the EU directives and most of legislation worldwide are based on the material centric thinking and implemented even on total mass recovery basis there is neither legislative incentive nor very strong economic incentives to work out the problem. In our research, we focus on industrial design towards sustainability from a product centric point of view from product collection to final metallurgical steps. It is vital, in the design phase of product, to understand the effects of decisions on recyclability to a saleable raw material. Main goal of our work is to create the fortunate circumstances in supply chain - to pass the barriers and find the effective and fruitful drivers - for reasonable use of raw materials and recycling co-operation with industry. The boundary conditions in the work are extractive metallurgical performance and the economic viability of all the steps. It can be shown from our work that small design alterations may have a large impact on the recyclability. The earlier the decisions are made in the product life chain the more positive impact they will have. It can also be shown, that a strong processing and metallurgical industry is vital to any meaningful recycling of the modern EoL products. Finally, it is also question of the individuals and values: supply and demand. Are you ready to take up the gauntlet: demand recyclable products."

Jan 1, 2014

By G. A. Wierink

This paper discusses a new method to increase flotation recovery. As known from literature, fine and coarse particles have different flotation rate constants, hydrodynamic behaviour and require different reagent regimes. The device discussed allows separate processing of finer and coarser slurry by extraction of a third stream, carrying finer slurry, from the flotation cell. By separate treatment of fine and coarse slurry operational conditions and so flotation recovery for both may be optimized more efficiently. Extraction and classification of the third stream is accomplished by low speed centrifugation and Taylor-Couette flow separation. This Dual Outlet Device (DOD) can be installed in a traditional flotation cell without need for equipment replacement. In order to asses different design options for the DOD a transparent laboratory scale model was built. For this scale model Computational Fluid Dynamics (CFD) simulations using the RANS k-e and LES turbulence models were performed. Essential insight in the dominant flow systems relevant to optimal operation of the DOD was obtained from the CFD simulations and flow visualization tests with the laboratory scale model. Based on these findings a number of configurations were investigated at pilot plant scale in a 5 m3 Outokumpu flotation cell. The results of the pilot plant study show that utilization of the DOD provides a method for in-cell control over particle size distribution in the slurry. Use of the DOD in a flotation cell may enhance flotation recovery and decrease flotation reagent consumption significantly, against marginal investment and operation costs.

Jan 1, 2014

By D. W. Fuerstenau

Understanding how cationic surfactants affect the interfacial behavior of quartz is important in mineral processing and environmental engineering. This paper presents the results of a study of the effect of the molecular structure of cationic surfactants on the interfacial behavior of finely ground natural quartz. Most of the experimental work involved the determination of zeta potentials and the stability of quartz suspensions. Some measurements of induction times and the flotation response of coarser particles are also included. How these surfactants affect interfacial behavior is discussed in terms of adsorption mechanisms. The molecular structure (number of hydrocarbon chains, type of ionic head group, number of ionic head groups on the molecule) of these reagents was found to significantly affect their surface activity.

Jan 1, 2014

By Anatoly N. Vinogradov, Vyacheslav A. Tsukerman

The North-West Russia for 70 years is one the main producers of Cu, Ni, Co, Al, P, REE, Zr, Ti, Ta, Nb, Fe ores and other minerals in the Europe. The largest mining companies locates in the Murmansk region, and they extracts about 100 mln. tons of ores and damps up to 250 mln. tons of waste annually. Nevertheless an environmental situation in the region is stable due to rational management and treatment of wastes on a base of the Noosphere Concept for Nature-using suggested by Vladimir Vernadsky. The Concept was performed practically in the Fersman’ scheme of “non-waste mining and metallurgical complex”, published in the monograph “Minerals of the Kola Peninsula: current status – analyses – prognoses” (1941) and served till now as a sort of “Bible” for industry managers lightening a strategy for an industrial “trophic chain”. The recent status of this scheme is shown on the picture below, and one can see that our concept is coincide with modern ideology known as the “Industrial Ecology”. Moving along this mainstream in the Kola Peninsula since 1929, when the first mining company “Apatit” was established, we provided the water close circuit in mineral dressing plants, hydrometallurgical treatment of slag and tailings, productions of building materials and adsorbents of wastes. The innovation set of technologies designed by the Kola Science Centre allow recently to involve tailing damps in re-exploitation as the technogenic deposits of valuable raw materials for fertilizers, tanning and cleaning agents, pigments, concretes and etc.

Jan 1, 2003

By G. S. Hansford, G. E. Searby

"Ferrous iron oxidation kinetics was measured in continuous culture at temperatures between 65 and 75ºC, using thermophilic microbes suitable for high temperature bioleaching. The resulting specific oxidation rates were modelled as a function of the ferric/ferrous iron ratio. The results were compared to those obtained by conventional mesophilic microbes.Microbially mediated ferrous iron oxidation is a vital sub-process in the mesophilic bioleaching of sulfide minerals and is expected to be of similar importance at elevated temperatures using thermophilicmicrobes.A thermophilic archaeal culture used in chalcopyrite bioleaching was successfully grown in continuous culture on ferrous sulfate, indicating the capability of the microbes to sustain growth for long periods on the energy provided by the conversion of ferrous iron to ferric iron, the primary leaching agent in sulfide mineral bioleaching.Steady state data was obtained at residence times of between 70 and 10 hours, with washout occurring at residence times between 11 and 9 hours, corresponding to a maximum growth rate (µmax) of between 0.09 and 0.11 hr-1. The reactions were followed by measurements of the solution redox potential, soluble iron concentrations, and offgas analysis of the oxygen and carbon dioxide utilisation rates."

Jan 1, 2003

By Fu Ping-Hao, Sergio Mauricio Vianna, Ewen Silvester, Emmy V. Manlapig

"Over the last 5 years, an ambitious project has been undertaken at the Julius Kruttschnitt Mineral Research Centre (JKMRC) aiming to isolate, study and, if possible, model the effect of particle size, liberation and collector adsorption density on the floatability of mineral particles. As part of this project, we have conducted highly controlled flotation test-work, combined with state-of-the-art solution and surface analytical techniques such as High Performance Liquid Chromatography (HPLC), Time of Flight Secondary Ion Mass Spectroscopy (TOF-SIMS) and detailed mineralogical analysis to fully characterize the flotation behavior of a natural ore.The flotation tests were undertaken using a high-grade lead-zinc ore from BHP-Billiton’s Cannington mine (Australia) in a specially designed continuously operated laboratory scale flotation rig. Solution and adsorbed collector concentrations were measured independently during the course of the flotation tests using HPLC based ex-situ techniques. Liberation studies were performed using the JKMRC Mineral Liberation Analyser (MLA) on selected size intervals of different streams to estimate the specific surface area of galena. These results were used to calculate the collector adsorption density (collector coverage) on galena particles, with the eventual aim of developing a mathematical model describing the relationship between pulp chemistry, feed mineralogy, and floatability of galena particles."

Jan 1, 2003

By I. Yu. Rasskazov, A. V. Rasskazova, N. M. Litvinova, N. A. Lavrik, V. G. Kryukov

The possibility of the intensification of the gravity processing of complex iron-manganese ore, which contains the finely dispersed inclusions of gold and platinum is shown. Clear mineral fractions of precious metals were sorted out of the different types of ores (quartz-braunite and carbonate- magnetite ore, ferruginous quartzite, carbon-containing shale, breccia-limestone and dolomite breccia). Composition and structures of precious-metals particles was detailed. The industrial content of platinum and gold was found. Precious-metals mineralization is character for all types of ores. High content of platinum is indicated in the carbonate-magnetite (up to 11.3 mg/kg) and quartz –braunite (up to 10 mg/kg) types of ore. Gold is presented in the ferruginous quartzite (up to 1.29 mg/kg) according to the data of the reduced mineralogical analysis. The composition of native platinum depends on the type of the ores: 1) quartz-braunite type contains isoferroplatinum (Pt3Fe) with Cu, Rh, Ir, Ru; 2) carbonate-magnetite type contains isoferroplatinum with Cu, Sn, Ni, Rh, Ir, Os; 3) pyritic-carbon ore contains isoferroplatinum with Sn, Ni; 4) ferruginous quartzite contains isoferroplatinum without admixtures. The ultrasonic treatment of mineral aggregates (P = 41.5 Watt, I = 15 W/cm2) made possible the liberation of fine particles of precious metals. Smooth-shaped or crystalline mineral aggregates are effectively liberated after acoustic treatment. Their surface is freed from impurities. The aggregates with the complex form and structure, which consist of the numerous plates and the grains, are not effectively liberated from impurities. It is shown that the ultrasonic treatment of aggregates with the fine inclusions of precious metals contributes to the liberation of the particles of platinum and gold and intensification of the gravity processing of refractory ore. This approach contributes the increase of the raw-material base of precious metals.

Jan 1, 2018

By Manuel Diaz

"In these difficult times for the mining world, mainly due to the global uncertainty about metal prices and the increased activity of opponents to the mining industry, it is essential that mining companies focus on efforts and strategies that will give them the most flexibility to succeed under the fury of these phenomena. The careful management of systems to control costs, and indicators to measure with great precision actual variations in costs and cash flows, are essential to adequately manage the uncertainty. Similarly, clear corporate and regional strategies designed to maximize cash flow and operating margin will allow the company to be better prepared to face any negative situations caused by declining metals prices, stricter government regulations and increasing social pressure. Gold Fields Limited, a corporation of South African origin and with more than 100 years in the gold mining business, has developed the ability to adapt to large changes generated by different global crisis throughout its history. This occasion will be no different. Given the critical situation of the mining industry in the world today, Gold Fields has embarked on a re-structuring plan at global level that will allow much closer control and real efficiency of production costs. This plan includes the creation of regional business units that allow greater independence for each region while still preserving the standards and cultural values of the Corporation. This presentation will explain why we believe that this approach combines the best aspects of the two styles of business, and what are the expected results. In the Americas Region, Gold Fields currently operates Cerro Corona, in Peru. In addition, the company is considering opportunities for growth in Chile, Brazil, Mexico and Canada."

Jan 1, 2014

By M. Minagawa, G. Granata, C. Tokoro, T. Kato

"In this work, we studied the mechanochemical activation of chalcopyrite by vertically stirred ball milling (VSBM) to enhance the dissolution of copper. By using x-ray diffraction (XRD) and laser diffraction particle size analysis, we investigated the effect of milling and milling conditions on particle size and phase composition of the chalcopyrite concentrate. To elucidate the efficiency of VSBM towards the mechanochemical activation of chalcopyrite, we also conducted leaching experiments in sulfuric acid-ferric sulfate media. Under all investigated milling conditions, the VSBM determined a dramatic decrease of particle size from over 100 µm of P80% up to about 13 µm. Furthermore, the XRD of the ground chalcopyrite specimens highlighted a partial oxidation of the mineral. In leaching, upon grinding by VSBM, the increase of copper extraction ranged from a minimum of +10% to a maximum of +40%, depending on the grinding conditions. In order to elucidate whether the dissolution enhancement was a consequence of the decreased particle size or of an induced mechanochemical reaction, we performed leaching experiments on activated and non-activated chalcopyrite sample having the same particle size. In addition, we determined the activation energy of leaching before and after vertically stirred ball milling. The leaching results on samples with the same particle size highlighted a greater copper extraction and higher dissolution rates upon mechanochemical activation. Whether performing grinding by VSBM or not, the leaching kinetics was found to be controlled by the chemical reaction on the surface of the chalcopyrite particle. By grinding the chalcopyrite concentrate by VSBM, the activation energy of leaching slightly decreased from 66 to 58 kJ/mol. INTRODUCTION Due to the increasing demand of copper, low grade ores and refractory minerals like chalcopyrite are expected to become the main copper source in the next years (Klauber, 2008). As a low-grade sulfide, chalcopyrite shall be processed hydrometallurgically. However, due to the formation of a protective layer of elemental sulfur during the oxidizing leaching, the dissolution of copper is slow and/or incomplete (De Bernardi and Carlesi, 2013). Therefore, the development of new technologies to enhance the extraction of copper from chalcopyrite is highly required."

Jan 1, 2018