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By V. G. Minenko, A. L. Samusev

For efficient leaching of gold from sulfide ores and the oxidation of sulfides into sulfates, it is necessary to introduce a substantial amount of oxidant - atomic oxygen, hydrogen peroxide, ozone, potassium or sodium hypochlorite. In this paper, hypochlorite electrochemical treatment is proposed as an effective method of intensification of refractory ore leaching. The objective of the study is to increase the gold recovery from refractory ores with the application of chlorinated solutions that are modified by chemical or electrochemical treatment. The advantages of the use of the modified chlorinated solutions instead of cyanide for gold-sulfide leaching are considered to be the following: a high concentration of the oxidizing agent (hypochlorite ions) in solution helps to achieve a high speed of gold dissolution in the form of chloride complexes; the possibility to produce hydrochloric acid solutions that may be used for the recovering gold by electrolysis; the possibility of the processing of carbonaceous, arsenic-bearing and others kinds of refractory gold ores. The mechanism of the interaction of the modified chlorine solutions with gold-bearing sulfides (pyrite and arsenopyrite) was investigated. The efficiency of the application of chemical and electrochemical leaching method was proved. The main factor that limits the rate of gold dissolution is a high concentration of sulfate ions (SO4 2-) formed in the solution by the oxidation of sulfide minerals. The optimal parameters of chemical and electrochemical leaching method and effective ways to remove sulfate ions were determined. The method helps to increase the level of the gold recovery up to 87% from refractory ores. The intensification of leaching by chemical and electrochemical treatment opens up opportunities for the creation of modern efficient and environmentally-friendly technologies that may be applied for gold extraction from refractory gold ores.

Jan 1, 2016

By Desmond M. Levins

"Australia has almost twenty per cent of the Western World's low-cost uranium reserves, located mostly in the Alligator Rivers region of the Northern Territory. At present, only one uranium mill is operating in Australia, but a number of new mills are planned for the early 1980s.Details are given of Australian uranium mining and milling proposals and the measures taken to minimize their environmental impact. Major factors affecting environmental impact are discussed, including treatment of liquid wastes, water management, control of radon and other airborne releases, and disposal of tailings. IntroductionAustralia is entering a new phase in uranium mining and milling activity . In the first phase of operations, between 1954 and 1971, about 10,000 tonnes of yellowcake was produced at five locations. Most of the production came from the mines at Rum Jungle in the Northern Territory and Mary Kathleen in Queensland. In the 1960s, the demand for uranium slumped, and much of the yellowcake produced at Rum Jungle was stockpiled by the Australian Atomic Energy Commission. The early uranium processing operations in Australia were typical of overseas practice at that time. Environmental problems were generally given low priority and pollution control measures were unacceptable by today's standards. There was little or no recycling of process water, acid waste streams were not neutralized and tailings dams were poorly designed. At Rum Jungle, oxidation of sulphides in waste heaps, tailings dumps and ore stockpiles subsequently led to destruction of vegetation and heavy metal pollution in a nearby river.In the early 1970s, major uranium deposits were discovered in the Alligator Rivers region of the Northern Territory. Significant orebodies were also located in the Great Artesian Basin in South Australia, in calcrete formations in Western Australia and at several locations in Northern Queensland. According to latest available estimates. Australia has about 160/0 of the Western World's uranium recoverable below $US 80 per kg U. Mining these orebodies will require pollution control measures more stringent than practised previously in Australia."

Jan 1, 1980

By O. Hyvärinen

Outokumpu has developed a new chloride leaching process called HydroCopper®. In this process copper sulfide concentrates are leached at atmospheric pressure in concentrated sodium chloride solution using cupric ions as the oxidant. Copper is recovered from the purified leach solution by precipitating cuprous oxide, which is then reduced to pure copper and further melted and cast directly into copper products. The key reactants: sodium hydroxide, hydrogen and chlorine are generated from the spent sodium chloride using chlor-alkali technology. An important feature in the HydroCopperTM process is that the gold contained in copper concentrates is leached as chloride complexes and recovered from solution by activated carbon. Conditions for the leaching of gold-bearing pyrite can also be achieved in the chloride system by optimizing the redox conditions. This paper deals with the basic factors affecting gold leaching from copper sulfide concentrates. Opportunities for the recovery of refractory gold associated with arsenopyrite and pyrite will also be discussed.

Jan 1, 2005

By T. R. Madhavan

The development of contact angles on highly polished ?uraninite surfaces, using sodium oleate and dodecyl ammonium acetate as collectors, has been studied at different collector and hydrogen ion concentrations. It was found that sodium oleate in acidic media (up to a neutral: PH) and dodecyl ammonium acetate in neutral and alkaline media give good contact angles. It appears that the combined forms of these collectors, viz., oleic acid and free amine, are more important in effecting contact. W ITH the emergence of uranium as a strategic metal in the last fifteen years, considerable effort has been directed toward the commercial recovery of uranium from its ores. This has resulted in the development of a uranium technology. It is only in recent years, However, that fundamental data regarding the floatability and surface properties of uraninite and ?pitchblende have been elucidated by different methods. Contact-angle measurement is one of the important tools for tl1e evaluation of the conditions of floatability

Jan 1, 1964

By Fulchand Shende

Around the world many potash mines experience brine inflow problems. The presence of brine in underground excavations may induce structural and stability problems. A study has been carried out to simulate the effect of brine on the performance of pillar support. The testing program consisted of loading potash specimens in a creep frame, and simulating inflows by continuously pumping brine into an experimental cell. Brine temperatures and load conditions were varied to simulate several mining and inflow conditions. Specimens were fitted with acoustic emission transducers to monitor energy emissions during an eight-hour test duration. Samples of brine were also collected to provide K+ and Na+ concentration data necessary for an accurate assessment of the dissolution process. Test results indicated that dissolution rates are highly dependent on brine temperature and load conditions. Loads approaching 50% UCS tend to generate very high rates of energy emissions, often leading to the failure of the simulated pillars. This study demonstrated that acoustic emission could be effectively used for predicting the performance of pillars when exposed to inflow brine.

May 1, 2001

By Debasis Deb, Ankur Narang, G. P. Raja Sekhar, Kamal C. Das

"The stability of underground structures made (especially) in jointed rock mass is of the utmost important to designers, engineers and operators. Rock bolting is generally being practised to reinforce excavation walls and roofs by minimizing the movement of rock joints. This study proposes a new analytical model for the prediction of displacements, axial load and shear stress of a fully grouted rock bolt intersected by single or multiple rock joint(s). The governing equations for rock bolt are derived based on the assumption that shear force generated by slippage along the bolt-grout interface has a linear relationship with respect to the relative displacement at the interface. The proposed model is novel compared to the existing literature in the sense that it accounts for rock kinematics as an enriched sum of a continuous part (elastic) and a discontunous (jump) part due to the presence of joint planes. The complete solution of the bolt displacement, axial load and shear stress is derived as a function of the rock displacements, and, it comprises of Heaviside and/or Dirac delta functions in the solution space due to the jump at the intersection point(s) of bolt(s) and joint(s).Our novel solution is able to predict the elastic behavior of a grouted bolt, subjected to opening of the joint planes in pull-out test and also in excavated tunnel. These two cases also serve as benchmarks for grouted rock bolts with multiple joints and can be used for validation of numerical and experimental models. Further, the solution is applied to analyze the behaviour of grouted rock bolt as well as cable bolt installed in circular tunnel, with variations in rock joint(s) opening displacement, shear stiffness in the boltgrout interface and locations of the joint planes. Results indicate that for a specified grout stiffness, the maximum axial load developed in the bolt for discontinuous distribution of rock mass displacement is significantly higher than that of the continuous distribution of rock displacement. This paper provides an analytical interpretation of bolt beaviour considering multiple joint planes with variable joint opening displacements. The results obtained via the analytical method are in line with the corresponding investigation done by other authors. Thus, our analytical treatment can be used to understand bolt behaviour in realistic situations."

Jan 1, 2015

By G. Bimpilas, G. N. Anastassakis

"Today, one of the most intense problems in mineral processing systems is referred to the treatment of fine (–100 µm), and even smaller size, particles. Fine mineral particles possess specific properties (small mass, high specific surface area, and high surface energy per unit area) that render their separation inefficient with conventional methods (physical, physicochemical) and equipment. As a result, it is not feasible to obtain a concentrate both of high grade and recovery in mineral value and a considerable amount of mineral fine particles is lost to the tailings. As evidence, we could cite numerous examples from industrial practice with considerable loss of mineral values to the tailings because of the fine particles size, e.g. phosphate, tungsten, tin, etc.The objective of the current paper is to investigate the possibility to separate magnetic gangue minerals and rocks (serpentine, ilmenite, and olivine) from magnesite by co-agglomerating all the gangue components and subsequent magnetic separation of the agglomerates.To meet the target, hydrophobic agglomeration tests were initially carried out on single minerals to define the favorable conditions for selective hydrophobic co-agglomeration of the gangue minerals. In this respect, the effect of the following factors was examined: pH, collector dose, conditioning time, and settling time of the agglomerates. Among the combinations examined, the most favorable proved that with amine in the basic pH region. The use of non-polar oil proved beneficial. The preliminary results were confirmed by tests on mineral mixtures. The application of magnetic separation resulted in the removal of gangue minerals and the recovery of magnesite concentrates of commercial grade (magnesite content 95% approximately) and high yield.The current paper contributes to the development of mineral processing, since it successfully copes with a very important problem of mineral processing, such as the efficient separation of fine particles."

Jan 1, 2016

By G. Ergin

The interactions taking place between Al-Mg alloys and the bed media during aluminum filtration are not yet well understood. These interactions were studied using the infiltration technique. The reaction interface was analyzed using different techniques such as SEM and TEM. Only spinel formation was observed at the interface regardless of the type of alumina and contact time. This paper discusses the results of the study.

Jan 1, 2004

By Denni Nikols

"Planning for coal beneficiation in the electric utility industry is relatively complex, involving the coordination of experts and specialists in a broad range of fields, as well as compliance with a wide variety of government regulations.This paper examines the role of the planner, reviews possible benefits of coal beneficiation, identifies potential problems and illustrates a typical planning schedule.The steps involved in the planning process are:Step I-Bench- and pilot- washability studyStep 2- Wash plant designStep 3- Power plant and boiler designStep 4-Mine designStep 5-Major environmental and technical problems to address.IntroductionElectrical utilities and coal have a long and intimate relationship . Cleaned coal is becoming an increasingly popular fuel with the utilities for a variety of reasons. Generally, the greatest impetus to burn a cleaned or prepared coal fuel comes from the need to control airborne pollutants.Long-range planning is a standard practice for electric utilities, forecasts of demand must be made well into the future. Since the lead time required to provide new facilities is often as long as 10 years and the cost very high , planning becomes an important task.For a utility that owns and directs the operation of its coal mines, the mine planning or fuel acquisition planning takes on the magnitude of other corporate planning functions. It is from this perspective that a utility would view coal preparation. Except for the interaction of a coal-fi red plant on the actual mine design the planning considerations o f a beneficiating facility for a captive mine or a contract raw coal supply are about the same. Because TransAlta Utilities is currently supplied from captive mines, this discussion will tend to focus in that direction.It is the role of a planner to plan. This is easy to say but it is not always easy to do. Often we are working within a context that resembles the geological time scale. Frequently the objectives are not clearly defined when we begin and ultimately our plans are tested in the waters of government regulations and cost benefit analyses .Planning for beneficiation of Plains coal, or any coal, provides just such a test. The planner's role in this endeavour requires a wide vision. While parts of the process may be amenable to classical methods of project scheduling, the broad range of subjects and interaction of seemingly unrelated tasks is sure to obscure some of the considerations that must be made. Therefore, the planner's chief role is coordinating the work of many experts and specialists toward the final objective.Among the specialists are combustion , geo technical, mining, civil , and mineral processing engineers , geologists, hydrogeologists, soil, and reclamation experts to list a few.When one considers coal beneficiation, the planning part o f that consideration is probably more complex than any other single engineering function. Due to the company's location in the Alberta Plains and the proximity o f the mine to the thermal generating station, this paper will tend to emphasize that situation.Beneficiation may offer some advantages over run-of-mine coal to the power plant opeator. Some of these advantages are: removal of a contaminant, power plant efficiency gains , lower plant capital costs (for new plants), possible lower mining costs."

Jan 1, 1984

By G. K. Rutherford, G. W. Van Loon

"Tailings in the mining and smelting industry are reject products of the refining process which are deemed too deficient in native are to warrant smelting. They are essentially finely ground rock materials which have been moved by alluvial suspension from the site of crushing to a deposit site. It is realized that components of flotation chemicals used in specific gravity separation may become part of the tailings and also that sewage sludge or other materials may be added at some stage to the tailing deposits.It would seem, then, that as tailings have a similar parent material to soils, namely rocks, and that they have also been comminuted to similar size fractions, they would react in similar ways to soils. There is an increasing body of evidence and experience which both supports and negates this supposition. It is the object of this paper to point out similarities and contrasts between these two materials which may influence the vegetation and rehabilitation of tailings.Soil-Formlnq FactorsThere are considered to be six soil-forming factors which impart the particular and unique properties harboured by a soil at any site. It is .relevant to consider each of these in turn, as each provides an historically based parameter with which to judge tailing properties.Parent MaterialsAlthough all mineral soils have originally come from rocks, for most soils the route has been rather circuitous. Soils may be formed directly from underlying rocks, as in some parts of tropical and semitropical regions today; these are sedentary soils. However, most soils of the world have been formed by materials which were transported to their present site by ice, water or wind, or as volcanic ash. Virtually all soils in Canada have been transported by ice or water and deposited on an extraneous rock surface during the last glacial retreat. Ice-deposited materials are extraordinarily heterogeneous in their size components and may range from very bouldery and gravelly to predominantly clay-sized materials. Water deposited sediments are usually homogeneous, but nevertheless these also show considerable level variations. In many parts of Canada, clay-sized materials deposited in ephemeral post-glacial lakes form the parent material for soils."

Jan 1, 1982

By S. Yadav, T. G. Murthy, C. Saldana

"An experimental study has been carried out in order to study the deformation of porous brittle materials under plane strain indentation. Gypsum, which is well known model system for understanding the behaviour of soft rocks, is used in this study. The effect of wedge angle is investigated in this research through this series of experiments, using wedges of 3 different apical angles. High-speed, high-resolution images are captured using a CMOS camera during the experiment. The images obtained are analyzed using a Particle Image Velocimetry (PIV) algorithm in order to obtain the evolving velocity, strain-rate and strain fields.INTRODUCTIONThe problem of indentation, which is usually referred to in the context of hardness testing is ubiquitous as a material characterization technique for a large class of solids. Mechanical properties of materials such as yield stress, flow stress, fracture toughness, elastic moduli etc. can be related to the hardness of a given solid. The indentation problem involves a given material or solid (whose properties are to be determined) indented by a relatively harder material (indenter) allowing the solid to undergo plastic deformation, which is then related to the yield stress of the material. The problem of indentation and its variants see many applications ranging from mining and petroleum industry, infrastructure industry, manufacturing, and biomedical sectors. Indentation has been extensively studied in metals, with accurate measurement of deformation parameters, stresses and comparison with analytical solutions. On the other hand, understanding of indentation in other class of solids such as cellular solids, porous solids, rocks, and soft solids is still nascent. In case of rocks, a comprehensive understanding of the indentation problem is very crucial because of the obvious applications in mining, petroleum and infrastructure sectors. The inherent porosity, the brittle nature of the rocks, adds to the complexity of indentation in these porous brittle solids. Various theoretical models with degrees of simplifying assumptions have been proposed to study the indentation in rocks. The most common model used in the study of indentation in rocks is a cavity expansion model, wherein a blunt indenter indenting into a rock is approximated with the expansion of cylindrical or spherical cavity in an elastic-plastic material. Complementary studies in understanding fracture initiation and propagation due to indentation has been largely based on the studies of traditional brittle materials such as glass."

Jan 1, 2015

By Robert B. Parsons

"The mining industry is adjusting its sights to take a shot at the rising level of non-profit taxes which threaten to handicap the industry 's competitive advantage. In the case of this particular expedition, the industry evidentally has a strong ally - the country's mines ministers. It appears that an initiative is under way to assess the impact of non-profit taxes on mining in Canada as compared to other mining nations.IntroductionSeventy-five years ago, Canadians were unceremoniously introduced to something called income tax. Since then, income tax has been identified as the source of countless evils ranging from the common cold (attributed to stress) to the demise of the economy. Some years later, the provinces jumped on the bandwagon with their own income taxes, and later on with mining taxes. These profit-based taxes had some appeal to elected officials and to a segment of the populace. The onus of the taxes varied directly with the ability to pay (in theory, at least). Previously, the principal sources of government revenues had been property taxes and customs duties, which were viewed as possibly being somewhat regressive in nature.The mining industry has always had concerns about different aspects of income and mining taxes - the tax rate is too high or the depreciation rate is too low, and so on. Recently, though, the industry has turned its sights on the expanding array of taxes which are not based on profit, including payroll taxes, capital taxes, water taxes, sales taxes, fuel taxes, property taxes, environmental levies and user fees. The industry is seriously concerned that the rising level of non-pro fit-based taxes is not only hampering the industry 's ability to reinvest in Canada, but is also placing Canada at a disadvantage in terms of trying to attract new investment capital."

Jan 1, 1992

By K. B. Chaudhuri, I. D. Webb, F. E. Rachor, F. A. Sauert

"A characteristic of all methods of copper concentrate smelting is that slags with a high copper content are produced at some phase of the operation. Recirculation to the smelting unit, electric furnace reduction or flotation are at present used on an industrial scale to recover the copper from these slags. This paper describes the application of the top-blowing technique, originally developed by KHD Humboldt- Wedag AG for refining of metallic copper, for the treatment of copper-containing slags. By this method, a mixture of a reducing gas and commercial oxygen is blown onto the melt at velocities which can be supersonic from the tip of a water cooled lance. The impingement of the reaction gas mixture on the surface of the slag forms a depression in the molten phase and a deflection of the jet which brings the slag into a rotating motion. This causes high rates of heat and mass transfer. Results of pilot-plant tests for batch and continuous treatment of slags are presented, and the potential applications of top blowing for industrial-scale operation are indicated. In combination with the cyclone as a smelting unit, this process appears to be economic for smelters of very low capacity."

Jan 1, 1980

By Andrew Cormier

"The Early YearsThe Grand Lake coal fields in New Brunswick undoubtedly can claim the distinction of being the first part of North America from which coal was mined and exported. The diaries of the Governor of Massachusetts during the first half of the 17th century clearly establish this fact. There is also a reference in the Massachusetts Colonial Records which indicate that coal exports to New England were carried on as early as 1639.It has generally been believed that Cape Breton mined and exported the first coal; but no account has yet been found to show that this took place earlier than 1676. Both at Grand Lake and Cape Breton the coal was near the surface and removed by hand.When the country passed entirely into British control, Joseph Garrison, a grantee of Maugerville in 1765 moved to Jemseg. While surveying the north side of Grand Lake he discovered outcroppings of coal on the shore of the lake and further inland along the banks of streams. It was he who named Newcastle Creek in reference to Newcastle in England, which was widely known for its coal mines. Joseph Garrison died in 1783, the same year that an influx of United Empire Loyalists increased settlement in Newcastle Creek in the area now known as Minto. Many Loyalists also settled on the shores on both sides of Grand Lake.At a number of points where streams cut channels through the overlying strata, the coal seams were exposed and it was at such outcroppings that the early operations were carried on. A tunnel was driven in the seam from the foot of the bank, affording both an outlet for the coal and natural drainage from the workings. The coal was loaded into boxes and wheeled over wooden tracks to a point on the surface where it could be dumped into wagons and hauled either direct to destination or to where it could be loaded into boats and conveyed via Grand Lake, Jemseg and Saint John river to points of distribution.In the latter part of the 18th century and first years of the 19th century, farmers were undisturbed by mining the coal found on their lands. This was soon to change and resulted in many years of contention between landowners and the Legislative Assembly.New Brunswick became a separate province from Nova Scotia in 1784 and the seat of government moved from Saint John to Fredericton in 1788. The new province had its first priorities; the establishment of counties, the building of roads, and the development of its natural resources. From 1805, records of coal and land development are fairly complete. These records show the increasing interest of the Province in developing the coal fields. This interest resulted in the granting of coal leases to many friends of the government, without any regard for the wishes of the farmers who owned and had occupied the land for many years. The farmers fought back with lawsuits and other forms of dissension but with little success. By the end of the 19th century there were very few farm operators left in the area."

Jan 1, 1992

By E. M. De Souza

"A scientific testing program, sponsored by the Mining Industry Research Organization of Canada (MIROC), was undertaken on the surface and underground facilities of Inca's Crean Hill Mine to investigate the effectiveness of using dry drilling with a dust control system.The surface test work consisted of the monitoring of advance rates and bit life white a series of 165 mm holes, wet and dry, were drilled at both mine air (0.69MPa) and high pressure air (1.72MPa). The results, based on statistical evaluations of field data, indicated that penetration rates can be increased by an average of 24% when drilling dry with high air pressure and by approximately 27.5% when drilling dry with mine air as compared with wet drilling under the same conditions. Dry drilling also has the effect of reducing button wear by approximately 69% using high pressure air. The underground test work employed a dust collection system developed for use with large diameter holes (165 mm) and high pressure drilling. The testing program has indicated that an average increase in penetration rate of 35% can be achieved when dry drilling in rock (waste) and of 49% when dry drilling in ore with high air pressure. Although preliminary dust monitoring did not indicate any appreciable increase in dust concentration during dry drilling, further dust monitoring is still required.A comparative cost analysis has indicated the potential for reduction in drilling costs when dry drilling is utilized. Further testwork is to be conducted to develop a reliable dust collection system for underground production."

Jan 1, 1992

By E. I. Vargha-Butler

The determination of surface tensions and contact angles of coal particles is of great interest for coal beneficiation processes such as froth flotation and oil agglomeration and for the inclusion of coal particles into oil droplets as a means of enriching the fuel. Methods for contact-angle measurements on small irregularly shaped solid particles have not been available in the past. Therefore, we recently developed a novel technique to determine contact angles and surf ace tensions of coal particles. Two types of bituminous and one type of subbituminous coal particles have been tested. The technique used is called the freezing-front technique and it considers the behaviour of the test particles (in the range of 20-250 pm) at the solidification front of carefully selected, well-defined solidifying melts (matrix materials) such as thymol, biphenyl, naphthalene, salol and 2-phenyl phenol.The results show that the technique works well, providing quantitative and detailed information on the wettability of coal particles. The sensitivity of the method is so high that a difference in contact angle of approximately 4 degrees between the smaller and the larger particles is clearly registered.

Dec 1, 1981

By I. Govender

Positron-Emission-Particle-Tracking (PEPT) has enabled the non-invasive observation of charge and slurry transport in model mills under operational conditions. We use high quality PEPT data to infer that the charge motion can be effectively described by a non-Newtonian granular fluid. An improved theory for slurry transport, including inertial effects, is presented.

Jan 1, 2012

By A. M. Reyes

Flow field hydrodynamics of serpentine flow channels was investigated numerically using computational fluid dynamics (CFD). The velocity profile simulated by the CFD model was evaluated with respect to experimental results from the literature. Rectangular and tapered flow channels were compared with respect to mixing and water management capabilities, and pressure drop. The CFD model was further developed to account for electrochemical reaction on the cathode side to determine which channel configuration was most effective in reactant conversion. The velocity profile differences between the channels were found to impact reactant conversion, as the rectangular channel had the highest conversion. With respect to water management, although the tapered channel was found to have a higher overall pressure drop, the rectangular channel was found to have higher shear and pressure forces acting on simulated liquid water droplets in the channel.

Jan 1, 2005

By R. G. L. McCready, R. O. van Everdingen, M. Kalin, R. van Everdingen

"This paper is based on data generated between October, 1986 and October, 1989, during the implementation of an Ecological Engineering close-out for a zinc mine in Northern Ontario, where 690000 tonnes of tailings contain 41.1% pyrite and 4.1% pyrrhotite. The objective was to determine rates of sulphide oxidation and iron precipitation in the tailings. Those rates are relevant for the assessment of the long-term effectiveness of biological systems employed in the removal of heavy metals from contaminated drainage issuing from tailings.Data were collected on the topography and stratigraphy of the tailings basin, subsurface temperatures and groundwater levels, and chemical analyses were made of water samples collected from a number of piezometers. The thickness of unsaturated tailings varied widely between individual piezometer locations; annual maxima ranged from 0.67 m to 3.55 m, and annual minima from 0 to 2.68 m. Sulphate concentrations ranged from 36 mg/L to 20180 mg/L; iron concentrations from 0.36 mg/L to 9938 mg/L; and zinc concentrations from 0.33 mg/L to 1123 mg/L.The geochemistry of the piezometer samples suggests that some of the initial Fe content, resulting from metal sulphide oxidation, is subsequently precipitated in the tailings pile and, possibly, in the underlying unconsolidated sediments, probably in the form of iron-hydroxide and Na-jarosite. Other metals such as Zn may be co-precipitated with Fe. The discharge of a portion of these metals to the environment would be delayed by this process. Some of the initial sulphate may also be lost from solution, probably by precipitation of gypsum; approximate saturation degrees for gypsum ranged from -3.27 to +0.47. The precipitated minerals will somewhat decrease the porosity and permeability of the tailings.Sulphide-oxidation rates, calculated using the analytical results and the estimated amount of annual recharge at the tailings site, average 0.0057 mol/kg/yr. Calculated iron-precipitation rates average 0.000386 mol/kg/yr. It is concluded that the characteristics of seepage from mining wastes may change with time, reflecting the solubilization of precipitated secondary minerals."

Jan 1, 1992

By R. A. Payant, J. A. Finch

Under certain conditions of air and moisture, sulphide materials can spontaneously heat, or selfheat. The reaction mechanisms of self-heating are not well understood. Most previous work has involved pyrrhotite because it is the most reactive sulphide. The current work investigates the self-heating behavior of sulphide mixtures composed of sulphides other than pyrrhotite. The four studied sulphides were pyrite, chalcopyrite, sphalerite and galena. The rest-potential was measured for each. Binary mixtures formed as a 1 : 1 weight ratio were pyrite-galena, chalcopyrite-galena, pyrite-chalcopyrite and chalcopyrite-pyrite. The four sulphides and the binary mixtures were subjected to standard self-heating tests. The four individual sulphides did not self-heat. However, mixtures of pyrite-galena and chalcopyrite-galena with rest-potential difference (?E) >0.3 volts did self-heat while the mixtures of pyrite-chalcopyrite and chalcopyritesphalerite with rest-potential differences (?E) = 0.1 volts did not self-heat. The results demonstrate that when certain non self-heating sulphides are combined they can self-heat. A possible explanation based on galvanic interaction and formation of hydrogen sulphide as an intermediate product is discussed.

Jan 1, 2009