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By G. Wang, L. R. Moore, Y. Xiong, A. Gorken

"Mining is a very water intensive industry. As such, the industry has become dependent on applying alternate sources in efforts to minimize the impact on the locally available fresh water. Sources such as recycled water, sea water, and even acid mine drainage have been applied at some limited applications, while other mines may not even have the option of fresh water available in their region. However, the different sources of water will have varying concentrations and types of soluble salts and suspended solids, which can lead to dramatic differences in mineral processing when comparing these types of waters. Water quality is known to affect bubble generation and strength, mineral surface charge, and even reagent coordination properties. This paper focuses on the exploration of how water quality and soluble salts affect the flotation of iron and titanium containing minerals from feldspar, and the design of flotation collectors for optimal performance in this water.INTRODUCTIONFeldspar is defined as a tectosilicate mineral with the generic structure of MAlxSixO8, where M represents the cation (Celik, 2001). Feldspar is most often found naturally occurring with quartz, iron containing minerals (i.e mica), and titanium containing minerals (i.e. rutile). The alumina component of feldspar is of interest to glass making, while the alkali metal component is of interest to ceramics (Vidyadhar, 2002). In glass making, the alumina is known to improve product hardness, durability, and resistance to chemical corrosion. In ceramics, the alkalis act as a flux; a flux lowers the melting temperature of the mineral mixture, and assists in connecting the other components present in ceramics. Quartz is stated as having a negative effect on the melting point of the feldspar. Although quartz is typically not removed during the feldspar applications in the glass industry, it needs to be reduced for the ceramics industry. Iron and titanium based minerals are known to have negative effects on color and quality of the products in both glass and ceramics. Thus, these “contaminants” must be reduced to a certain product specification via feldspar beneficiation (Table 1)."

Jan 1, 2016

By Brian C. Maynard

"Blast design is becoming more and more important as industrial limitations change in regard to economical and physical restraints. Certainly there are ways to alter the nature of the blast by using different explosives, various hole sizes and modifying the timing and charging details. However, it is not possible to alter the fabric of the rock mass. Therefore, it is necessary to learn more about the rock mass and its role in the blast design, and the resulting fragmentation. The major determinant in the degree of fragmentation, or lack of it, is proposed to be the inherent fragmentation of the in situ rock mass. A practical method of quantifying the discontinuities existing in the rock mass is presented and discussed. Likewise, the effects of inherent fragmentation on the resulting muckpile are reviewed. Finally, a fragmentation model combining the calculated inherent fragmentation and the Kuzram model is shown using a sample blast.IntroductionIn blasting, discontinuity characteristics (Fig. 1) control the method by which the rock mass will behave. Research carried out by Piteau (1970) showed a number of characteristics important in engineering design and, as proposed, in blasting processess. These included:• the nature of their occurrence (i.e. sets or isolated);• orientation and position in space;• continuity; and• intensity"

Jan 1, 1990

By I. S. Thompson

A program of geochemical till prospecting, carried out by Derry, Michener & Booth in 1974, was instrumental in t~ e discovery of a copper deposit in Currie Township, Ontario, beneath thick lacustrine deposits of the Abitibi Clay Belt. The prospecting system involved the continuous collection of glacial sands and gravels beneath the clays, using a track-mounted, dual-tube rotary drill, and the separation and geochemical analysis of the heavy mineral content for Cu, Zn, Pb, Ag and Au. In one of 22 holes drilled down-ice from nine Canadian Nickel airborne EM conductors, fragments of chalcopyrite-bearing graphitic argillite, assaying 12% Cu, were recovered from a 14-foot gravel section beneath 83 feet of clay. Ultimately, mineralization was identified in 10 of 11 additional holes drilled up to 3,000 feet down-ice from the Currie deposit. The glacial fan, when compared to the 1,200- by 165-ft area of the subcropping mineralization, is at least 20 times the area of the deposit and is the result of glacio-fluvial reworking of the mineralized ground moraine. The Currie deposit is contained within a Keewatin succession of graphitic argillite, dacite tuff and graywacke, which is intruded by dacite and feldspar porphyry sills and dykes and truncated by a Keweenawan diabase dyke. Grade and thickness of the mineralization, which lies chiefly within the argillite, is related to felsic intrusives and hydrothermal alteration, and to fold hinges.

Jan 1, 1979

By G. J. Kipouros, P. W. Kingston, W. F. Caley

"Current practice in advanced materials processing has involved the dispersion of a second-phase, commonly SiC, glass, or other non-metallic fibres/whiskers/particulates to enhance physical characteristics of the matrix. These matrices may be either ceramic or metallic but in either case it is important that the physical and chemical properties of each phase be compatible. The dispersed, finely divided second phase is often both expensive and foreign-produced and may exhibit chemical instability at elevated temperatures. Thus, it would appear that certain naturally-occurring industrial mineral fibres/whiskers/particulates might offer an attractive and low-cost alternative. Suitable candidates, such as wollastonite and sillimanite, are available in Canada and may be milled to produce particles whose shape is appropriate for this application. It is suggested that wollastonite, in particular, may be a useful modifying agent in metal matrix composites utilizing AI, Al-Si, Zn-Al or other light metals and alloys. In addition, the possible use of these minerals in ceramic matrix materials is also addressed, with reference to a preliminary thermodynamic analysis of the systems involved.IntroductionBackgroundA composite material may be thought of as consisting of a matrix component, the properties of which are improved by the addition of a second component or dispersed phase which forms a distinct three-dimensional interface with the matrix. This matrix is commonly either metallic or ceramic, which leads to the two most popular types of composites: metal-matrix composites (MMC); and ceramic-matrix composites (CMC).Such materials are by no means new. Early composites include fiberglass, mixtures of plaster and horsehair in wall plastering, as well as use of natural materials such as bamboo in fishing rods. Some of the newer applications include high strength, low-weight bicycle rims, as well as the more familiar role in aircraft and automobile engine components."

Jan 1, 1993

By Juergen Antrekowitsch, Stefan Steinlechner

"Waelz oxide from steel mill dust recycling is usually sold to the primary zinc industry, where it is first charged to the roasters to eliminate the remaining fluorides and chlorides. This limits the overall amount of secondary materials which can be used because of different operating problems in the roasters. Another option, in the case where the halides are low, would be direct leaching with low or medium concentrated sulphuric acid. Unfortunately, because of the carryover of some steel mill dust, iron is also present in the Waelz oxide, reaching contents up to 5 wt.%. Since the objective is to treat the solution more or less directly by electrowinning, with only a few simple preliminary purification steps, iron in the solution is a very important factor. Various trials have been done to investigate the dissolution behavior of the iron contained in the Waelz oxide. Although the zinc extraction should reach a maximum, all other elements, especially iron, should be low. This paper describes the results of our research in this area and offers possible options for Waelz oxide utilization. There is also a focus on how other elements, present in the material, influence the dissolution behaviour of zinc and iron, and whether a loss of zinc is unavoidable, if low iron dissolution is required.INTRODUCTION One of the most important secondary zinc resources is the zinc oxide originating from steel mill dust recycling. For the treatment of high zinc containing steel mill dusts, the Waelz kiln process is the so called “best available technology” and it dominates the industry, with roughly a 90% market share. The product Waelz oxide contains mostly zinc oxide, but it also contains lead compounds and halides due to evaporation with the zinc. In addition, it contains iron and some slag compounds due to mechanical carry-over. The presence of halides limits the use of the material as an alternative concentrate for primary zinc electrowinning. Such halides can be reduced to a certain extent by washing and/or solvent extraction (see following chapter). Although lead is not troublesome and theoretically represents a second recoverable valuable metal, iron is unwanted and causes additional problems during leaching. Even though Waelz oxide is generally a highly welcome input material in primary zinc metallurgy, due to its high zinc content, it still contains halides, and in the majority of cases, the oxide must first be treated in a roasting process. Different circumstances, like accretion formation because of the lead and halogen compounds as well as unwanted cooling effects in the roaster, limit the amount of Waelz oxide which can be substituted for the primary concentrate. Another, even more limiting factor, is the allowable concentrations of chlorides and fluorides in zinc electrowinning, the last step in the primary zinc processing route (Ruetten, 2011)."

Jan 1, 2016

By M. Sukhram

This paper presents a technique to determine the direction of velocity in liquid aluminum (Al) by measuring the temperature distribution within a cylindrical rod while it is inserted into the flow. The heating pattern of the rod is a result of the interaction of the thermal fields of the rod with the liquid Al. This interaction freezes aluminum onto the cylinder in a characteristic pattern and as a result the temperature response within the rod also follows a distinctive heating pattern. Monitoring the temperature within the cylindrical rod as a function of spatial and temporal coordinates, the direction of velocity can be inferred. Experimental research work involving liquid Al was conducted at the University of Toronto using the Revolving Liquid Metal Tank (RLMT). The RLMT is a resistance furnace which can hold up to 50kg of liquid Al. In this RLMT tangential velocities up to 0.35m1s can be generated. Experimental data for different superheat and magnitude of velocity demonstrate that the sensor records different heating patterns under different fluid flow conditions. Using the transient temperature information, the direction of velocity of the molten Al flow field can be detected.

Jan 1, 2011

By G. A. Gillett, C. F. Bonney

"The Davy McKee combined mixer-settler (CMS), is a liquid-liquid contactor, which has been commercially applied to the recovery of uranium from dilute sulphuric acid-bearing leach liquors. CMS differs from most other solvent extraction systems in that the mixing and separation of the phases is carried out in the same vessel.IntroductionTypical solvent extraction plants for the recovery of uranium operate at organic to aqueous feed flow ratios of 1 : 2 to 1 : 30. Because it is beneficial to mix the organic and aqueous phases at an organic/aqueous (O / A) ratio of between I : 2 and 2 : I there is incompatibility between the over-all and operating O /A ratios.Conventional mixer-settler designs require an external recycle of the minority flow which results in the possibility of over-mixing, increased settling requirements and entrainment losses. Other workers have approached this problem in terms o f enhanced sett ling and this has been partly successful.Davy McKee's approach involved a radical rethink of the principles of liquid-liquid contact and separation.Description of CMSThe CMS has the important advance that the required mixing O/A ratio can be achieved without external recycle and is not affected by the O /A ratio of the feeds. Three zones co-exist within the CMS unit-a central mixing zone and upper and lower separation zones. A pump impeller on a draught tube is installed within the mixing zone and baffles are installed above and below the mixing zone. Conventional mixer- settlers have several undesirable features which ca n largely be eliminated using the CMS system:"

Jan 1, 1983

By Samantha A. Beeson, Colin Poole

"A selective flocculation-floe flotation technique is already in use in the Canadian potash industry for the removal of water-insoluble slimes, but the process is currently limited in its application and reagent consumption is high. The work described in this paper details investigations into the separation of sylvite and halite from water-insoluble slimes by selective flocculation utilising other commercially available polymers.Preliminary flocculation performance tests were undertaken on pure sylvite, halite and water-insoluble minerals to establish the importance of a number of experimental parameters. The data from these single mineral tests was then used to establish optimum parameters for the separation of sylvite and halite from a synthetic mixture similar in composition to a typical potash ore. Under optimum conditions, separation was achieved with high recoveries using dispersant and flocculant dosages significantly lower than those currently used in plant practice.IntroductionAlthough solar evaporation and solution mining are used in some operations, most potash is extracted by conventional underground techniques and is then processed by froth flotation, in order to separate the valuable sylvite (KCI) from halite (NaCl) and water-insoluble gangue minerals. Flotation is usually preceded by a desliming stage to remove water-insoluble fines, but this also results in high potash losses and affects process brine requirements. To overcome these problems, one plant operated by Cominco in Saskatchewan uses a selective flocculation -floe flotation process (Banks, 1979/1980), in which a polyacrylamide flocculant is added to produce floes of water-insoluble material with minimal incorporation of halides. A collector is then added to render the floes hydrophobic and suitable for removal by froth flotation.A number of workers have also investigated the use of selective flocculation in potash processing, but these too have been concerned with developments in the removal of water-insoluble slimes (Williams, 1960; Brogiotti et al, 1974; Chan et al, 1986; Thompson et al, 1979; etc.). This paper provides results of novel investigations into the selective flocculation of sylvite and halite from water-insoluble minerals and discusses the possible mechanisms involved."

Jan 1, 1995

By Wei Zhang, Jinhong Zhang

"The adsorption of ethyl xanthate on copper sulfides, i.e., chalcopyrite, chalcocite and bornite, has been studied in situ in aqueous solutions by applying an atomic force microscopy (AFM). AFM images show that xanthate, such as potassium ethyl xanthate (KEX), adsorbs strongly on chalcocite and bornite mainly in the form of insoluble metal xanthate, which binds strongly with the mineral surface without being removed by flushing with ethanol alcohol. This adsorption mechanism is totally different from the one obtained with chalcopyrite/xanthate system, during which oily dixanthogen is the main adsorption product on chalcopyrite surface. The findings obtained from the present AFM study suggest that an AFM image analysis is a powerful tool for the study of the collector’s adsorption on mineral surface and as well the development of novel collector for copper sulfide flotation.INTRODUCTIONIn mining industry, copper sulfide minerals, i.e., chalcopyrite, chalcocite and bornite, are usually separated selectively from non-valuable gangue by froth flotation, which treats the highest throughput and produces the maximum economic outcome of any surface chemistry process. In flotation, collectors are added into the pulp (mixture of water and fine-grained minerals) to selectively adsorb onto the target mineral and render its surface with high hydrophobicity, which is generally beneficial for a strong mineralbubble attachment and thus a high flotation recovery.The adsorption of collector on mineral surface, therefore, is vital for a successful flotation process and it has been studied by applying various surface analysis techniques, such as IR (Infrared Spectroscopy), CV (Cyclic Voltammetry) and XPS (X-ray Photoelectron Spectroscopy). (Poling, 1963; Allison et al., 1972; Mielczarski et al., 1984; Leppinen et al., 1989; Kartio et al., 1996) These studies have revealed a lot of information, such as the reaction, product and mechanism, of the adsorption of chemicals on mineral surface. It is also of great interest to directly get the image of adsorbed collectors on mineral surface changing with pulp chemistry, such as pH, redox potential, ionic strength and chemical’s dosage."

Jan 1, 2016

By Kazuteru Tozawa, Robert G. Robins

"The stability of calcium arsenate is discussed in relation to the possible misuse of lime in the treatment of gold processing waste waters. Stability diagrams have been derived and experimental results cited to show that calcium arsenate has a higher solubility in neutral to alkaline solution than has previously been recognized and this solubility is further enhanced by the presence of carbon dioxide, bicarbonate or carbonate.IntroductionThe removal of arsenic from gold mine waste waters has been of interest for more than thirty years, but with the recent emphasis on clean water standards there has been renewed activity in relation to that problem. The processing of gold-bearing sulphides which contain arsenopyrite and other complex arsenic sulphides is well established. Initial roasting to oxidize the sulphides leaves the arsenic in the form of both arsenic and arsenic, in which forms it is soluble in the subsequent leaching stage. Further oxidation of the leach liquors is required before the well-established procedure of precipitating calcium arsenate with lime, which is carried out despite an immense lack of knowledge of the calcium-arsenic-water system.The solubility product and free energy of formation for Ca3(AsO4)2, which are to be found in recent and reliable sources of data, originate from the work of Chukhlansev, whose experimental determination of the concentration of calcium from the solubility of calcium arsenate in solutions of various pH yields the results plotted in Figure 1. This is the work which has resulted in a wide acceptance of the ""insolubility"" of calcium arsenate and the use of lime to stabilize arsenic in that form.Laguitton attempted to further elucidate the chemistry of the lime addition method for treating arsenical waste waters from gold processing operations. The low solubility product for Ca3(AsO4)2 was the basis for his examination of likely chemical equilibria in the system. Laguitton and other workers have not considered atmospheric carbon dioxide as an important component in this system."

Jan 1, 1982

By M. H. Kotze, V. Yahorava

A gold-selective ion exchange resin, containing tributylamine groups, was developed by Mintek for the recovery of gold from cyanide leach solutions. The Dow Chemical Company and, more recently, Purolite commercialized the production of this gold selective resin for use in the gold mining industry, and it is marketed as Dow XZ-91419.00 and Purolite A194 respectively. A novel application of this resin is the selective recovery and separation of AuCl4 - f rom p latinum group metals (PGMs) in chloride and nitrate solutions. The current paper describes potential benefits of this type of resin for selective recovery and upgrading of gold from low grade chloride or nitrate waste streams, and the possibility of gold separation from PGMs during their refining in chloride media.

Jan 1, 2014

By D. F. Machuca-Mory

The new algorithm for high-order simulation of ore deposit grades termed HOSIM is based on the concept of spatial cumulants. The algorithm is tested using data from Apensu, a structurally controlled gold deposit in Ghana. The required high-order spatial structures are obtained from a training image or analogue of the deposit. Using the available drillhole data and training image, HOSIM realizations are able to model well the grades and geometry of the large and well sampled mineralized structures. However, under-sampled small structures remain difficult to model. HOSIM offers a promising alternative for the spatial simulation of complex non-Gaussian orebody attributes of interest.

Jan 1, 2011

By L. Mercier, R. Narendrula, F. Desmarais, L. Amaratunga, A. Aledresse

Thiosulfate is recognized as a promising alternative lixiviant to cyanide for the extraction of gold from ore bodies. Gold thiosulfate ([Au(S2O3)2]2), however, is not well-adsorbed by activated charcoal, making industrial scale use of thiosulfate for gold leaching impractical at present. Because of their high specific surface areas (500-1000 m2g-1) and uniform open-framework nanoporosity (pore channel diameters in the range 3-10 nm), functionalized mesoporous silicas are widely recognized as highly effective materials for the selective, rapid and high capacity uptake of mercury, gold and platinum group ions. In the present work, the efficient and rapid adsorption of gold thiosulfate by thiol-functionalized mesoporous silica (hereafter designated MP-HMS) is demonstrated, whereby the thiol groups in the materials bind with the gold complexes by ligand displacement. The adsorbed gold could be leached out using cyanide, regenerating the adsorbent for further uptake cycles. Functionalized mesoporous silica is thus a promising candidate for the preconcentration of gold from thiosulfate leachate solutions.

Jan 1, 2011

By I. Pérez-Rey, J. Arzúa, L. R. Alejano

"The decrease in strength with increasing rock specimen size is usually associated to the increase in the number of defects inside the specimens at small scale (centimeters) but also to the role of the rock mass structure at the rock mass scale (meters to decimeters).This matter of concern was particularly focused when determining the size of pillars in underground mines. Some formulae regarding strength of pillars have been proposed but they usually consider only the size and shape of the pillars and the strength of the intact rock. The structure tends to be overlooked or hidden behind the scale, but it is probably very relevant. For standard tunnel design, the approach by Hoek and Brown (1997), taking the structure into account in terms of the GSI, is commonly used. However, this approach does not specifically consider the size of the tunnel. Thus, a size larger than the so-called representative elementary volume is implicitly contemplated.The authors have recently performed a lab study on the effect of the structure in the strength, deformability and post-failure characteristics of granite at lab scale (NX size) extended here. This experimental program included intact and artificially jointed rock specimens. Obtained results permit to observe the changes in strength, deformability and post-failure behavior of this “small scale rock masses”, associating the role of the structure to the observed complete stress-strain response of the specimen, which can improve our understanding of the actual complete mechanical response of rock masses."

Jan 1, 2015

By Stanley Davidson

Introduction The ore deposit mined by Falconbridge Nickel Mines, Limited, is one of the numerous nickel-copper sulphide bodies marginal to the large oyster-shaped mass of differentiated norite in the Sudbury district, famous as the world's most important nickel producing field. The unique character of the ore deposits of the district has resulted in its intensive geological study over a period of more than fifty years. The results of these studies have given rise to a voluminous geological literature and to a great deal of controversy as to the genesis of the ores. This description of the structural geology at the Falconbridge mine is presented in the hope that it may form a small part of the chain of evidence leading to a reasonably satisfactory explanation of the ore genesis. The mine, named after Falconbridge township in which the deposit occurs, lies along the southeast margin of the norite mass which, however, is here concealed beneath a deep mantle of glacial sands and gravels averaging over 100 feet in thickness. As a consequence, the deposit was not discovered by the early prospectors, and it was not until 1916-17 that E. J. Longyear, of Minneapolis, located the ore by drilling. The discovery was foreshadowed in 1899 by the work of Thomas A. Edison, who found indications of the deposit by what is believed to have been a combination of magnetic and electrical geophysical surveys. He sank a prospect shaft over what has to date proven to be the largest and richest ore section in the mine. A wet quicksand layer at the rock surface proved impenetrable, however, and the "Edison' shaft never reached bed-rock.

Jan 1, 1946

By Bian Xue, Wu Wenyuan

High quality, mono-dispersed, hollow CeO2 microspheres with high surface area were produced by a spray pyrolysis method at 700oC. CeCl3 was used as the raw material of the process rather than Ce(NO3)3 because the latter is relatively difficult to obtain in industrial quantities. X-ray diffraction and electron microscopy results confirm the high quality synthesis of hollow CeO2 microspheres with narrow size distribution, good mono-disperse, and good reproducibility. The process of the formation of mono-dispersive CeO2 microspheres was investigated by chemical dynamics and a possible mechanism is proposed. This simple method for synthesis of CeO2 microspheres is easily scaled up to fabricate other metal oxide nanostructured materials at industrial scale.

Jan 1, 2014

By R. G. Bradburn

"Brenda Mines Limited is a low grade open pit mining and milling operation located near Peachland, British Columbia. The mill was brought into production in late 1969 at a rated capacity of 24,000 tons per day. Tt currently treats an average of 30,000 tons per day of an ore that has an average grade of 0.130% copper and 0.030% molybdenum.Description of Crushing and Grinding CircuitsRun of mine ore is delivered to a primary gyratory crusher. The minus seven inch product is separated into plus and minus one inch fractions on two parallel vibrating screens. The fine product is conveyed directly to the mill fine ore bins, while the coarse fraction is sent to a 45,000 ton stockpile.Material from the stockpile is fed to two standard cone crushers which operate in an open circuit with five secondary vibrating screens. The minus five-eighth inch product from these screens is conveyed to the mill fine ore bins while the coarse fraction is fed to four shorthead cone crushers. These crushers operate in closed circuit with the screens."

Jan 1, 1981

By Renato Macciotta

The argillaceous formation known as the Opalinus Clay is host to the Mont Terri Underground Research Laboratory. The URL was developed to investigate the hydrogeological, geochemical and geotechnical properties of the formation. Underground excavations at the site are characterized by non-elastic and time-dependent deformations. Excavations trending perpendicular to the strike of the bedding presented relatively minor deformations, however, tunnels parallel to the strike of the bedding showed much larger non-elastic deformations. This paper presents an analysis of the measured response of a tunnel trending parallel to the strike of the bedding in Opalinus Clay. The measured convergence is compared to tunnel experience in weak rocks to assess the tunnel stability.

Jun 1, 2012

By Y. M. Shneerson, E. E. Zhmarin, E. M. Vigdorchik

One of the Gipronickel Institute activities is research and development of customized leaching technologies. The work is performed in several steps. Leaching kinetics are studied on a lab-scale according to a special procedure. Experimental data are processed using mathematical models of batch and continuous processes. Reliability of kinetic data and preliminary calculations is verified experimentally in laboratory reactors of various capacities. If necessary, certain parameters of the mathematical model are adjusted after pilot plant tests in continuous mode ( 4-reactor train, each with 25 L capacity). The specified kinetic characteristics along with the mathematical model are used for further development of industrial leaching technology.

Jan 1, 2005

By Ludwig Strah

"The paper outlines the history of rubber mill liners beginning with the awarding of the first North American patent rights in 1923. It includes the early-day applications and installations of the 1920s and 1930s through to their present-day application. Over-all rubber mill liner design is discussed in relation to present day installations employing rubber mill liners in various grinding applications. A brief overview is given of a manufacturer's procedures to produce rubber mill liners.IntroductionIn early 1910, it became apparent that the productive life of the silver mines in Cobalt, Ontario, could be substantially prolonged by mining lower-grade ores.The mining of lower-grade ores required the establishment of treatment facilities which initially employed jaw crushers, stamp mills, jigs and concentrating tables. The recovery of silver in other than a coarse metallic form required the additional step which was introduced at that time: the cyanidation of silver concentrates from the tables. The resultant requirement for increased and improved recovery led to the introduction of grinding mills, i.e. tube mills.Shortly after the introduction of the tube mills to the Nipissing Mine's mill in 1914, the idea of using rubber as a mill liner material was spawned. However, no action was taken due to the advent of World War I. It is interesting to note that the idea of rubber mill liners emanated from having used pieces of solid rubber tire as an emergency repair on a set of liners when a liner had broken and no immediately available spare was on site.The credit for this ingenuity and subsequent application for a patent on rubber mill liners falls to James John Denny, the mill superintendent, and Rolla Barnum Watson, the general manager of Coniagas Mines Limited. The patent application was formally made on December 3, 1921. The U.S. Patent Office issued Patent No. 1,470,597 on October 16, 1923."

Jan 1, 1982